DOI QR코드

DOI QR Code

Effect of nano size $Y_2O_3$ addition on the superconducting properties and microstructure of YBCO thin film prepared by TFA-MOD method.

TFA-MOD 방법에 의한 YBCO 박막제조에서 nano size $Y_2O_3$ 첨가효과

  • 박진아 (한국산업기술대 에너지대학원) ;
  • 김병주 (한국산업기술대 에너지대학원) ;
  • 홍계원 (한국산업기술대 에너지대학원) ;
  • 이희균 (한국산업기술대 신소재공학과) ;
  • 유재무 (한국기계연구원 신기능재료연구본부) ;
  • 김영국 (한국기계연구원 신기능재료연구본부)
  • Published : 2006.09.01

Abstract

The effect of the addition of the nano size $Y_2O_3$ powder on the microstructurte and superconducting properties of YBCO thin film deposited on LAO single crystalline substrate by TFA-MOD method was studied. Nano size $Y_2O_3$ powder was added to the stoichiometric precursor solution with a cation ratio of Y : Ba . Cu = 1 : 2 : 3 prepared using TFA as chelating agent. Precursor solutions with and without $Y_2O_3$ addition were coated on $LaAlO_3(100)$ single crystalline substrates by dip coating method. Calcination and conversion heat treatments were performed in controlled atmosphere containing moisture Current carrying capacity(Jc) of YBCO film was enhanced about 50% by $Y_2O_3$ doping and it is thought to be due to the better connectivity of YBCO grains and/or the flux pinning by the $Y_2O_3$ particles embedded in YBCO grains.

Keywords

References

  1. Yuh Shiohara and Yuji Aoki, 'Activity of R&D for coated conductors in Japan', Physica C 426-431, Part 1, pp 1-7, 2005 https://doi.org/10.1016/j.physc.2005.02.138
  2. A. Gupta, R. Jagannathan, E. I. Cooper, E. A. Giess, J. I. Landman, and B. W. Hussey, 'Superconducting oxide films with high transition temperature prepared from metal trifluoroacetate precursors'. Appl. Phys. Lett., 52, 2077-2079, 1988 https://doi.org/10.1063/1.99752
  3. P. C. Mclntyre, M. J. Cima, and M. F. Ng, 'Metalorganic deposition of high-Jc Ba YCu O thin films from trifluoroacetate precursors onto (100) SrTiO ,' J. Appl. Phys., vol. 68, pp. 4183-4187, 1990 https://doi.org/10.1063/1.346233
  4. T. Araki, T. Yuasa, H. Kurosaki, Y. Yamada, I. Hirabayashi, T. Kato, T. Hirayama, Y. Iijima, and T. Saito, 'High-Jc YBa Cu O films on metal tapes by the metalorganic deposition method using trifluoroacetates.' Supercond. Sci. Technol., vol. 15, pp. L1 - L3, 2002 https://doi.org/10.1088/0953-2048/15/1/301
  5. Dr. Gregory J. Yurek, 'HTS INDUSTRY STATUS AND OUTLOOK', AMSC 2005 DOE peer revierw August 2, 2005
  6. Hiroshi Fuji, Ryo Teranishi, Yutaka Kito, Junko Matsuda, Koichi Nakaoka, Teruo Izumi, Yuh Shiohara, Yutaka Yamada, Akimasa Yaiima and Takashi Saitoh, 'Progress on TFA-MOD coated conductor development', Physica C, 426-431, Part 2, pp 938-944, 2005 https://doi.org/10.1016/j.physc.2005.02.153
  7. Yuji Aoki, Ryo Teranishi, Yutaka Kitoh, Hiroshi Fuji, Koichi Nakaoka, Toshi Koyama, Junko S. Matuda, Teruo Izumi, Yuh Shiohara, Yoshitaka Tokunaga 'Fabrication of 10-m class Y-123 coated conductors using continuous reel-to-reel process by TFA-MOD method', Physica C 426-431, Part 2, pp 945-948, 2005 https://doi.org/10.1016/j.physc.2005.03.076
  8. Geo-Myung Shin, Sung-Hun Wee, Hee-Gyoun Lee, Gye-Won Hong, Kyu-Jeong Song, Chan Park, Seung-Hyun Moon, and Sang-Im Yoo, Fabrication of High-Jc YBCO Films by the TFA-MOD Process Using YBCO Powder as Precursor', IEEE Trans. Appl. Supercond. vol. 15(2) 2649-2651. 2005 https://doi.org/10.1109/TASC.2005.847758
  9. S. H. Wee, G. M. Shin, K. J. Song, G.W. Hong, C. Park, S. H. Moon, and S. I. Yoo, 'Fabrication of YBCO thin film on SrTi03 (100) substrate by modified TFA-MOD method,' J. Kor. Ins. Appl. Supercond. & Cryo. vol. 6, pp. 12-17, 2004
  10. Seung-Yi Lee, Seul-A Song, Byeong-Joo Kim, Jin-A Park, Ho-Jin Kim, Hee-Gyoun Lee, Gye-Won Hong, Seog Heon Jang, Jinho Joo, Jai-Moo Yoo, Halder Pradeep,, 'Effects of Excess Yttrium Addition on YBCO Thin Films Prepared by TFA-MOD Process.', Progress in Supercond. vol. 7(1) 87-91, 2005
  11. A. Kaneko, J. Matsuda, R. Teranishi, K. Nakaoka, Y. Aoki, H. Fuji, K. Murata, T. Goto, A. Yoshinaka, A. Yajima, T. Izumi and Y. Shiohara, 'Fabrication of Y1-xRExBa2Cu307-y film by advanced TFA-MOD process', Physica C, 426-431. 949-953, 2005 https://doi.org/10.1016/j.physc.2005.03.083
  12. U. Schoop, M. W. Rupich, C. Thieme, D. T. Verebelyi, W. Zhang, X. Li, T. Kodenkandath, N. Nguyen, E. Siegal, L. Civale, T. Holesinger, B. Maiorov, A. Goyal, and M. Paranthaman, 'Second generation HTS wire based on RABiTS substrates and MOD YBCO', IEEE Trans. Appl. Supercond. vol. 15(2) 2611-2616, 2005 https://doi.org/10.1109/TASC.2005.847681
  13. Winnie Wong-Ng et al, 'Phase Equilibrium Relations of High Tc Superconductors', NIST, Presented at the 2003 Annual Peer Review U.S. Department of Energy, Superconductivity Program for Electric Systems, July 23, 2003 Washington, D.C