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The Present and the Prospects for Batteries (전지기술의 국내외 연구동향)

  • 이주성
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 1999.10a
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    • pp.1-2
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    • 1999
  • 시간과 공간의 구애를 받지 않는 양질의 음성, 화상, 문자정보의 교환을 위한 노력으로 디지털 휴대폰과 휴대용 컴퓨터가 등장하면서 음성과 문자정보의 교환분야에 커다란 진보를 이룩하였다. 그러나 현재는 휴대폰이 음성정보에 문자정보교환이 추가된 상황이기 때문에, 아직도 관련 정보교환기술 및 기기개발이 진행되고 있다. 앞으로 휴대폰과 휴대용 컴퓨터의 기능을 통합하고 화상정보까지 결합된 휴대용 정보기기를 위해서는 전자회로의 집적화 및 통신속도 증대가 필수적이다. 또한 이들 휴대용 정보기기를 구동시키기 위한 전력도 증가될 것으로 예측되기 때문에, 현재 전원으로 사용되는 2차전지보다 에너지 밀도가 더욱 증패된 전지가 요구될 것으로 예상된다. 그리고 내연기관의 배기에 의해 발생되는 환정오염문제를 해결하기 위한 방법중의 일환으로 전기자동차 개발이 진행되고 있으며, 이들 전기자동차에 2차전지를 장착하기 위해서 경제성이 있고, 고속충전이 가능하고, 안전성이 높은 고에너지 밀도의 2차 전지 개발이 요구되고 있다. 현재 2차전지는 음극재료나 양극재료에 따라 낚축전지, 니켈/카드륨(Ni/Cd) 전지, 니켈/수소(Ni/MH) 전지, 라륨 2 차전지등이 있으며, 전극재료의 고유특성에 의해 전위와 애너지 밀도가 결정된다. 특히 리튬 2차전지는 리튬의 낮은 산화환원전위와 분자량으로 인해 에너지 밀도가 높기 때문에 앞에서 언급한 휴대용 전자기기의 구동전원으로 많이 사용되고 있다. 리튬 2차전지는 음극 재료가 금속리튬인 경우는 리튬금속으로, 탄소재료인 경우는 리튬이온이라 하며, 한편으로 전해질이 고체 고분자이거나 혹은 역체 유기용매와 리튬염을 고분자와 혼성시킨 겔(gel)인 경우는 고분자로, 전해짙이 리튬염이 전리되어 있는 유동성 액체일 경우는 고분자를 생략하여 구분하고 있다. 즉 리튬금속 2 차전지(LB), 리튬이온 2 차전지(LIB), 리튬금속 고분자 2차전지(LPB), 리튬 이온 고분자 2차전지(LIPB)로 크게 구분된다. 금속리듐을 음극으로 사용하고 전해질로는 리튬염이 전리되어 있는 액체유기용매 를 사용한 리튬금속 2차전지는, 금속리튬전극이 충방전 과정을 반복하면서, 전리된 리튬이 균일하게 산화환원되지 못하고 표변에서 양극방향으로 성장하는 수지상 (dendrite) 현상으로 인해 안전성 확보에 문게가 있었다. 리튬과 알루미늄 합금형태로 음극에 사용한 동전형 전지는 상용화 되었지만, 이러한 단점을 개선하기 위해 리튬이온이 금속으로 석활되는 환원반응전위보다 높은 전위에서 전극재료가 충전되면서 리튬이온이 저장되고, 방전되면서 배출되는 탄소를 음극재료로, 그리고 리튬이온이 충방 전시 가역적으로 삼입 탈리되는 층상의 리튬금속산화물을 양극으로 구성하고, 엑체 전해질과 다공성 고분자 분리막을 사용한 것이 LIB이다. LIB에서 리튬이온의 이동이 가능한 액체전해질의 가능을 고분자 전해질이 대신함으로서 보다 높은 안정성을 확보 한 전지가 LIPB 이다. 또한 고분자 전해질을 사용한 경우 금속리튬상에서의 수지상 성장이 저하되는 현상이 관찰됨으로서, 이론용량이 3,860mAh/g 에 달하는 리튬금속 혹은 합금을 고분자 전지에서 음극으로 사용하고자 하는 2 차전지가 LPB 이다. 리튬 2차전지는 비록 1989년 액체전해질을 사용한 금속리튬 2차전지의 실패전력을 안고있지만 궁극적으로는 이론적으로 최대의 에너지밀도를 가지고 있는 LPB를 지 향할 것으로 예상되지만 가까운 장래에 실현되기는 어려울 것이다. 따라서 향후의 라튬 2차전지의 전개방향은 현재의 LIB를 고분자 전해질을 채용하는 LIPB로 진행시커면서 저가의 전극재료개발을 지속적으로 추진할 것으로 예상된다. 현재 리튬 2차전지는 소형전지에 국한되고 있지만 전기자동차나 전력저장용으로 이를 대형화시커기 위해서는 열적특성이 우수하고 저가인 전극재료개발이 선행되야하기 때문에, 저가의 탄소재료와 코발트산화물을 대신할 수 있는 철, 망칸 또는 니켈산 화물의 개발이 필요하다.

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Cryptosporidium spp., Giardia intestinalis, and Enterocytozoon bieneusi in Captive Non-Human Primates in Qinling Mountains

  • Du, Shuai-Zhi;Zhao, Guang-Hui;Shao, Jun-Feng;Fang, Yan-Qin;Tian, Ge-Ru;Zhang, Long-Xian;Wang, Rong-Jun;Wang, Hai-Yan;Qi, Meng;Yu, San-Ke
    • Parasites, Hosts and Diseases
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    • v.53 no.4
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    • pp.395-402
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    • 2015
  • Non-human primates (NHPs) are confirmed as reservoirs of Cryptosporidium spp., Giardia intestinalis, and Enterocytozoon bieneusi. In this study, 197 fresh fecal samples from 8 NHP species in Qinling Mountains, northwestern China, were collected and examined using multilocus sequence typing (MLST) method. The results showed that 35 (17.8%) samples were positive for tested parasites, including Cryptosporidium spp. (3.0%), G. intestinalis (2.0%), and E. bieneusi (12.7%). Cryptosporidium spp. were detected in 6 fecal samples of Macaca mulatta, and were identified as C. parvum (n=1) and C. andersoni (n=5). Subtyping analysis showed Cryptosporidium spp. belonged to the C. andersoni MLST subtype (A4, A4, A4, and A1) and C. parvum 60 kDa glycoprotein (gp60) subtype IId A15G2R1. G. intestinalis assemblage E was detected in 3 M. mulatta and 1 Saimiri sciureus. Intra-variations were observed at the triose phosphate isomerase (tpi), beta giardin (bg), and glutamate dehydrogenase (gdh) loci, with 3, 1, and 2 new subtypes found in respective locus. E. bieneusi was found in Cercopithecus neglectus (25.0%), Papio hamadrayas (16.7%), M. mulatta (16.3%), S. sciureus (10%), and Rhinopithecus roxellana (9.5%), with 5 ribosomal internal transcribed spacer (ITS) genotypes: 2 known genotypes (D and BEB6) and 3 novel genotypes (MH, XH, and BSH). These findings indicated the presence of zoonotic potential of Cryptosporidium spp. and E. bieneusi in NHPs in Qinling Mountains. This is the first report of C. andersoni in NHPs. The present study provided basic information for control of cryptosporidiosis, giardiasis, and microsporidiosis in human and animals in this area.

The Effect of NaOH treatment-Citric acid neutralization of Korean Standard Operating Procedure (SOP) on Physicochemical Compositions of Domestic Swine Excrement for the Connection to Thermophilic Aerobic Oxidation (TAO) (구제역 긴급행동지침(SOP)상의 화학처리방법으로 처리된 양돈분뇨의 고온호기산화공정 적용 연구)

  • Kim, Ha-Je;Kim, Soo-Ryang;Hong, In-Gi;Jeon, Sang-Jun;Kim, Cho-Rong;Jung, Gwang-Hwa;Han, Ho;Kim, Dong-Kyun;Lee, Myung-Gyu
    • Journal of Animal Environmental Science
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    • v.19 no.2
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    • pp.81-88
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    • 2013
  • We planned to study how the chemical disposal designed by SOP can affect on physicochemical compositions of the livestock excrement. According to Livestock Manure Management Scheme, we experimented in two steps; the first step, NaOH treatment-Citric acid neutralization, and then the second procedure, Thermophilic Aerobic Oxidation (TAO) system. Physicochemical compositions of the 3-days-old samples after NaOH treatment were pH 10.31, EC 24.54 mS/cm, SCOD 3,022 mg/L, T-N 4,315 mg/L, $NH{_4}^+-N$ 1,960 mg/L, and not detected E. coli.. And those of one-day-old samples after citric acid neutralization were pH 7.36, EC 32.89 mS/cm, $SCOD_{Mn}$ 12,733 mg/L, T-N 4,787 mg/L, $NH{_4}^+-N$ 2,450 mg/L, and E. coli. not detected. In contrast, the physicochemical compositions of the treatment plots after the second treatment with TAO system (72hr) were pH 9.42 EC 24.21 mS/cm, $SCOD_{Mn}$ 3,660 mg/L, T-N 3,616 mg/L, $NH{_4}^+-N$ 1,190 mg/L, and no detection of E. coli.

Physio-Chemical Studies on the Maturity of Hot Pepper Fruits - Part VI. Effects of Cation on Growth and Important Components - (신미종(辛味種) 고추의 성숙(成熟)에 따른 생리화학적(生理化學的) 변화(變化)에 관(關)한 연구(硏究) - [제6보(第六報)] 성장(成長)과 주요성분(主要成分)의 함량(含量)에 미치는 Cation 영향(影響) -)

  • Lee, Sung-Woo;Kim, Kwang-Soo;Kim, Soon-Dong
    • Applied Biological Chemistry
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    • v.18 no.4
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    • pp.234-238
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    • 1975
  • To determine the effect of canons on growth and major components of hot pepper fruit, various combinations of K, Ca and Mh concentration in culture media were employed. The results analyzed by using binary interaction method were: 1. For the ideal condition for growth, the plant height was found by 57% K-435 Ca in KCa group and $58.5%\;K^++41.5%\;Mg^{++}$ in KMg group. The number of node was showed by $59%\;K^++41%\;Ca^{++}$ and $60%\;K^++40%\;Mg^{++}$. 2. The ideal condition for the maximum yield was by $60%\;K^++40%\;Ca^{++}$ and $62%\;K^++38% Mg^{++}$. For matured fruit yield, $57%\;K^++43%\;Ca^{++}$ and $63%\;K^++37%\;Mg^{++}$ was found ideal. 3. There were no significant differences in the amount of free sugars and capsaicin between tge treatments. 4. The nitrogen level was almost constant in all treatments however, the ratio of Fe/Mn in each treatment was showed from 2 to 3.

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Cultivation of Scenedesmus accuminatus, Azolla-anabaena and Lemner minor L. Using the Effluent of Methane Fermented Hog Waste (메탄발효폐액(醱酵廃液)을 이용(利用)한 녹조류(綠藻類), 아졸라 및 좀개구리밥 배양(培養)에 관(関)한 연구(硏究))

  • Lee, Myoung-Goo;Lee, Sang-Kyu
    • Korean Journal of Soil Science and Fertilizer
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    • v.15 no.2
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    • pp.141-146
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    • 1982
  • Laboratory and greenhouse experments were conducted to find out the optimum dilution time of methane fermented effluent of hog waste which was high pH (7.85), $NH_4$-N (683ppm), electric conductivity (8.3mmhos/cm) and BOD (about 1,000ppm) and the interval of effluent change which will provide maximun yield of green algae (Scenedesmus accuminatus), duck weed (Lemner minor L.) and Azolla anabaena (Azolla pinnata). The results of this experiment are summerized as follows. 1. The maximum yield were obtained at 5 times diluted effluent ($NH_4$-N : 137ppm) and exchange of 4 day intertval, from 25 times to 50 times dilution ($NH_4$-N : 7-14ppm) and 4 day interval, and 50 times dilution ($NH_4$-N : 14 ppm) and exchange the effluent at 4-8 day interval for green algae, duck weed and azolla growth, respectively. 2. Purification of the effluent was enhenced by growth of the green algae, duck weed and azolla due to decrease of pH, $MH_4$-N and electric conductivity of effluent. The degree of purification was higher in case of azolla growth than duck week growth.

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Nano-scale Design of electrode materials for lithium rechargeable batteries

  • Gang, Gi-Seok
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2012.05a
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    • pp.72-72
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    • 2012
  • Lithium rechargeable batteries have been widely used as key power sources for portable devices for the last couple of decades. Their high energy density and power have allowed the proliferation of ever more complex portable devices such as cellular phones, laptops and PDA's. For larger scale applications, such as batteries in plug-in hybrid electric vehicles (PHEV) or power tools, higher standards of the battery, especially in term of the rate (power) capability and energy density, are required. In PHEV, the materials in the rechargeable battery must be able to charge and discharge (power capability) with sufficient speed to take advantage of regenerative braking and give the desirable power to accelerate the car. The driving mileage of the electric car is simply a function of the energy density of the batteries. Since the successful launch of recent Ni-MH (Nickel Metal Hydride)-based HEVs (Hybrid Electric Vehicles) in the market, there has been intense demand for the high power-capable Li battery with higher energy density and reduced cost to make HEV vehicles more efficient and reduce emissions. However, current Li rechargeable battery technology has to improve significantly to meet the requirements for HEV applications not to mention PHEV. In an effort to design and develop an advanced electrode material with high power and energy for Li rechargeable batteries, we approached to this in two different length scales - Atomic and Nano engineering of materials. In the atomic design of electrode materials, we have combined theoretical investigation using ab initio calculations with experimental realization. Based on fundamental understanding on Li diffusion, polaronic conduction, operating potential, electronic structure and atomic bonding nature of electrode materials by theoretical calculations, we could identify and define the problems of existing electrode materials, suggest possible strategy and experimentally improve the electrochemical property. This approach often leads to a design of completely new compounds with new crystal structures. In this seminar, I will talk about two examples of electrode material study under this approach; $LiNi_{0.5}Mn_{0.5}O_2$ based layered materials and olivine based multi-component systems. In the other scale of approach; nano engineering; the morphology of electrode materials are controlled in nano scales to explore new electrochemical properties arising from the limited length scales and nano scale electrode architecture. Power, energy and cycle stability are demonstrated to be sensitively affected by electrode architecture in nano scales. This part of story will be only given summarized in the talk.

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Electrochemical Hydrogenation Behavior of Surface-Treated Mg-based Alloys for Hydrogen Storage of Fuel Cell (연료전지의 수소저장용 마그네슘계 합금의 표면제어에 의한 전기화학적 수소화 거동 연구)

  • Kim, Ho-Sung;Lee, Jong-Ho;Boo, Seong-Jae
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.20 no.7
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    • pp.46-52
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    • 2006
  • The effects of surface treatment on the hydrogen storage properties of a $Mg_2Ni$ alloy particle were investigated by the microvoltammetric technique, in which a carbon-filament microelectrode was manipulated to make electrical contact with the particle in a KOH aqueous solution. It was found that the hydrogen storage properties of $Mg_2Ni$ at room temperature were improved by the surface treatment with a nickel plating solution. The sodium salts(sodium phosphate and sodium dihydrogen citrate) contained in the nickel plating solution made the alloy form an amorphous-like state, resulting in an improved hydrogen charge/discharge capacity at room temperature as high as about 150[mAh/g] from the original value of 17[mAh/g]. Potential-step experiment was carried out to determine the apparent chemical diffusion coefficient of hydrogen atom($D_{app}$) in the alloy. Since the alloy particle we used here was a dense, conductive sphere, the spherical diffusion model was employed for data analysis. $D_{app}$ was found to vary the order between $10^{-8}{\sim}10^{-9}[cm^2/s]$ over the course of hydrogenation and dehydrogenation process.

Effect of Vapor-Cooled Heat Stations in a Cryogenic Vessel (극저온액체 저장용기에서 열전도 차폐단의 영향)

  • Kim, S.Y.;Kang, B.H.;Choi, H.J.
    • Transactions of the Korean hydrogen and new energy society
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    • v.9 no.4
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    • pp.169-176
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    • 1998
  • An experimental study on effect of vapor-cooled heat stations in a 5.5 liter cryogenic vessel has been performed. The cryogenic vessel is made of stainless steel of thickness of 1mm and insulated by the combined insulation of vacuum, MLI(multi-layer insulation) and vapor-cooled radiation shield. Vapor-cooled heat stations are also constructed based on the 1-dimensional thermal analysis to reduce the heat inleak through a filling tube. Thermal analysis indicates that the vapor-cooled heat stations can substantially enhance the performance of vessel for cryogenic fluids with high $C_p/h_{fg}$ where $C_p$ the specific heat and $h_{fg}$ the heat of vaporization, such as $LH_2$ and LHe. The experimental results for $LN_2$ shows that the total heat inleak into inner vessel consists of 14% radiation and 86% conduction through the filling tube. Therefore, it is expected that the conduction heat in leak of the vessel for high $C_p/h_{fg}$ cryogenic fluids can be significantly reduced. powders. The amount of copper coating was 20wt%. In order to examine corrosion behavior of the electrodes, the corrosion current and the current density, in 6M KOH aqueous solution after removal of oxygen in the solution, were measured by potentiodynamic and cyclic voltamo methods. The results showed that Co in the alloy increased corrosion resistance of the electrode whereas Ni decreased the stability of the electrode during the charge-discharge cycles. The electrode used Si sealant as a binder showed a lower corrosion current density than the electrode used PTFE and the electrode used Cu-coated alloy powders showed the best corrosion resistance.

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Soft Magnetoresistive Properties of Conetic Thin Film Depending on Ta Buffer Layer (버퍼층 Ta에 의존하는 코네틱 박막의 연자성 자기저항 특성)

  • Choi, Jong-Gu;Hwang, Do-Guwn;Lee, Sang-Suk;Choi, Jin-Hyub;Lee, Ky-Am;Rhee, Jang-Rho
    • Journal of the Korean Magnetics Society
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    • v.19 no.6
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    • pp.197-202
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    • 2009
  • The property of soft magnetism for the Corning glass/non-buffer or buffer Ta/Conetic(NiFeCuMo)/Ta prepared by the ion beam deposition sputtering was studied. The effect of crystal property and post annealing treatment depending on the thickness of Conetic thin films was investigated. The coercivities of Conetic thin films with easy and hard direction along to the applying magnetic field during deposition were compared with each other. The coercivity and magnetic susceptibility of Ta(5 nm)/Conetic(50 nm) thin film were 0.12 Oe and 1.2 ${\times}\;10^4$, respectively. From these results, firstly, the Conetic thin film was more soft magnetism thin film than other one such as permalloy NiFe. Secondly, the usage of soft magnetism Conetic thin film for GMR-SV (giant magneoresistance-spin valve) or MTJ (Megnetic Tunnel Junction) structure in a low magnetic field can be possible.

The Effects of Anti-Inflammatory Activities and Active Fractions Analysis of Ethanol Extract from Red Rose Petals (붉은 장미꽃잎 에탄올 추출물의 활성 분획물 분석 및 항염증 활성 효과)

  • Kim, Hyun Kyoung
    • The Journal of the Convergence on Culture Technology
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    • v.6 no.2
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    • pp.543-551
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    • 2020
  • Red rose petals are usually disposed but they are an abundant source of phenolics and traditionally used as food supplement and as herbal medicine. Of the Various phenolics, they are known to have anticancer, antioxidant, and anti-inflammatory properties. In this study, we investigated the anti-inflammatory effects of red rose ethanolic extracts(GRP) on lipopolysaccharide (LPS)-activated RAW 264.7 cells. The results demonstrated that pretreatment of GRP(500㎍/mL) significantly reduced NO production by suppressing iNOS protein expression in LPS-stimulated cells. Anti-inflammatory effects byred rose petal were observed in the following. Red rose petal inhibited the translocation of NF-κB from the cytosol to the nucleus via the suppression of IκB-α phosphorylation and also inhibited LPS-stimulated NF-κB transcriptional activity. These findings suggest that red rose petal exert anti-inflammatory actions and help to elucidate the mechanisms underlying the potential therapeutic values of red rose petal. Therefore, red rose petal could be regarded as a potential source of natural anti-inflammatory agents.