• Korean Journal of Food Science and Technology
• /
• v.43 no.5
• /
• pp.532-536
• /
• 2011

The internal standard method using ion chromatography combined with tandem mass spectrometry (IC-MS/MS) for quantifying perchlorate in different types of food was established. Because the presence of ions and other biomolecules in matrices usually interrupts accurate determination of perchlorate, it is necessary to develop efficient, reproducible method to determine perchlorate concentrations in food. In this study, the internal standard method was compared with the external standard method to determine perchlorate concentrations in standard samples. The obtained method detection limit (MDL) for perchlorate was 0.005 ${\mu}g/L$ for bottled water, 0.12 ${\mu}g/L$ for milk, 0.27 ${\mu}g/kg$ for rice, 0.16 ${\mu}g/kg$ for vegetables, and 0.07 ${\mu}g/kg$ for seaweed, respectively. The limit of quantitation (LOQ) was calculated by multiplying the MDL by 7. The recoveries of perchlorate from food samples spiked with perchlorate ranged from 98 to 105% and their percent relative standard deviation (%RSD) levels were <20%. This method was successfully applied for the quantitative determination of perchlorate in various kinds of food.

• Analytical Science and Technology
• /
• v.25 no.5
• /
• pp.307-312
• /
• 2012

To perform inhalation toxicity test by using experiment animals, we set up an analytical method to monitor didecyldimethylammonium chloride (DDAC) in aerosol nebulized into inhalation chambers by ion chromatography. DDAC was adsorbed by XAD-2 resin and analyzed with conductivity detector. Recovery of DDAC desorbed by acetonitrile from XAD adsorbent was 87.8%. The method detection limit (MDL) and the limit of quantitation (LOQ) were 2.97 ${\mu}g/m^3$ and 8.92 ${\mu}g/m^3$, respectively. Repeatability was calculated as RSD 7.8% in the range of 0~20 ${\mu}g/mL$. Time needed to analyze a sample was less than 5 minutes. Therefore, the analysis of DDAC by ion chromatography was practically useful in monitoring DDAC in inhalation chambers with rapidity and sensitivity manner to perform inhalation toxicity test using experimental animals.

• Journal of Korean Society of Environmental Engineers
• /
• v.37 no.5
• /
• pp.303-311
• /
• 2015

To determine the concentrations of selected 10 perfluorinated compounds (PFCs), a field study was conducted in the water body of Yeongsan River Water System. Raw water samples were collected in the spring and the fall, respectively, which included 18 sampling sites. Collected samples were equally mixed and then served as an analytical sample. The concentration of perfluorooctanesulfonate (PFOS) and perfluorooctanoate (PFOA) were in range of 20.80-92.0 ng/L and ND-28.40 ng/L respectively. Perfluorononanoate (PFNA) and perfluorohexanesulfonate (PFHxS) were ranged from ND to 42.20 ng/L and from ND to 11.47 ng/L. The detection frequencies of other PFCs selected in this study were very sparse at very low concentrations, except for PFOS, PFOA, PFNA and PFHxS. PFOS was higher detection frequency and concentration in both spring and fall, PFOA and PFNA were in spring, and PFHxS was in fall. As a result, the observed concentrations of PFCs in the downtown water area of Gwangju, located in the wastewater treatment plants, were relatively higher than other sampling points.

• Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
• /
• v.38 no.6
• /
• pp.543-551
• /
• 2020

In this paper, we introduce a method to improve the accuracy of the length estimation of targets using a radar. The HRRP (High Resolution Range Profile) obtained from a received radar signal represents the one-dimensional scattering characteristics of a target, and peaks of the HRRP means the scattering centers that strongly scatter electromagnetic waves. By using the extracted scattering centers, the downrange length of the target, which is the length in the RLOS (Radar Line of Sight), can be estimated, and the real length of the target should be estimated considering the angle between the target and the RLOS. In order to improve the accuracy of the length estimation, parametric estimation methods, which extract scattering centers more exactly than the method using the HRRP, can be used. The parametric estimation method is applied after the number of scattering centers is determined, and is thus greatly affected by the accuracy of the number of scattering centers. In this paper, in order to improve the accuracy of target length estimation, the number of scattering centers is estimated by using AIC (Akaike Information Criteria), MDL (Minimum Descriptive Length), and GLE (Gerschgorin Likelihood Estimators), which are the source number estimation methods based on information theoretic criteria. Using the ESPRIT algorithm as a parameter estimation method, a length estimation simulation was performed for simple target CAD models, and the GLE method represented excellent performance in estimating the number of scattering centers and estimating the target length.

• Communications for Statistical Applications and Methods
• /
• v.12 no.3
• /
• pp.659-672
• /
• 2005

This paper evaluates discretization of continuous variables to select relevant variables for supervised learning using mutual information. Three discretization methods, MDL, Histogram and 4-Intervals are considered. The process of discretization and variable subset selection is evaluated according to the classification accuracies with the 6 real data sets of UCI databases. Results show that 4-Interval discretization method based on quantiles, is robust and efficient for variable selection process. We also visually evaluate the appropriateness of the selected subset of variables.

• Communications for Statistical Applications and Methods
• /
• v.11 no.3
• /
• pp.465-474
• /
• 2004

Data visualization is the automation process and the discovery process to data sets in an effort to discover underlying information from the data. It provides rich visual depictions of the data. It has distinct advantages over traditional data analysis techniques such as exploring the structure of large scale data set both in the sense of number of observations and the number of variables by allowing great interaction with the data and end-user. We discuss the principles of data visualization and evaluate the characteristics of various tools of visualization according to these principles.

• Fibers and Polymers
• /
• v.2 no.3
• /
• pp.122-128
• /
• 2001

UV-curable polyurethane acrylate prepolymers were prepared from diisocyanates [isophorone diisocyanate (IPDI), 2,4-toluene diisocyanate (TDI), or 4,4'-dicyclohexylmethane diisocyanate (H$_{12}$MDI)], diols [ethylene glycol (EG), 1,4-butane diol (BD), or 1,6-hexane diol (HD)], polypropylene glycol as a polyol. UY-curable mixtures were formulated from the prepolymer (90 wt%), reactive diluent monomer trimethylol propane triacrylate (10 wt%). and photoinitiator 1-hydroxycy-clohexyl ketone (3 wt% based on prepolymer/diluent). The effects of different diisocyanates/low molecular weigh dial on the dynamic mechanical thermal properties and elastic recovery of UV-cured polyurethane acrylate films were examined. The tensile storage modulus increased a little in the order of EG > BD > HD at the same diisocyanate. Two loss modulus peaks for all samples are observed owing to the glads transition of softs segments ($T_gh$) and the glass transition temperature of hard segments ($T_gh$). For the same diisocyanate, $T_gh$, decreased, however, $T_gh$ increased, in the order of HD > BD > EG. The elastic recovery also increased in the order of HD > BD > EG at the same diisocyanate. In case of same diols, $T_gh$ increased in the order of $H_12$MDl > TDI > IPDI significantly. The ultimate elongation and elastic recovery increased in the order of TDI > IPDI > $H_12$MDl at the same diol.l.

• Journal of KIISE:Software and Applications
• /
• v.27 no.5
• /
• pp.521-528
• /
• 2000

One of the hidden problems in a domain theory is that an agent does not understand the meaning of its action. Graphplan uses mutex to improve efficiency, but it does not understand negation and suffers from a redundancy problem. Introducing a negative function not in IPP partially helps to solve this kind of problem. However, using a negative function comes with its own price in terms of time and space. Observing that a human utilizes opposite concept to negate a fact based on MDL principle, we hypothesize that using a positive atom rather than a negative function to represent a negative fact is a more efficient technique for building an intelligent agent. We show empirical results supporting our hypothesis in IPP domains. To autonomously learn the human-like concept, we generate a cycle composed of opposite operators from a domain theory and extract opposite literals through experimenting with the operators.

• Analytical Science and Technology
• /
• v.26 no.6
• /
• pp.375-380
• /
• 2013

Ammonium biflouride ($NH_4HF_2$) digestion was studied for germanium analysis in rock and sediment by inductively coupled plasma mass spectrometry (ICP/MS). QLO-1 and SDO-1 are used for reference materials from USGS. Sediment, basalt and ball clay for GeoPT were chosen as real samples. The loss of germanium in open vessel digestion was well known which can be caused by easy transformation to volatile compounds. But ammonium bifluoride digestion could suppress loss of germanium in open vessel digestion. Germanium recovery was not influenced by hydrogen peroxide with ammonium bifluoride digestion. Furthermore, the new method was simple and rapid in germanium analysis by ICP/MS. MDL(method detection limit) was 0.015 ${\mu}g/g$ and germanium recovery was 106~128%.

• Journal of the Korean Institute of Telematics and Electronics C
• /
• v.36C no.7
• /
• pp.10-16
• /
• 1999

This paper describes a low voltage swing bus driver using FCSR(Feedback Control Swing voltage Reduction) which can control bus swing voltage within a few hundred of mV. It is proposed to reduce power consumption in On-chip interface, especially for MDL(Merged DRAM Logic) architecture wihich has wide and large capacitance bus. FCSR operates on differential signal dual-line bus and on precharged bus with block controlling fuction. We modeled driver and bus to scale driver size automatically when bus environment is variant. We also modeled coupling capacitance noise(crosstalk) of neighborhood lines which operate on odd mode with parallel current source to analysis crosstalk effect in the victim-line according as voltage transition in the aggressor-line and environment in the victim-line. We built a test chip which was designed to swing 600mV in bus, shows 70Mhz operation at 3.3V, using Hyundai 0.8um CMOS technology. FCSR operate with 250Mhz at 3.3V by Hspice simulation.