• Title/Summary/Keyword: M3W

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Metal-Dinitrosyl Complexes(Ⅳ) : Synthesis and Characterization of Symmetric and Asymmetric Dinuclear Molybdenum and Tungsten Complexes (금속-디니트로실 착물 (제 4 보) : 몰리브덴과 텅스텐의 대칭 및 비대칭 이핵 착물의 합성과 특성)

  • O, Sang O;Mo, Seong Jong
    • Journal of the Korean Chemical Society
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    • v.38 no.7
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    • pp.485-495
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    • 1994
  • Several new symmetric and asymmetric homo and hetero dinuclear complexes of the type $[Cl(dppp)(NO)_2M({\mu}-pyz)M'(NO)_2(dppp)Cl][ClO_4]_2$ and $[Cl(phen)(NO)_2M({\mu}-pyz)M'(NO)_2(dppp)Cl][ClO_4]_2$(M,M'= Mo or W; phen = 1,10-phenanthroline; dppp = 1,3-bis(diphenylphosphino)propane; pyz = 1,4-pyrazine) were synthesized in three-steps starting from $[M(NO)_2Cl_2]_n(M = Mo, W)$. The final products were purified by eluting it through silica gel column ($2{\times}20$ cm) with acetone as the eluent. Characterization of these complexes and some related complexes was accomplished through UV-vis., $^1H$-NMR, $^{13}C$-NMR and IR spectroscopies as well as elemental analysis. The infrared spectra indicate that the NO groups occupy cis-positions of the octahedral. The $^1H$ and $^{13}C-NMR$ data for the new compounds revealed a dimeric structures with bridged pyz.

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Fabrication of Porous Al2O3 Ceramics Using Thermoplastic Polymer (열가소성 고분자를 이용한 다공질 알루미나의 제조)

  • 이상진;김해두
    • Journal of the Korean Ceramic Society
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    • v.41 no.7
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    • pp.513-517
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    • 2004
  • Porous alumina ceramics with aligned plate-shaped pores were fabricated by using thermoplastic microsphere in order to show the anisotropy in thermal conductivity. The mixed powder of alumina and microsphere was pressed under 15 MPa till 20$0^{\circ}C$ to deform polymer into platelet-shape and sintered at 1,00$0^{\circ}C$ for 1 h. The sintered specimen with 10 wt% microsphere has 45.3% porosity and the bending strength of 44 MPa. The microstructural investigation confirmed the pore structure of platelet-shape, the thermal conductivities for vertical and parallel directions are 3.803 W/mK and 7.818 W/mK, respectively, the ratio between two directions exceeds 2.

Studies on reactive ion etching of GaN using BCl$_{3}$ (BCl$_{3}$를 이용한 GaN계 질화합물 반도체의 RIE에 관한연구)

  • 윤관기;최용석;이일형;유순재;이진구;김송강
    • Proceedings of the IEEK Conference
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    • 1998.06a
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    • pp.409-412
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    • 1998
  • BCl/sub 3/ 및 Cl/sub 2/ 반응가스를 사용하여 RIE 장치로 GaN의 건식식각을 연구하였다. RF 전력, 반응가스의 유량 및 반응가스의 혼합비 등의 변화에 따른 최적의 식각공정 조건 및 결합특성을 연구하였다. RF 전력에 따른 GaN의 식각율은 챔버압력 25mTorr, BCl/sub 3/ 유량 40 sccm의 조건에서 RF 전력이 100W일때 17nm/min을 얻었다. BCl/sub 3/의 유량에 따른 식각율은 RF 전력 100W 챔버압력 20mTorr, Cl/sub 2/ 유량 5sccm의 조건에서 BCl/sub 3/ 유량이 40 sccm일때 65nm/min을 얻었다. Cl/sub 2//BCl/sub 3/ 혼합가스 비율에 따른 식각율은 Cl/sub 2/ 유량을 5sccm으로 고정하고 BCl/sub 3/ 유량을 변화시켰을때 RF 전력 100W 및 챔버압력 20mTorr의 조건에서 혼합비가 0.25일때 50nm/min을 얻었다. RF 전력에 따른 PR의 식각율은 챔버압력 25mTorr, Cl/sub 2/ 유량 0 sccm 및 BCl/sub 3/ 유량 40 sccm의 조건에서 RF 전려이 100W일때 15nm/min을 얻었다. 또한, 챔버압력 20mTorr, Cl/sub 2/ 유량 5 sccm 및 BCl/sub 3/ 유량 20sccm의 조건에서 RF 전력이 100W 일때 82nm/min을 얻었다.

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A Study on Deep Geothermal Energy and Potential of Geothermal Power Generation in Mongolia (몽골의 심부 지열에너지 자원과 지열발전에 관한 연구)

  • Hahn, Jeong-Sang;Yoon, Yun-Sang;Kiem, Young-Seek;Hahn, Chan;Park, Yu-Chul;Mok, Jong-Gu
    • Journal of the Korean Society for Geothermal and Hydrothermal Energy
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    • v.8 no.3
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    • pp.1-11
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    • 2012
  • Mongolia has three(3) geothermal zones and eight(8) hydrogeothermal systems/regions that are, fold-fault platform/uplift zone, concave-largest subsidence zone, and mixed intermediate-transitional zone. Average temperature, heat flow, and geothermal gradient of hot springs in Arhangai located to fold-fault platform/uplift zone are $55.8^{\circ}C$, 60~110 mW/m2 and $35{\sim}50^{\circ}C/km$ respectively and those of Khentii situated in same zone are $80.5^{\circ}C$, 40~50 mW/m2, and $35{\sim}50^{\circ}C/km$ separately. Temperature of hydrothermal water at depth of 3,000 m is expected to be about $173{\sim}213^{\circ}C$ based on average geothermal gradient of $35{\sim}50^{\circ}C/km$. Among eight systems, Arhangai and Khentii located in A type hydrothermal system, Khovsgol in B type, Mongol Altai plateau in C type, and Over Arhangai in D type are the most feasible areas to develop geothermal power generation by Enhanced Geothermal System (EGS). Potential electric power generation by EGS is estimated about 2,760 kW at Tsenher, 1,752 kW at Tsagaan Sum, 2,928 kW at Khujir, 2,190 kW at Baga Shargaljuut, and 7,125 kW at Shargaljuut.

Effect of Tungsten on PtRuW/C Catalysts for Promoting Methanol Electro-oxidation (메탄올 전기산화반응 증진을 위한 PtRuW/C 촉매에서 텅스텐의 효과에 관한 연구)

  • Noh, Chang Soo;Sohn, Jung Min;Park, Young-Kwon
    • Applied Chemistry for Engineering
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    • v.23 no.6
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    • pp.561-566
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    • 2012
  • PtRuW/C catalysts were prepared with the different molar ratios of Pt : Ru : W and their compositions were analyzed by energy dispersive X-ray (EDX). The uniform distribution of particles was observed using transmission electron microscopy (TEM). An average crystalline size of 3.5~5.5 nm was calculated based on x-ray diffraction (XRD) data. The electrochemical properties such as electrochemically active surface areas, current densities, specific activities and poisoning rates, were analyzed via CO stripping, linear sweep voltammetry and chronoamperometry. From the analysis, we observed that ternary alloy catalysts, except $PtRu_2W_2/C$, have higher current densities, specific activities and stabilities than those of commercial binary catalysts. Among all in-house catalysts, Pt5Ru4W/C showed the highest specific activity of $121.05mA{\cdot}m^{-2}$ and the lowest poisoning rate of $0.01%{\cdot}s^{-1}$.

A Study on the Behavior of PHC-W Retaining Wall Method Based on the Numerical Analysis Results (수치해석 결과를 이용한 PHC-W흙막이공법의 거동에 관한 연구)

  • Choi, Jeong Pyo;Jin, Hong Min;Kim, Chea Min;Kim, Sung Su;Choi, Yongkyu
    • Journal of the Korean Geotechnical Society
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    • v.33 no.2
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    • pp.5-15
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    • 2017
  • PHC-W retaining wall method is one of the economical retaining wall methods. PHC-W pile used in PHC-W retaining wall method has special shape with flat surfaces so that the PHW-C retaining wall, with overlapped piles, shows outstanding vertical control and impermeability. In order to evaluate two types of retaining walls, numerical analysis were performed. The selection of cases depended on N values of the ground and ground properties, and two types of PHC-W retaining walls (defined as type A and B) were constructed. For a case that consists of inorganic clay and sand with less than 30 of N value, the maximum excavation depths for type A and B were respectively 10.5 m and 11.0 m. At the other case of which N value is above 30, the depths were 17.0 m and 19.5 m. From the results, it was found that maximum excavation depth, horizontal displacement, and safety factor for flexural strength of the wall were influenced by ground properties.

Effect of Nd:YAG Laser Irradiation to Mental Region for Sensory Nerve Conduction Change (하악 이공부에 조사된 Nd:YAG 레이저가 감각신경전도변화에 미치는 영향)

  • Jeon, Jae-Woo;Kim, Kyoung-Hee;Ko, Myong-Yun;Ahn, Yong-Woo;Park, Jun-Sang
    • Journal of Oral Medicine and Pain
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    • v.30 no.4
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    • pp.447-455
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    • 2005
  • The purpose of this study was to examine the effect of Nd:YAG laser irradiation for sensory nerve conduction change. Nd:YAG laser was irradiated to mental region for 5 minutes with the parameters that 10 Hz and 20 Hz of 100 mJ/pulse. Target size of irradiation was 30 mm diameter of circle and target-tip distance was about 10 mm. Therefore, the power density were 212 $mW/cm^2$ and 424 $mW/cm^2$. Sensory nerve conduction was evaluated with $Neurometer^{\circled}$ CPT/C before and after Nd:YAG laser irradiation. As an outcomes, the current perception threshold(CPT) and pain tolerance threshold(PTT) were obtained. We made a comparison of these two values and the results were as follows. 1. There was no significant difference in CPT at 1W, 10 Hz and 2 W, 20 Hz Nd:YAG laser irradiation. 2. There was no significant difference in PTT at 10 Hz, 20 Hz of 100 mJ/pulse Nd:YAG laser. 3. There were no significant differences in CPT and PTT between 1 W, 10 Hz group and 2 W, 20 Hz group. Therefore, We can make a conclusion that Nd:YAG laser irradiation to mental region have no effect on mental nerve conduction in our study model.

Preparation and Thermal Conductivity of Poly(organosiloxane) Rubber Composite with Low Hardness (저경도 Poly(organosiloxane) Rubber Composite의 제조와 열전도 특성)

  • Kang Doo Whan;Yeo Hak Gue
    • Polymer(Korea)
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    • v.29 no.2
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    • pp.161-165
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    • 2005
  • $\alpha,\omega-Vinyl$ poly(dimethyl-methylphenyl) siloxane propelymer (VPMPS ) was prepared by the equilibrium polymerization of octamethylcyclotetrasiloxane $(D_4)$, 1,3,5-trimethyl-1,3,5-triphenylcyclotrisiloxane $(D_3^{MePh})$, and 1,1,3,3-tetramethyl-1,3-divinylsiloxane (MVS) as end-blocker. And also, $\alpha,\omega-hydrogen$ poly(dimethyl-methyltrifluoropropyl)siloxane prepolymer (HPDMFS) was prepared from $D_4$, 1,3,5-trimethyl-1,3.5-trifluoropropylcyclotrisiloxane $(D_3^{MeF3P})$, and 1,1,3,3-tetramethyldisiloxane. Poly(organosiloxane) rubber composite containing high thermal conductive filler was prepared by compounding VPMPS, HPDMFS, spherical alumina, and catalyst in high speed dissolver. The crosslinking density of poly (organosiloxane) composite was measured by oscillation rheometer. Poly(organosiloxane) composites of TC-POXR-2 and TC-POXR-4 prepared by controlling average diameters of thermal conductive filler, spherical alumina according to Horsfield's packing model were shown to 1.13 W/mK for TC-POXR-2 and 1.19 W/mK for TC-POXR-4.

Improvement of Fungal Cellulase Production by Mutation and Optimization of Solid State Fermentation

  • Vu, Van Hanh;Pham, Tuan Anh;Kim, Keun
    • Mycobiology
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    • v.39 no.1
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    • pp.20-25
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    • 2011
  • Spores of Aspergillus sp. SU14 were treated repeatedly and sequentially with $Co^{60}$ ${\gamma}$-rays, ultraviolet irradiation, and N-methyl-N'-nitro-N-nitrosoguanidine. One selected mutant strain, Aspergillus sp. SU14-M15, produced cellulase in a yield 2.2-fold exceeding that of the wild type. Optimal conditions for the production of cellulase by the mutant fungal strain using solid-state fermentation were examined. The medium consisted of wheat-bran supplemented with 1% (w/w) urea or $NH_4Cl$, 1% (w/w) rice starch, 2.5 mM $MgCl_2$, and 0.05% (v/w) Tween 80. Optimal moisture content and initial pH was 50% (v/w) and 3.5, respectively, and optimal aeration area was 3/100 (inoculated wheat bran/container). The medium was inoculated with 25% 48 hr seeding culture and fermented at $35^{\circ}C$ for 3 days. The resulting cellulase yield was 8.5-fold more than that of the wild type strain grown on the basal wheat bran medium.