• Tribology and Lubricants
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• v.17 no.2
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• pp.146-152
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• 2001

Environmentally adapted synthetic base oils of polyalkylene glycols (PAGs) and polyol esters (POEs) show a high polarity because of their functional groups containing oxygen atom. The lubricating performance of these polar base oils was investigated by using a four-ball tribometer under boundary lubrication condition. Four polyalkylene glycols and five polyol ester base oils were used as sample base oils of high polarity. A mineral oil (MO) and alkylnaphthalene (AN) were used as low polarity base oils. Tricrecylphosphate (TCP) was added to all the base oils, in the range of 10 mmol/L-2000 mmol/L, as an antiwear additive. All the TCP-for-mutated base oils showed optimum concentration characteristics for minimizing wear. The order of optimum concentration of all the base oils was in a good accordance with the order of relative stability of TCP in base oils. The interaction model on solvation between additive and different polar base oils can expect the stability order of TCP. Thus, the model on solvation can explain well the order of optimum concentration of all the base oils, by using the effect of polarity (dielectric constant, $\varepsilon$) and molecular size (molecular weight, MW) of them on stability of TCP in polar base oils. Finally, a good correlation of the optimum concentration for all the base oils was obtained when it was arranged as a function of C∝(M $W_{Base Oil}$/M $W_{TCP}$)$^{-2}$.71/.($\varepsilon$$_{Base Oil}$)$^{3.38}$ by these two parameters.s..

• Archives of Pharmacal Research
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• v.10 no.1
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• pp.50-59
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• 1987

(E)-2-Phenylcyclopropylamine ((E)-TCP), (Z)-2-Phenylacyclopropylamine ((Z)-TCP), (E)-1-methyl-2-phenylcyclopropylamine ((E)-MTCP), and (Z)-1-methyl-2-phenylcyclopropylamine ((Z)-MTCP) were synthesized and used to determine to what extent 1-methylsubstitution and stereochemistry of 2-phenycyclopropylamines affect inhibition of monoamine oxidase (MAO). Inhibition of rat brain mitochondrial MAO-A and B by the compounds were measured using serotonin and benzylamine as the substrate, respectively and $IC_{50}$ values obtianed with 95% confidence limits by the method of computation. For the inhibition of MAO-A, (E)-MTPC ($IC_{50}$ = 6.2 * $10^{-8}$M) was found to be 37 times more potent than (Z)-MTCP ($IC_{50}$ = 7.8 * $10^{-8}$M), was 7 times more potent than (Z)-MTCP($IC_{50}$= 4.7 * $10^{-7}$M) and (E)-TCP($IC_{50}$ =7.8 * $10^{-8}$M),0.6 times as potent as (Z)- TCP ($IC_{50}$ = 4.4 * $10^{-8}$M). The results suggested that while without 1-methyl group, potency of a (Z)-isomer was comparable to that of (E)-isomer, the methyl group in its (Z)-position was very unfavorable to the inhibition of MAO and that in its (E)-position, the methyl group contributed positively to the potency as found by the fact that (E)-MTCP was 1-5 times more potent than (E)-TCP. In view of the selective inhibition of MAO-A- or B over MAO-A and 1-methyl substitution as well as the stereochemical factors did not significantly influence the selectivity.

• Korean Journal of Materials Research
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• v.29 no.2
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• pp.129-135
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• 2019

A powder mixture of 70 wt% $Al_2O_3$ and 30 wt% hydroxyapatite (HA) is sintered at $1300^{\circ}C$ or $1350^{\circ}C$ for 2 h at normal pressure. An $MgF_2$-added composition to make HA into fluorapatite (FA) is also prepared for comparison. The samples without $MgF_2$ show ${\alpha}$ & ${\beta}$-tricalcium phosphates (TCPs) and $Al_2O_3$ phases with no HA at either of the sintering temperatures. In the case of $1,350^{\circ}C$, a $CaAl_4O_7$ phase is also found. Densification values are 69 and 78 %, and strengths are 156 and 104 MPa for 1,300 and $1,350^{\circ}C$, respectively. Because the decomposition of HA produces a $H_2O$ vapor, fewer large pores of $5-6{\mu}m$ form at $1,300^{\circ}C$. The $MgF_2$-added samples show FA and $Al_2O_3$ phases with no TCP. Densification values are 79 and 87 %, and strengths are 104 and 143 MPa for 1,300 and $1,350^{\circ}C$, respectively. No large pores are observed, and the grain size of FA ($1-2{\mu}m$) is bigger than that of TCP ($0.7{\mu}m{\geq}$) in the samples without $MgF_2$. The resulting $TCP/Al_2O_3$ and $FA/Al_2O_3$ composites fabricated in situ exhibit strengths 6-10 times higher than monolithic TCP and HA.

• Journal of the Korean Ceramic Society
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• v.45 no.10
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• pp.579-583
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• 2008

A porous $Al_2O_3$, scaffold coated with tricalcium phosphate(TCP) was fabricated by replica method using polyurethane(PU) foam as a fugitive material. Successive coatings of $Al_2O_3$ and hydroxyapatite(HAp) were applied via dip coating onto polyurethane foam, which has a slender and well interconnected network. A porous structure was obtained after sequentially burning out the foam and then sintering at $1500^{\circ}C$. The HAp phase was changed to TCP phase at high temperature. The scaffold showed excellent interconnected porosity with pore sizes ranging from $300{\sim}700{\mu}m$ in diameter. The inherent well interconnected structural feature of PU foam remained intact in the fabricated porous scaffold, where the PU foam material was entirely replaced by $Al_2O_3$ and TCP through a consecutive layering process. Thickness of the $Al_2O_3$ base and the TCP coating was about $7{\sim}10{\mu}m$ each. The TCP coating was homogeneously dispersed on the surface of the $Al_2O_3$ scaffold.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.8 no.6
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• pp.1166-1174
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• 2004

In this paper, a design of RISC-based transmission wrapper processor for TCP/IP protocol stack is described. The processor consists of input and output buffer memory with dual bank structure, 32-bit RISC microprocessor core, DMA unit with on-the-fly checksum capability, and memory module. To handle the various modes of TCP/IP protocol, hardware-software codesign approach based on RISC processor is used rather than the conventional state machine design. To eliminate large delay time due to sequential executions of data transfer and checksum operation, DMA module which can execute the checksum operation along with data transfer operation is adopted. The designed processor exclusive of variable-size input/output buffer consists of about 23,700 gates and its maximum operating frequency is about 167MHz under 0.35${\mu}m$ CMOS technology.

• Archives of Craniofacial Surgery
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• v.19 no.3
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• pp.181-189
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• 2018

Background: Autogenous bone grafts have several limitations including donor-site problems and insufficient bone volume. To address these limitations, research on bone regeneration is being conducted actively. In this study, we investigate the effects of a three-dimensionally (3D) printed polycaprolactone (PCL)/tricalcium phosphate (TCP) scaffold on the osteogenic differentiation potential of adipose tissue-derived stem cells (ADSCs) and bone marrow-derived stem cells (BMSCs). Methods: We investigated the extent of osteogenic differentiation on the first and tenth day and fourth week after cell culture. Cytotoxicity of the 3D printed $PCL/{\beta}-TCP$ scaffold was evaluated by 3-(4,5-dimethylthiazol-2-yl)-5-(3-carboxymethoxyphenyl)-2-(4-sulfophenyl)-2H-tetrazolium assay, prior to osteogenic differentiation analysis. ADSCs and BMSCs were divided into three groups: C, only cultured cells; M, cells cultured in the 3D printed $PCL/{\beta}-TCP$ scaffold; D, cells cultured in the 3D printed $PCL/{\beta}-TCP$ scaffold with a bone differentiation medium. Alkaline phosphatase (ALP) activity assay, von Kossa staining, reverse transcription-polymerase chain reaction (RT-PCR), and Western blotting were performed for comparative analysis. Results: ALP assay and von Kossa staining revealed that group M had higher levels of osteogenic differentiation compared to group C. RT-PCR showed that gene expression was higher in group M than in group C, indicating that, compared to group C, osteogenic differentiation was more extensive in group M. Expression levels of proteins involved in ossification were higher in group M, as per the Western blotting results. Conclusion: Osteogenic differentiation was increased in mesenchymal stromal cells (MSCs) cultured in the 3D printed PCL/TCP scaffold compared to the control group. Osteogenic differentiation activity of MSCs cultured in the 3D printed PCL/TCP scaffold was lower than that of cells cultured on the scaffold in bone differentiation medium. Collectively, these results indicate that the 3D printed PCL/TCP scaffold promoted osteogenic differentiation of MSCs and may be widely used for bone tissue engineering.

• Journal of the Korean Society of Safety
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• v.13 no.2
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• pp.109-115
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• 1998

Tri-cresyl phosphate(TCP) was synthesized by reaction of phosphorus chloride with mixed cresol(mixture of m-cresol, p-cresol, and others) in the presence of $AlCl_3$. Some of unwanted products and unreactants colored TCP. In order to separate TCP from these, vaccume distillation was carried twice, but colorless TCP could not be producted. Separation of unwanted materials by 2% NaOH solution was introduced before first and second distillation and optimal separation conditions such as NaOH concentration, mixing volume ratio, mixing time, and rpm were investigated for new batch separation and production of colorless TCP Optimal conditions were 2% NaOH solution, 35% mixing volume ratio of 2% NaOH solution, 1.5 hours of mixing time, and 20 rpm.

• International Journal of Control, Automation, and Systems
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• v.3 no.1
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• pp.122-129
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• 2005

We describe the MiniWeb[7] TCP/IP stack (mIP), which is an extremely small implementation of the TCP/IP protocol suite running 8 or 32-bit micro controllers intended for embedded control systems, and satisfying the subset of RFC1122 requirements needed for host­to-host interoperability over different platforms. Our TCP/IP implementation does sacrifice some of TCP's mechanisms such as fragmentation, urgent data, retransmission, or congestion control. Our implementation is applicable to web based controllers. The network protocols are tested in operational networks using CommView and Dummynet where the various operational parameters such as bandwidth, delay, and queue sizes can be set and controlled.

• Proceedings of the Korea Information Processing Society Conference
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• 2015.10a
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• pp.780-783
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• 2015

MODBUS/TCP는 단순하며 기능이 다양해 산업제어시스템에서 높은 점유율로 사용되는 통신 프로토콜이다. 오랜 시간 많은 사용과 더불어 안전한 MODBUS/TCP를 위한 연구 또한 많이 이루어졌지만, 이는 공개키 적용, SSL과 같은 라이브러리 연동, SCTP와 연동한 Hybrid 형식 등이 대부분이다. hard real system에서 주로 사용되는 MODBUS/TCP는 무엇보다 정해진 timeout 시간 내에 통신이 이루어지도록 해야 한다. 따라서 앞서 말한 방법은 하드웨어 가속기, 충분한 메모리 요구량 등의 문제가 따른다. 본 논문은 hard real system의 산업제어시스템에서 요구하는 timeout 시간을 충족하며 안전한 통신을 제공하는 보안 적용 방안을 소개하며 실험의 결과를 통해 실질적으로 효과적인 대안임을 보이고자 한다.

• Proceedings of the Korea Information Processing Society Conference
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• 2012.04a
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• pp.567-569
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• 2012

TCP의 성능저하는 버티컬 핸드오버에서만 발생하는 것이 아니라 호라이즌탈 핸드오버에서도 발생할 수 있다. 핸드오버 시 패킷 포워딩을 할 경우, 패킷은 라우터를 통해 소스 셀로 전송이 되었다가 단말이 이동한 타겟 셀로 다시 라우터를 통해 전송이 이루어지기 때문에 TCP 연결의 RTT가 증가하거나 패킷 리오더링에 의한 3dup ACK가 발생하는 문제가 있다. 또한 핸드오버 직후 포워딩된 데이터와 새 데이터가 합쳐져 일시적으로 데이터양이 급증하는 문제가 있다. 이 문제를 해결하기 위하여 Freeze TCP와 연동하여 패킷 리오더링과 타임아웃으로 인한 패킷 손실 문제를 해결한다. 핸드오버 직후 압축모드 기법을 사용하여 일시적인 데이터 폭주문제를 해결한다.