• Title/Summary/Keyword: M-TAR

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Study on Plrene Removal Characteristic From An Artificially Contaminated EPA Synthetic Soil Matrix With Varying Heat Treatment Conditions (Pyrene으로 오염된 EPA토양의 열적처리조건에 따른 오염물질 제거 특성 연구)

  • 김영규;양고수
    • Journal of Korea Soil Environment Society
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    • v.5 no.2
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    • pp.55-66
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    • 2000
  • A U.S EPA Synthetic soil matrix was used for reference neat soil and pyrene contaminated soil. For the contaminated soil, 4.79 wt.% pyrene was dissolved completely into the djchlorornethane, and the soil was evenly soaked with the pyrene solution. The contaminated soil samples(50$\pm$0.5mg) were heated in a modified electrical screen heater reactor which consisted of a thin stainless foil (3.5cm$\times$13cm$\times$0.00254cm, 302 stainless steel shim), two electrodes, and a 20cm dia. $\times$30cm tall cylindrical Pyrex chamber sealed at both ends by aluminum flanges. The heating rate and time conditions were selected as $455^{\circ}C$ @ $1137^{\circ}C$ /s, $760^{\circ}C$ @ $950^{\circ}C$ /s and $977^{\circ}C$ @ $977^{\circ}C$/s. Tar samples after heating the soils were collected on the aluminum foil funnel and a glass filter paper (25mm dia. filter paper) The tar sample and remnant soil on the reactor were extracted with dichloromethane covering the filters, foils and soil by sonicating each in the waterbath for 10 minutes. The extractions were run on a HPLC. At the low peak temperature(about $455^{\circ}C$ @ $1137^{\circ}C$/s) the color of tar was "white", at the middle peak temperature (about 76$0^{\circ}C$ @ 95$0^{\circ}C$/s) the color of tar was "pink brown", at the high peak temperature (about 977$^{\circ}C$ @ 977$^{\circ}C$/s) the color of tar was "dark brown". Cyclopeta(cd)pyrene (CPEP) , which is an interesting species due to mutagenic effect on human cells, was detected in tar samples only above the middle peak temperature. This species was not detected at the low peak temperature. Six isomers of bipyrene were detected. Phenanthrene(C$_{14}$ $H_{10}$) and cyclopenta(def)phenanthrene(C$_{15}$ $H_{10}$) were also detected, but their content was very small relative to the other listed compounds.to the other listed compounds.

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Effects of Moxi-tar Herbal Acupuncture of LI11 on inflammatory bowel disease induced by TNBS in mice (생쥐의 급 ${\cdot}$ 만성 대장염에 대한 곡지의 구진 약침 효과)

  • Song, Moon-Young;Gwon, Oh-Sang;Jang, Jae-Hoon;Jang, Jae-Yeong;Park, Sung-Ik;Kim, Jae-Hyo;Kim, Kyung-Sik;Sohn, In-Chul
    • Korean Journal of Acupuncture
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    • v.24 no.4
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    • pp.131-149
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    • 2007
  • Objectives : The purpose of the present study is to evaluate the effects of herbal acupuncture (HA) with Moxi-tar for the treatment to intestinal disease in mice with 2, 4, 6 - trinitrobenzenesulfonic acid (TNBS) induced colitis. Methods : Mice were administered with 5% TNBS at day 1 and day 7. To investigate effects of HA with Moxi-tar at LI11, treatments were carried out at day -1, day 1, day 3, day 5, and day 7. It was checked on the weight and width of colon, diarrhea, edema, survival rate, changes of body weight, and myeloperoxygenase (MPO) activity. Furthermore, we carried out immunohistochemical staining and Western blot and analyzed mRNA expression by RT-PCR. Results : HA of Moxi-tar at LI11 in preventive mode suppressed macroscopic damages and damages of intestinal epithelial cells and infiltration of immune cells in the colon by TNBS. HA in early and preventive mode ameliorated various symptoms by TNBS. TNBS injection increased MPO activity in colon while HA in preventive mode suppressed increase of MPO activity. HA down-regulated NF-kB activity and reduced expression of TNF-a, IL-1b, and ICAM-1 in colon of TNBS treated mice. Similar to experiment at colon, HA down-regulated NF-kB activity and reduced expression of TNF-a, IL-1b, and ICAM-1 by TNBS in mesenteric lymph node. HA in therapeutic mode suppressed errosion and shortening of colon and MPO activity by TNBS and suppressed mRNA expression of TNF-a, IL-1b, and ICAM-1 in the colon. Conclusions : This study demonstrates that HA with Moxi-tar at LI11 represents a potential therapeutic method of inflammatory bowel diseases.

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Effects of Puerariae Radix extract on the activity of antioxidant (갈근(葛根) 추출물이 항산화에 미치는 영향)

  • Eun, Young-Joon;Song, Yun-Kyung;Lim, Hyung-Ho;Kwon, Ki-Rok;Rhim, Tae-Jin
    • Journal of Pharmacopuncture
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    • v.10 no.3
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    • pp.53-62
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    • 2007
  • Objective The objective of this study was to investigate the antioxidative effects of Puerariae Radix extract. Method Total antioxidant capacity (TAC), Total antioxidant response (TAR), Total phenolic content, Reactive oxygen species (ROS), 1,1-Diphenyl-2-picrylhydrazyl (DPPH) free radical scavenging activities, lipid peroxidation were examined. Result Total antioxidant status was examined by total antioxidant capacity(TAC) and total antioxidant response(TAR) against potent free radical reactions. TAC and TAR of Puerariae Radix extract at the concentration of 5 mg/ml were 2.02 and 1.50 mM Trolox equivalents, respectively. Total phenolic content of Puerariae Radix extract at the concentration of 5 mg/ml was 2.29 mM gallic acid equivalent. Concentration of Puerariae Radix extract at which DPPH radical scavenging activity was inhibited by 50% was 5.91 mg/ml as compared to 100% by pyrogallol solution as a reference. The inhibitory effect of the extract on lipid peroxidation was examined using rat liver mitochondria induced by FeSO4/ascorbic acid. Puerariae Radix extract at the concentration of 1 mg/ml slightly but significantly decreased TBARS concentration. The extract further prevented lipid peroxidation in a dose-dependent manner. The effect of Puerariae Radix extract on reactive oxygen species (ROS) generation was examined using cell-free system induced by hydrogen peroxide/FeSO4. Addition of 1 mg/ml of Puerariae Radix extract significantly reduced dichloroflurescein (DCF) fluorescence. The extract caused concentration-dependent attenuation of the increase in DCF fluorescence, indicating that the extract significantly prevented ROS generation in vitro. Thus antioxidant effects of Puerariae Radix extract seem to be due to, at least in part, the prevention from free radicals-induced oxidation, followed by inhibition of lipid peroxidation. Conclusion As a result, Puerariae Radix seems to have antioxitative effect and antioxidant compount.

Preparation of Activated Carbon Fiber from Chemically Modified Coal-tar Pitch

  • Lee, Dong-Jun;Yang, Gap-Seung;Ryu, S.K.;Kim, Y.J.
    • Proceedings of the Korean Fiber Society Conference
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    • 1996.10a
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    • pp.117-123
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    • 1996
  • Cabon fiber of general purpose was prepared from coal tar pitch modified with 10% benzoquinine(BQ) at 380C for 3 hours. Such a modified pitch raised the softening of the pitch from 85C to 271C at the yield of 40%. The modified pitch was spun smoothly at a rate of 480m/min into a fiber of 20um diameter. The fiber was stabilized stepwise at 236C (5C/min) and 312C (1C/min) for 3 hours each. Both carbonized and graphitized fibers exhibited tensile strength of 570MPa which appears large enough as a precursor for active carbon fiber. The activated carbon fiber prepared exhibited relatively high surface area of 2062m2/g at 76% burn-off and rather narrow distribution pore size of 20A.

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Urinary 1-hydroxypyrene glucuronide and genetic polymorphisms of xenobiotic metabolism enzymes in shipbuilding workers using coal tar paint (콜타르가 함유된 페인트 사용 조선업 근로자에서 요중 1-hydroxypyrene glucuronide와 대사효소 유전자 다형성에 관한 연구)

  • 이경호;이정미;최인미;김재용;임형준;이상윤;윤기정;고상백;최홍렬
    • Environmental Mutagens and Carcinogens
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    • v.20 no.1
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    • pp.34-39
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    • 2000
  • Although shipbuilding workers were exposed to a variety of genotoxic compounds including polycyclic aromatic hydrocarbons (PAHs), limited number of studies were conducted to evaluate the biomarkers related to PAH exposure in painting workers in shipbuilding industry. One hundred and thirty three workers including 73 employees using coal tar paints were recruited from a shipbuilding company located in South Korea. Urinary 1-hydroxypyrene glucuronide (1-OHPG), as internal dose of PAH exposure, were measured by synchronous fluorescence spectroscopy after immunoaffinity purification using monoclonal antibody 8E11. Glutathione S-transferase (GST)M1 and GSTT1 genotypes were assessed by multiplex PCR. Information on demographic characteristics, smoking gabit, diet, job title, use of personal protective equipments were collected by self-administered questionnaire. Urinary 1-OHPG were higher in workers using coal tar paints than in workers using general paints, however, the difference was not statistically significant (p=0.20, Mann-Whitney U test). Urinary 1-OHPG levels in smokers were higher than in non-smokers (p<0.05 by Mann-Whitney U test) and there was a significant increase in urinary 1-OHPG levels with the numbers of cigarettes consumed per day (Spearman's correlation coefficient = 0.28, p=0.02). Genetic polymorphisms of GSTM1 and GSTT1 did not influence the level of 1-OHPG in study subjects. Multiple regression analysis show that smoking is the only significant predictor for lon-transformed 1-OHPG (overall model R2=0.1). These results suggest that workers using coal tar paints were exposed to significant amount of PAHs and individual difference in xenobiotic metabolism might affect the levels of internal dose of PAHs.

The Opportunities for New Filters in the Developing Low Tar Markets (저타르 담배의 시장증대에 따른 새로운 필터의 역할)

  • Shepherd, R.J.K.;Taylor, M.J.
    • Proceedings of the Korean Society of Tobacco Science Conference
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    • 1997.10a
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    • pp.79-90
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    • 1997
  • The world-wide cigarette market is becoming increasingly regulated. This involves restrictions on the freedom to advertise, restrictions on where people can smoke, and in some ways of most importance, limits on cigarette smoke deliveries. In particular, in an increasingly large number of countries maximum tar legislation is being enacted. In many cases, such as the European Union, this type of legislation is progressive and over time it is entirely conceivable that maximum permitted tar deliveries will be reduced to as low as 5 mg, possibly with additional restrictions on smoke nicotine deliveries. In addition, the pace of change is increasing as more and more countries embark on tar reduction programmes. The key challenge facing the cigarette industry is to manage these changes in such a way which ensures that product acceptability is maintained at as high a level as is possible in these circumstances. There are a number of ways of achieving this involving filter ventilation, modifying blends and using different filter constructions The real innovation comes when combining these in a way that gives the most acceptable balance of all these competing variables as far as the smoker is concerned. Undoubtedly, the nature of the filter is of crucial importance in designing the most acceptable low tar products, and this paper will discuss some of the filter types which are currently in use in the various low tar markets around the world. Also, some thoughts about the future in terms of new filter developments will be presented.

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The Effect of Some Additives on the Components of Cigarette Smoke (첨가제가 담배 연기성분에 미치는 영향)

  • Ra Do-Young;J도 Byong-Kwon;Lee Chang-Kook;Cho Si-Hyung;Lee Dong-Wook
    • Journal of the Korean Society of Tobacco Science
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    • v.27 no.1 s.53
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    • pp.40-50
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    • 2005
  • The influence of tobacco additives on the composition of the combustion products in mainstream smoke is discussed. The effect of additives on the chemical composition of smoke have been further evaluated in order to discover additives that would alter the chemical composition of smoke. Tobacco was uniformly treated at a 1-5$\%$ level with 8 classes of additives. Group M treated with alkali metal salt and group S, F, O give lower tar, nicotine and CO values than the control. Group AN treated with natural antioxidant gives higher tar and CO values than the control. The increases are most probably due to the high transfer rate of the ingredients to smoke. M3 and P1 reduced above the $50\%$ of TSNA from the smoke. M4 and P1 reduced above the $50\%$ of HCN from the smoke. These results suggest that tobacco additives alter pyrolysis or combustion product distribution and provide fundamental data to lead the development of a RRP(reduced risk product).

An Experimental Study on the Fire Risk of a Firewood Boiler (화목보일러 화재위험성에 관한 실험적 연구)

  • Lee, Sung-Ryong
    • Fire Science and Engineering
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    • v.29 no.3
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    • pp.37-42
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    • 2015
  • In this study, experiments were carried out to evaluate the fire risk of a firewood boiler, which is mainly used as a winter heating apparatus in rural areas. The ambient temperatures of the combustion chamber and the duct were measured. The fire risk of tar inside the duct was also investigated. The temperature decreased less than $40^{\circ}C$ in the region more than 40 cm from the combustion chamber. Fire- flakes were scattered in the range of less than 60 cm from the combustion chamber. The temperature inside the rose to above $600^{\circ}C$. At 2 m from the boiler body, the temperature inside the duct was increased to about $420^{\circ}C$. The ignition temperature of tar was about $398^{\circ}C$. The temperatures of the boiler and duct surface were above $300^{\circ}C$. Combustible material ignited when it contacted the boiler surface or duct surface.

Design and Implementation of Disk Archive System Exploiting De-duplication Scheme (데이터 중복 제거 기반의 디스크 아카이브 시스템 설계 및 구현)

  • Kang, Sung-Woon;Jung, Ho-Min;Ko, Young-Woong;Lee, Jeong-Gun
    • Proceedings of the Korea Information Processing Society Conference
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    • 2011.04a
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    • pp.204-206
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    • 2011
  • 기존의 TAR와 같은 아카이브 포맷은 파일의 중복을 제거하는 기능이 포함되지 않아 리눅스 배포 미러와 같이 버전단위로 저장되는 시스템에서 디스크 공간의 낭비가 발생했다. 본 연구에서는 중복 제거 기능이 포함된 아카이브 포맷인 DTAR와 이를 지원하는 DTM 유틸리티를 제안하였다. 주요 아이디어는 DTAR 헤더에 SHA1 해시를 삽입하고 SHA1 해시를 노드로 하는 R-B Tree를 생성하여 중복을 검색 및 제거하는 것이다. 실험 결과 DTAR가 tar.gz보다 최대 31% 공간을 절약하고, 수행 시간도 줄어드는 것을 확인하여 효율적임을 보였다.