• Title/Summary/Keyword: M/N ratio

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Dye removal from water using emulsion liquid membrane: Effect of alkane solvents on efficiency

  • Ghaemi, Negin;Darabi, Farzaneh;Falsafi, Monireh
    • Membrane and Water Treatment
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    • v.10 no.5
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    • pp.361-372
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    • 2019
  • Effect of different alkane based solvents on the stability of emulsion liquid membrane was investigated using normal alkanes (n-hexane, n-heptane, n-octane and n-decane) under various operating parameters of surfactant concentration, emulsification time, internal phase concentration, volume ratio of internal phase to organic phase, volume ratio of emulsion phase to external phase and stirring speed. Results of stability revealed that emulsion liquid membrane containing n-octane as solvent and span-80 (5 % (w/w)) as emulsifying agent presented the highest amount of emulsion stability (the lowest breakage) compared with other solvents; however, operating parameters (surfactant concentration (5% (w/w)), emulsification time (6 min), internal phase concentration (0.05 M), volume ratio of internal phase to organic phase (1/1), volume ratio of emulsion phase to external phase (1/5) and stirring speed (300 rpm)) were also influential on improving the stability (about 0.2% breakage) and on achieving the most stable emulsion. The membrane with the highest stability was employed to extract acridine orange with various concentrations (10, 20 and 40 ppm) from water. The emulsion liquid membrane prepared with n-octane as the best solvent almost removed 99.5% of acridine orange from water. Also, the prepared liquid membrane eliminated completely (100%) other cationic dyes (methylene blue, methyl violet and crystal violet) from water demonstrating the efficacy of prepared emulsion liquid membrane in treatment of dye polluted waters.

Optimum Conditions for the Removal of External Organic Carbon Sources in a Submerged Denitrification Biofilter (탈질 여과조에서 외부 탄소원 제거를 위한 적정 체류 시간과 외부 탄소원 종류 및 질산염 농도에 대한 외부 탄소원의 적정 비율)

  • 오승용;조재윤;윤길하
    • Journal of Aquaculture
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    • v.12 no.1
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    • pp.47-56
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    • 1999
  • Denitrification by anaerobic bacteria is one of the most common processes of removing nitrate from recirculating aquaculture systems. This process is affected by many factors such as external carbon sources, hydraulic retention time (HRT), and $COD/NO_3-N$ ratio. Although external organic carbon sources are essential for the denitrification process, these also contribute to increase dissolved organic carbon concentration in recirculating aquaculture systems. So these external organic carbons must be removed from the systems. This study was conducted to find out the optimum operating conditions for the removal of external organic carbons in a submerged denitrification biofilter. Combinations of two external carbon sources (glucose and methanol), two HRT (4- and 8-hour), and four different C:N ratios (3, 4, 5, and 6) were used in this experiment. The removal efficiencies of organic carbon sources at 8-hour HRT were always better than those at 4-hour's (P<0.05). Maximum removal efficiencies were achieved when C:N ratio was 5 in both glucose and methanol. The removal efficiencies of methanol were always better than those of glucose. The maximum removal efficiencies of glucose and methanol were 76.5% and 84.0%, respectively and the removal rates were 223.5 $g/m^2/day$ and 247.1$g/m^2/day$. The maximum removal rates of glucose (290.9 $g/m^2/day$) and methanol (355.6 $g/m^2/day$) were achieved at 4-hour HRT and 5 C:N ratio. But the concentrations of SCOD in the effluent of both glucose ($52.5 mg/\ell$) and methanol ($40.9 mg/\ell$) were too high for rearing fish. Therefore, the optimum operating conditions for the removal of external carbon in a submerged denitrification biofilter were 8-hour HRT and 5 C:N ratio. And methanol showed better efficiency as an external carbon sources.

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Studies on the Properties of 2-Methoxy-5-Nitrophenol Complex Salts (2-Methoxy-5-Nitrophenol 금속착염의 화학적 성질에 관한 연구)

  • 김선덕;우세홍;김명운
    • Journal of Environmental Health Sciences
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    • v.1 no.1
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    • pp.21-27
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    • 1974
  • This work was carried out to investigate the chemical properties of the chelate compounds which were produced with 2-methoxy-5-nitrophenol(MNG) and metal salt such as copper nitrate and manganese nitrate. And obtained results were as in the followings. 1) The binding ratio of the chelate compounds formation were determined by using the molar ratio concentration method and their chemical structures were identified by IR-spectrum. 2) In the absorbance measuring, 2-methoxy-5-nitrophenol coordinated with manganese and copper showed the maximum absorbance at $430 m\mu$ and $410 m\mu$ respectively. 3) The binding ratio of chelated compounds were measured by molar ratio method and continuous variation method with spectrophotometer, which was identified as 1:2. 4) The conditional formation constant(log Kn value) of manganese and copper chelate compounds were 6.70, 6.75, respectively according to the equation of $log\frac{A-AM\circ n MNG}{AMm MNG-A}=n log (M\circ)+log Kn$ 5) The dissociations degree of manganese and copper chelate compound were $2, 300{\times} 10^{-7}$, $2, 346{\times} 10^{-7}$ respectively according to the molar calculation method.

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Assessment of In Vitro Oocyte Maturation in Two Gobiid Fish Species, Chasmichthys dolichognathus and Tridentiger trigonocephalus after Exposure to Benzo[a]pyrene

  • Hwang, In-Joon;Baek, Hea-Ja
    • Development and Reproduction
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    • v.15 no.3
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    • pp.223-230
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    • 2011
  • Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous environmental contaminants derived from incomplete combustion of carbons and crude oil. In this study, we investigated the effects of benzo[a]pyrene (B[a]P), a representative PAHs on in vitro sex steroid hormone production and germinal vesicle breakdown (GVBD) using isolated oocytes of longchin goby (Chasmichthys dolichognathus) and chameleon goby (Tridentiger trigonocephalus). Oocytes in diameters of 0.8-0.9 (end vitellogenic stage) and 0.9-1.0 mm (germinal vesicle migratory stage) from longchin goby and 0.5 mm (fully vitellogenic stage) from chameleon goby were used. In GVBD assay, B[a]P at 10 nM stimulated GVBD in the oocytes of 0.8-0.9 mm from longchin goby. B[a]P at 1 nM stimulated GVBD in the oocytes with diameter 0.5 mm from chameleon goby. In steroid production from oocytes of longchin goby, B[a]P at 100 nM decreased testosterone (T) production, B[a]P at 1,000 nM increased estraiol-17 (J (E2) production and 10 and 100 nM increased $17,20{\beta}$-dihydroxy-4-pregnen-3-one ($17{\alpha}20{\beta}P$) production in the oocytes with diameter 0.8-0.9 mm. B[a]P at 1,000 nM increased E2 production, 100 and 1,000 nM increased $17{\alpha}20{\beta}P$ production in the oocytes with diameter 0.9-1.0 mm. In steroid production of oocytes from chameleon goby, B[a]P at 1,000 nM increased $E_2$ production. B[a]P at 10 nM increased $17{\alpha}20{\beta}P$ production. In the ratio of $E_2$ to T ($E_2$/T), B[a]P at 100 and 1,000 nM increased $E_2$/T in the oocytes of longchin goby. B[a]P at 100 nM also increased $E_2$/T in the oocytes of chameleon goby. Taken together, these results suggest that B[a]P have not only weak estrogenic effects but progestogenic effects on oocyte maturation.

Performance Analysis of Diversity Received DS-CDMA/MDPSK Signals in m-distribution and Rician Fading Environments (m-분포 페이딩과 라이시안 페이딩 환경 하에서의 다이버시티 수신된 DS-CDMA / MDPSK 신호의 성능 분석)

  • 이정도;강희조
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.9 no.2
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    • pp.191-198
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    • 1998
  • The error are equation of DC-CDMA/MDPSK signal has been derived in m-distribution and Rician fading channels. Predeteception multipath MRC(Maximal Ratio Combining) diversity technique is employed for improving the bit error rate performance. The suitability of modeling a Rician fading environment by properly chosen m-distribution model is examined. Using the derived equation the error performance has been evaluated and shown in figures as a function of PN code sequence length(N), user number(U), multipath number(P), fading index(m), Rician factor(K), number of diversity branches(L) and ($E_b/N_o$). The results show that the error performance in Rician fading agrees well with that in m-distribution fading as fading becomes weak and as user number(U) increases and as multipath number(P) increases and diversity number(L) increases.

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The analysis of leakage current of InGaAsP/InP PBH-LD fabricated by LPE (LPE 방법으로 제작된 InGaAsP/InP PBH-LD의 누설전류해석)

  • 최미숙;김정호;홍창희
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2002.11a
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    • pp.481-485
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    • 2002
  • In this study, we fabricated the PBH-LD by meltback method using the LPE. The PBH-LDs are analyzed the leakage current that flows through leakage current path like the p-n diode and p-n-p-n current blocking layer. We observed the variation of threshold current with the leakage width $W_{ι}$. As a consequence, we confirmed that the threshold current became low in the decrease of the leakage width and in the increase of the ratio of specific resistivity of leakage region to active region. We also compared between the calculated threshold current in the absence of leakage region and the measured threshold current in the device. As a result, the ratio of specific resistivity was about 0.5 in the measured LDs, which have the width of a active layer of 1.4${\mu}{\textrm}{m}$ and leakage width of 0.6${\mu}{\textrm}{m}$.

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Estimation on the Coefficient of Repair & Maintenance Costs for Power Tiller (경운기의 수리비계수(修理費係數) 산정(算定)에 관한 연구(硏究))

  • Kang, C.H.;Park, N.J.;Jung, D.H.
    • Journal of Biosystems Engineering
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    • v.15 no.2
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    • pp.143-150
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    • 1990
  • This study was conducted to estimate the ratio of Repair & Maintenance (R&M) costs to purchasing price that is one of the important factors for calculating the management costs of farm machinery. For this purpose, hour of use and R & M costs of power tiller and its attachments utilized results that were investigated with 400 sample units, 50 units by years of use from 1 to 8 years in 1988. The results obtained are summarized as follows; 1. The ratio of R & M costs per hours and annual R & M costs, accumulated R & M costs when sercice life of power tiller is 7 years were 0.017%, 5.50% and 38.52%, respectively. And in case of rotary, these ratio when its service life is 6 years were 0.072%, 7.16% and 43.0%, respectively. 2. The relationship between accumulated hours of use(t) and accumulated R & M costs(Y) of power tiller and its attachments were $Y=19.3t^{1.3}$ in power tiller, $Y=0.03t^{2.09}$ in plow, $Y=48.84t^{1.25}$ in rotary and $Y=7.45t^{1.15}$ in trailer. 3. The ratio of accumulated R & M costs to purchasing price when service life of power tiller is 7 years was 38.5%, and in case of rotary, this ratio when its service life is 6 years was 43.0%.

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A Clock Regenerator using Two 2nd Order Sigma-Delta Modulators for Wide Range of Dividing Ratio

  • Oh, Seung-Wuk;Kim, Sang-Ho;Im, Sang-Soon;Ahn, Yong-Sung;Kang, Jin-Ku
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.12 no.1
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    • pp.10-17
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    • 2012
  • This paper presents a clock regenerator using two $2^{nd}$ order ${\sum}-{\Delta}$ (sigma-delta) modulators for wide range of dividing ratio as defined in HDMI standard. The proposed circuit adopts a fractional-N frequency synthesis architecture for PLL-based clock regeneration. By converting the integer and decimal part of the N and CTS values in HDMI format and processing separately at two different ${\sum}-{\Delta}$ modulators, the proposed circuit covers a very wide range of the dividing ratio as HDMI standard. The circuit is fabricated using 0.18 ${\mu}m$ CMOS and shows 13 mW power consumption with an on-chip loop filter implementation.

The Analysis of Protection Ratio and Its Effect of Interference-to-Noise Ratio for Digital Microwave System with Diversity

  • Suh Kyoung-Whoan;Jang Won-Gyu
    • Journal of electromagnetic engineering and science
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    • v.6 no.3
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    • pp.189-195
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    • 2006
  • In this paper, the derivation of the protection ratio for the digital microwave system with diversity is newly suggested for a basic guidance of initial planning for frequency coordination, and computational results are presented for an actual radio frequency band. The net filter discrimination has been also examined to see the effect of the adjacent channel protection ratio caused by adjacent channel interference. In addition, the protection ratios for the space or frequency diversity system are analyzed in terms of diversity improvement factors to find out an equivalent allowable noise-to-interference ratio (N/I) from degraded fade margin. According to results for 6.2 GHz system, with the space diversity of 25 m distance between antennas or the frequency diversity of ${\Delta}f/f=0.05$, under 64-QAM and 60 km at BER $10^{-6}$, the protection ratio can be greatly reduced in comparison to the non-diversity system. So, assuming that only the same protection ratio as the non-diversity system is kept, it is shown that the system with diversity may get more interference level of N/I allowing from 9.0 to - 5.9 dB or from 6.0 to - 4.3 dB for the space or frequency diversity. In consequence, it is concluded that the diversity system is more robust or tolerable for interferences or fades, which may play an important role in overcoming N/I to some extent.

Correlationship of Vertical Distribution for Ammonia Ion, Nitrate Ion and Nitrifying Bacteria in a Fixed Bed Nitrifying Biofilm

  • Choi, Gi-Chung;Byun, Im-Gyu
    • Journal of Environmental Science International
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    • v.21 no.12
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    • pp.1455-1462
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    • 2012
  • The vertical distributions of nitrifying bacteria in aerobic fixed biofilm were investigated to evaluate the relationship between nitrification performance and microbial community at different HRT. Fluorescent in situ hybridization (FISH) and portable ion selective microelectrode system were adopted to analyze microbial communities and ions profiles according to the biofilm depth. Cilia media packed MLE (Modified Ludzack-Ettinger) like reactor composed of anoxic, aerobic I/II was operated with synthetic wastewater having COD 200 mg/L and $NH_4{^+}$-N mg/L at HRT of 6 hrs and 4 hrs. Total biofilm thickness of aerobic I, II reactor at 4 hrs condition was over two times than that of 6 hrs condition due to the sufficient substrate supply at 4 hrs condition (6 hrs; aerobic I 380 ${\mu}m$ and II 400 ${\mu}m$, 4 hrs; aerobic I 830 ${\mu}m$ and II 1040 ${\mu}m$). As deepen the biofilm detection point, the ratio of ammonia oxidizing bacteria (AOB) was decreased while the ratio of nitrite oxidizing bacteria (NOB) was maintained similar distribution at both HRT condition. The ratio of AOB was higher at 4 hrs than 6 hrs condition and $NH_4{^+}$-N removal efficiency was also higher at 4 hrs with 89.2% than 65.4% of 6 hrs. However, the ratio of NOB was decreased when HRT was reduced from 6 hrs to 4 hrs and $NO_2{^-}$-N accumulation was observed at 4 hrs condition. Therefore, it is considered that insufficient HRT condition could supply sufficient substrate and enrichment of AOB in all depth of fixed biofilm but cause decrease of NOB and nitrite accumulation.