• Title/Summary/Keyword: Luminescence Effect

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Effect of pH on the Luminescence of $(Y,Gd)BO_3:Eu^{3+}$ Phosphor Prepared by the Coprecipitation Method

  • Lee, Gwan-Hyoung;Kang, Shin-Hoo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1514-1517
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    • 2005
  • The $(Y,Gd)BO_3:Eu^{3+}$ phosphor was made by coprecipitation method. The precipitated powders were amorphous. The value of pH in the process of coprecipitation was critical for the luminescence of phosphors. The particle size and morphology were influenced by pH value. The lower calcination temperature and hydrothermal synthesis leads to the distortion of lattices. The distorted lattices changed the symmetry of $Eu^{3+}$ site. The broken inversion symmetry in the distorted lattice caused the increased emission of $^5D_0{\rightarrow}^7D_2$ transition.

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Luminescence Behavior of $YNbO_4$ and $YNbO_4:Bi$

  • Chang, Hyun-Ju;Lee, Seung-Kwon;Han, Cheong-Hwa;Park, Hee-Dong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2000.01a
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    • pp.35-36
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    • 2000
  • The luminescence behaviors of Yttrium niobate and Bi doped Yttrium niobate were investigated under UV and low voltage electron excitations and interpreted with the first-principle calculations. In the UV excitation and emission spectra of $YNbO_4$ and $YNbO_4:Bi$, we were able to separate host contribution and Bi contribution and found that the shift in emission peak to longer wavelength is mainly due to Bi contribution. Using density functional theory, the cluster calculations were carried out for both $YNbO_4$ and $YNbO_4:Bi$. From the calculated density of states, we were also able to explain the charge transfer gap in the host and the effect of Bi in the excitation and emission spectra theoretically.

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Doping and Annealing Effect on Luminescent Characteristics of $_2$ Phosphor Thin Films (ZnGa$_2$O$_4$형광박막의 발광특성에 미치는 도핑 및 어닐리의 효과)

  • 정영호;정승묵;김석범;김영진
    • Journal of the Korean Ceramic Society
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    • v.35 no.6
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    • pp.619-625
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    • 1998
  • Mn doped {{{{ {Zn {Ga }_{2 }O }_{4 } }} thin film phosphors were prepared on Si(100) wafers and ITO coated glass substrates by rf magnetron sputtering technique and the effects of the substrates dopant and the sputtering paramet-ers were analyzed, Changes of the oreintation were observed after annealine tratment. The grain size of {{{{ {Zn {Ga }_{2 }O }_{4 } }} : Mn thin film deposited on Si wafer was smaller than that on ITO/glass substrate which resulted in higher PL intensity. The PL spectra of Mn doped {{{{ {Zn {Ga }_{2 }O }_{4 } }} thin films showed sharp green luminescence spec-trum. According to CL spectrum it could be concluded that Mn ions acted as an actuator for green emission by substituting Zn atom sites.

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Investigation of Glass Substrate Sealing for ECL Application using Laser Welding Technology (레이저 웰딩 기술을 이용한 ECL용 유리 기판 접합에 대한 고찰)

  • Sung, Youl-Moon
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.29 no.12
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    • pp.28-32
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    • 2015
  • In this work, we reported fabrication of sealing the glass substrate using laser treatment at low temperature for electrochemical luminescence (ECL) cell. The laser treatment at temperature is using laser diode. The glass substrate sealing by laser treatment tested at 3-10W, 2-5 mm/s for build and tested. The sealing laser treatment method will allow associate coordination between the two glass substrate was enclosed. The effect of laser treatment to sealing the glass substrate was found to have cracks and air gap at best thickness of about 550-600 im for condition 3 W, 3 mm/s. The surface of sealing was roughness which was not influent to electrodes It can reduce the cracks, crevices and air gaps as well, improves the performance viscosity in butter bus bar electrodes. Therefore, it is more effective viscosity between two FTO glasses substrate.

High Luminescence Properties of YPV nano size phosphors by a Liquid Phase Precursor Method

  • Jo, D.S.;Dulda, A.;Masaki, T.;Yoon, D.H.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.1293-1296
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    • 2009
  • The synthesis of nano-size ($Y_{0.955}Eu_{0.1}$)($P_{0.7}V_{0.45}$)$O_4$ red phosphors were conducted by using a Liquid Phase Precursor (LPP) method. In this method, cellulose pulp was used as a template showing the micro fibre structures to obtain the nano size YPV red phosphor. Aqueous solutions of raw materials were impregnated into cellulose pulp and subsequently impregnated pulp was dried and fired at $800-1200^{\circ}C$ for 1h. The effect of luminescence properties on compositions and temperatures was evaluated with photoluminescence spectrum, X-ray diffraction and FE-SEM, and TEM. High efficiency (~110%) of phosphor of size of ~500nm fired at $1150^{\circ}C$ was obtained compared with the micro size of commercial product. High efficiency behaviors of nano size phosphors were discussed in this paper.

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Oxide and fluoride single crystals for scintillator applications

  • M. Nikl;K. Blazek;P. Fabeni;A. Vedda;M. Martini;M. Kobayashi;K. Shimamura;T. Fukuda
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.12 no.1
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    • pp.21-26
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    • 2002
  • Luminescence and scintillation properties of $PbWO_{4},\;XAIO_{3}$ (X = Y, Lu, Y-Lu) and $LiBaF_{3}$ based scintillators are reported. The effect of present and often not understood defect states is demonstrated in different scintillator parameters and related measurements are discussed. Importance of understanding of defect states participating in the processes of energy transfer and storage in the scintillating materials is emphasised.

A Research on Life of Organic Lumminescence Devices (유기EL 소자의 수명에 관한 연구)

  • Lee, Han-Sung
    • Proceedings of the KIEE Conference
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    • 2002.06a
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    • pp.110-113
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    • 2002
  • Organic EL has been expected to adopt to a new styles of technology that make flat display after Tang & Vanslyke made good electric luminescence device in late 1980s. Their studies based on multi layer structure that consists of emitting layer and carrier transporting layer using proper organic material. In this study. we made multi layer device using $Eu(TTA)_3(phen)$ as a luminescence material by PVD and investigate luminous properties of each device. But oxidization of organic layer by ITO. energy walls in both pole interface. contaminations of ITO surface, importance of protecting membrane, diffusive dimming of light to cathode organic layer. these causes of degradations are common facts of a macromolecule and micromolecule. We think these degradation caused by the impact of heat and electro-chemical factor, bulk effect and interface phenomenon. and raise a question.

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Gold Nanoparticle Optical Effect on Graphene (금 미세 입자에 의한 그래핀 광학 특성 변화)

  • Park, Byeongho;Lim, Juhwan;Jun, Seong Chan
    • Transactions of the Society of Information Storage Systems
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    • v.9 no.1
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    • pp.1-4
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    • 2013
  • Graphene and Graphene oxide have intense interest in fields such as physics, chemistry, and materials science, among others. They are the promising material for solving the current limitation that organics have barely luminescence. We observed variation of photoluminescence on graphene oxide based solution with Gold nanoparticle. Gold nanoparticles lead to shift the peak wavelength of graphene oxide and to enhance the photoluminescence intensity totally. This shows the possibility that control the luminescence property of graphene oxide by adding gold nanoparticle.

pH and Micellar Effects on the Quenching of Tris(2,2'-bipyridine)Ruthenium(Ⅱ) Luminescence by 1-Alkyl-4,4'-bipyridinium : Evidence of Deep Enbedment of the Quencher Cations in Sodium Dodecyl Sulfate Micelle

  • 박준우;김유나
    • Bulletin of the Korean Chemical Society
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    • v.18 no.2
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    • pp.185-189
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    • 1997
  • The effect of pH and sodium dodecyl sulfate (SDS) micelle on the quenching of Ru(bpy)32+ luminescence by N-alkyl-4,4'-bipyridinium ions (RBPY+: R=methyl, octyl, dodecyl, benzyl) were investigated. In the absence of SDS, the quenching rate at pH 2 is similar to that of the corresponding methylalkyl viologens and much greater than that in pH 8 solution due to greater reducibility of the protonated form of RBPY+ (HRBPY2+). The quenching rate at pH 2 is strongly enhanced by the presence of SDS, while that at basic pH is greatly retarded. These observations are explained by deep embedment of RBPY+ into the hydrophobic hydrocarbon region of the micelle, whereas Ru(bpy)32+ and HRBPY2+ locate in the Stern layer of the micelle.