• Title/Summary/Keyword: Low temperature phase

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Nitrogen Monoxide Gas Sensing Properties of Copper Oxide Thin Films Fabricated by a Spin Coating Method (스핀코팅법으로 제작한 산화구리 박막의 일산화질소 가스 감지 특성)

  • Hwang, Hyeonjeong;Kim, Hyojin;Kim, Dojin
    • Korean Journal of Materials Research
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    • v.25 no.4
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    • pp.171-176
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    • 2015
  • We present the detection characteristics of nitrogen monoxide(NO) gas using p-type copper oxide(CuO) thin film gas sensors. The CuO thin films were fabricated on glass substrates by a sol-gel spin coating method using copper acetate hydrate and diethanolamine as precursors. Structural characterizations revealed that we prepared the pure CuO thin films having a monoclinic crystalline structure without any obvious formation of secondary phase. It was found from the NO gas sensing measurements that the p-type CuO thin film gas sensors exhibited a maximum sensitivity to NO gas in dry air at an operating temperature as low as $100^{\circ}C$. Additionally, these CuO thin film gas sensors were found to show reversible and reliable electrical response to NO gas in a range of operating temperatures from $60^{\circ}C$ to $200^{\circ}C$. It is supposed from these results that the p-type oxide semiconductor CuO thin film could have significant potential for use in future gas sensors and other oxide electronics applications using oxide p-n heterojunction structures.

Effects of Warm-up Performance on SI Engine with Exhaust Heat Recovery System (배기열 회수장치 적용에 따른 SI 엔진의 웜업 성능에 미치는 영향)

  • Park, Kyoun-Suk;Suh, Ho-Cheol;Park, Sun-Hong;Kim, In-Tae;Jang, Sung-Wook
    • Transactions of the Korean Society of Automotive Engineers
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    • v.19 no.6
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    • pp.53-60
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    • 2011
  • The effect of exhaust heat recovery system can be evaluated by two well known method. First method is to measure the time duration from engine start under cold coolant temperature till coolant get warmed. By this methodology coolant warming duration can be index of warm-up effect. Second method is to analyze heat balance of the engine during warm-up phase under steady engine operation so that wasted energy by losses such as cooling and exhaust can be index of warm-up effect. This study focused on evaluation of warming-up effect by both methodology above mentioned using 2L SI engine under from idle to 2000rpm steady condition. Results, idle operation showed low heat recovery efficiency but under higher engine speed condition, remarkable heat recovery efficiency improvement was observed. In 2000rpm steady condition, warm-up duration of engine is decreased by exhaust heat recovery system.

Heat Transfer Correlation to Predict the Evaporation of a Water Droplet in Superheated Steam during Reflood Phase of a LOCA

  • Kim, Yoo;Ban, Chang-Hwan
    • Journal of Energy Engineering
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    • v.9 no.3
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    • pp.261-268
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    • 2000
  • A heat transfer correlation to predict the vaporization of a water droplet in highly superheated steam during a loss-of-coolant accident(LOCA) of a nuclear power plant is provided. Vaporization of liquid fuel or water droplets in superheated air or steam and subsequent interface heat transfer between a liquid droplet and superheated gas is typically correlated by way of a Nusselt number as a function of Reynolds number, Prantl number, and in some cases including mass transfer number. Presently available correlations and experimental data of the evaporation of liquid droplets in air or steam are analyzed and a new Nusselt number correlation is proposed taking Schmidt number into consideration in order to account for binary diffusion of the vapor as well, Nu$\_$f/(1+B)$\^$0.7/=2+0.53Sc$\_$f/$\^$-1/5/Re$\_$M/$\^$$\sfrac{1}{2}$/Pr$\_$f/$\^$$\sfrac{1}{3}$/ for which properties are evaluated at film condition except the density of Reynolds number evaluated at ambient condition. Diverse correlations for various combinations of liquid and gas species are put into single equation. The blowing correction factor of (1+B)$\^$0.7/ is confirmed appropriate, and a criterion to distinguish so-called high- and low-temperature condition of ambient gas is set forth.

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Adhesion improvement between metal and ceramic substrate by using ISG process (ISG법에 의한 금속과 세라믹기판과의 밀착력 향상)

  • 김동규;이홍로;추현식
    • Journal of the Korean institute of surface engineering
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    • v.32 no.6
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    • pp.709-716
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    • 1999
  • Ceramic is select for an alternative substrate material for high-speed circuits due to its low-thermal expansion. As, in this study, ceramic was prepared by ISG (interlayer sol-gel) process using metal salts and a metal alkoxide as the starting materials. Generally ceramic substrate is used electroless copper plating for the metallization. But it has been indicate weakely the adhesion strength between the substrate and copper layer. Therefore, this research, using the ISG process on the preparation of homogeneous and possible preparation at law temperature fabricated sol solution. Using of the dip coating method was coated for the purpose of giving the anchoring effect on the coating layer and enhancing the adhesion strength between the $Al_2$O$_3$ substrate and copper layer. This study examined primary the characteristic of the sol making condition and differential thermal analysis (DTA) X-ray diffraction (XRD) were mearsured to identify the crystal phase of heat treatment specimens. The morphology of the coated films were studied by scanning electron microscopy(SEM). As a resurt, XRD analysis was obtained patterns of $\alpha$-cordierite after heat-treatment about 2 hours at $1000^{\circ}C$. SEM analysis could have seen a large number of voids on coated film. The more contants of$ Al_2$$O_3$ Wt% was increased the more voids was advanced. Peel adhesion strength has a maximum in the contants of the TEOS:ANE of 1:0.7 mole%. In this case, adhesion strength has been measured 1150gf, peel adhesion strength were about 10 times more than uncoated of the ceramics film.

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Effects of the SiC Particle Size and Content on the Sintering and Mechanical Behaviors of $Al_2O_3$/SiC Particulate Composites

  • Ryu, Jung-Ho;Lee, Jae-Hyung
    • The Korean Journal of Ceramics
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    • v.3 no.3
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    • pp.199-207
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    • 1997
  • $Al_2O_3$/SiC particulate composites were fabircated by pressureless sintering. The dispersed phase was SiC of which the content was varied from 1.0 to 10 vol%. Three SiC powders having different median diameters from 0.28 $\mu\textrm{m}$ to 1.9 $\mu\textrm{m}$ were used. The microstructure became finer and more uniform as the SiC content increased except the 10 vol% specimens, which were sintered at a higher temperature. Under the same sintering condition, densification as well as grain growth was retarded more severly when the SiC content was higher or the SiC particle size was smaller. The highest flexural strength obtained at 5.0 vol% SiC regardless of the SiC particle size seemed to be owing to the finer and more uniform microstructures of the specimens. Annealing of the specimens at $1300^{\circ}C$ improved the strength in general and this annealing effect was good for the specimens containing as low as 1.0 vol% of SiC. Fracture toughness did not change appreciably with the SiC content but, for the composites containing 10 vol% SiC, a significantly higher toughness was obtained with the specimen containing 1.9$\mu\textrm{m}$ SiC particles.

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Design and analysis of a signal readout integrated circuit for the bolometer type infrared detect sensors (볼로미터형 적외선 센서의 신호처리회로 설계 및 특성)

  • Kim, Jin-Su;Park, Min-Young;Noh, Ho-Seob;Lee, Seoung-Hoon;Lee, Je-Won;Moon, Sung-Wook;Song, Han-Jung
    • Journal of Sensor Science and Technology
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    • v.16 no.6
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    • pp.475-483
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    • 2007
  • This paper proposes a readout integrated circuit (ROIC) for $32{\times}32$ infrared focal plane array (IRFPA) detector, which consist of reference resistor, detector resistor, reset switch, integrated capacitor and operational amplifier. Proposed ROIC is designed using $0.35{\;}{\mu}m$ 2P-4M (double poly four metal) n-well CMOS process parameters. Low noise folded cascode operational amplifier which is a key element in the ROIC showed 12.8 MHz unity-gain bandwidth and open-gain 89 dB, phase margin $67^{\circ}$, SNR 82 dB. From proposed circuit, we gained output voltage variation ${\Delta}17{\};mV/^{\circ}C$ when the detector resistor varied according to the temperature.

Structure and Stability of γ-Aminobutyric acid-(H2O)n (n = 0-5) Clusters: Zwitterionic vs. Canonical forms

  • Kim, Ju-Young;Schermann, Jean Pierre;Lee, Sung-Yul
    • Bulletin of the Korean Chemical Society
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    • v.31 no.1
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    • pp.59-63
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    • 2010
  • Calculations are presented for the $\gamma$-aminobutyric acid-$(H_2O)_n$ (n = 0-5) clusters in both canonical and zwitterionic forms. We examine the effects of microsolvation on the structures and transformation between the canonical and zwitterionic forms. The canonical forms are predicted to be more stable for n = 0-4. With five microsolvating water molecules, the two forms of $\gamma$-aminobutyric acid become quasidegenerate, with the energies of zwitterionic forms slightly (by 1 - 3 kcal/mol) higher. The lowest energy zwitterionic conformer of $\gamma$-aminobutyric acid-$(H_2O)_5$ cluster is calculated to isomerize to canonical form through a barrier-less proton transfer process and is thus predicted to be kinetically unstable. Therefore, we predict that the canonical conformers of $\gamma$-aminobutyric acid should be observed predominantly in the gas phase at low temperature in presence of up to five water molecules.

Evaporating Heat Transfer Characteristics of R-l34a in a Horizontal Smooth Channel

  • Pamitran, A.S.;Choi, Kwang-Il;Oh, Jong-Taek;Oh, Hoo-Kyu
    • International Journal of Air-Conditioning and Refrigeration
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    • v.14 no.4
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    • pp.156-165
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    • 2006
  • Convective boiling heat transfer coefficients were measured in a horizontal minichannel with R-l34a. The test section was made of stainless steel tube with an inner diameter of 3.0 mm and a length of 2m. It was uniformly heated by applying electric current directly to the tube. Local heat transfer coefficients were obtained for heat fluxes from 10 to $40kW/m^2$, mass fluxes from 200 to $600kgT/m^2s$, qualities up to 1.0, and the inlet saturation temperature of $10^{\circ}C$. The experimental results were mapped on Wojtan et $al.'s^(7)$ and Wang et $al.'s^(8)$ flow pattern maps. The nucleate boiling was predominant at low vapor quality whereas the convective boiling was predominant at high vapor quality. Laminar flow appeared in the flow with minichannel. The experimental results were compared with six existing two-phase heat transfer coefficient correlations. A new boiling heat transfer coefficient correlation based on the superposition model for refrigerants was developed with mean and average deviations of 10.39% and -3.66%, respectively.

Preparation and Their Properties of Hot-Melt Adhesive using Styrene Block Copolymer and Petroleum Resin (스타이렌 블록 공중합체(SBC)와 석유수지를 이용하여 제조한 핫멜트 접착제의 제조 및 특성)

  • Jeong, Booyoung;Cheon, Jungmi;Yoo, Chongsun;Chun, Jeahwan
    • Journal of Adhesion and Interface
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    • v.9 no.4
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    • pp.12-16
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    • 2008
  • Hot-melt adhesive was solid phase in room temperature as 100% solid contents. So it has advantage which attach to substrate with the low pressure heat, fast adhesion speed and environment friendly. In this study, We studied about the effect of a kind of SBS resin and petroleum resin as a tackifier resin and their ratio for hot-melt adhesive on properties. The styrene and $C_9$ resin contents in hot-melt adhesive was increased with increasing viscosity, tensile strength, peel strength and thermal resistance.

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Field Emission Characteristics of Deffctive Diamond Films

  • Koh, Ken-Ha;Park, Kyung-Ho;Lee, Soon-Il
    • Journal of the Korean Vacuum Society
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    • v.7 no.s1
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    • pp.160-166
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    • 1998
  • The field emission characteristics of defective diamond films grown by microwave plasma enhanced chemical vapor deposition (MPECVD) have been studied. X-ray diffraction, the poor crystal quality and/or small grain sizes of the diamond phase and the inclusion of the non-diamond carbon phases in these films have been condirmed by raman spectroscopy, scanning electron microscopy, atomic force microscopy, and the reflectance measurements. The degrees of the film defectiveness and the emission characteristics were dependent on the methane concentration. Current-versus-voltage measurements have demonstrated that the defective diamond films have good electron emission characteristics. characteristics strongly suggests the defect-related electron-emission mechanism. The defective diamond films deposited on Si substrates show the field emission current density of 1$\mu\textrm{A}/\textrm{cm}^2$ and 1mA/$\textrm{cm}^2$ have been measured at electric fields as low as 4.5V/$\mu\textrm{m}$ and 7.6V/$\mu\textrm{m}$, respectively. We also observed the similar emission characteristics from the defective diamond film deposited on Cr/Si substrate and could decrease the deposition temperature to $600^{\circ}C$.

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