• Membrane Journal
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• v.26 no.3
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• pp.187-196
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• 2016

Pressure-assisted forward osmosis (PAFO) process has recently been under spotlight for its potential to improve forward osmosis (FO) process performance by applying low hydraulic pressure on the feed side. Structure parameter, one of the governing factors in estimating water flux and solute flux across FO membranes in the solution-diffusion model (S-D model), determines solute resistivity in FO and PAFO processes. This study aims to estimate the trend of structure parameter change with respect to varying additional hydraulic pressure condition in PAFO.

• Membrane Journal
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• v.11 no.3
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• pp.109-115
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• 2001

Pore-filled ion-exchange membranes in which polypropylene(PP) microporous membrane was used as a nascent membrane were prepared by an in-situ cross-linking technique. Poly(vinylbenzyl chloride)(PVBCI) reacted with piperazine(PIP) or 1,4-diaminobicyclo[2,2,2]octane(DABCO) in a di-methylforamide(DMF) solution was filled in the pores of the microporous base membrane. After gellation the remaining chloromethyl groups were, then reacted with an amine such as trimethylamine to form positively charged, ammonium site. This will produce the pore-filled anion-exchange membrane. It was shown that this simple 2 step procedure gave dimensionally stable, pore-filled membranes in which the MG of polymer gel and degree of cross-linking could be easily controlled by the concentration of PVBCI and cross-linker in the starting DMF solution. Specially, high water permeability (7.8 kg/$m^2$hr, host membrane: PP3, MG: 73%, degree of cross-linking: 10%, crosslinker: PIP) at ultra low pressure(100 kPa) indicates the produced pore-filled membranes is usable as a water softening membrane.

• Membrane Journal
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• v.30 no.6
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• pp.385-394
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• 2020

In the gas separation process, the separation membranes have to not only show high gas transport and selectivity but also exhibit exceptional stability at high temperature and pressure. However, when the polymeric membranes (particularly, glassy polymers) are exposed to the condensable gases (i.e., CO2, H2S, hydrocarbon, etc.), the polymer chains are prone to swell, leading to low stability. As a result, the plasticization behavior reduces the gas selectivity in the separation of mixture gases at high pressures and thus results in limited applications to the separation processes. To address these issues, many strategies have been studied such as thermal treatment, polymer blending, thermally rearrangement, mixed-matrix membranes, cross-linking, etc. In this review, we will understand the plasticization behavior and suggest potential methods based on the previously reported studies.

• Proceedings of the Membrane Society of Korea Conference
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• 1995.06a
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• pp.39-50
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• 1995

The membrane processes that are commonly uscd in water and wastewater treatment are reverse osmosis (Ro), ultrafiltration (UF) and microfiltration (MF), which utilize pressure differentials. There is also nano-filtration (NF), or low-pressure reverse osmosis, which is positioned midway between conventional reverse osmosis and ultrafiltration. Reverse osmosis membranes reject dissolved ions, while ultrafiltration can be used to reject relatively larger molecules, such as protein, polysacchalides and so on. Microfiltration is capable of eliminating particles at submicron level. This paper summarizes the characteristics of MSAS process first, as it is the main membrane process applied to wastewater treatment. Two successful examples of the applications, the cases of individual building reuse system and nightsoil treatment, are then shown. The latest trend of new membrane applications, i.e., immersed-type MSAS is also introduced.

• Membrane Journal
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• v.17 no.3
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• pp.161-173
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• 2007

Membrane filtration processes are increasingly popular for drinking water treatment that requires high quality of water. Low pressure membrane(LPM) processes such as microfiltration(MF) and ultrafiltration(UF), however, are ineffective in the removal of dissolved organic matter and also membrane fouling is still an important issue to be resolved. High pressure membranes(HPMs) may guarantee better water quality, but at the high energy consumption. Thus, various approaches to combine LPM processes with other physicochemical methods have been recently made to achieve their efficiency to the level comparable to that of HPM processes. In this work, therefore, hybrid processes that coupled MF/UF with coagulation, adsorption, chemical reactions(e.g., chelation and oxidation) are reviewed regarding system design and performance and also membrane surface modifications conducted by grafting and polyelectrolyte multilayer formation were assessed.

• Journal of Biomedical Engineering Research
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• v.23 no.1
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• pp.27-32
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• 2002

The purpose of this study was to evacuate the effects of the number of tied hollow fibers in a novel membrane oxygenator that satisfied the limiting factor of minimizing the friction loss in the intravascular blood flow Pattern. The membrane oxygenator is a bundle consisted of several hundred ho1low fibers haying the outside diameter of 380 $\mu m$ and the axial jacket length of 600 mm. The eight different variation of tied hollow fibers in a bundle were designed. and the liquid flow pattern was controlled by a pump. The liquid pressure drop was measured by in vitro experiments using water and g1ycero1. Uniform blood flow pattern was observed for each number of tied hollow fibers. Pressure drop was 13-16 mmHg outside of the membrane oxygenator consisting of up to 700 ho1low fibers. More effective contact of liquid with the tied ho1low fibers was observed as a decrease in the number of the tied hollow fibers. and resulted in the enhancement of the friction tractor

• Applied Chemistry for Engineering
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• v.24 no.5
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• pp.456-470
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• 2013

Hollow-fiber membranes, is one of the new technologies that is growing rapidly in the past few decades. In addition, separation membranes using polymer materials, have attracted attentions in various fields including gas separation, fuel cells, water treatment, wastewater treatment, and organic separation. Nanofiltration (NF) membranes having the separation characteristics in the intermediate range between ultrafiltration and reverse osmosis (RO) membranes for liquid separation, with relatively low investment cost and operating pressure lower than that of RO membranes, have high permeance and rejection performance of multivalent ions as well as organic compounds of molecular weight between $200{\sim}1000gmol^{-1}$. In this paper, we would like to review the research trends on the various structure control and characterization of NF hollow fiber membranes with respect to materials and the methods of preparation (phase inversion method and interfacial polymerization method). Currently, most of NF membranes have been manufactured by plate and frame types or spiral wound types. But hollow fiber types have delayed in commercial products, because of the weak strength when to produce on the basis of the existing materials, therefore the development of new materials or improvement of existing materials will be needed. If improving manufacturing technology is available, hollow fiber types will replace spiral wound types and gradually show a higher market share.

• Proceedings of the Membrane Society of Korea Conference
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• 2002.04a
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• pp.23-46
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• 2002

The cryogenic, pressure swing adsorption and membrane methods have been used to separate air into nitrogen and oxygen. The air separation membrane is made of the polymers, of which manufacturing process is complicate and it causes a little high production cost. Polymer membrane has temperature limit in usage and low durability even at moderate temperature. Therefore, inorganic membranes have been studied for years. As formation of unit alumino-silicate membrane, unit cells of membrane were made with a few coating methods. In this study the dipping of substrate into sols, application of vacuum to the opposite side of substrate with coating and rotating of the substrate in the sols were found as good coating memthods to make a uniform coating and to control the thickness of membrane. The membrane coats were examined by SEM and XRD. The sample ESZl-1 was compared with those of samples that prepared by another method. The present developed coating methods could be applied to the various types of zeolite membrane formation, that is A- X-, Y- ZSM- and MCM-types of membranes. Also these membrane forming methods could be applied to formation of catalyst absorbed zeolite membrane, of which zeolite absorb the catalytic metals. The product obtained from these coating methods could be applied to the industrial gas and liquid phase catalytic reaction and separation processes.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2008.03a
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• pp.866-870
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• 2008

In this study, we designed cold gas propulsion system with minimum 0.25 mm nozzle and micro-thrust measurement system to analyze flow characteristic of micro propulsion system in ambient and vacuum condition. Argon and Nitrogen are used for propellant and the result of experiments is compared with CFD analysis and theory. But there is a point where reduced scale versions of conventional propulsion systems will no longer be practical. Therefore, a fundamentally different approach to propulsion systems was taken. That is thermal transpiration based micro propulsion system. It has no moving parts such as lubricants, pressurizing system and can pump the gaseous propellant by temperature gradient only(cold to hot). We are advancing basic research of propulsion system based on thermal transpiration in vacuum conditions and had tried experiment process and theoretical access in advance. To characterize membrane of Knudsen pump, we select Polyimide material that has low thermal conductivity(0.29 W/mK) and can stand high temperature($300^{\circ}C$) for long time. And we fabricated hole diameter 1, 0.5, 0.2, 0.1 mm using precision manufacturing. Experimental results show that pressure gradient efficiency of Knudsen pump is increased to maximum 82% according to Knudsen number and thick membranes are more effective than thin membranes in transition flow regime.

• Membrane and Water Treatment
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• v.8 no.2
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• pp.185-199
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• 2017

Low-pressure membrane filtration is increasingly used for tertiary treatment of wastewater effluent organic matter (EfOM), mainly comprising organic base/neutral compounds. In-line coagulation with underdosing, charge neutralization, and sweep floc conditions prior to ultrafiltration (UF) was studied to determine removals of the EfOM components and consequent reduction of fouling using polyethersulfone membranes. Coagulation and UF substantially reduced fouling for all coagulation conditions while removing from 7 to 38% of EfOM organic acids. From 7 to 16% of EfOM organic base/neutrals were removed at neutral pH but there was no significant removal for slightly acid coagulation conditions even though fouling was substantially reduced. Sweep floc produced the lowest resistance to filtration but may be inappropriate for in-line use due to the large added volume of solids. Charge-neutralization resulted in poor recovery of the initial flux with hydraulic cleaning. Under-dosing paralleled sweep floc in reducing hydraulic resistance to filtration (for sub-critical flux) and the initial flux was also easily recovered with hydraulic cleaning. Hydrophobic and hydrophilic base/neutrals were identified on the fouled membranes but as previously reported the extent of fouling was not correlated with accumulation of organic base/neutrals.