• Title/Summary/Keyword: Low heavy oil

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The Study on Characteristics of Polystyrene by Low Temperature Pyrolysis by using Co and Mo Dispersed Catalysts (Co 및 Mo 기반 촉매에 의한 폴리스티렌의 저온 열분해 특성에 관한 연구)

  • Park, Jun-Gyu;Kim, Jae-Kon;Lee, Bong-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.4
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    • pp.676-685
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    • 2016
  • This study investigated the conversion of oil products from polystyrene by using dispersed Co and Mo catalyst on reaction time and concentration change for knowledging on characteristics at low temperature (425, 450 and $475^{\circ}C$) pyrolysis and reaction time(20~80 min, 15 min interval) in a batch reactor. It will be showed the conditions for optimum pyrolysis at reaction temperature $450^{\circ}C$ and the reaction time 35min, and the main components of the converted liquid oil were styrene and benzene derivatives by GC/MS. The oil products formed during pyrolysis were classified into gas, gasoline, kero, diesel and heavy oil according to the domestic specification of petroleum products. The pyrolysis conversion rate was showed as Co catalyst > Mo catalyst > Thermal in all reaction time at reaction temperature $450^{\circ}C$. The yields rate of gas, kerosine, diesel were the most hight at Mo Catalyst, gasoline was at thermal and heavy oil was at Co catalyst. The conversion rate and yields of the pyrolysis products were the most height when Co catalyst ratio was 100%.

Studies on Pyrolysis Behaviour of Banana Stem as Precursor for Porous Carbons

  • Manocha, Satish;Bhagat, Jignesh H.;Manocha, Lalit M.
    • Carbon letters
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    • v.2 no.2
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    • pp.91-98
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    • 2001
  • Porous carbons have been prepared from different parts of banana stems using two different routes, viz., by pyrolysing the mass at different temperatures as well as by treating the dried mass with chemicals followed by pyrolysis. The pyrolysis behaviour of all these materials has been studied up to $1000^{\circ}C$. Samples treated with acids exhibit more increase in surface area as compared to those treated with alkalies or salts. Analysis of BET surface area shows that the carbon prepared at low temperature shows mixed porosity, i.e., micro and mesopores. Samples heated to high temperature above $700^{\circ}C$ show decrease in macroporosity and increase in microporosity. Liquid adsorption studies have been made using methylene blue and heavy oil. The activated carbons so prepared exhibit higher oil adsorption mainly in the macro and mesopores.

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Life-Time Prediction of HNBR Diaphragm in Oil Reservoir (유압구동장치 동력원용 고무 다이아프램 저유기의 수명 예측 연구)

  • Kim, Sol A
    • Journal of Drive and Control
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    • v.18 no.2
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    • pp.32-37
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    • 2021
  • The piston reservoir is mainly used in hydraulic blow-down system for aerospace engineering. The reservoir is heavy due to both hydraulic cylinder and piston in pressurization. The positive expulsion tank with rubber diaphragm has been mostly applied propellant and fuel tank at low pressure to satellites. To reduce weight, the reservoir that can be used at high pressure with rubber diaphragm was developed. In this research, the prediction of life-time for the rubber diaphragm was implemented through an accelerated life test, as a part of development of new reservoir. Also, the diaphragm was stored in an temperature chamber at the same condition as and operation with hydraulic oil. As a result, the life-time for a rubber diaphragm was successfully evaluated via Arrhenius law and Time-Temperature Superposition based on failure times over temperatures in the accelerated test.

A study on the Stable Supply of Fishery Oil in Korea (어업용 유류의 안정적인 공급에 관한 연구)

  • 강연실;이광남
    • The Journal of Fisheries Business Administration
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    • v.31 no.1
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    • pp.115-133
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    • 2000
  • The policy of suppling tax-exempt fishery oil in Korea has a history of almost 40 years, which was initiated by the National Federation of Fisheries Cooperatives in 1965. In 1999 the volume of fishery oil supplied to the earning fishermen and fishing entrepreneurs amounted to 8,390 thousand DM, 500 billion won in total. This paper analyzes the oil supplying system to fishermen in Korea and shows that the structural obstacles to the stable provision of fishery oil lies in the ineffective bargaining power (fixing price). Provided that the NFFC as a buyer, which is not equipped with the storage facilities for oil bids for a unit-price contract of fishery oil, there exists a possibility of collusion among 5 local oil refineries corporations to influence the oil price, making it difficult to reach a resonable price of oil. Though the international bids and direct imports following the liberalization of oil imports would help lower the unit price, purchasing and importing the oil out of season at a lower price would not be guaranteed without the oil storage facilities. Furthermore, the current supply system of oil is quite vulnerable to the extraneous factors and, say when the oil price soars unpredictably, it is almost impossible to supply low - priced fishery oil to fishermen. The National Federation of Fisheries Association of Japan(Zengyoren), for instance, possesses 10 oil storage facilities, which had been built across the country during the last 20 years (1964-1984). The storage capacity of these facilities reaches 0.6million DM(by kind, 0.56million DM for A heavy oil, 38thousand D/M kerosene, 5thousand D/M for diesel fuel oil). Allowing no intermediary of production associations(fisheries cooperatives) the NFFA's capacity for keeping oil in reserve rises much higher. As these storage facilities can keep the oil amounting to as much as of 70 days demand in reserve, a stable supply of fishery oil on favorable terms is secured. In contrast with Japan case, unequipped with the storage facilities for fishery oil, Korea does not have much bargaining power for bringing down the price of fishery oil. To make matters worse, the oil storing capacity of the member cooperatives is the volume of only 8 days demand. In case the oil price rises, it is almost impossible to supply the oil to the fishermen at a price lower than the price risen.

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Study of heavy fuel oil fly ash for use in concrete blocks and asphalt concrete mixes

  • Al-Osta, Mohammed A.;Baig, Mirza G.;Al-Malack, Muhammad H.;Al-Amoudi, Omar S. Baghabra
    • Advances in concrete construction
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    • v.4 no.2
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    • pp.123-143
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    • 2016
  • Use of heavy fuel fly ash (HFFA) (diesel and cracked fuel) for power generation in Saudi Arabia has generated and accumulated large quantities of HFFA as a byproduct. In this research, HFFA is studied with the emphasis on the utilization of this waste material in concrete blocks and asphalt concrete mixes. Two types of mixes, one with low and other with high cement content, were studied for concrete blocks. Different mixes having varying percentages of HFFA (0% to 25%), as cement/sand replacement or as an additive, were studied. The performance of concrete blocks is evaluated in terms of compressive strength, water absorption, durability and environmental concerns. The results showed that blocks cannot be cast if more than 15% HFFA is used; also there is a marginal reduction in the strength of all the mixes before and after being exposed to the sulfate solution for a period of ten months. HFFA is studied in asphalt concrete mixes in two ways, as an asphalt modifier (3&5%) and as a filler (50%) replacement, the results showed an improvement in stiffness and fatigue life of mixes. However, the stability and indirect tensile strength loss were found to be high as compared to the control mix due to moisture damage, indicating a need of using antistripping agents. On environmental concerns, it was found that most of the concerned elements are within acceptable limits also it is observed that lower concentration of barium is leached out with the higher HFFA concentrations, which indicates that HFFA may work as an adsorbent for this leaching element.

Introduction of KIER Pyrolysis Process and 3,000 ton/yr Demonstration Plant (KIER의 열분해유화 공정 기술과 실증플랜트 소개)

  • Shin, Dae-Hyun;Jeon, Sang-Gu;Kim, Kwang-Ho;Lee, Kyong-Hwan;Roh, Nam-Sun;Lee, Ki-Bong
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.479-482
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    • 2008
  • Since late of 2000, KIER has developed a novel pyrolysis process for production of fuel oils from polymer wastes. It could have been possible due to large-scale funding of the Resource Recycling R&D Center. The target was to develop an uncatalyzed, continuous and automatic process producing oils that can be used as a fuel for small-scale industrial boilers. The process development has proceeded in three stages bench-scale unit, pilot plant and demonstration plant. As a result, the demonstration plant having capacity of 3,000 tons/year has been constructed and is currently under test operation for optimization of operation conditions. The process consisted of four parts ; feeding system, cracking reactor, refining system and others. Raw materials were pretreated via shredding and classifying to remove minerals, water, etc. There were 3 kind of products, oils(80%), gas(15%), carbonic residue(5%). The main products i.e. oils were gasoline and diesel. The calorific value of gas has been found to be about 18,000kcal/$m^3$ which is similar to petroleum gas and shows that it could be used as a process fuel. Key technologies adopted in the process are 1) Recirculation of feed for rapid melting and enhancement of fluidity for automatic control of system, 2) Tubular reactor specially-designed for heavy heat flux and prevention of coking, 3)Recirculation of heavy fraction for prevention of wax formation, and 4) continuous removal & re-reaction of sludge for high yield of main product (oil) and minimization of residue. The advantages of the process are full automation, continuous operation, no requirement of catalyst, minimization of coking and sludge problems, maximizing the product(fuel oil) yield and purity, low initial investment and operation costs and environment- friendly process. In this presentation, background of pyrolysis technology development, the details of KIER pyrolysis process flow, key technologies and the performances of the process will be discussed in detail.

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A Study on the Development of Educational Programs for LNG Bunkering in Consideration of the Safety System

  • Han, Se-Hyun;Yun, Yong-Sup;Kim, Jong-Su;Lee, Young-Chan
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.22 no.3
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    • pp.268-277
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    • 2016
  • This paper aims at presenting bunkering educational programs for LNG fueled ship taking into consideration existing similar education programs and safety systems at the international level in order to enhance both seafarers' and vessels' safety. Heavy fuel oil has typically been used as fuel of ship propulsion. The competitiveness of the fuel oil is recently getting weak in terms of cost and environmental aspects. Liquefied natural gas is introduced for ship propulsion in the maritime field as a new energy source replacing heavy fuel oil. In order to prepare for installation and operation of LNG fueled propulsion ship on board, International Maritime Organization has discussed this subject for about 10 years. As a result of the discussion on such ships in IMO, the International Code of Safety for Ships Using Gases or Other Low-Flash-Point Fuels entered into force on the year 2015. International organizations and several countries therefore drives actively entire researches and other businesses with a view to providing equipment and system of LNG bunkering. The systems are divided into ship-to-ship transfer, terminal / pipeline-to-ship transfer and truck-to-ship transfer. By adopting transfer system of LNG bunkering, many human resources will be needed in these areas on scene as well as on managing, operating, trading, finance, design of LNG bunkering industries. LNG bunkering is just in the beginning stage. Hence, this paper reviews and proposes professional educational programs of LNG bunkering in consideration of technical aspects of the safety system of LNG bunkering based on the types of bunkering systems.

Development of Large Propulsion Motor Bearings Considering Slope Conditions (경사조건을 고려한 대용량 추진 전동기용 베어링 개발에 대한 연구)

  • Oh, Seung Tae;Choi, Jin Woo;Kang, Byeng Hi;Kim, Jin;Choi, Seong Pil;Bin, Jae Goo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.37 no.2
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    • pp.241-248
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    • 2013
  • In this study, bearings were developed for a high-power propulsion motor operating in inclined operation conditions through a simulation and similitude-experimental methods using commercial rotating machinery dynamics analysis software. The developed journal bearing is electrically insulated and has low thermal conductivity because each part is connected with 2-4 -mm-thick epoxy plates. To realize an appropriate oil thickness, an oil lift system is adopted, and a half separated structure is applied to ensure the feasibility of maintaining very heavy components. This study discusses some of the key design aspects of sleeve bearing design for high-torque and low-speed propulsion motor applications. Furthermore, the conditions of variable slope tests are examined to prevent oil leakage from the bearing lip seal on the test rig.

A Performance Analysis of Gas Turbine Using Low Caloric Value Syngas Fuel (저열량의 합성가스 연료를 사용한 가스터빈의 성능해석)

  • 서석빈;김종진;안달홍;이성노;박종호
    • Journal of Energy Engineering
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    • v.11 no.3
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    • pp.187-193
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    • 2002
  • IGCC (Integrated Gasification Combined Cycle) power plant is becoming more attractive because it allows that various fuels like coal, heavy oil md even residue oil and wood are used in a gas turbine. This paper presents a prediction of performances of gas turbine when low caloric value syngas fuels produced from the IGCC is used in it originally designed with natural gas fuel. Using a systemic method which predicts a gas turbine behavior with limited design data, when natural gas, design fuel and four other types of syngas are used in GE 7FA gas turbine, its performances are predicted on design and off-design conditions.

Size Distribution and Source Identification of Airborne Particulate Matter and Metallic Elements in a Typical Industrial City

  • Ny, Mai Tra;Lee, Byeong-Kyu
    • Asian Journal of Atmospheric Environment
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    • v.4 no.1
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    • pp.9-19
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    • 2010
  • The size distribution of airborne particulate matter (PM) and the concentrations of associated metallic elements were investigated in a busy urban region of a typical Korean industrial city. The PM concentrations measured during the spring, except for those in the size range of 1.1 to 2.1 ${\mu}m$, were slightly higher than the PM concentrations in the summer. Coarse particles contributed greatly to the variation in PM concentrations in the spring, while fine and submicron particles contributed largely to the variation in PM concentrations in the summer. The difference in size modes of the PM concentrations between spring and summer may be explained by the Asian dust effect and its accompanying wind direction and speed. Extremely high enrichment factors (EFs) values (6,971 to 60,966) for all of the size distributions in PM were identified for cadmium (Cd). High EFs values (12 to 907) were also identified for other heavy metals including Cr, Cu, Ni, Pb, Zn and Mn. Low EF values (0.29 to 8.61) were identified for Ca, K, Mg and Na. These results support the common hypothesis that most heavy metals in ambient PM have anthropogenic sources and most light metals have crustal sources. The results of principal components analyses and cluster analyses for heavy metals indicate that the principal sources of PM and metals were emissions from non-ferrous metal smelters, oil combustion, incinerators, vehicular traffic and road dust.