• 제목/요약/키워드: Low flow oxygen

검색결과 250건 처리시간 0.029초

DEMS(Diethoxymethylsilane) precursor를 이용한 PECVD 저유전물질 박막증착연구 (The study on low dielectric thin film deposition using DEMS precursor by PECVD)

  • 강민구;김대희;김영철;서화일
    • 반도체디스플레이기술학회지
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    • 제7권4호
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    • pp.35-39
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    • 2008
  • We studied deposition of low-k SiOCH dielectric film by PECVD. DEMS(diethoxymethlysilane) precursor, which has two ethoxy groups along with one methyl group attached to the silicon atoms, was used as precursor. The SiOCH film was deposited as a function of oxygen flow rates ranging from 0 to 100sccm. The deposition rate($\AA$/min) of SiOCH film was increased due to the increase of oxygen radical as a function of $O_2$ flow rates. The dielectric constant was decreased from 3.0 to 2.77, as the film was annealed at $450^{\circ}C$ for 30 min. So, it could account that the dielectric constant changes sensitively with $O_2$ flow rates. Also, the leakage current of the annealed film exhibited stable curve than that of asdeposited. These results were caused by the increase of Si-O-Si group and decrease of Si-CH group and OH group within the film by annealing.

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XRD 분석에 의한 결정구조와 PL 분석에 의한 광학적 특성의 상관성 (Relationship between Optical Properties Analyzed by Photoluminance of Bonding Structure Analyzed by X-ray Diffractometer)

  • 오데레사
    • 반도체디스플레이기술학회지
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    • 제15권1호
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    • pp.70-75
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    • 2016
  • GZO films prepared on ITO glasses were annealed at various temperatures in a vacuum condition to research the relationship between oxygen vacancies and optical properties. GZO films after annealing in a vacuum showed the various optical-chemical properties depending on the annealing temperatures and oxygen gas flow rate during the deposition. The oxygen vacancy of GZO film prepared by oxygen gas flows of 22 sccm increased with increasing the annealing temperatures, because of the extraction of oxygen by the annealing. But the intensity of photoluminance of GZO with 22 sccm decreased in accordance with the annealing temperature, because of the reduction of ionized charge carriers. The oxygen vacancy by the extraction of oxygen enhanced a depletion, so the widen depletion had the strong Schottky barrier and the PL intensity due to the low carrier density decreased.

중심합성설계와 반응표면분석법을 이용한 수처리용 산소-플라즈마와 공기-플라즈마 공정의 최적화 (Optimization of Air-plasma and Oxygen-plasma Process for Water Treatment Using Central Composite Design and Response Surface Methodology)

  • 김동석;박영식
    • 한국환경과학회지
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    • 제20권7호
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    • pp.907-917
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    • 2011
  • This study investigated the application of experimental design methodology to optimization of conditions of air-plasma and oxygen-plasma oxidation of N, N-Dimethyl-4-nitrosoaniline (RNO). The reactions of RNO degradation were described as a function of the parameters of voltage ($X_1$), gas flow rate ($X_2$) and initial RNO concentration ($X_3$) and modeled by the use of the central composite design. In pre-test, RNO degradation of the oxygen-plasma was higher than that of the air-plasma though low voltage and gas flow rate. The application of response surface methodology (RSM) yielded the following regression equation, which is an empirical relationship between the RNO removal efficiency and test variables in a coded unit: RNO removal efficiency (%) = $86.06\;+\;5.00X_1\;+\;14.19X_2\;-\;8.08X_3\;+\;3.63X_1X_2\;-\;7.66X_2^2$ (air-plasma); RNO removal efficiency (%) = $88.06\;+\;4.18X_1\;+\;2.25X_2\;-\;4.91X_3\;+\;2.35X_1X_3\;+\;2.66X_1^2\;+\;1.72X_3^2$ (oxygen-plasma). In analysis of the main effect, air flow rate and initial RNO concentration were most important factor on RNO degradation in air-plasma and oxygen-plasma, respectively. Optimized conditions under specified range were obtained for the highest desirability at voltage 152.37 V, 135.49 V voltage and 5.79 L/min, 2.82 L/min gas flow rate and 25.65 mg/L, 34.94 mg/L initial RNO concentration for air-plasma and oxygen-plasma, respectively.

산소부화 LPG 화염에서 혼합형 재연소 방법에 의한 NOx 저감 효과 (The Effect of Hybrid Reburning on NOx Reduction in Oxygen-Enriched LPG Flame)

  • 이창엽;백승욱
    • 한국연소학회지
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    • 제12권4호
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    • pp.14-21
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    • 2007
  • In order to enhance combustion efficiency, oxygen-enriched combustion is used by increasing the oxygen ratio in the oxidizer. However, since the flame temperature increases, NOx formation in the furnace seriously increases for low oxygen enrichment ratio. In this case, reburning is a useful technology for reducing nitric oxide. In this research, experimental studies have been conducted to evaluate the hybrid effects of reburning/selective non-catalytic reaction (SNCR) and reburning/air staging on NOx formation and also to examine heat transfer characteristics in various oxygen-enriched LPG flames. Experiments were performed in flames stabilized by a co-flow swirl burner, which were mounted at the bottom of the furnace. Tests were conducted using LPG gas as main fuel and also as reburn fuel. The paper reported data on flue gas emissions, temperature distribution in furnace and various heat fluxes at the wall for a wide range of experimental conditions. Overall temperature in the furnace, heat fluxes to the wall and NOx generation were observed to increase by low level oxygen-enriched combustion, but due to its hybrid effects of reburning, SNCR and Air staging, NOx concentration in the exhaust have decreased considerably.

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가압형 경수로 압력용기 재료인 저합금강의 동적 붕산 부식 실증 연구 (Dynamic Boric Acid Corrosion of Low Alloy Steel for Reactor Pressure Vessel of PWR using Mockup Test)

  • 김성우;김홍표;황성식
    • Corrosion Science and Technology
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    • 제12권2호
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    • pp.85-92
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    • 2013
  • This work is concerned with an evaluation of dynamic boric acid corrosion (BAC) of low alloy steel for reactor pressure vessel of a pressurized water reactor (PWR). Mockup test method was newly established to investigate dynamic BAC of the low alloy steel under various conditions simulating a primary water leakage incident. The average corrosion rate was measured from the weight loss of the low alloy steel specimen, and the maximum corrosion rate was obtained by the surface profilometry after the mockup test. The corrosion rates increased with the rise of the leakage rate of the primary water containing boric acid, and the presence of oxygen dissolved in the primary water also accelerated the corrosion. From the specimen surface analysis, it was found that typical flow-accelerated corrosion and jet-impingement occurred under two-phase fluid of water droplet and steam environment. The maximum corrosion rate was determined as 5.97 mm/year at the leakage rate of 20 cc/min of the primary water with a saturated content of oxygen within the range of experimental condition of this work.

원추형 연소로에서 공기 유속에 따른 MILD 연소특성 (MILD Combustion Characteristics with Inlet Air Velocity in a Conical Combustor)

  • 김태권;하지수;조아론
    • Journal of Advanced Marine Engineering and Technology
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    • 제36권6호
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    • pp.774-779
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    • 2012
  • MILD(Moderate and Intense Low Oxygen Dilution) 연소는 연소 가스의 재순환을 이용하여 고온 형성을 최대한 억제하고 질소산화물의 발생을 저감하는 동시에 연소로의 내부 온도 균일화를 통한 열 이용 효율을 향상시킬 수 있는 연소기술이다. 본 연구에서는 원추형 연소로에서 연료 유량은 고정하고 공기 유량으로 당량비(${\Phi}$)를 조절하고 배기가스를 측정하여 MILD 연소특성을 도출하였다.

분류층 건식 석탄가스화기에서의 가스화 특성 (Gasification characteristics in an entrained flow coal gasifier)

  • 유영돈;윤용승;안달홍;박호영
    • 대한기계학회논문집B
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    • 제21권12호
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    • pp.1690-1700
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    • 1997
  • Entrained coal gasification tests with Datong coal were performed to assess the influence of oxygen/coal ration and pressure. When gasification condition in oxygen/coal ratio has changed from 0.5 to 1.0, optimal gasification condition from low pressure runs was oxygen/coal ratio of approximately 0.9 where CO was produced about 40% and H, about 20%. Under the pressure condition of 12-14 atmospheres, optimal oxygen/coal ratio value was in the region of 0.6 where CO was produced about 55% and H2about 25%. From these results, it was found that the oxygen/ coal ratio for the maximum production of CO and H, was decreasing with the increase in gasifier pressure and also, with increasing oxygen content, carbon conversion was increased. For the Chinese Datong coal, cold gas efficiency was in the range of 40-80%.

실험계획법에 의한 $Cr_3C_2 - 7wt%NiCr$ 용사분말의 HVOF 용사변수 최적화 (Optimization of HVOF Spray Parameters for $Cr_3C_2 - 7wt%NiCr$ Coating Powder by Experimental Design Method)

  • 김병희;서동수
    • Journal of Welding and Joining
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    • 제15권1호
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    • pp.125-134
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    • 1997
  • This study was conducted by L9 orthogonal array to obtain optimum spray parameters for This study was conducted by L9 orthogonal array to obtain optimum spray parameters for $Cr_3C_2 - 7wt%$(80wt%Ni-20wt%Cr) coating powder. The factors were hydrogen flow rate, oxygen flow rate, gun-to-work distance, powder feed rate. And evaluation methods for the coating were surface roughness, oxygen concentration, micro-hardness, pore size and distribution, low angle ($30^{\circ}$) erosion rate, and microstructure of coating. The optimum HVOF spray conditions were proved as follows : hydroen flow rate ; 681 SLPM, oxygen flow rate ; 215 SLPM $H^2/O^2 ratio= 3.16), gun-to-work distance ; 22cm, powder feed rate; 25g/min. The hardness (Hv300) was 1147 and the erosion rate ($30^{\circ}$degree) was $3.16\times10^{-4}$g/g. It is believed that the optimized spray conditions can be improved the wear-resistance and anti-erosion characteristics of the coating.

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Effect of the oxygen flow ratio on the structural and electrical properties of indium zinc tin oxide (IZTO) films prepared by pulsed DC magnetron sputtering

  • Son, Dong-Jin;Nam, Eun-Kyoung;Jung, Dong-Geun;Ko, Yoon-Duk;Choi, Byung-Hyun;Kim, Young-Sung
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2010년도 제39회 하계학술대회 초록집
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    • pp.168-168
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    • 2010
  • Transparent conduction oxides (TCOs) films is extensively reported for optoelectronic devices application such as touch panels, solar cells, liquid crystal displays (LCDs), and organic light emitting diodes(OLEDs). Among the many TCO film, indium tin oxide(ITO) is in great demand due to the growth of flat panel display industry. However, indium is not only high cost but also its deposits dwindling. Therefore, many studies are being done on the transparent conductive oxides(TCOs). We fabricated a target of IZTO(In2O3:ZnO:SnO2=70:15:15 wt.%) reduced indium. Then, IZTO thin films were deposited on glass substrates by pulsed DC magnetron sputtering with various oxygen flow ratio. The substrate temperature was fixed at the room temperature. We investigated the electrical, optical, structural properties of IZTO thin films. The electrical properties of IZTO thin films were dependent on the oxygen partial pressure. As a result, the most excellent properties of IZTO thin films were obtained at the 3% of oxygen flow rate with the low resistivity of $7.236{\times}10^{-4}{\Omega}cm$. And also the optical properties of IZTO thin films were shown the good transmittance over 80%. These IZTO thin films were used to fabricated organic light emitting diodes(OLEDs) as anode and the device performances studied. The OLED with an IZTO anode deposited at optimized deposition condition showed good brightness properties. Therefore, IZTO has utility value of TCO electrode although it reduced indium and we expect it is possible for the IZTO to apply to flexible display due to the low processing temperature.

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회귀식을 이용한 황룡A 유역에서의 유황별 유달율 산정 (Estimation of Pollutant Loads Delivery Ratio by Flow Duration Using Regression Equation in Hwangryong A Watershed)

  • 정재운;윤광식;주석훈;최우영;이용운;류덕희;이수웅;장남익
    • 한국농공학회논문집
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    • 제51권6호
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    • pp.25-31
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    • 2009
  • In this study, pollutant loads delivery ratio by flow duration in Hwangryoung A watershed was estimated. The delivery ratio was estimated with measured data by Ministry of Environment(MOE) and the regression equation based on geomorphic parameters. Eight day interval flow data measured by the MOE were converted to daily flow to calculate daily load and flow duration curve by correlating data of neighboring station which has daily flow data. Regression equation developed by previous study was tested to study watershed and found to be satisfactory. The delivery ratios estimated by two methods were compared. For the case of Biochemical oxygen demand(BOD), the delivery ratios of low flow condition were 7.6 and 15.5% by measured and regression equation, respectively. Also, the delivery ratios of Total phosphorus(T-P) for normal flow condition were 13.3 and 6.3% by measured and regression equation, respectively.