• Title/Summary/Keyword: Long-term durability

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A First Principles Study on Nano-scale Pt Alloy Structures for Fuel Cell Catalysts (제일원리전산을 이용한 연료전지용 나노 스케일 백금 합금촉매에 대한 열역학적 구조 분석)

  • Noh, Seung-Hyo;Han, Byung-Chan
    • 한국태양에너지학회:학술대회논문집
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    • 2012.03a
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    • pp.217-221
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    • 2012
  • Over the last decade, performances of low temperature fuel cells are substantially improved by developing highly active Pt-M alloy catalysts. The electrochemical stability of those catalysts, however, still does not meet the commercial grade for fuel cells to be long-term power sources of electrical vehicles. To unveil a major mechanism causing such weak durability, we extensively utilize ab-initio computations on nano-scale Pt-Co alloy catalysts and analyze thermodynamically the most stable structure as a function of compositional variation. Our results indicate that there is a certain feature governing the particle distribution of a specific alloy element on the nano-scale catalysts, which aggravates the electrochemical degradation.

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An Experimental Study on the Compressive Strength of Cement Mortar mixing Anion Exchange Resin (음이온교환수지 혼입 시멘트 모르타르의 압축강도에 관한 실험적 연구)

  • Jeong, Do-Hyun;Lee, Yun-Su;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.05a
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    • pp.54-55
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    • 2018
  • Reinforced concrete is a building material that is generally used in modern society. Securing the performance of reinforced concrete is directly connected to the durability and longevity of the building. One of the major factors that deteriorate the durability of concrete is harmful ion. Recently, the quality and improvement method of reinforced concrete for penetration of harmful ion has been studied. In this study, the bead type ion exchange resin is substituted for 0%, 3%, and 6% of the fine aggregate volume in the mortar. The speciments underwent underwater curing and were checked for compressive strengths of 3 days and 28 days. From the results of compressive strength, it can be seen that the higher the substitution ratio of the ion exchange resin, the lower the early strength and long-term strength development, especially the early strength development.

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Evaluation of Durability Performance of Wet- Mixed Shotcrete with Powder Types Cement Mineral Accelerator (시멘트 광물계 급결제를 사용한 습식 숏크리트의 내구성 평가)

  • Won Jong-Pil;Sung Sang-Kyoung;Park Chan-Gi;Cho Yong-Jin;Choi Seok-Won;Park Hae-Geun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.253-256
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    • 2004
  • Recently, construction works of scale are getting larger with economic growth. Shotcreting is one of major processes in tunnels construction. Accelerator is used in tunnel and underground structures to ensure early strength of shotcrete. Silicate based accelerator and aluminate based accelerator is getting widely in the field. But these accelerators have many problems due to decesase of long-term strength and low quality of the hardened shotcrete. in order to solve these problems, recently developed powder types cement mineral accelerator. In this study, we tested chloride permeability, freezing and thawing and accelerated carbonation of shotcrete. As a result of the test, wet-mixed shotcrete with powder types cement mineral accelerator exhibited durability improvement compared to the conventional shotcrete accelerator.

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An Experimental Study on the Neutralization of High-Flowable Concrete (고유동콘크리트의 중성화에 관한 실험적 연구)

  • Jeon, Hyun-Kyu;Lim, Jin-Kyu;Seo, Chee-Ho
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.3 no.3
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    • pp.177-185
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    • 1999
  • In this study, study about fly ash and blast-furnace slag used as substitutive materials for cement, and the influence on the neutralization of high flow concrete durability with these substitutive materials was performed and analyzed. The results are as follows 1) Aggregate segregation was partially improved with the progress of the admixture input at the mix proportion above slump flow 65 cm 2) Compressive strength with the progress of the increasement of fly ash input was decreased in early age, but decrease range was improved in long term age. Also, in case of blast-furnace, similar or improved compressive strength was appeared. 3) The neutralization depth with fly ash input was noticeably increased. But blast-furnace slag was effective to prevent. 4) In this experiment, high powder content was advantageously affected on preventive effect of the neutralization, and the relationship between the compressive strength and the neutralization depth was inversely proportional.

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Degradation mechanisms of concrete subjected to combined environmental and mechanical actions: a review and perspective

  • Ye, Hailong;Jin, Nanguo
    • Computers and Concrete
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    • v.23 no.2
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    • pp.107-119
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    • 2019
  • In-service reinforced concrete structures are simultaneously subjected to a combination of multi-deterioration environmental actions and mechanical loads. The combination of two or more deteriorative actions in environments can potentially accelerate the degradation and aging of concrete materials and structures. This paper reviews the coupling and synergistic mechanisms among various deteriorative driving forces (e.g. chloride salts- and carbonation-induced reinforcement corrosion, cyclic freeze-thaw action, alkali-silica reaction, and sulfate attack). In addition, the effects of mechanical loads on detrimental environmental factors are discussed, focusing on the transport properties and damage evolution in concrete. Recommendations for advancing current testing methods and predictive modeling on assessing the long-term durability of concrete with consideration of the coupling effects are provided.

A Brief Review on Variables and Test Priorities of Photovoltaic Module Life Expectancy

  • Padi, Siva Parvathi;Chowdhury, Sanchari;Zahid, Muhammad Aleem;Kim, Jaeun;Cho, Eun-Chel;Yi, Junsin
    • Current Photovoltaic Research
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    • v.9 no.2
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    • pp.36-44
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    • 2021
  • To endorse the reliability and durability of the solar photovoltaic (PV) device several tests were conducted before exposing to the outdoor field in a non-ideal condition. The PV module has high probability that intend to perform adequately for 30 years under operating conditions. To evaluate the long term performance of the PV module in diversified terrestrial conditions, one should use the outdoor performance data. However, no one wants to wait for 25 years to determine the module reliability. The accelerating stress tests performing in the laboratory by mimicking different field conditions are thus important to understand the performance of a PV module. In this review, we will discuss briefly about different accelerating stress types, levels and prioritization that are used to evaluate the PV module reliability and durability before using them in real field.

Optimization of MIL-53 Metal-organic Framework Coatings for Enhanced Durability in Carbon Dioxide Capture (이산화탄소 포집 성능 향상을 위한 MIL-53 금속-유기 골격체 코팅의 최적화)

  • Dae-Hyeon Kim;Sung-Jun Lee;Dong-Gyu Ahn;Chang-Lae Kim
    • Transactions of Materials Processing
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    • v.33 no.4
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    • pp.261-269
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    • 2024
  • This study aimed to optimize the MIL-53 metal-organic framework coatings for enhanced durability in carbon dioxide capture applications. We synthesized MIL-53 powders using a hydrothermal method and deposited them on stainless-steel substrates by spin coating at various speeds, ranging from 300 to 2,000 rpm. The microstructure, surface properties, and tribological characteristics of the coatings were analyzed systematically. The results indicated that the spin speed significantly impacted the coating uniformity and defect formation. Coatings prepared at moderate speeds of 500 to 1,000 rpm exhibited optimal thickness and density, resulting in superior wear resistance. The tribological tests revealed that the coatings prepared at 700 to 1000 rpm had the lowest wear rates. These findings offer valuable insights for the development of durable MOF-based coatings for carbon dioxide capture and other applications requiring long-term stability under mechanical stress.

Development of New Electroplating Alloy (Au-Cu) for Increasing the Durability of PCB Commutator in Vibration Motor (진동모터용 PCB 정류자의 내구성 향상을 위한 신 합금도금 (Au-Cu) 개발)

  • Kim, Young-Tae;Lee, Sung-Jae;Park, Sung-Jun
    • Journal of the Korean Society for Precision Engineering
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    • v.26 no.6
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    • pp.114-121
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    • 2009
  • Mobile phone is a representative personal communication tool among wireless communication devices. Recently, with the miniaturization and light-weight trend of mobile phone, the vibration motor has been replaced by coin type. The required performances of coin type vibration motor needed by user are long life, higher vibration, and thin thickness. Also the most important factor determines the performance of vibration motor is long-term reliability, which is mainly related to PCB plating technique for commutator. In this study, three types of fault were categorized to analyze the cause for malfunction of vibration motor. And, hardness and surface morphology on plating surface are also investigated to optimize the plating method and plating conditions. As a result, new plating method and conditions were proposed to increase the durability of PCB commutator.

Long-Term Experiment of Chloride Penetration in Concrete through Cracks (콘크리트의 균열부를 통한 염소이온 침투의 장기 실험연구)

  • Yoon, In-Seok;Sung, Jae-Duck
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.809-812
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    • 2008
  • Over the past few decades, considerable numbers of studies on the durability of concrete have been carried out extensively. The majority of these researches have been performed on sound uncracked concrete, although most of in-situ concrete structures have more or less micro-cracks. It is only recent approach that the attention has shifted towards the influence of cracks and crack width on the penetration of chloride into concrete. The penetration of chlorides into concrete through the cracks can make a significant harmful effect on reinforcement corrosion. Author of this study examined the effect of cracks on chloride penetration by short tem experiment. However, it is necessary to accomplish the effect by long term experiment to get reliable goal. In this study, the long term experiment was carried out and the experimental result was compared with short term experiment. Crack tends to decrease with elapsed time because of self-healing. Especially this trend was obvious in concrete sample with wide crack with.

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A Study on the Evaluation of the Durability of Concrete Using Copper Slag Aggregates (동슬래그 골재를 함유한 콘크리트의 내구성 평가 연구)

  • Lee, Mun-Hwan
    • Journal of the Korea Concrete Institute
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    • v.20 no.6
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    • pp.773-784
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    • 2008
  • Even if the exploitation of copper slag produced during the smelting process of copper as aggregate for construction purpose has been permitted since 2004 in Korea, the lack of sufficient data enabling to evaluate its long-term stability that is its durability has to date impeded its application. This study intends to investigate experimentally the durability characteristics of 18 and 27 MPa-class commercial concretes in which natural sand (fine aggregates) has been partially replaced by copper slag through accelerated and exposure tests so as to provide bases promoting the application of copper slag concrete. The experimental results revealed insignificant difference of the durability characteristics in most of the mix proportions in which 30% of natural sand was replaced by copper slag. In the case where crushed sand was adopted, tests verified similar characteristics for replacement ratio of 50%. Particularly, the results of the exposure test conducted during 8 years demonstrated that equivalent level of durability was secured compared to the case using natural sand. In the case of 18MPa-class lower grade concrete, exposure test verified also that the physical lifetime similar to 50 years could be secured until carbonation reaches cover depth of 20 mm.