• Title/Summary/Keyword: Long-term deterioration

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Development of Surface Coating Technology fey Metallic Bipolar Plate in PEMFC : I. Study on Surface and Corrosion Properties (PEMFCB금속분리판 코팅 기술 개발 : I. 표면 및 부식 특성 평가)

  • Chung, Kyeong-Woo;Kim, Se-Yung;Yang, Yoo-Chang;Ahn, Seung-Gyun;Jeon, Yoo-Taek;Na, Sang-Mook
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.348-351
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    • 2006
  • Bipolar plate, which forms about 50% of the stack cost, is an important core part with polymer electrolyte membrane in PEMFC. Bipolar plates have been commonly fabricated from graphite meterial having high electrical conductivity and corrosion resistance. Lately, many researchers have concentrated their efforts on the development of metallic bipolar plate and stainless steel has been considered as a potential material for metallic bipolar plate because of its high strength, chemical stability, low gas permeability and applicability to mass production. However, it has been reported that its inadequate corrosion behavior under PEMFC environment lead to a deterioration of membrane by dissolved metal ions and an increase in contact resistance by the growth of passive film therefore, its corrosion resistance as well as contact resistance must be improved for bipolar plate application. In this work, several types of coating were applied to 316L and their electrical conductivity and corrosion resistance were evaluated In the simulated PEMFC environment. Application of coating gave rise to low interfacial contact resistances below $19m{\Omega}cm^2$ under the compress force of $150N/cm^2$. It also made the corrosion potential to shift in the posit ive direct ion by 0.3V or above and decreased the corrosion current from ca. $9{\mu}A/cm^2$ to ca. $0.5{\mu}A/cm^2$ in the mixed solution of $0.1N\;N_2SO_4$ and 2ppm HF A coat ing layer under potentiostatic control of 0.6V and $0.75V_{SCE}$ for 500 hours or longer showed some instabilities, however, no significant change in coat Ing layer were observed from Impedance data. In addition, the corrosion current maintained less than $1{\mu}A/cm^2$ for most of time for potentiostatic tests. It indicates that high electrical conductivity and corrosion resistance can be obtained by application of coatings in the present work.

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Modified Nikaidoh Procedure for Patient with TGA, Restrictive VSD, and PS (페동맥 협착과 심실중격결손을 동반한 대혈관 전위에서 시행한 변형 니카이도 술식)

  • Jeon, Jae-Hyun;Seong, Yong-Won;Kim, Woong-Han;Chang, Hyoung-Woo;Chung, Eui-Suk;Kwak, Jae-Gun
    • Journal of Chest Surgery
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    • v.42 no.1
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    • pp.87-91
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    • 2009
  • The surgical management of complete transposition of the great arteries, ventricular septal defect, and pulmonary stenosis still remain a significant challenge. The Rastelli (REV procedure) remains the most widely applied procedure for surgical repair of these lesions. Although the Rastelli procedure can be performed with good early results, the intermediate- and long-term results have been less than satisfactory because of deterioration of the hemodynamic performance of the LVOT or RVOT. We performed a modified Nikaidoh procedure as an alternative surgical procedure in a 19-month-old boy weighing 10.4 kg with this anomaly. Aortic translocation with biventricular outflow tract reconstruction resulted in a more "normal" anatomic repair and postoperative echocardiography showed straight, direct, and unobstructed ventricular outflow.

Deterioration Degree and Material Research of Metal Archival Objects (금속류 행정박물의 손상도 및 재질 연구)

  • Park, Hyung-Ho;Cho, Nam-Chul;Na, Mi-Sun
    • Journal of Conservation Science
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    • v.26 no.1
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    • pp.33-41
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    • 2010
  • The archival objects are tangible evidence reflecting public work as forming archives which are administrative, historic, symbolic, cultural and artistic value. They are produced from the various countries so that they have different material and manufacture techniques. However there are difficulties in conservation and management because the material investigation and conservation management system are not established. Therefore this research presents fundamental data for the efficient conservation management by material investigation and condition check metal archival objects. Among the public official presents made of metal, 12 pieces which are discoloration, oxidation, loss or crack are chosen for this research. In order to examine extensive condition of metal archival objects, the condition check card used from the domestic museum and the national museum in Japan are collected and then the new check card is produced. X-ray is used to know the making technique, binding means between different material. Portable-XRF is also used for the chemical composition analysis of metal archival objects, and then classifying respectively according to their material. As a result of condition check, it is possible to investgate the appearance character, deteriorated parts and weak parts of structure. Also P-XRF could find out the composition of metal archival objects which is different from existing condition check card. Therefore the research results can be used as fundamental data for further conservation and management as well as long-term conservation.

Structural performance evaluation of precast concrete segment using synthetic fibres (프리캐스트 콘크리트 세그먼트의 합성섬유 보강재 적용에 따른 구조적 성능 평가)

  • Lee, Hoseong;Kim, Changyong;Lee, Sean S.;Kim, Seungjun;Lee, Kyeongjin
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.20 no.2
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    • pp.469-483
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    • 2018
  • Steel bars have been widely used as the primary reinforcement for Precast Segmental Concrete Lining for TBM Tunnels. Previously, studies have been carried out to gauge the potential for steel fiber reinforcement to replace the use of steel bar reinforcements in the segmental lining to reduce the amount of the steel bar reinforcement. Steel fiber reinforcements have been investigated and widely applied to SFRC TBM linings to improve the constructability of SFRC TBM linings worldwide. However, the steel fiber reinforcement often caused punctures to the water membranes inside tunnel lining and had long-term durability deterioration issues caused by steel corrosion, as well as cosmetic problems. Therefore, this paper sought to gauge the potential of synthetic fiber reinforcements, which have proven to be very attractive substitutes for steel fiber reinforcements. This study analyzed the performance of both steel and synthetic fiber reinforcements in segmental linings and evaluated the applicability of the fiber reinforcements to the TBM Precast Concrete Segmental Linings of TBM tunnels. As a conclusion, this study demonstrates that the potential use of steel and synthetic fibers in various combination, can substitute the rebar reinforcement in the concrete mix for segmental concrete linings.

Conservational Treatment and Deterioration Assessment of the Sculptured Standing Buddha Named Taehwa 4 Year in the Jincheon, Korea (진천태화4년명 마애불의 풍화훼손도 평가와 보존처리)

  • Lee, Chan Hee;Kim, Sun Duk;Han, Byeong Il;Kim, Yeong Taek;Lee, Myeong Seong
    • Journal of Conservation Science
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    • v.16 s.16
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    • pp.39-51
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    • 2004
  • The standing Buddha named Taehwa 4 yew in the Jincheon were sculptured with rock cliff of the dark grey shale. Front of the Buddha statue shows $N40^{\circ}W$ strike with nearly vertical dip toward the back side. Rock blocks of the Buddha statue well developed with bedding and laminations whereas rock surface distributed into the various irregular discontinuities. Sculptured lines of the Buddha were uncertain because of degradation and exfoliations on the rock surface. The surface near the Buddha statue is highly contaminated with lichen and mosses, and accelerate physical and biological weathering owing to the roots of weed and bush along the fracture systems. For the conservational treatment, we treated with primary wet cleaning by air gun and secondary cleaning treatment using distilled water. Separated rock surface and fractured parts fasten and/or fill up the boundaries of the rock blocks using epoxy resin for conservation of rock properties. Some brittle surface was treatment with water repellent consolidant of ethyl silicates, and heterogeneous surface carried out color matching by acrylic pigments. Upper part of the Buddha statue dig out small ditch for rain water drainage, and near surface of the Buddha statue treat removal works for lichen, weeds and bush. The duration capacity of the Buddha constituting rocks are degraded by various weathering factors, therefore we suggest that this Buddha statue have need to do long term monitoring and synthetic conservation researches.

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Deterioration Assessment and Conservational Scientific Diagnosis of the Stone Pagoda in the Bunhwangsa temple, Gyeongju, Korea (경주 분황사석탑의 풍화훼손도 평가와 보존과학적 진단)

  • Yi, Jeong-Eun;Lee, Chan-Hee;Lee, Myeong-Seong
    • Journal of Conservation Science
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    • v.18 s.18
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    • pp.19-32
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    • 2006
  • The stone pagoda of the Bunhwangsa temple made by piling small brick-shaped stones. The major rock forming stone bricks are andesites with variable genesis. Rock properties of the pagoda roof stone suffer partly including multiple peel-offs, exfoliation, decomposition like onion peels, cracks forming round lines and falling off stone pieces. The stylobates and tabernacles in all the four directions the pagoda are mostly composed of granitic rocks. Those rock properties are heavily contaminated by lichens and mosses with the often marks of inorganic contamination by secondary hydrates that are dark black or yellowish brown. Within the four tabernacles and northern pagoda body situated to relatively high humidity. There are even light gray precipitate looking like stalactites between the northern and western rocks of the body Their major minerals are calcite, gypsum and clays. The stone lion standing in the southeast and northeast side are alkali granite, while that in the southwest and northwest lithic tuff. Total rock properties of the pagoda are 9,708 pieces, among the all properties, fractured blocks are 11.0%, fall out blocks are 6.7% and covered blocks by precipitates are 7.0%, respectively. The pagoda has highly deteriorated the functions of the rock properties due to physical, chemical and biological weathering, therefore, we suggest that this pagoda has need to do long term monitoring and synthetic conservation researches.

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A Study on Local Economic Resilience after Disasters through Time Series Analysis -Focusing on the Sewol Ferry Disaster- (시계열자료 분석을 통한 재난발생 이후 지역경제 회복력(resilience)에 관한 연구 -세월호 참사를 중심으로-)

  • Kwon, Seol A
    • The Journal of the Korea Contents Association
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    • v.18 no.5
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    • pp.456-463
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    • 2018
  • Increases in disasters and damage caused by the disasters in modern society, have a negative impact on local economy. In particular, a local economic downturn leads to a deterioration in quality of life of local residents and causes mental and material damage. Therefore, in order to achieve stable and sustainable local economic development, it is necessary to strengthen the resilience of the local economy. This study aims to estimate indicators of local economic resilience of Jindo County after the Sewol Ferry disaster, analyze a trend of the economic level after the disaster through time series data and suggest improvement plans of the local crisis management and restoration policy that considers future economic resilience. Results of this study showed that a decrease in the number of tourists and of workers in related industries hit tourism industry, causing a loss to the local economy and that an increase in a drinking rate of and stress awareness rate of local residents was a stress factor due to disaster impacts. These findings provides policy implications that it is necessary to make efforts for improving the depressed local image by utilizing local resources in the area, to build a sustainable long-term economic recovery policy and to provide psychological treatment and the relevant government and local government's support for relieving the stress of local residents due to the disaster impacts.

Critical Strengthening Ratio of CFRP Plate Using Probability and Reliability Analysis for Concrete Railroad Bridge Strengthened by NSM (확률.신뢰도 기법을 적용한 CFRP 플레이트 표면매립보강 콘크리트 철도교의 임계보강비 산정)

  • Oh, Hong-Seob;Sun, Jong-Wan;Oh, Kwang-Chin;Sim, Jong-Sung;Ju, Min-Kwan
    • Journal of the Korea Concrete Institute
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    • v.21 no.6
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    • pp.681-688
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    • 2009
  • The railroad bridges have been usually experienced by vibration and impact in service state. With this reason, it is important that the effective strengthening capacity should be considered to resist the kind of service loading. In this study, NSM strengthening technique is recommended for the concrete railroad bridge because of its better effective resistance for dynamic loading condition and strengthening cost than the conventional externally bonded strengthening using fiber sheet. However, to widely apply NSM method for the concrete railroad bridge, it needs that the strengthening ratio has to be reasonably evaluated with geometrical and material uncertainties, especially for the concrete bridge under long-term service state without the apparent design history and detail information such as concrete compressive strength, reinforcing ratio, railroad characteristics. The purpose of this study is to propose the critical strengthening ratio of CFRP plate for the targeted concrete railroad bridge with uncertainties of deterioration of the structures. To do this, Monte Carlo Simulation (MCS) for geometrical and material uncertainties have been applied so that this approach may bring the reasonable strengthening ratio of CFRP plate considering probabilistic uncertainties for the targeted concrete railroad bridge. Finally, the critical strengthening ratio of NSM strengthened by CFRP plate is calculated by using the limit state function based on the target reliability index of 3.5.

Evaluation of Deterioration of Larix kaempferi Wood Heat-treated by Superheated Steam through Field Decay Test for 12 Months (12개월 야외 내후성 시험에 의한 과열증기 열처리된 낙엽송재의 열화 평가)

  • Park, Yonggun;Han, Yeonjung;Park, Jun-Ho;Chung, Hyunwoo;Kim, Hyunbin;Yang, Sang-Yun;Chang, Yoon-Seong;Yeo, Hwanmyeong
    • Journal of the Korean Wood Science and Technology
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    • v.46 no.5
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    • pp.497-510
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    • 2018
  • In this study, the decay resistance of larch wood, which was heat treated by superheated steam, was evaluated by the field decay test. During the field decay test of 12 months, non-treated wood has been severely damaged by termite, however, no visible damage has occurred in the preservative-treated wood and superheated steam heat-treated wood. Results of field decay test showed approximately 5% mass loss of the non-treated wood and the preservative-treated wood, and approximately 1% mass loss of the superheated steam heat-treated wood. After the field decay test for 12 months, the residual amount of preservatives remaining in the preservative-treated wood was lower than that before the field decay test. It was considered that the preservative was partially eluted during the field decay test, and the mass loss of the preservative-treated wood was thought to be similar to that of the non-treated wood. Through this study and additional long-term monitoring test, superheated steam heat treatment can be considered to be an environmental-friendly method to enhance the decay resistance of wood against rot fungi and/or insect without chemical treatment such as preservative injection.

Comparative Study on the Bond Strength between Direct Tensile Test and Indirect Tensile Test for Bonded Concrete Overlay (직접인장 및 간접인장 실험방법에 따른 접착식 콘크리트 덧씌우기의 부착강도 비교 고찰)

  • Kim, Young Kyu;Lee, Seung Woo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.33 no.3
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    • pp.1153-1163
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    • 2013
  • Bonded concrete overlay is a favorable maintenance method since the material properties are similar to existing concrete pavements. In addition, bonded concrete overlay has advantage of structural performance based on being bonded together, both for the overlay layer and the existing pavement which perform as one monolithic layer. Therefore, it is important to have a suitable bond strength criteria for long term performance of bonded concrete overlay. This study aimed to investigate the affecting of bond strength on various bond characteristics, and to compare the bond strength between direct tensile test and indirect tensile test due to various conditions such as overlay materials, compressive and flexure strength of existing pavement, and deterioration status of existing pavement. As a result of this study, bond strength occurred by both of direct and indirect tensile test due to monotonic load is highly correlated such as coefficient of determination of 0.75 and P-value of 0.002. However, bond strength by indirect tensile test was relatively higher than bond strength by direct tensile test. It was known that correlation between direct and indirect tensile test was possible to use the characteristics analysis of bond fatigue behavior based on bond strength due to cyclic load which can simulate real field behavior of bonded concrete overlay.