• Title/Summary/Keyword: Local corrosion

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Steel Pile Corrosion in Potential Acid Sulfate Soil (잠재성 특이산성토중 강관말뚝의 부식)

  • Lee, Seung-Heon;Park, Mi-Hyeun;Yoon, Kyung-Sup
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2003.10a
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    • pp.559-562
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    • 2003
  • The results and discussions of surveyed case site at constructed steel pile in potential acid sulfate soil were as follows. Topography at surveyed site was local alluvial valley and that site soils was classified as BanGog and YuGye series as detailed soil surveyed results in RDA and soil texture was Clay/Clay Loam. Soils pH was neutral, which was average 7.5 but much decreased to average 4.2 after $H_2O_2$ treatment. Organic matter and sulfate ions contents were very rich. The corrosion was severe at ground water fluctuation depth. Deposits colored black were attached to steel pile surface, which because of violent reaction in treatment HCI solution, were guessed as corrosion products (FeS) reduced by sulfate reducing bacteria(SRB). Consequently, main cause was thought microbiologically induced corrosion at this site where there is ground water fluctuation occurring oxidation and reduction reactions in turn and the soil is potential acid sulfate soil.

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Micro-electrochemical Characteristics of Sensitized 304 Stainless steel Using Micro-droplet cell Techniques (마이크로 드로플릿 셀 기법을 이용한 예민화 된 304 스테인리스강의 미세전기화학 특성)

  • Kim, Kyu-Seop;Lee, Jae-Bong
    • Corrosion Science and Technology
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    • v.9 no.6
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    • pp.300-309
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    • 2010
  • The influences of sensitization on localized corrosion resistance of 304 stainless steel, were investigated, using micro-dropletcell techniques. Micro-droplet cell allows one to align the micro-electrode to the desired spot of the working electrode and measure directly local current with the potentiodynamic polarization, linear polarization and a.c. impedance. Micro-electrochemical tests were carried out inside of the grain and on grain boundaries separately. It was found that sensitization decreased the pitting potential, increasing corrosion current density around grain boundaries. Galvanic current density was also measured between grain and grain boundaries.

A Study on the Initiation of Pitting Corrosion of Fe-17Cr Alloy Using Micro-Droplet Cell Technique (Micro-droplet cell을 이용한 Fe-17Cr 합금의 공식 발생에 대한 연구)

  • Kim, Jae-Jung;Lee, Jae-Bong
    • Korean Journal of Metals and Materials
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    • v.46 no.12
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    • pp.809-816
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    • 2008
  • The influences of various parameters such as inclusions, surface roughness, exposed areas and chloride ion concentrations on the initiation of pitting of Fe-17Cr alloy were investigated, using micro-droplet cell technique. Micro-droplet cell allows one to align the micro-electrode to the desired spot of the working electrode and measure directly local currents with the potentiodynamic polarization. Micro electrochemical tests were carried out at the inclusions after EDX analysis of inclusion. EDX analysis identified inclusions as Cr-oxides. It was found that some active inclusions among Cr-oxide inclusions acted as initiation sites for pitting corrosion. In addition, the rougher surface and the denser chloride ion concentration offered easier pit initiation sites, causing the more susceptible to pitting corrosion.

Computational Analysis of Structural Behavior of Subsea Pipelines with Local Corrosion (국부 부식을 가지는 심해저 파이프라인의 구조응답에 대한 전산 해석적 연구)

  • Choi, Kwang-Ho;Lee, Chi-Seung;Ryu, Dong-Man;Koo, Bon-Yong;Song, Joon-Kyu;Lee, Jae-Myung
    • Journal of Ocean Engineering and Technology
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    • v.29 no.1
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    • pp.100-110
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    • 2015
  • To meet the increasing demand for energy around the world, offshore and subsea energy development is constantly being conducted. This trend is accompanied by an increasing demand for pipeline installation, which brings numerous problems, including those related to accessibility, high pressure, and corrosion. Among these, corrosion is a primary factor in pipeline fractures, and can cause severe environmental and industrial damage. Hence, accurate corrosion assessment for corroded pipelines is very important. For this reason, the present study investigated the mechanical behavior of an idealized corroded subsea pipeline with an internal/external pressure load using the commercial FEA code ABAQUS. Then, the analysis result was compared with corrosion assessment codes such as ASME B31G, DNV RP F101, ABS. Finally, a fitness-for-service assessment was conducted.

Effect of Stress on the Polarization Characteristic of Al-brass (Al-황동의 분극특성에 미치는 응력의 영향)

  • Lim, Uh-Joh;Jeong, Hae-Kyoo;Sim, Kyong-Tae
    • Journal of the Korean Society of Safety
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    • v.19 no.2
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    • pp.1-5
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    • 2004
  • Al-brass is the raw material of mnufacturing tubes for heat exchanger of vessel where seawater is used to coolant because it has high level of heat coductivity and excellent mechanical properties and high level of corrosion resistance due to cuprous oxide($Cu_2O$) layer against seawater. However, damage of Al-brass tubes for heat exchanger of vessel is reported that local corrosion such as stress corrosion cracking occurred by synergism effect between mechanical factor and corrosion environment. In this study, to investigate on the effect of stress on the polarization characteristics of Al-brass. At the stress of 0% and 95% yield strength by constant displacement tester, in 3.5% NaCl + 0.1% $NH_4OH$ solution, the polarization tests were carried out. And thus open circuit potential, corrosion current density, anodic polarization, cyclic polarization and dezincification behavior of Al-brass are investigated.

Relation between total degradation of steel concrete bond and degree of corrosion of RC beams experimental and computational studies

  • Maurel, Olivier;Dekoster, Mickael;Buyle-Bodin, Francois
    • Computers and Concrete
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    • v.2 no.1
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    • pp.1-18
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    • 2005
  • This paper presents a study on the effects of localized steel-concrete bond degradation on the flexural behaviour of RC beams. A finite element analysis is undertaken to complete the experimental analysis. The first part deals with an experimental study on beams where bond was removed by using plastic tube at different locations and for various lengths. The flexural behaviour was studied at global scale (load-deflection) and local scale (moment-curvature). The second part, a numerical study using a simplified special finite element (rust element) modelling the rust layer occurring between reinforcement and concrete with corrosion was conducted in order to find the relation between the degree of corrosion and the degradation of the steel-concrete bond. The computed value of the corrosion degree corresponding to the total degradation of bond has been used in a second time to model the tests, in order to evaluate the influence of the loss of bond, the steel cross section reduction, and the combination of both. The results enable to evaluate the influence of the different corrosion effects on the flexural behaviour, according to the length and the location of the corroded zone.

Numerical Simulation of Interactions between Corrosion Pits on Stainless Steel under Loading Conditions

  • Wang, Haitao;Han, En-Hou
    • Corrosion Science and Technology
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    • v.16 no.2
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    • pp.64-68
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    • 2017
  • The interactions between corrosion pits on stainless steel under loading conditions are studied by using a cellular automata model coupled with finite element method at a mesoscopic scale. The cellular automata model focuses on a metal/film/electrolyte system, including anodic dissolution, passivation, diffusion of hydrogen ions and salt film hydrolysis. The Chopard block algorithm is used to improve the diffusion simulation efficiency. The finite element method is used to calculate the stress concentration on the pit surface during pit growth, and the effect of local stress and strain on anodic current is obtained by using the Gutman model, which is used as the boundary conditions of the cellular automata model. The transient current characteristics of the interactions between corrosion pits under different simulation factors including the breakdown of the passive film at the pit mouth and the diffusion of hydrogen ions are analyzed. The analysis of the pit stability product shows that the simulation results are close to the experimental conclusions.

Fracture Behavior of Welded Pipes with Local Wall Thinning (감육을 가지는 배관 용접부의 파괴거동)

  • Ahn, Seok-Hwan;Nam, Ki-Woo;Jeong, Jeong-Hwan;Kim, Yong-Un
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.90-95
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    • 2003
  • Fracture behaviors of pipes with local wall thinning are very important for the integrity of nuclear power plant. In pipes of energy plants, sometimes, the local wall thinning may result from severe erosion-corrosion (E/C) damage. However, the effects of local wall thinning on strength and fracture behaviors of piping system were not well studied. In this paper, the monotonic bending tests were performed of full-scale welded and unwelded carbon steel pipes with local wall thinning. A monotonic bending load was applied to straight pipe specimens by four-point loading at ambient temperature without internal pressure. The observed failure modes were divided into four types; ovalization, crack initiation/growth after ovalization, local buckling and crack initiation/growth after local buckling. Also, the strengths of welded and unwelded piping system with local wall thinning were evaluated.

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Fracture Behavior Evalustion of Pipes with Local Wall Thinning (감육배관의 파괴거동 평가)

  • Ahn, S.H.;Nam, K.W.;Kim, S.J.;Kim, H.S.;Kim, J.H.;Do, J.Y.
    • Proceedings of the KSME Conference
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    • 2001.11a
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    • pp.61-66
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    • 2001
  • Fracture behaviors of pipes with local wall thinning is very important for the integrity of nuclear power plant. In pipes of energy plants, sometimes, the local wall thinning may result from severe drosion-corrosion damage. However, effect of local wall thinning on strength and fracture behaviors of piping system were not well studied. In this paper, the monotonic bending tests were performed of full-scale carbon steel pipes with local wall thinning. A monotonic bending load was applied to straight pipe specimens by four-point loading at ambient temperature without internal pressure. From the tests, fracture behaviors and fracture strength of locally thinned pipe were manifested systematically. The observed failure modes were divided into four types; ovalization, ovalization+cracking, local buckling and local buckling+cracking. Also, maximum load was successfully evaluated.

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Effect on Corrosion Characteristics of SS 400 Steel by Alkali Water pH from Electrolysis of City Water (수돗물의 전기분해에 의해서 생성된 알카리수의 pH가 SS 400강의 부식특성에 미치는 영향)

  • Moon, Kyung-Man;Ryoo, Hae-Jeon;Kim, Yun-Hae;Jeong, Jae-Hyun;Baek, Tae-Sil
    • Journal of Ocean Engineering and Technology
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    • v.31 no.3
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    • pp.248-255
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    • 2017
  • Many rivers and seas have been affected by environmental contamination. Therefore, city water supplies often require a high-degree purification treatment to provide safe drinking water. However, in order to achieve a high-degree purification treatment, a large amount of chlorine has to be added to sterilize city drinking water. The added chlorine reacts chemically with water and forms hypochlorous and chlorine ions. The hypochlorous ionizes with hypochlorous ions and hydrogen ions. As a result, the city water contains a large amount of chlorine ion. As such, when city water is used with domestic boilers, many kinds of heat exchangers, and the engines of vehicle and ships, there are often corrosion problems. In this study, alkali water was electrochemically made by electrolysis of city water, and corrosion properties between alkali and city water were investigated with an electrochemical method. Most of the chlorine ions are thought to not be contained in the alkali water because the alkali water is created in the cathodic chamber with an electrolysis process. In other words, the chlorine ion can be mostly removed by its migration from a cathodic chamber to an anodic chamber. Moreover, the alkali water also contains a large amount of hydroxide ion. The alkali water indicated relatively good corrosion resistance compared to the city water and the city water exhibited a local corrosion pattern due to the chlorine ion created by a high-degree purification treatment. In contrast, the alkali water showed a general corrosion pattern. Consequently, alkali water can be used with cooling water to inhibit local corrosion by chlorine ions in domestic boilers, various heat exchangers and the engine of ships and for structural steel in a marine structure.