• Title/Summary/Keyword: Local corrosion

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Effects of Hydroxide and Silicate ions on the Plasma Electrolytic Oxidation of AZ31 Mg Alloy (AZ31 마그네슘 합금의 플라즈마전해산화 피막 형성에 미치는 수산화 이온 및 규산 이온의 영향)

  • Moon, Sungmo;Yang, Cheolnam;Na, Sangjo
    • Journal of the Korean institute of surface engineering
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    • v.47 no.4
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    • pp.147-154
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    • 2014
  • Formation behavior of PEO (Plasma Electrolytic Oxidation) films on AZ31 Mg alloy was studied in aqueous solutions containing various concentrations of hydroxide ion ($OH^-$) and silicate ion ($SiO_3{^{2-}}$) by voltage-time curves, and corrosion resistance of the PEO film-covered specimen was investigated by immersion test in 0.5 M NaCl solution. From the analyses of the voltage-time curves, it is suggested that two different types of anions are essentially needed for the formation of PEO films on AZ31 Mg alloy: film formation agent and local film breakdown agent. $SiO_3{^{2-}}$ ion acts only as a film formation agent but $OH^-$ ion acts not only as a film formation agent but also film breakdown agent. The PEO films prepared on AZ31 Mg alloy in alkaline silicate solution showed very good corrosion resistance without any pitting or filiform corrosions up to 480 h of immersion in 0.5 M NaCl.

Reliability of Maintained Hull Girders of Two Bulk Carrier Designs Subjected to Fatigue and Corrosion

  • Soares, C.Guedes;Garbatov, Y.
    • Journal of Ship and Ocean Technology
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    • v.3 no.1
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    • pp.27-41
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    • 1999
  • The objective of the paper is to study the impact of changing the traditional hull design of bulk carriers by providing them with a double hull while keeping the same deadweight. It is demonstrated that by introducing the double hull the structural reliability is increased throughout the entire life and also the extend of the needed repair is reduced. The results are obtained with recently developed mathematical tools for the reliability assessment of ship hulls subjected to the existence of multiple cracks both in the stiffeners and in the plating and it models the crack growth process. The effect of corrosion is represented as time dependent. The long-term stress range acting on the elements is defined as a function of the local transverse pressure of the internal cargo and outside sea water combined with the stresses resulting from the longitudinal bending of the hull, which is a combined with the stresses resulting from the longitudinal bending of the hull, which is a combineation of horizontal and vertical bending moments. The effect of maintenance actions is modelled as a stochastic process. The results show that a different design of the midship section improves the structural safety and also the economy with respect to structural repair of bulk carriers.

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Development of Tungsten CMP (Chemical Mechanical Planarization) Slurry using New Abrasive Particle (새로운 연마입자를 이용한 텅스텐 슬러리 개발)

  • Yu, Young-Sam;Kang, Young-Jae;Kim, In-Kwon;Hong, Yi-Koan;Park, Jin-Goo;Jung, Seok-Jo;Byun, Jung-Hwan;Kim, Moon-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.571-572
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    • 2006
  • Tungsten CMP needs interconnect of semiconductor device ULSI chip and metal plug formation, CMP technology is essential indispensable method for local planarization. This Slurry development also for tungsten CMP is important, slurry of metal wiring material that is used present is depending real condition abroad. It is target that this research makes slurry of efficiency that overmatch slurry that is such than existing because focus and use colloidal silica by abrasive particle to internal production technology development. Compared selectivity of slurry that is developed with competitor slurry using 8" tungsten wafer and 8" oxide wafer in this experiment. And removal rate measures about density change of $H_2O_2$ and Fe particle. Also, corrosion potential and current density measure about Fe ion and Fe particle. As a result, selectivity find 83:1, and expressed similar removal rate and corrosion potential and current density value comparing with competitor slurry.

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Fabrication of Low Carbon Steel Coated with 18%Cr-2.5%Ni-Fe Powder by Laser Cladding and Its Application on Plastic Injection Mold for Aluminum Diecasting

  • Kim, Cheol-Woo;Yoo, Hyo-Sang;Cho, Kyun-Taek;Jeon, Jae-Yeol;Choi, Se-Weon;Kim, Young-Chan
    • Korean Journal of Materials Research
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    • v.31 no.11
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    • pp.601-607
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    • 2021
  • Laser cladding a surface treatment process that grants superior characteristics such as toughness, hardness, and corrosion resistance to the surface, and rebuilds cracked molds; as such, it can be a strong tool to prolong service life of mold steel. Furthermore, compared with the other similar coating processes - thermal spray, etc., laser cladding provides superior bonding strength and precision coating on a local area. In this study, surface characteristics are studied after laser cladding of low carbon steel using 18%Cr-2.5%Ni-Fe powder (Rockit404), known for its high hardness and excellent corrosion resistance. A diode laser with wavelength of 900-1070 nm is adopted as laser source under argon atmosphere; electrical power for the laser cladding process is 5, 6, and 10 kW. Fundamental surface characteristics such as crossectional microstructure and hardness profile are observed and measured, and special evaluation, such as a soldering test with molten ALDC12 alloy, is conducted to investigate the corrosion resistance characteristics. As a result of the die-soldering test by immersion of low carbon alloy steel in ALDC12 molten metal, the clad layer's soldering thickness decreases.

Numerical models for stress analysis of non-uniform corroded tubular members under compression

  • Chinh, Vu Dan;Nguyen, Ha Thi Thu
    • Structural Engineering and Mechanics
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    • v.84 no.4
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    • pp.517-530
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    • 2022
  • In re-assessing the Jacket-type fixed steel structures, the current standards often allow the simplicity of corrosion sections using local buckling or equivalent section approach to applying empirical formulae of frame stress and resistance analyses. However, those approaches can lead to significant errors for non-uniform corroded frames in a specific area, including force distribution, stress, and allowable strength of the tubular section, compared to the actual cases. This paper investigates a suitable approach to determine the actual stress on non-uniform corroded tubular frames under compression through the non-linear ABAQUS model by considering the effect of large deformation on the frame axis and the frame section. There are 3 scenarios of interest. In the 1st and 2nd scenarios with simple corrosion cases, the stress ratios using the numerical model and theoretical formulae correspond to the calculation of allowable strength reduction ratios in standards. However, scenario 3, which describes non-uniform corroded sections based on survey data, provides considerable differences in results. Therefore, it proves the reliable and effective results when using this method to analyze the resistance of the actual corroded section in the Jacket platforms.

Electrochemical Evaluation of Corrosion Property of Welded Zone of Seawater Pipe by DC Shielded Metal Arc Welding with Types of Electrodes (선박 해수배관에서 용접봉의 종류에 따라 직류 아크 용접한 용접부위의 부식특성에 관한 전기화학적 평가)

  • Lee, Sung-Yul;Lee, Kyu-Hwan;Won, Chang-Uk;Na, Shane;Yoon, Young-Gon;Lee, Myeong-Hoon;Kim, Yun-Hae;Moon, Kyung-Man;Kim, Jin-Gyeong
    • Journal of Ocean Engineering and Technology
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    • v.27 no.3
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    • pp.79-84
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    • 2013
  • The seawater pipes in the engine rooms of ships are surrounded by severely corrosive environments caused by fast flowing seawater containing chloride ions, high conductivity, etc. Therefore, it has been reported that seawater leakage often occurs at a seawater pipe because of local corrosion. In addition, the leakage area is usually welded using shielded metal arc welding with various electrodes. In this study, when seawater pipes were welded with four types of electrodes(E4311, E4301, E4313, and E4316), the difference between the corrosion resistance values in their welding zones was investigated using an electrochemical method. Although the corrosion potential of a weld metal zone welded with the E4316 electrode showed the lowest value compared to the other electrodes, its corrosion resistance exhibited the best value compared to the other electrodes. In addition, a heat affected zone welded with the E4316 electrode also appeared to have the best corrosion resistance among the electrodes. Furthermore, the corrosion resistance of the weld metal zone and heat affected zone exhibited relatively better properties than that of the base metal zone in all of the cases welded with the four types of electrodes. Furthermore, the hardness values of all the weld metal zones were higher than the base metal zone.

ALLOY STRUCTURE AND ANODIC FILM GROWTH ON RAPIDLY SOLIDIFIED AL-SI-BASED ALLOYS

  • Kim, H.S.;Thompson, G.E.;Wood, G.C.;Wright, I.G.;Maringer, R.E.
    • Journal of the Korean institute of surface engineering
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    • v.17 no.2
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    • pp.29-40
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    • 1984
  • The structure of rapidly solidified Al-Si-based alloys and its relationship to subsequent anodic film growth in near neutral and acid solutions have been investigated. Solidification of the alloys proceeds via pre-dendritic nuclei, associated with rugosity of the casting surface, from which cellular-type growth, comprised of aluminium-rich material surrounded by silicon-containing material, emanates. Observation of ultramicrotomed sections of the alloys and their anodic films reveals the local oxidation of the silicon-rich phase and its incorporation into the anodic alumina film, formed in near neutral solutions. Such incorporation occurs but resultant isolation of the silicon-rich phase is not possible for anodizing in phosphoric acid, and a three-dimensional network of the oxidized silicon-containing phase, with continuing development of porous anodic alumina, is observed.

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Development of the Condition Assessment Scheme of Aged Ships (노후선박의 Condition Assessment Scheme의 개발)

  • 박영일;백점기;이제명;고재용
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2004.04a
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    • pp.77-82
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    • 2004
  • This study presents reliability assessment of merchant ships with focus on hull girder ultimate limit state, taking into account the time-dependent effects of corrosion, fatigue cracking and local denting. Some considerations for establishing a reliability-based repair and maintenance scheme are also made so as to keep a ship's hull girder strength reliability at an acceptable level even later in life.

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The Durability of Ships Considering Fatigue Cracking

  • Liu, Donald;Thayamballi, Anil
    • Journal of Ship and Ocean Technology
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    • v.1 no.1
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    • pp.57-72
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    • 1997
  • The larger trends related to cracking in ocean going vessels (primarily tankers and bulk carriers) are reviewed on the basis of available data. The typical interrelated causes of such cracking are: high local stresses, extensive use of higher strength steels, inadequate treatment of dynamic loads, adverse operational factors (harsh weather, improper vessel handling), and controllable structural degradation (corrosion, wear, stevedore damage). Three consequences of cracking are then discussed: structural failure, pollution, and increased maintenance. The first two, while rare, are potentially of high consequence including loss of life. The types of solutions that can be employed to improve the durability of ships in the face of fatigue cracking are then presented. For existing vessels, these solutions range from repairs based on structural analysis or service experience, control of corrosion, and enhanced surveys. For new vessels, the use of advanced design procedures that specifically address dynamic loads and fatigue cracking is necessary. As the preferred solution to the problem of cracking in ships, this paper advocates prevention by explicit design by first principles.

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Stress Analysis in Polymeric Coating Layer Deposited on Rigid Substrate

  • Lee, Sang Soon
    • Corrosion Science and Technology
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    • v.14 no.4
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    • pp.161-165
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    • 2015
  • This paper presents an analysis of thermal stress induced along the interface between a polymeric coating layer and a steel substrate as a result of uniform temperature change. The epoxy layer is assumed to be a linear viscoelastic material and to be theromorheologically simple. The viscoelastic boundary element method is employed to investigate the behavior of interface stresses. The numerical results exhibit relaxation of interface stresses and large stress gradients, which are observed in the vicinity of the free surface. Since the exceedingly large stresses cannot be borne by the polymeric coating layer, local cracking or delamination can occur at the interface corner.