• 한국응용과학기술학회지
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• 제40권6호
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• pp.1191-1200
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• 2023

The lithium ion battery has applied to various fields of energy storage systems such as electric vehicle and potable electronic devices in terms of high energy density and long-life cycle. Despite of various research on the electrode and electrolyte materials, there is a lack of research for investigating of the binding materials to replace polymer based binder. In this study, we have investigated petroleum pitch/polymer composite with various ratios between petroleum pitch and polymer in order to optimize the electrochemical and physical performance of the lithium-ion battery based on petroleum pitch/polymer composite binder. The electrochemical and physical performances of the petroleum pitch/polymer composite binder based lithium-ion battery were evaluated by using a charge/discharge test, cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and universal testing machine (UTM). As a result, the petroleum pitch(MP-50)/polymer(PVDF) composite (5:5 wt % ratio) binder based lithium-ion battery showed 1.29 gf mm^-1 of adhesion strength with 144 mAh g^-1 of specific dis-charge capacity and 93.1 % of initial coulombic efficiency(ICE) value.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1997년도 추계학술대회 논문집
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• pp.497-500
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• 1997

Conducting polymer is new material in lithium secondary battery. conducting polymer has a lot of merit which is flexible and good handing so that this material is used battery system, solid polymer electrolytes airs used PEO(Polyethylene oxide) and PEO/PMMA branding material adding by liquid plasticizer or lithium salt polymer electrolyte which is added liquid plasticizer, lithium salt decreased the crystallity and thermal stability is over than 13$0^{\circ}C$. it is very useful tn apply lithium secondary battery system.

• 전기화학회지
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• 제2권1호
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• pp.1-4
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• 1999

리튬이차전지는 충방전의 반복 동안의 액체전해질과 리튬음극과의 반응으로 수지상결정의 성장으로 리튬이 차전지에 있어서 안전성의 문제를 일으킨다. 고분자 전해질은 수지상 결정 형성을 억제하며 전해질에 성능을 향상시키는 연구가 활발히 진행중이다. 본 연구에서는 겔 전해질에 $Al_2O_3$를 첨가하여 전해질의 표면구조와 임피던스 특성을 조사하였다. 리튬이온의 수율은 $10wt\%\;PAN-Al_2O_3$ 전해질에 5mV의 전압을 인가했을 때 0.29였고 전해질의 이온전도도는 상온에서$2.3\times10^{-4} S/cm$였다. 무기 충진제가 고분자 전해질에 첨가되었을 때 이온전도도 및 이온수율은 무기 충진제가 첨가되지 않은 것보다 높게 나타났다.

• 한국전기전자재료학회논문지
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• 제18권1호
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• pp.68-74
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• 2005

In this work, polymerization conditions of the gel polymer electrolyte (GPE) were studied to obtain better electrochemical performances in a lithium-ion polymer battery. When the polymerization temperature and time of the GPE were 70$^{\circ}C$ and 70 min, respectively, the lithium polymer battery showed excellent a rate capability and cycleability. The TMPETA (trimethylolpropane ethoxylate triacrylate)/TEGDMA (triethylene glycol dimethacrylate)-based cells prepared under optimized polymerization conditions showed excellent rate capability and low-temperature performances: The discharge capacity of cells at 2 Crate showed 92.1 % against 0.2C rate. The cell at -20 $^{\circ}C$ also delivered 82.4 % of the discharge capacity at room temperature.

• 전력전자학회논문지
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• 제16권2호
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• pp.199-207
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• 2011

전기 장치용 리튬폴리머 전지의 전기적 모델링은 전기에너지 공급시스템의 특성을 파악하는데 매우 중요하다. 본 논문은 리튬폴리머 전지의 동적특성을 모사하기 위한 전기적 등가 모델을 제안하였다. 리튬폴리머 전지의 충/방전 실험은 Maccor 8500 충방전시험장치를 사용하였다. 측정된 데이터를 이용하여 전지의 R-C 값을 선정하였으며, 선정된 값은 다항식 함수와 지수 함수를 사용하여 수식으로 나타내었다. 시뮬레이션 결과와 실험결과를 비교하여 제안된 모델의 타당성을 검증하였다

• Journal of Electrochemical Science and Technology
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• 제10권2호
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• pp.250-255
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• 2019

Poly(ethylene oxide) (PEO)-based solid polymer electrolytes (SPEs) show promise for improving the lithium ion battery safety. However, due to oxidation of the PEO group and corrosion of the Al current collector, PEO-based SPEs have not previously been effective for use in $LiCoO_2$ (LCO) cathode materials at room temperature. In this paper, a semi-interpenetrating polymer network (semi-IPN) PEO-based SPE was applied to examine the performance of a LCO/SPE/Li metal cell at different voltage ranges. The results indicate that the SPE can be applied to LCO-based lithium polymer batteries with high electrochemical performance. By using a carbon-coated aluminum current collector, the Al corrosion was mostly suppressed during cycling, resulting in improvement of the cell cycle stability.

• 한국조명전기설비학회:학술대회논문집
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• 한국조명전기설비학회 2009년도 춘계학술대회 논문집
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• pp.72-75
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• 2009

In this paper, lithium-ion-polymer battery based standalone photovoltaic energy storage is presented. conventional system was difficult to choose hi-directional DC-DC converter because of unbalanced voltage of batteries. The other side, lithium-ion-polymer battery hardly contains unbalanced voltage between each batteries. And Lithium Polymer Battery is clean battery because is doesn't contain heavy metals such as Nickel, Cadmium. We analyzed validity of algorithms according to load pattern for the system through the simulation and experimental results.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2000년도 추계학술대회 논문집
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• pp.359-362
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• 2000

The purpose of this study is to research and develop graphene composite for lithium polymer battery. VO(graphene) composite is one of the promising material as a electrode active material for lithium polymer battery(LPB). We investigated AC impedance response and charge/discharge cycling of VO(graphene)/SPE/Li cells. The first discharge capacity of VO(graphene) cathode with 50wt.% V$_2$O$\sub$5/ was 150mAh/g, while that of VO(graphene) cathode with 85wt.% V$_2$O$\sub$5/ was 248mAh/g. The Ah efficiency was above 98% after the 2nd cycle. The discharge capacity of VO(graphene) anode with 3wt.% V$_2$O$\sub$5/ was 718 and 266mAh/g at cycle 1 and 10 at room temperature, respectively. The VO(graphene) anode with 3wt.% V$_2$O$\sub$5/ in PVDF-PAN-PC-EC-LiC1O$_4$ electrolyte showed good capacity with cycling.

• 전기학회논문지P
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• 제65권4호
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• pp.340-345
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• 2016

Railway vehicle battery is supplying the power required for the initial start-up of the train, in the event of a fault in the vehicle, or catenary for supplying emergency power is one of the components are very important. Currently, the railway vehicles such as nickel-cadmium batteries are being used [1,2]. Ni-Cd batteries as a battery installed in the railway vehicles have a strong corrosion resistance is included, The charge-discharge performance is significantly degraded in cold weather, there is a danger of deterioration or explosion. Train accidents have been caused a lot of damage due to rapid deterioration and cracking of the battery and memory due to the effect of Ni-Cd batteries. In order to solve the problems, There is no risk of degradation, deterioration and leakage, cracking and exploding. maintenance is simple and applied measures proposed to apply Lithium Polymer battery of high performance. In addition, the lack of capacity problems identified by testing the different special systems is replaced by a 70Ah lithium-polymer battery is possible without changing the batteries of 50Ah caused by installing additional equipment in existing older trains were applied to the vehicle.

• 전력전자학회논문지
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• 제17권6호
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• pp.532-538
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• 2012

This paper proposes the Mathematical Modeling for HEV High-power Lithium-Polymer Battery. The nonlinear system of the Lithium Battery electrical characteristic express mathematical state equation. We also test charge/discharge and temperature experimental used to identify parameters of the cell find parameter of the least error. The proposed model experimental results is used with battery cycler to verify of the proposed model.