• Journal of the Korean Society of Manufacturing Process Engineers
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• v.21 no.9
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• pp.85-91
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• 2022

The demand for electric vehicles has increased because of environmental regulations. The lithium-ion battery, the most widely used type of battery in electric vehicles, is composed of a cathode, an anode, and an electrolyte. It is manufactured according to the pole plate, assembly, and formation processes. To improve battery performance and increase manufacturing efficiency, the manufacturing process must be optimized. To do so, simulation can be used to reduce wasted resources and time, and a finite-element method can be utilized. For high simulation quality, it is essential to reflect the material properties of the electrode by considering the pores. However, the material properties of electrodes are difficult to derive through measurement. In this study, the representative volume element method, which is a homogenization method, was applied to estimate the representative material properties of the electrode considering the pores. The representative volume element method assumes that the strain energy before and after the conversion into a representative volume is conserved. The method can be converted into one representative property, even when nonhomogeneous materials are mixed in a unit volume. In this study, the material properties of the electrode considering the pores were derived. The results should be helpful in optimizing the electrode manufacturing process and related element technologies.

• Journal of Electrochemical Science and Technology
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• v.12 no.2
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• pp.272-278
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• 2021

In this study, high nickel layered LiNi_0.8Co_0.1Mn_0.1O₂ cathode materials for lithium-ion batteries were modified by yttrium doping and poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) coating. The effects of yttrium doping and PEDOT:PSS coating on the structural and electrochemical properties of the LiNi_0.8Co_0.1Mn_0.1O₂ cathode material were investigated and compared. The substitution of nickel with an electrochemically inert yttrium was confirmed to be successful in stabilizing the layered structure framework. Moreover, coating the surfaces of the LiNi_0.8Co_0.1Mn_0.1O₂ particles with a conductive polymer, PEDOT:PSS, improved the capacity retention, thermal stability, and impedance of the cathode material by increasing its ionic and electric conductivities.

• International Journal of Internet, Broadcasting and Communication
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• v.15 no.3
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• pp.129-134
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• 2023

Although the use of batteries is rapidly increasing worldwide to improve carbon neutrality and energy efficiency, performance degradation due to the increase in the number of uses is inevitable as it is a finite resource that can be applied according to capacity and specifications. Deterioration and failure of batteries are recognized as important problems in various applications using batteries, including electric vehicles. In order to solve these problems, a diagnostic technology capable of accurately predicting battery life and grasping state information is required, but it is difficult in a non-linear form due to internal structure or chemical change. In this paper, the factors that generally cause battery performance change are directly applied to check whether there are external changes and impedance changes in the battery, and to analyze whether they affect battery life. Impedance change trends and result values were confirmed using a universal impedance spectroscopy method and a self-developed internal impedance measurement method. The results did not significantly affect the impedance change trend. It was confirmed that the increase in the number of times of battery use was prominent in the impedance change trend.

• Journal of Electrochemical Science and Technology
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• v.14 no.2
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• pp.139-144
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• 2023

In this study, carbon-coated porous nanofibers were prepared via electrospinning and the performance of Li[Ni_0.93Co_0.07]O₂ (NC) synthesized by electrospinning (E-NC) and co-precipitation (C-NC) was compared. E-NC had a discharge capacity of 206 mAh g^-1 at 0.1C (17 mA/g), which is 10% higher than that of C-NC (189.2 mAh g^-1). E-NC shows a high-rate performance of 118.32 mAh g^-1 (61.7%) at 5C (850 mA/g), which is 50% higher than that of C-NC (78.22 mAh g^-1 = 45.7%). Charge transfer of the carbon-coated porous nanofiber E-NC decreased by 35% compared to C-NC after 20 cycles as observed using electrochemical impedance spectroscopy. The results of this study show that the nanofiber structure with carbon coating shortens the Li-ion diffusion path, improves electrical conductivity, resulting in excellent rate performance.

• Journal of Appropriate Technology
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• v.5 no.1
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• pp.33-37
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• 2019

One of main problems in developing electricity grid for archipelago country like Indonesia is the geographical concerns as it consists of many islands. In some rural areas, electricity has not been available yet due to the limited infrastructure access, leading to high investment cost. In this study, a portable energy storage system based on the lithium-ion batteries called Tabung Listrik or TaLis (DC-based power bank) and DC house system were proposed as the solution for providing electricity for rural areas with relatively lower cost. TaLis is designed to be portable so it is easy to carry around as well as it can be used for many purposes. Since 2017, TaLis prototype has been used as the energy storage in a DC house system at Sekolah Master Indonesia, where an array of PV rooftop is functioned as the main DC power supply. Besides, some TaLis were also dispatched for emergency response during the disaster situations in Indonesia, such as during the measles outbreak in Asmat-Papua, the earthquake disaster in Lombok and tsunami in Palu.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2021.11a
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• pp.140-141
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• 2021

ESS refers to a device that can store electrical energy produced by renewable energy generation, etc. and use it when necessary. Lithium-ion batteries are composed of high energy density and combustible electrolyte, so once ignited, it is difficult to extinguish. Many studies have been conducted to solve the problem of the battery itself as the cause of the fire. However, there is also a problem with the structure in which ESS(hereinafter referred to as ESS storage) is installed itself. Therefore, the purpose of this paper is to provide data to solve the problems related to ignition and fire spread due to the problem of ESS storage. In summer, the internal temperature of the ESS storage rises due to solar radiation to trigger a fire, so it is necessary to prevent an internal temperature rise due to solar radiation. Research on standards, materials used, structures, etc. for ESS storage and new regulations are required.

• Journal of Advanced Engineering and Technology
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• v.5 no.4
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• pp.349-353
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• 2012

Recently, Mobile multimedia equipments as smart phone and tablet pc requirement is increasing and this market is also being expanded. These mobile equipments require large multi-media function, so more power consumption is required. For these reasons, the needs of power management IC as switching type dc-dc converter and linear regulator have increased. DC-DC buck converter become more important in power management IC because the operating voltage of VLSI system is very low comparing to lithium-ion battery voltage. There are many people to be concerned about digital DC-DC converter without using external passive device recently. Digital controlled DC-DC converter is essential in mobile application to various external circumstance. This paper proposes the DC-DC Buck Converter using the AVR RISC 8-bit micro-processor control. The designed converter receives the input DC 18-30 [V] and the output voltage of DC-DC Converter changes by the feedback circuit using the A/D conversion function. Duty ratio is adjusted to maintain a constant output voltage 12 [V]. Proposed converter using the micro-processor control was compared to a typical boost converter. As a result, the current loss in the proposed converter was reduced about 10.7%. Input voltage and output voltage can be displayed on the LCD display to see the status of the operation.

• Journal of the Korean Electrochemical Society
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• v.20 no.4
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• pp.67-74
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• 2017

Layered Ni-rich NCM cathode materials $Li[Ni_xCo_{(1-x)/2}Mn_{(1-x)/2}]O_2$ ($x{\geq}0.6$) have advantages of high energy density and cost competitive over $LiCoO_2$. The discharge capacity of NCM increases proportionally to the Ni contents. However, there is a problem that it is difficult to realize the stable electrochemical performance due to cation mixing. In this study, synthesis conditions for the layered Ni-rich NCMs are investigated to achieve deliver the ones having good electrochemical performances. Synthesis parameters are atmosphere, lithium source, synthesis time, synthesis temperature and Li/M (M=transition metal) ratio. The degree of cation mixing gets worse as the Ni content is increased from $Li[Ni_{0.6}Co_{0.2}Mn_{0.2}]O_2$ (NCM6) to $Li[Ni_{0.8}Co_{0.1}Mn_{0.1}]O_2$ (NCM8). It is confirmed that higher level of cation mixing affects negatively on the electrochemical performance of NCMs. Optimum synthesis conditions are explored for NCMx (x=6, 7, 8) in order to reduce the cation mixing. Under optimized conditions for three representative NCMx, a high initial discharge capacity and a good cycle life are obtained for $180mAh{\cdot}g^{-1}$, 96.2% (50 cycle) in NCM6, $187mAh{\cdot}g^{-1}$, 94.7% (50 cycle) in NCM7, and $201mAh{\cdot}g^{-1}$, 92.7% (50 cycle) in NCM8, respectively.

• Journal of the Korean Electrochemical Society
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• v.19 no.3
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• pp.80-86
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• 2016

High Ni content layered oxide materials for the positive electrode in lithium-ion batteries have high specific capacity. However, their poor electrochemical and thermal stability at elevated temperature restrict the practical use. A small amount of $Al_2O_3$ was added to the mixture of transition metal hydroxide and lithium hydroxide. The $LiNi_{0.6}Co_{0.2}Mn_{0.2}O_2$ was simultaneously doped and coated with $Al_2O_3$ during heat-treatment. Electrochemical characteristics of modified $LiNi_{0.6}Co_{0.2}Mn_{0.2}O_2$ were evaluated by the galvanostatic cycling and the LSTA(linear sweep thermmametry) at the constant voltage conditions. The nano-sized $Al_2O_3$ added materials show better cycle performance at elevated temperature than that of micro-sized $Al_2O_3$. As the added amount of nano-$Al_2O_3$ increased, the thermal stability of electrode also enhanced, but the use of 2.5 mol% Al showed the best high temperature performance.

• Clean Technology
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• v.24 no.1
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• pp.77-84
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• 2018

In this study, $Li_4Ti_5O_{12}$ anode materials for lithium ion battery were synthesized by dry ball-mill method. Polyvinyl chloride (PVC) as a carbon source was added to improve electrochemical properties. When the PVC was added after $Li_4Ti_5O_{12}$ formation, the spinel structure was well synthesized and it was confirmed by X-ray diffraction (XRD) experiments. When the carbon material was added before the synthesis and the heat treatment was performed, it was confirmed that a material having a different crystal structure was synthesized even when a small amount of carbon material was added. In the case of $Li_4Ti_5O_{12}$ without the carbon material, the electrical conductivity value was about $10{\mu}S\;m^{-1}$, which was very small and similar to that of the nonconductor. As the carbon was added, the electrical conductivity was greatly improved and increased up to 10,000 times. Electrochemical impedance spectroscopy (EIS) analysis showed that the size of semicircle corresponding to the resistance decreased with the carbon addition. This indicates that the resistance inside the electrode is reduced. According to the Cyclic voltammetry (CV) analysis, the potential difference between the oxidation peak and the reduction peak was reduced with carbon addition. This means that the rate of lithium ion insertion and deinsertion was increased. $Li_4Ti_5O_{12}$ with 9.5 wt% PVC added sample showed the best properties in rate capabilities of $180mA\;h\;g^{-1}$ at 0.2 C-rate, $165mA\;h\;g^{-1}$ at 0.5 C-rate, and $95.8mA\;h\;g^{-1}$ at 5 C-rate.