• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.12
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• pp.339-345
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• 2020

In the field of defense, one-shot devices such as missiles are stored for a long period of time after they are manufactured, so it is essential to predict their storage life. A study was conducted to find the shelf life of a Li-ion battery used in one-shot devices. To do this, a Li-ion battery that has been used in weapon systems for more than 5 years was secured. A non-functional test was performed on the battery to check for external changes or failures. After the non-functional test, a discharge test was performed to measure the performance after storing it. Through the test, the performance was checked, including the initial charging voltage, discharge time, and battery temperature, and the trend of the change was identified. An F-test, One-way ANOVA, and regression analysis were performed to verify the aging, and the shelf life of the battery was estimated by an approximation formula that was derived through a regression analysis. As a result of the ANOVA, the p-value was less than the reference value of 0.05, and the performance of the battery decreased by more than 15% after a certain period of time. This change is assumed to result from the change in physical properties of the lithium polymer cell.

• Journal of Power Electronics
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• v.15 no.3
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• pp.775-785
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• 2015

Many equalization circuits have been proposed to improve pack performance and reduce imbalance. Although bidirectional equalization topologies are promising in these methods, pre-equalization global equalization strategy is lacking. This study proposes a novel state-of-charge (SoC) equalization algorithm for bidirectional equalizer based on particle swarm optimization (PSO), which is employed to find optimal equalization time and steps. The working principle of bidirectional equalization topologies is analyzed, and the reason behind the application of SoC as a balancing criterion is explained. To verify the performance of the proposed algorithm, a pack with 12 LiFePO4 batteries is applied in the experiment. Results show that the maximum SoC gap is within 2% after equalization, and the available pack capacity is enhanced by 13.2%. Furthermore, a comparison between previously used methods and the proposed PSO equalization algorithm is presented. Experimental tests are performed, and results show that the proposed PSO equalization algorithm requires fewer steps and is superior to traditional methods in terms of equalization time, energy loss, and balancing performance.

• Bulletin of the Korean Chemical Society
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• v.32 no.5
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• pp.1483-1490
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• 2011

The protection effect of a $ZrO_2$ coating layer on a $LiCoO_2$ thin film was characterized. A wide and smooth $LiCoO_2$ thin film offers sufficient opportunity for careful observation of the reaction at the interface between cathode (coated and uncoated) and electrolyte. The formation of a $ZrO_2$ coating on a $LiCoO_2$ thin film was confirmed by secondary ion mass spectrometry. Scanning electron and atomic force microscopy were used to characterize the surface morphologies of coated and uncoated films before and after cycling. A $ZrO_2$-coated $LiCoO_2$ film showed a higher discharge capacity and rate capability than an uncoated film. This may be associated with a surface protection effect of the coating. The surface of a pristine film was damaged during cycling, whereas the coated film maintained a relatively clear surface under the same measurement conditions. This result clearly demonstrates the protection effect of a $ZrO_2$ coating on a $LiCoO_2$ thin film.

• JSTS:Journal of Semiconductor Technology and Science
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• v.14 no.5
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• pp.549-556
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• 2014

This paper proposes a highly power-efficient single-inductor multiple-outputs (SIMO) DC-DC converter with a gate charge sharing method in which gate charges of output switches are shared to improve the power efficiency and to reduce the switching power loss. The proposed converter was fabricated by using a $0.18{\mu}m$ CMOS process technology with high voltage devices of 5 V. The input voltage range of the converter is from 2.8 V to 4.2 V, which is based on a single cell lithium-ion battery, and the output voltages are 1.0 V, 1.2 V, 1.8 V, 2.5 V, and 3.3 V. Using the proposed gate charge sharing method, the maximum power efficiency is measured to be 87.2% at the total output current of 450 mA. The measured power efficiency improved by 2.1% compared with that of the SIMO DC-DC converter without the proposed gate charge sharing method.

• Journal of Electrical Engineering and Technology
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• v.12 no.1
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• pp.29-38
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• 2017

This paper presents a study on the state-of-charge (SOC) reference based active cell balancing in real-time. The optimal references of SOC are determined by using the proposed active cell balancing system with the bidirectional DC/DC converters via the dual active bridge (DAB) type. Then, the energies between cells can be balanced by the power flow control of DAB based bidirectional DC/DC converters. That is, it provides the effective management of battery by transferring energy from the strong cell to the weak one until the cell voltages are equalized to the same level and therefore improving the additional charging capacity of battery. In particular, the cell aging of battery and power loss caused from energy transfer are considered. The performances of proposed active cell balancing system are evaluated by an electromagnetic transient program (EMTP) simulation. Then, the experimental prototype is implemented in hardware to verify the usefulness of proposed system.

• Proceedings of the KIPE Conference
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• 2013.11a
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• pp.115-116
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• 2013

Recently environmental problems such as greenhouse gas emissions has become a global problem. As a result, the current that can be easily used to Petroleum and coal reserves of fossil energy and environmental issues, coupled with the limitations of this finding for renewable energy to replace the movement is spreading around the world. Among them Energy Storage System with secondary battery technology has been increased interest in, Redox flow batteries, unlike the conventional theory, the life of the rechargeable battery almost no restrictions existing lithium-ion batteries 10 times more than the life of the road. In this paper, power plant or power system, installed in a building that can cope with the rapid increase in demand for power redox flow battery for 100kW PCS will be introduced.

• Carbon letters
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• v.26
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• pp.1-10
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• 2018

Biochar obtained from the thermal conversion of biomass has high potential as a substitute material for activated carbon and other carbon-based materials because it is economical, environmentally friendly, and carbon-neutral. The physicochemical properties of biochar can also be controlled by a range of activation methods such as physical, chemical, and hydrothermal treatments. Activated biochar can be used as a catalyst for the catalytic pyrolysis of a biomass and as an absorbent for the removal of heavy metal ions and atmospheric pollutants. The applications of biochar are also expanding not only as a key component in producing energy storage materials, such as supercapacitors, lithium ion batteries, and fuel cells, but also in carbon capture and storage. This paper reviews the recent progress on the activation of biochar and its diverse present and future applications.

• Journal of the Korean Ceramic Society
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• v.50 no.2
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• pp.168-172
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• 2013

This work presents the effects of binders on the electrochemical performance of Si-C composites as the anode of lithium ion batteries. PAI (polyamide-imide) was used as an organic binder, and PAN (polyacrylonitrile), PAA (polyacrylic acid) and CMC + SBR (carboxymethyl cellulose + styrene-butadiene rubber) were used as aqueous binders. As a result, stabilization time for the cell with a Si-C composite anode synthesized using aqueous binders became shorter than an organic binder. Particularly in the case of the cell using PAA binder, better performance was observed in terms of adhesion strength, initial efficiency, the volume expansion ratio, Coulombic efficiency, and capacity retention.

• Journal of the Korean Electrochemical Society
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• v.6 no.2
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• pp.98-102
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• 2003

Urethane acrylate oligomer was synthesized and used in a gel polymer electrolyte (GPE) and then its electrochemical performances were evaluated. $LiCoO_2/GPE/graphite$ cells were prepared and their performances depending on discharge currents and temperatures were evaluated. The precursor containing $5 vol\%$ curable mixture had a low viscosity relatively. ionic conductivity of the gel polymer electrolyte at room temperature and $-20^{\circ}C$ was ca. $5.9\times10^{-3}S{\cdot}cm^{-1}\;and\;1.4times10^{-3}S{\cdot}cm^{-1}$, respectively. GPE showed good electrochemical stability up to potential of 4.5V vs. RLi/Li^+.\;LiCoO_2/GPE/graphite$ cell showed a good high-rate and low-temperature performance.

• Applied Chemistry for Engineering
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• v.26 no.1
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• pp.67-73
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• 2015

Using a computational fluid dynamics technique, the flow characteristics and particle residence time in a Taylor reactor were studied. Since flow characteristics in a Taylor reactor are dependent on the operating conditions, effects of the inlet flow velocity and reactor rotational speed were investigated. In addition, the particle residence time of $LiNiMnCoO_2$ (NMC), which is a cathode material in lithium-ion battery, is estimated in the Taylor vortex flow (TVF) region. Without considering the complex chemical reaction at the inlet, the effect of Taylor flow was studied. The results show that the particle residence time increases as the rotating speed increased and the flow rate decreased.