• Journal of the Korean Society for Heat Treatment
• /
• v.25 no.3
• /
• pp.126-133
• /
• 2012

Semi-solid forming of the high melting point alloys such as steel is a promising near-net shape forming process for decreasing manufacturing costs and increasing the quality of the final products. This paper presents the microstructure characteristics of SKH51 (high speed tool steel) during heating and holding in the mushy zone between $1233^{\circ}C$ and $1453^{\circ}C$, which has been measured by differential scanning calorimetry (DSC). The results of heating/holding experiments showed that the grain size and the liquid fraction increased gradually with temperature up to $1350^{\circ}C$. The drastic grain growth occurred at heating above $1380^{\circ}C$. The strain-induced melt-activated (SIMA) process has been applied to obtain globular grains in the billet materials. Working by mechanical upsetting and successive heating of SKH51 into the temperatures in the mushy zone resulted in globular grains due to recrystallization and partial melting.

• Mass Spectrometry Letters
• /
• v.2 no.1
• /
• pp.12-15
• /
• 2011

The Korean government has regulated emission of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) in waste water of manufacturing facilities producing chlorinated compounds since 2009. As this regulation is expected to be reinforced in 2013 to 50 pg I-TEQ/L, a large sample volume is required for the analysis of trace amounts of PCDD/Fs in waste water. Liquid-liquid extraction (LLE) is used to extract PCDD/Fs from aqueous samples; however, its low efficiency makes it inadequate for analyzing large sample volumes. Herein, we present a disk-type solid-phase extraction (SPE) method for the analysis of dioxin at a part per quadrillion level in waste water. This SPE system contains airtight glass covers with a decompression pump, which enables continuous semi-automated extraction. Small (0.5 L) and large (7 L) samples were extracted using LLE and SPE methods, respectively. The method detection limits (MDLs) were 0.001.0.25 and 0.015.4.1 pg I-TEQ/L for the SPE and LLE methods, respectively. The concentrations of detected congeners with both methods were similar. However, the concentrations of several congeners that were not detected with the LLE method were quantified using the SPE method.

• Proceedings of the KIEE Conference
• /
• 1998.07e
• /
• pp.1699-1701
• /
• 1998

This paper was studied on the surface discharge characteristics on the solid insulators in the Liquid Nitrogen($LN_2$) at atmospheric pressure. Liquid Nitrogen has been widely used as a tooling and insulating materials for superconducting and cryogenic cable. Considering the effect of bubbles, we observed tracking Phenomena on the surface of solid insulators and investigated surface breakdown characteristics of several solid insulators.

• Journal of the Society of Cosmetic Scientists of Korea
• /
• v.24 no.3
• /
• pp.73-80
• /
• 1998

This Study was performed to get the suitable oil dispersion agent by assessment of color strength of organic pigment in non-aqueous systems. Organic pigment is used as a color expression material with other body pigments in the make-up products. But occasionally aggregation or agglomeration occurs for the lack of affinity with medium, This function is the cause of disturbing homogeneous dispersion, and then bring about an instability of products. Our study, research of dispersion mechanism between the pigment and oil phase, has been executed to solve this problem, and find a oil dispersion agent having optimum dispersion condition. Generally dispersion is related to between the solid-liquid mutual properties and electrical phenomena associated with solid-liquid interface. This factor is determined to input energy, milling time, optical properties, particle size, rheological properties, etc. Ideal dispersion state is told that coloring primary solid particle is homogeneously dispersed in medium. Good dispersed colorants are strongly and clearly appeared. We are already known that the particle size of organic pigment, chemical properties and viscosity of medium, refractive index. Consequently We determine the affinity of medium and organic pigment by measuring of color strength in the same mechanical condition. UV-VISIBLE RECORDING SPECTRO PHOTOMETER is used for measuring apparatus. We can decided the dispersion level of oil dispersion agent by measuring absorbance of color strength in the visible range that diluted medium for colloid colorant particles.

• Journal of Welding and Joining
• /
• v.20 no.5
• /
• pp.93-98
• /
• 2002

The effect of bonding misfit on single crystallization of transient liquid phase (TLP) bonded joints of single crystal superalloy CMSX-2 was investigated using MBF-80 insert metal. The bonding misfit was defined by (100) twist angle (rotating angle) at bonded interface. TLP bonding of specimens was carried out at 1523K for 1.8ks in vacuum. The post-bond heat treatment consisted of the solution and sequential two step aging treatment was conducted in the Ar atmosphere. The crystallographic orientation analysis across the TLP bonded joints was conducted three dimensionally using the electron back scattering pattern (EBSP) method. EBSP analyses f3r the bonded and post bonded heat treated specimens were conducted. All bonded joints had misorientation centering around the bonded interface for as-bonded and post-bond heat treated specimens with rotating angle. The average misorientation angle between both solid phases in bonded interlayer was almost identical to the rotating angle at bonded interface. HRTEM observation revealed that the atom arrangement of both solid phases in bonded interlayer was quite different across the bonded interface. It followed that grain boundary was formed in bonded interface. It was confirmed that epitaxial growth of the solid phase occurred from the base metal substrates during TLP bonding and single crystallization could not be achieved in joints with rotating angle.

• Solar Energy
• /
• v.10 no.2
• /
• pp.44-58
• /
• 1990

Heat transfer characteristics of heat storing processes in paraffin-filled horizontal circular cylinder is studied. The unmelted solid paraffin is allowed to fall on the bottom wall under gravity. In the upper liquid phase, natural convection is considered to take place while in the lower liquid film between the solid paraffin and the wall conduction is thought to take place instead. Experimental analyses are also carried out. The amount of the latent heat stored is obtained by recording the time wisely changing side area of the solid paraffin photographically. The mass of paraffin melted in the upper section is obtained by substracting the amount of melted mass in the lower section from the total mass melted and therefrom variation of heat transfer rate in each section is studied.

• Bulletin of the Korean Chemical Society
• /
• v.30 no.1
• /
• pp.61-66
• /
• 2009

An analytical method based on solid-phase extraction and gas chromatography / mass spectrometry has been developed for measurement of acaricides (amitraz, bromopropylate, coumaphos, cymiazole, and tetradifon) in honey sample. In the stability test of acaricides in honey, amitraz underwent a rapid degradation into 2,4-dimethylaniline (DMA), 2,4-dimethylphenylformamide (DMPF), and N-(2,4-dimethylphenyl)-N'-methylformamidine (DMPMF), whileas other acaricides were found to be stable even for over three months. Extraction of five acaricides from 5g of honey sample was carried out by liquid-liquid extraction using 20mL of ethylacetate. For purification, Florisil-SPE cartridge with elution of 5mL of n-hexane/ acetone (55:45, v/v) was found to remove interferences effectively. Quantification was performed using gas chromatography / mass spectrometry in the selected ion monitoring mode. Spiking experiments were carried out to determine the recovery, precision, and limits of detection (LODs) of the method. The overall recovery values from honey spiked at 0.02 and 0.20 ${\mu}g/g$ levels, respectively, were found to be greater than 75% for all acaricides. The method detection limits for acaricides were ranged from 0.1 to 3 ppb. The developed method in this study was applied for the monitoring of acaricides in honey products collected from urban markets in Korea.

• Structural Engineering and Mechanics
• /
• v.29 no.1
• /
• pp.91-111
• /
• 2008

This paper outlines the development of a computational model in order to analyze the dynamic behaviour of coupled fluid-structure systems such as a) liquid containers, b) a set of parallel or radial plates. In this work a hybrid fluid-solid element is developed, capable of simulating both membrane and bending effects of the plate. The structural mass and stiffness matrices are determined using exact integration of governing equations which are derived using a combination of classical plate theory and a finite element approach. The Bernoulli equation and velocity potential function are used to describe the liquid pressure applied on the solid-fluid element. An impermeability condition assures a permanent contact at the fluid-structure interface. Applications of this model are presented for both parallel and radial plates as well as fluid-filled rectangular reservoir. The effect of physical parameters on the dynamic behaviour of a coupled fluid-structure system is investigated. The results obtained using the presented approach for dynamic characteristics such as natural frequency are in agreement to those calculated using other theories and experiments.

• Journal of the Korean Solar Energy Society
• /
• v.36 no.1
• /
• pp.19-26
• /
• 2016

Biomass has been used for energy sources from the prehistoric age. Biomass are converted into solid, liquid or gaseous fuels and are used for heating, electricity generation or for transportation recently. Solid biofuels such as bio-chips or bio-pellet are used for heating or electricity generation. Liquid biofuels such as biodiesel and bioethanol from sugars or lignocellulosics are well known renewable transportation fuels. biogas produced from organic waste are also used for heating, generation and vehicles. Biomass resources for the production of above mentioned biofuels are classified under following 4 categories, such as forest biomass, agricultural residue biomass, livestock manure and municipal organic wastes. The energy potential of those biomass resources existing in Korea are estimated. The energy potential for dry biomass (forest, agricultural, municipal waste) were estimated from their heating value contained, whereas energy potential of wet biomass (livestock manure, food waste, waste sludge) is calculated from the biological methane potential of them on annual basis. Biomass resources potential of those 4 categories in Korea are estimated to be as follows. Forest biomass 355.602 million TOE, agricultural biomass 4.019 million TOE, livestock manure biomass 1.455 million TOE, and municipal organic waste 1.074 million TOE are available for biofuels production annually.

• Journal of Ocean Engineering and Technology
• /
• v.35 no.2
• /
• pp.121-130
• /
• 2021

In this study, a computational fluid dynamics (CFD) simulation based on an Eulerian-Eulerian approach was used to evaluate the mixing performance of a mud agitator through the distribution of bulk particles. Firstly, the commercial CFD software Star-CCM+ was verified by performing numerical simulations of single-phase water mixing problems in an agitator with various turbulence models, and the simulation results were compared with an experiment. The standard model was selected as an appropriate turbulence model, and a grid convergence test was performed. Then, a simulation of the liquid-solid multi-phase mixing in an agitator was simulated with different multi-phase interaction models, and lift and drag models were selected. In the case of the lift model, the results were not significantly affected, but Syamlal and O'Brien's drag model showed more reasonable results with respect to the experiment. Finally, with the properly determined simulation conditions, a multi-phase flow simulation of a mud agitator was performed to predict the mixing time and spatial distribution of solid particles. The applicability of the CFD multi-phase simulation for the practical design of a mud agitator was confirmed.