• Korean Journal of Materials Research
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• v.8 no.10
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• pp.884-889
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• 1998

Amorphous silicon films of large area have been crystallized by a line shape excimer laser beam of one dimensional scanning with a gaussian profile in the scanning direction. In order to characterize the crystalline phase transition of thickness variables in excimer laser annealing(ELA), angle wrapping method was used. And also to characterize the residual stresses of crystalline phase transition in the case of angle wrapped-crystalline silicon on corning 7059 glass, polarized raman spectroscopies were measured at various laser energy density and substrate temperature. The residual stress varies from $9.0{\times}10^9$ to $9.9{\times}10^9$, and from $9.9{\times}10^9$ to $1.2{\times}10^10$dyne/${cm}^2$ of the substrate temperature at room temperature and varies from $8.1{\times}10^9$ to $9.0{\times}10^9$, and from $9.0{\times}10^9$ to $9.9{\times}10^9$dyne/${cm}^2$ of the substrate temperature at $400^{\circ}C$ as a function of direction from surface to substrate. According to the direction from the surface in liquid phase to the interface and from the interface to near the substrate in solid phase of recrystallized Si thin film, respectively. Thus, the stress is increased from(Liquid phase to solid phase) with phase transition.

• Journal of the Korean Ceramic Society
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• v.34 no.11
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• pp.1099-1106
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• 1997

In the present study, the effect of TiB2 addition on the sintering behavior of ZrB2 ceramics was studied with hot pressing under Ar atmosphere. Hot pressing experiments were carried out in graphite dies at the 1$700^{\circ}C$, 180$0^{\circ}C$ under Ar atmosphere. The sintering density increased with increasing TiB2 contents. With the addition of 10wt% TiB2 almost theoretical density could be achieved by hot-pressing at 180$0^{\circ}C$. Zr-Ti-Fe-B compound in liquid phase was observed from the EDS and WDS analysis. It was considered that sinterability was enhanced due to the mass transfer through liquid phase formed at the sintering temperature. In addition of TiB2, transition metal of groups IV, substitutional solid solution could be formed.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.11 no.10
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• pp.4041-4046
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• 2010

Wholly aromatic polyesters having flexible alkoxy side chain were synthesized by direct polycondensation. The synthetic polymers have been characterized by $^1H$-NMR, FT-IR. DSC, TGA, optical polarizing microscope and X-ray diffractometer. The inherent viscosities (${\eta}_{inh}$) measured in 1,1,2,2-tetrachloroethane (TCE) were 0.46~2.41 dL/g. The polymers having side chain showed double melting transition, ie, solid-sanidic liquid crystalline (LC) phase transition ($T_{m1}$) and sanidic LC phase-nematic LC phase transition ($T_{m2}$). As incresing length of alkoxy side chain, phase transition temperatures decreased and solubilities in organic solvents incresed. The peaks of $2{\theta}\;{\simeq}5$ and $2{\theta}\;{\simeq}20$ in X-ray diffractograms are due to crystallization of polymer main chain and of long side chain, respectively.

• 한국전산유체공학회:학술대회논문집
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• 2003.10a
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• pp.21-22
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• 2003

We perform two kinds of computer simulations on polydisperse hard-sphere systems; a molecular-dynamics simulation on atomic systems and a Brownian-dynamics simulation on colloidal suspensions. Analyses of the mean square displacement, the radial distribution function, and the pressure suggest that there exist three phase regions, a liquid phase region, a metastable phase region, and a crystal phase region, where the freezing and melting points are shifted to the values higher than in monodisperse case. It is also shown that the long-time behavior of colloidal suspensions is exactly the same as that of atomic systems.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.23 no.8
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• pp.945-956
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• 1999

This work reports a set of approximate analytical solutions describing the initial transient process of close-contact melting between a rectangular parallelepiped solid and a flat plate on which either constant temperature or constant heat flux is imposed. Not only relative motion of the solid block tangential to the heating plate, but also the density difference between the solid and liquid phase is incorporated in the model. The thin film approximation reduces the force balance between the solid weight and liquid pressure, and the energy balance at the melting front into a simultaneous ordinary differential equation system. The normalized model equations admit compactly expressed analytical solutions which include the already approved two-dimensional solutions as a subset. In particular, the normalized liquid film thickness is independent of all pertinent parameters, thereby facilitating to define the transition period of close-contact melting. A unique behavior of the solid descending velocity due to the density difference is also resolved by the present solution. A new geometric function which alone represents the three-dimensional effect is introduced, and its properties are clarified. One of the representative results is that heat transfer is at least enhanced at the expense of the increase in friction as the cross-sectional shape deviates from the square under the same contact area.

• Archives of Pharmacal Research
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• v.9 no.2
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• pp.75-79
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• 1986

The effect of phenothiazine derivatives on the thermotropic transition of liposomal lipid bilayer made of dipalmitoyl phosphatidylchline and dipalmitoyl phosphatidic acid was investigated with differential scanning calorimetry. The thermograms of the liposomal bilayer incorporated with levomepromazine, chlopromazine, prochloperazine, perphenazine and fluphenazine were obtained and the size of cooperative unit of the transition were calculated from the ratio of the van't Hoff enthalpy change to the calculated enthalpy change of the transition. The results showed that incorporation of phenothiazine derivatives into the liposomal bilayer reduced the transition temperature at which the transition from solid state to liquid-crystalline state occurs, and broadened the thermogram peaks. Phenothiazine derivatives also significantly reduced the size of cooperative unit of the transition. The effect of the drugs was proportional to the concentration of the drug in the bilayer. This means that phenothiazine derivatives might have significant fluidizing effects on the biomembrane. The sizes of cooperative unit were successfully corrlated with phar-macological activities of the drugs and the surface pressure increases of lipid monolayer by these drugs. These correlations might be ascribed to a possible hydrophobic nature of interaction between the biomembrane and the drugs involved in their pharmacology.

• Archives of Pharmacal Research
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• v.11 no.3
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• pp.181-184
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• 1988

The effect of clover saponin on the phase transition of liposomal lipid bilayers of dimyristoyl phosphatidylcholine was investigated with differential scanning calorimetry. The thermograms of the liposomal bilayers incorporated with the clover saponin were obtained, and the enthalpy changes and the sizes of cooperative unit of the transition were calculated. The results showed that incorporation of the clover saponin into the liposomal bilayers effectively reduced the transition temperature at which the transition from solid state to liquid-crystalline state occurs, and broadened the thermogram peaks. It also reduced the size of cooperative unit of the transition. These results indicate that the clover saponin might have significant effect on the fluidity of biological membranes.

• Geomechanics and Engineering
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• v.13 no.1
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• pp.1-23
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• 2017

A coupled liquid-gas-solid three-phase model, linking two numerical codes (TOUGH2/EOS3 and $FLAC^{3D}$), was firstly established and validated by simulating an in-situ air flow test in Essen. Then the coupled model was employed to investigate responses of multiphase flow and soil skeleton deformation to compressed air or freshwater injection using the same simulation conditions in an aquifer of Tianjin, China. The simulation results show that with injecting pressurized fluids, the vertical effective stress in some area decreases owing to the pore pressure increasing, an expansion of soil skeleton appears, and land uplift occurs due to support actions from lower deformed soils. After fluids injection stops, soil deformation decreases overall due to injecting fluids dissipating. With the same applied pressure, changes in multiphase flow and geo-mechanical deformation caused by compressed air injection are relatively greater than those by freshwater injection. Furthermore, the expansion of soil skeleton induced by compressed air injection transfers upward and laterally continuously with time, while during and after freshwater injection, this expansion reaches rapidly a quasi-steady state. These differences induced by two fluids injection are mainly because air could spread upward and laterally easily for its lower density and phase state transition appears for compressed air injection.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.37 no.4
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• pp.445-450
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• 2024

The expansion of lithium-ion battery usage beyond portable electronic devices to electric vehicles and energy storage systems is driven by their high energy density and favorable cycle characteristics. Enhancing the stability and performance of these batteries involves exploring solid electrolytes as alternatives to liquid ones. While sulfide-based solid electrolytes have received significant attention for commercialization, research on amorphous-phase glass solid electrolytes in oxide-based systems remains limited. Here, we investigate the glass transition temperatures and sintering behaviors by changing the molecular ratio of Li₂O/B₂O₃ in borate glass comprising Li₂O-B₂O₃-Al₂O₃ system. The glass transition temperature is decreasing as increasing the amount of Li₂O. When we sintered at 450℃, just above the glass transition temperature, the samples did not consolidate well, while the proper sintered samples could be obtained under the higher temperature. We successfully obtained the borate glass ceramics phases by melt-quenching method, and the sintering characteristics are investigated. Future studies could explore optimizing ion conductivity through refining processing conditions, adjusting the glass former-to-modifier ratio, and incorporating additional Li salt to enhance the ionic conductivity.

• Bulletin of the Korean Chemical Society
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• v.25 no.5
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• pp.694-698
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• 2004

A new method for the simultaneous determination of seven transition metal ions in water and food by microcolumn high-performance liquid chromatography has been developed. The lead, cadmium, mercury, nickel, cobalt, silver and tin ions were pre-column derivatized with tetra-(4-aminophenyl)-porphyrin ($T_4$-APP) to form the colored chelates which were then enriched by solid phase extraction with $C_{18}$ cartridge. The enrichment factor of 50 was achieved by eluted the retained chelates from the cartridge with tetrahydrofuran (THF). The chelates were separated on a ZORBAX Stable Bound microcolumn ($2.0{\times}50\;mm,\;1.8\;{\mu}m$)with methanol-tetrahydrofuran (95 : 5, v/v, containing 0.05 mol/L pyrrolidine-acetic acid buffer salt, pH = 10.0) as mobile phase at a flow rate of 0.5 mL/min and detected with a photodiode array detector from 350-600 nm. The seven chelates were separated completely within 2.0 min. The detection limits of lead, cadmium, mercury, nickel, cobalt, silver and tin are 4 ng/L, 3 ng/L, 6 ng/L, 5 ng/L, 5 ng/L, 6 ng/L, 4 ng/L respectively in the original samples. This method was applied to the determination of the seven transition metal in water and food samples with good results.