• Title/Summary/Keyword: Liquid types

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Fluctuation of Solid-Liquid Interface of Faceted Phase and Nonfaceted Phase by Periodic Temperature Variation

  • Oh, Sung-Tag;Kim, Young Do;Song, Young-Jun;Suk, Myung-Jin
    • Korean Journal of Materials Research
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    • v.26 no.11
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    • pp.644-648
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    • 2016
  • In order to examine how the solid-liquid interface responds to temperature variation depending on the materials characteristics, i.e. faceted phase or nonfaceted phase, the moving solid-liquid interface of transparent organic material, as a model substance for metallic materials (pivalic acid, camphene, salol, and camphor-50wt% naphthalene) was observed in-situ. Plots of the interface movement distance against time were obtained. The solid-liquid interface of the nonfaceted phase is atomically rough; it migrates in continuous mode, giving smooth curves of the distance-time plot. This is the case for pivalic acid and camphene. It was expected that the faceted phases would show different types of curves of the distance-time plot because of the atomically smooth solid-liquid interface. However, salol (faceted phase) shows a curve of the distance-time plot as smooth as that of the nonfaceted phases. This indicates that the solid-liquid interface of salol migrates as continuously as that of the nonfaceted phases. This is in contrast with the case of naphthalene, one of the faceted phases, for which the solid-liquid interface migrates in "stop and go" mode, giving a stepwise curve of the distance-time plot.

Solidification Analysis for Surface Defect Prediction of Rheology Forming Process Considering Flow Phenomena of Liquid and Solid Region (액상과 고상의 유동현상을 고려한 레오로지 성형공정의 표면결함예측을 위한 응고해석)

  • Seo, Pan-Ki;Jung, Young-Jin;Kang, Chung-Gil
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.26 no.10
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    • pp.1971-1981
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    • 2002
  • Two-dimensional solidification analysis during rheology forming process of semi-solid aluminum alloy has been studied. Two-phase flow model to investigate the velocity field and temperature distribution is proposed. The proposed mathematical model is applied to the die shape of the two types. To calculate the velocities and temperature fields during rheology forming process, the each governing equations correspondent to the liquid and solid region are adapted. Therefore, each numerical model considering the solid and liquid coexisting region within the semi-solid material have been developed to predict the defects of rheology forming parts. The Arbitrary Boundary Maker And Cell(ABMAC) method is employed to solve the two-Phase flow model of the Navier-Stokes equation. Theoretical model basis of the two-phase flow model is the mixture rule of solid and liquid phases. This approach is based on using the liquid and solid viscosity. The Liquid viscosity is pure liquid state value, however solid viscosity is considered as a function of the shear rate, solid fraction and power law curves.

Liquid-Liquid Dispersion of an Immiscible Liquid Phase (n-Hexane/Water) System in a Stirred Tank (교반조에서 비혼화성 액상(n-헥산/물)계의 액-액분산)

  • Kim, Tae-Ok;Kim, Dong-Uk;Chun, Jong-Han
    • Applied Chemistry for Engineering
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    • v.4 no.3
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    • pp.537-543
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    • 1993
  • The effect of agitation on liquid-liquid dispersion was investigated in an immisible liquid phase(n-hexane/water) system. Four different types of six-bladed turbine impellers were used: a flat blade, two screen blades and a solid edged 60 mesh screen blade. We found that the extent of dispersion of organic phase and power consumption of agitator were decreased in the order of flat, solid edged, 60 mesh, and 40 mesh blades at same agitation speed. And the minimum agitation speed for complete dispersion of organic phase was increased with increasing volume fraction of organic phase. Also, mean diameter of liquid droplets of dispersed phase was decreased with increasing agitation speed and it was increased in the order of solid edged, flat, 60 mesh, and 40 mesh screen blades at same agitation speed. At complete dispersion, the minimum power consumption was not vary significantly with impeller blade types, but the solid edged screen blade impeller gave the smallest and uniform sizes of liquid droplets, and it had a good performance for liquid-liquid dispersion. In this condition, Power number was not affected by Reynolds number and it was constant in turbulent flow region, and Sauter mean diameter($d_{32}$) of liquid droplets was expressed as a function of volume fraction of organic phase(${\phi}$) and Weber number($N_{We}$) as follows: $d_{32}/D=a(1+b{\phi})N_{We}{^{-0.6}}$.

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Process Analysis for Rheology Forming Considering Flow and Solidification Phenomena in Lower Solid Fraction (저고상율 소재의 유동 및 응고현상을 고려한 레올로지 성형공정해석)

  • Jung, Young-Jin;Cho, Ho-Sang;Kang, Chung-Gil
    • Journal of the Korean Society for Precision Engineering
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    • v.18 no.9
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    • pp.156-164
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    • 2001
  • Two-dimensional solidification analysis during rheology forming process of semi-solid aluminum alloy has been studied. Two-phase fluid flow model to investigate the velocity field and temperature distribution is proposed. The proposed mathematical model is applied to the die shape of the two types. To calculate the velocity and temperature fields during rheology forming process, the earth governing equation correspondent to the liquid and solid region are adapted. Therefore, each numerical models considering the solid and liquid region existing within the semi-solid material have been developed to predict the deflect of rheology forming gnarls. The Arbitrary Boundary Maker And Cell (ABMAC) method is employed to solve the two-phase flow model of the Navier-Stokes equation. Theoretical model on the basis of the two-phase flow model is the mixture rule of solid and liquid phases. This approach is based on the liquid and solid viscosity. The liquid viscosity is pure liquid state value, however solid viscosity is considered as a function of the shear rate, solid fraction and power law curves.

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The Effect of Storage Container Types on Odor Emission and Quality of Piggery Liquid Slurry Fertilizer in the farms (농가의 돈분액비 저장형태가 악취발생과 액비품질에 미치는 영향)

  • Park, Moo-Eon;Kang, An-Seok;Kim, Si-Chang
    • Korean Journal of Soil Science and Fertilizer
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    • v.39 no.3
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    • pp.136-143
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    • 2006
  • The study was carried out to evaluate odor emission during storage time and quality of liquid slurry fertilizer along with three storage container types installed at farmer's fields in Cheorwon. Liquid slurry manure stored in the liquid-circulated or the air-injected tank was very homogeneous in concentration of nutritional elements because of well mixing operation, while nutritional concentration of the manure stored in the non-treated tank was significantly different from top to bottom in the tank, which may bring about partially irregular growth of plant after its application. The potential capacity of offensive odor emitted from liquid slurry manure stored in the liquid-circulated or the air-injected tank was much lower than that emitted from manure stored in the non-treated tank. Low potential capacity may less emit offensive odor after application of piggery liquid slurry on the field. The efficiency in oder to reduce odor emission from liquid manure was slightly higher in the liquid-circulated tank than the air-injected tank

Evaluation of Exposure to Indoor Volatile Organic Compounds by Utilizing Emission Characteristics and Emission Factor of Household Mosquito Repellents (가정용 모기살충제의 배출 특성 및 배출계수를 이용한 실내 휘발성 유기화합물질 노출 평가)

  • Jo, Wan-Kuen;Lee, Jong-Hyo
    • Journal of Environmental Science International
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    • v.18 no.10
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    • pp.1123-1134
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    • 2009
  • This study was designed to evaluate qualitatively and quantitatively the pollutant compositions, which were emitted from three types of mosquito repellents(MRs)(mat-, liquid-vaporized, and coil-type) by utilizing a 50-L environmental chamber. A qualitative analysis revealed that 42 compounds were detected on the gas chromatography/mass spectrometer system, and that the detection frequency depended upon chemical types. Nine of the 42 compounds exhibited a detection frequency of 100%. Four aromatic compounds(benzene, ethyl benzene, toluene, and xylene) were detected in all test MRs. The concentration equilibriums in the environmental chamber were achieved within 180 min after sample introduction. The coil-type MR represented higher chamber concentrations as compared with the mat- or liquid-vaporized-type MR, with respect to the target compounds except for naphthalene. In particular, the chamber concentrations of ethyl benzene, associated with the use of coil-type MR, were between 0.9 and $65\;mg\;m^{-3}$ whereas those of mat- and liquid-vaporized-type MRs we~e between 0.5 and $2.0\;mg\;m^{-3}$and 0.3 and $1.4\;mg\;m^{-3}$, respectively. However, naphthalene concentrations in the chamber, where a liquid-vaporized-type MR was placed, were measured as between 17.8 and $56.3\;mg\;m^{-3}$, but not detected in the chamber, where a mat- or coil-type MR was placed. The empirical model fitted well with the time-series concentrations in the environmental chamber(in most cases, determination coefficient, $R^2$ ≿ 0.9), thereby suggesting that the model was suitable for testing emissions. In regards to the target compounds except for benzene, although they were emitted from the MRs, health risk from individual exposure to them were estimated not to be significant when comparing exposure levels with no observed adverse exposure levels or lowest observed adverse exposure levels of corresponding compounds. However, it was concluded that the use of MRs could be an important indoor source as regards benzene.

Liquid-Liquid Extraction for Recovery of Paclitaxel from Plant Cell Cultures by Adding Inorganic Salts (식물세포배양으로부터 파클리탁셀 회수를 위한 무기염이 첨가된 액-액 추출)

  • Ha, Geon-Soo;Kim, Jin-Hyun
    • Korean Chemical Engineering Research
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    • v.54 no.1
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    • pp.135-139
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    • 2016
  • We developed a liquid-liquid extraction method using an inorganic salt to dramatically improve the recovery efficiency of the anticancer agent paclitaxel from plant cell cultures. As a result of liquid-liquid extraction using a diverse types of inorganic salt (NaCl, KCl, $K_2HPO_4$, $NaH_2PO_4$, $NaH_2PO_4{\cdot}2H_2O$), NaCl gave the highest yield (~96%) and lowest partition coefficient (0.053) of paclitaxel. The optimal NaCl/solvent ratio, methylene chloride/MeOH ratio, and pure paclitaxel content for liquid-liquid extraction using NaCl were 1% (w/v), 26% (v/v), and 0.066% (w/v), respectively. Under the optimal conditions developed in the present method, most of the paclitaxel (~96%) was recovered from biomass by a single extraction step. In addition, this method facilitated 3-fold higher recovery efficiency of paclitaxel in a shorter extraction number than the conventional liquid-liquid extraction method.

The color comparison of zirconia fabricated by using various coloring liquids (수종의 색소체용액으로 제작된 유색 지르코니아의 색조비교)

  • Oh, Gye-Jeong;Jung, Jong-Hyun
    • Journal of Technologic Dentistry
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    • v.36 no.4
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    • pp.247-253
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    • 2014
  • Purpose: The aim of this study was to evaluate the effect of colored zirconia with different coloring liquids. Methods: Total 30 specimens were prepared. Specimens were classified into 6 groups: IPS e.max Ceram(P), Uncolored zirconia(C), VITA In-Ceram$^{(R)}$2000 YZ LL1(L), Zirkonzahn coloring liquid(Z), Wieland coloring liquid(W), and Kuwotech coloring liquid(K). Four different types of zirconia coloring liquid, VITA In-Ceram$^{(R)}$ 2000 YZ LL1(VITA Zahnfabrik, Germany), Zirkonzahn coloring liquid(Zirkonzahn, Italy), Wieland coloring liquid(Wieland, Germany), Kuwotech coloring liquid(Kuwotech, Korea) were used to fabricate colored zirconia by using infiltrating method and then completely sintered. The color of the all specimens was measured using the spectrophotometer(CM-2600d, Konica Minolta, Japan) and expressed in terms of the 3-coordinated values(CIE $L^*a^*b^*$). Color differences were calculated using the equation $${\Delta}E^*=[({\Delta}L^*)^2+({\Delta}a^*)^2+({\Delta}b^*)^2]^{1/2}$$. Results: $L^*a^*b^*$ values of the colored zirconia were affected by the coloring liquids. The uncolored zirconia(C) group showed the highest $L^*$ value and zirkonzahn coloring liquid(Z) group showed the lowest $L^*$ value. Zirkonzahn coloring liquid(Z) showed the highest $a^*$ value and VITA In-Ceram 2000 YZ LL1(L) group showed the highest $b^*$ value. Generally, the color difference(${\Delta}E^*$) in all groups showed higher than 3.7 except between IPS e.max Ceram(P) and wieland coloring liquid(W) group. Conclusion: Within the limitations of this study, various coloring liquids influenced the $L^*$, $a^*$, and $b^*$ values of colored zirconia. IPS e.max Ceram(P) and wieland coloring liquid(W) group did not show clinically perceiving color difference.

Thermal Performance Test of Liquid Cooling Type Cold Plates for Robot Cooling (로봇 냉각을 위한 수냉식 냉각판의 열적 성능 평가)

  • Karng, Sanrng-Woo;Lee, Suk-Won;Hwang, Kyu-Dae;Kim, Seo-Young
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.1864-1869
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    • 2007
  • In this study, we compare thermal performance between four different types of cold plates for humanoid robot cooling. Two commercially available cold plates made of copper have different dimensions and internal flow paths: One has $20{\times}20$ $mm^2$ base area with micro-channels and the other has $62.5{\times}62.5$ $mm^2$ base area with 85 round pin-fins. And two different types of cold plates of $20{\times}20$ $mm^2$ base area with 7 mm high are made of PC (polycarbonate), which aims to reduce the weight of cooling system. All cold plates are mounted on a $20{\times}20$ $mm^2$ copper block with two cartridge heaters of 30 $W/cm^2$. The overall heat transfer coefficient and thermal resistances for the liquid-cooled cold plates are obtained. The copper cold plate with micro-channels showed the best performance. Polycarbonate cold plates display fairly good thermal performance with more reduced system weight.

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Evaluation of Apparent Viscosity Properties for Electro-Rheological Fluid (ER유체의 겉보기 점도특성 평가에 관한 연구)

  • ;Morishita, Shin
    • Tribology and Lubricants
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    • v.14 no.2
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    • pp.42-48
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    • 1998
  • Electro-Rheological (ER) fluid is a class of functional fluid whose apparent viscosity can be varied by the applied electric field strength. The ER fluid is classified into two types; one is a dispersive fluid and the other is a homogeneous. Dispersive ER fluid is a colloidal suspension of fine semiconducting particles in a dielectric liquid and liquid crystal (LC) is classed as homogeneous type ER fluid. LC has been originally developed for some electronic display devices. Various mechanical components applying ER fluid have been developed, and the their performance typically depends on the characteristics of ER fluid which have generally been evaluated by a rotational viscometer. However, the ER fluid introduced into various mechanical components undergoes not only simple shear flow but press flow or oscillating flow. For the evaluation of ER fluid, the authors developed an reciprocating type viscometer. The amplitude is controlled on 5 mm at the frequency from 50 to 1000 Hz. In the present paper, the performance of several types of ER fluid is evaluated by the reciprocating type viscometer and compared with those evaluated by a rotational viscometer.