• 제목/요약/키워드: Liquid Film Evaporation

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단일액상원료를 사용하는 MOCVD법에 의한 YBa$_2Cu_3O_x$ 박막 제조에 관한 연구 (Preparation of YBa$_2Cu_#O_x$ films by MOCVD using single liquid solution source)

  • 김보련;이희균;홍계원;지영아;신형식
    • 한국초전도학회:학술대회논문집
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    • 한국초전도학회 1999년도 High Temperature Superconductivity Vol.IX
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    • pp.129-132
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    • 1999
  • A new single solution source MOCVD technique for the deposition of YBCO film has been developed, using a ultrasonic atomizer to feed the precursors into an evaporation zone. This method being investigated as a basis for future long wire fabrication, for example the electric power use, the magnatic applications, etc.. YBCO films were prepared on MgO(100) substrate, using mixture of Y, Ba, and Cu ${\beta}$ -diketonate chelate was dissolve in tetrahydrofuran as a solution sources. X-ray diffraction measurement indicated that the thin film grew epitaxially with the c-axis orientation perpandicular to the surface of the surface.

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키토산을 이용한 유기 발광 소자에 관한 연구 (A Sutdy on Organic Emission Device of Chitosan Used)

  • 정기택;강수정;김남기;노승용
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 하계학술대회 논문집 Vol.5 No.2
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    • pp.1062-1065
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    • 2004
  • The importance of display is becoming increasingly important due to the development of information and industry where it leads to diverse and abundant information in today's society. The demand and application range for FPD(Flat Panel Display), specifically represented by LCD(Liquid Crystal Display) and PDP(Plasma Display Panel), have been rapidly growing for its outstanding performance and convenience amongst many other forms of display. The current focus has been on OLED(Organic Light Emitting Diode) in the mobile form, which has just entered into mass production amid the different types of FPD. Many studies are being conducted in regards to device, vacuum evaporation, encapsulation, and drive circuits with the development of device as a matter of the utmost concern. This study develops a new type of light-emitting materials by synthesizing medical polymer organic chitosan and phosphor material CuS. Chitosan itself satisfies the Pool-Frenkel Effect, an I-V specific curve, with a thin film under $20{mu}m$, and demonstrates production possibility for a living body sensors solely with the thin film. Furthermore, it enables production possibility for EML of organic EL device(Emitting Layer) with liquid Green light emitting and Blue light emitting as a result of synthesis with phosphor material.

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수직관내 미포화수의 강제대류 천이비등에 대한 역학적 모델 (A Mechanistic Model for Forced Convective Transition Boiling of Subcooled Water in Vertical Tubes)

  • Lee, Kwang-Won;Baik, Se-Jun;Han, Sang-Good;Joo, Kyung-Oin;Yang, Jae-Young
    • Nuclear Engineering and Technology
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    • 제27권4호
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    • pp.503-517
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    • 1995
  • 강제대류 천이비등 열유속을 보다 실제 적으로 예측하기 위한 역학적 모델을 개발하였다. 이 모델은 가열된 벽면 근처를 어떤 기포기둥(Vapor Blanket)이 통과할 때 일어나는 다단계 비등과정 즉, 임계 기포기둥의 형성, 기포기둥밑의 미소액막(Macrolayer)의 기화 및 고갈, 그리고 얇은 기체막에서 일어나는 불안정한 막비등과정에 기초하였다. 핵비등이탈점 (DNB )과 막비등이탈점 (DFB)사이의 천이비등 곡선상의 열유속은 임계 기포기둥이 주어진 벽면을 통과할 동안 상기한 각 비등과정의 지속 시간비(Time Fraction)를 각 비등열유속에 곱한 후 그것을 합하여 정량화하였다. 이 모델의 예측치를 현재까지 발표된 문헌들에 나타난 실험치와 비교한 결과, 본 모델은 저건도 및 10 bar 근처의 고압조건의 실험치를 잘예측하는 것으로 나타났다.

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Refinement of Gd2O3 inclusions in the GdBa2Cu3O7-δ films fabricated by the RCE-DR process

  • Park, I.;Oh, W.J.;Lee, J.H.;Moon, S.H.;Yoo, S.I.
    • 한국초전도ㆍ저온공학회논문지
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    • 제20권4호
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    • pp.46-49
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    • 2018
  • To improve in-field critical current densities ($J_c$) of $GdBa_2Cu_3O_{7-{\delta}}$ (GdBCO) coated conductors(CCs) fabricated by the reactive co-evaporation by deposition and reaction (RCE-DR) process, employing the nominal composition of Gd:Ba:Cu=1:1:2.5, we tried to refine the $Gd_2O_3$ particles trapped in the GdBCO superconducting matrix. For this purpose, we carefully selected the processing conditions on the stability phase diagram of GdBCO for this composition. By lowering the growth temperature of $Gd_2O_3$ in the liquid, we could refine the average particle size of $Gd_2O_3$ particles trapped in the GdBCO matrix and also achieve the zero-resistive transition temperatures ($T_{c,zero}$) of 92.3~94.2 K. Unfortunately, however, it was unsuccessful to achieve enhanced in-field $J_c$ values from these samples because of an air-contamination of the amorphous precursor film before its conversion into crystalline GdBCO film, suggesting that any exposure of the amorphous precursor film to air is fatal in obtaining high performance GdBCO CCs via the RCE-DR process.

빛의 간섭현상을 이용한 증기용착 성장속도 측정법의 실험적 연구 (Optical(Interferometric) Measurements of Vapor Deposition Growth Rate and Dew Points in Combustion Gases)

  • 김상수;송영훈
    • 대한기계학회논문집
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    • 제10권3호
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    • pp.343-348
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    • 1986
  • 본 연구는 이와 같은 필요성에 의해 빛의 간섭현상을 이용하여 액체막이 부차 적인 유동을 일으키기 이전에 용착성장속도를 정량적으로 측정할 수 있었고, 터어빈 날개의 부식에 직접적으로 문제를 일으키는 황산나트륨과 황산칼륨의 용착성장속도를 측정하였다. 본 연구는 종래 액체막의 성장속도만을 빛의 간섭현상을 이용하여 측정 해오던 측정범위를 광원으로 사용된 레이저의 편광상태, 굴절율, 입사각등의 변화에 따른 간섭신호의 비교연구를 통해 고체상태막의 성장속도 및 막이 기화되어 증발되는 현상도 측정하였다. 따라서 증기상태의 무기염이 금속표면에 용착될 때 적용해온 Rosner의 이론을 실험결과와 비교할 수 있었고 응축된 상태로 증기에 표함되어 있는 경우와 이슬점(dew point:표면에 더 이상 용착이 일어나지 못하는 표면온도)의 해석에 보다 확장된 개념들을 도입할 수 있었다.

ELECTROCHROMIC BEHAVIOR OF AMORPHOUS NICKELPHTHALOCYANINE THIN FILMS

  • Masui, Masayoshi;Suzuki, Masato;Kaneko, Fujio;Takeuchi, Manabu
    • 한국표면공학회지
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    • 제29권6호
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    • pp.735-738
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    • 1996
  • Amorphous nickelphthalocyanine(NiPc) thin films were prepared by vacuum evaporation and their electrochromic behavior and voltammograms were examined in the five kinds of aqueous electrolytes. Amorphous NiPc films were prepared on indium-tin-oxide(ITO) glass substrates cooled to-$120^{\circ}C$ by using liquid nitrogen under a vacuum of $2.4 \times 10^{-4}$. The voltammetric and electrochromic measurements were made using a potential galvanostat. In order to confirm the color change, optical vis-transmission spectra of the NiPc films were measured by a spectrophotometer with various electrode potential applied. The NiPc amorphous thin films exhibited most clearly electrochromism in $KNO_3$ aqueous electrolyte. The specimen films underwent 3 color transitions (from blue to yellow-green, then to red violet, then to dark blue), corresponding to the three peaks on the voltammograms in $KNO_3$ aqueous electrolyte. Blue is color of the as-prepared film. When the potential was swept, charge compensation was attained upon oxidation by injection of anions from the electrolyte and upon reduction by expulsion of anions.

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마이크로핀 관의 기하학적 형상면화에 대한 열전달 특성(II) -증발 열전달- (Heat transfer with geometric shape of micro-fin tubes (II) -Evaporating heat transfer-)

  • 곽경민;장재식;배철호;정모
    • 설비공학논문집
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    • 제11권6호
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    • pp.789-798
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    • 1999
  • The evaporating heat transfer experiments with refrigerant HCFC 22 are performed for performance evaluation using 4 and 6 kinds of microfin tubes with outer diameter of 9.52mm and 7.0mm, respectively. Used microfin tubes have different shape and number of fins with each other, The experimental results are represented with effects of quality, mass flux and EPR. The evaporating heat transfer characteristics are represented by the existence of not only heat transfer area and turbulence promotion effect but also additional other enhancement mechanism, which are the overflow of the refrigerant over the microfin and microfin arrangement. Microfin tubes having a shape which can give much overflow over the microfin show large evaporating heat transfer coefficients. The effect of refrigerant overflow is much severe in evaporation than condensation. The effect of microfin arrangement is related to overflow effect of the refrigerant over the microfin.

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튜닝폭 거리조절 센서를 이용한 근접장 마이크로파 현미경의 수중 측정을 위한 연구 (A Study for a Near-Field Microwave Microscope Using a Tuning Fork Distance Control System in liquid Environment)

  • 김송희;유형근;;김종철;이기진
    • 비파괴검사학회지
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    • 제27권4호
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    • pp.345-353
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    • 2007
  • 근접장 마이크로파 현미경을 이용하여 수중에서 시료의 표면이미지에 대한 비파괴적 측정에 관한 연구를 하였다. 이때 근접장 마이크로파 현미경은 3.5-5.5 GHz에서 작동되었다. 본 연구에서는 수중에서 시료의 표면특성을 손상 없이 측정하기 위해 강성힘을 이용한 튜닝폭(tuning fork) 거리조절 시스템으로 팁과 시료 사이의 거리를 10 nm로 유지하였다. 더불어, 공기 및 수중에서 튜닝폭의 진동진폭의 변화와 공진주파수의 변화를 측정하여 수중에서 튜닝폭리 반응특성을 저하시키는 원인에 대해 알아보았다. 물 속에 시료가 충분히 잠기고, 동시에 물의 영향을 최소화하기 위해 팁의 길이를 2 mm로 제작하여 튜닝폭의 한 쪽면에 붙였다. 또한 측정과정에서 나타나는 증발현상을 해소하기 위해 엑츄에이터를 이용하여 보충용 수조를 제작하였으며, 보다 정확한 수중측정을 위해 보정프로그램을 응용하였다. 이를 통해, 시료의 공기 및 수중 측정의 가능성을 확인하기 위해 도체시료의 표면특성을 관측하고 비교하였다.

VISUALIZATION AND MEASUREMENT OF A NARROW-CONE DI GASOLINE SPRAY FOR THE IMPINGEMENT ANALYSIS

  • Park, J.S.;Im, K.S.;Kim, H.S.;Lai, M.C.
    • International Journal of Automotive Technology
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    • 제5권4호
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    • pp.221-238
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    • 2004
  • Wall interactions of direct injection spray were investigated using laser-sheet imaging, shadowgraphy, wetted footprint and phase Doppler interferometry techniques. A narrow-cone high-pressure swirl injector is used to inject iso-octane fuel onto a plate, which has three different impact angles inside a pressurized chamber. Heated air and plate conditions were compared with unheated cases. Injection interval was also varied in the heated case to compare dry- and wet- wall impingement behaviors. High-speed macroscopic Mie-scattering images showed that presence of wall and air temperature has only minor effect on the bulk spray structure and penetration speed for the narrow-cone injector tested. The overall bulk motions of the spray plume and its spatial position at a given time are basically unaffected until a few millimeters before impacting the wall. The surface properties of the impact surface, such as the temperature, the presence of a preexisting liquid film also have a small effect on the amount of wetting or the wetted footprint; however, they have strong influence on what occurs just after impact or after a film is formed. The shadowgraph in particular shows that the plate temperature has a significant effect on vapor phase propagation. Generally, 10-20% faster horizontal vapor phase propagation is observed along the wall at elevated temperature condition. For impingement onto a preexisting film, more splash and evaporation were also observed. Contrary to some preconceptions, there is no significant splashing and droplet rebounding from surfaces that are interposed in the path of the DI gasoline spray, especially for the oblique impact angle cases. There also appears to be a dense spray front consists of large sac spray droplets in the oblique impact angle cases. The bulk of the spray is not impacted on the surface, but rather is deflected by it The microscopic details as depicted by phase Doppler measurements show that the outcome of the droplet impaction events can be significantly influenced. Only droplets at the spray front have high enough Weber numbers for wall impact to wet, splash or rebound. Using the sign of vertical velocity, the time-resolved downward droplets and upward droplets are compared. The Weber number of upward moving droplets, which seldom exceeds unity, also decreases as the impact angle decreases, as the droplets tend to impact less and move along the wall in the deflected spray plume.

극세관 헬리컬 코일 증발관내 R-22의 열전달 및 압력손실 특성 (Characteristics of Heat Transfer and Pressure Drop of R-22 Inside an Evaporating Tube with Small Diameter Helical Coil)

  • 김주원;김정훈;서석기;김정훈;김종수
    • 대한기계학회논문집B
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    • 제24권5호
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    • pp.699-708
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    • 2000
  • To make compact evaporator, experiments that show characteristics of evaporating heat transfer and pressure drop in the helically coiled small diameter tube were taken in this research. The experiments were performed with HCFC-22 in the helically coiled small diameter tube; inner diameter=1.0(mm), tube length=2.0(m), and curvature diameter=31, 34, 46.2(mm). The experiments were also carried out with the following test conditions; saturation pressure=0.588(MPa), mass velocity=$150{\sim}500(kg/m^2s)$, and heat flux=$1{\sim}5(kW/m^2)$. The experiment results are that the empirical correlation to predict heat transfer coefficient for single phase flow in helically coiled small diameter tube was obtained. It was found that dry-out is occurred at low-quality region for evaporation heat transfer because of breaking of annular liquid film. The friction factor of single phase flow of helically coiled tube was agreed with Prandtl's correlation. Finally, It was proposed for correlation that can precisely predict the friction factor of two phase flow of helically coiled tube.