• Title/Summary/Keyword: Light irradiation

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Studies on the Graft Polymerization-Graft Polymerization of Styrene to Polyvinyl Alcohol by Ultraviolet Light (Graft 重合에 關한 硏究-紫外線 照射에 依한 Polyvinyl alcohol 과 Styrene 의 Graft 重合에 關하여)

  • Shim, Jyong-Sup;Jun, Kyong-Chul
    • Journal of the Korean Chemical Society
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    • v.6 no.1
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    • pp.64-68
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    • 1962
  • The graft polymerization of styrene to polyvinyl alcohol using a photosensitizer(benzophenone) and ultraviolet light was studied. Styrene was grafted onto polyvinyl alcohol up to when polyvinyl alcohol was pre-immersed in water and irradiated by ultraviolet light for 24 hours styrene solution of benzophenone(0.01 molarity). The highest percentage of graft obtained in the grafting which was proceeded in the presence of water added immediately before irradiation was 29%. The grafting was proportional to irradiation time within a certain limit of time, i.e., 24 hours, and presumably was initiated at the surface. After a certain degree of grafting a definite maximum was reached. Graft polymer prepared in this experiment showed high resistance to various solvents.

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Photodegration Properties of Dye in TiO$_2$ Nanocomposite (TiO$_2$ 나노합성물에서 Dye의 광열화 특성)

  • 정재훈;조종래;문정오;양종헌;문병기;손세모;정수태
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.517-520
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    • 2001
  • The optical properties of TiO$_2$ thin films dispersed in epoxy film, which were prepared with bits-(4,4'-P-toluenesulfonylacidic isoproplyidene) cycolhexadiol(BTSPC) and UVI 6990 in dry sol-gel process, were investigated. In the case of irradiating UV light on TiO$_2$ thin films, how many nanoparticles of TiO$_2$ are dispersed in epoxy film was investigated by AFM. The absorption peak of the films was showed at 360nm. Squarylium dye was dispersed in TiO$_2$-epoxy film. Photodegration concerned with amount of dye and time of UV light irradiation was investigated. UV light irradiation on the film occurred dramatical photodegration.

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Realization of Static Image on OLEO using Photoluminescence Degradation (PL Degradation을 활용한 OLED 소자의 사진 이미지 구현)

  • Suh, Won-Gyu;Moon, Dae-Gyu
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.9
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    • pp.859-862
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    • 2008
  • We have realized static image on organic light emitting diodes (OLEDs) using photoluminescence degradation. Ultraviolet (UV) was irradiated to the glass side of device. UV power was 350 Wand the wavelength was 365 nm. The UV irradiation gives rise to the degradation of photoluminescence. Due to the degradation, the current density-voltage curve was shifted to the higher voltage side and the luminescence was also degraded by the current and photoluminescence drop. The negative imaged films were prepared to control the transmittance of UV. The UV light was passed through the film. By this method, the film image was transferred to the device with reversed image and the static image was realized on the OLED.

PHOTOCATALYTIC REACTION OF $TiO_2$ FOR PURIFICATION OF AIR

  • Yin, X.J.;Cai, R.X.
    • Journal of the Korean institute of surface engineering
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    • v.32 no.3
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    • pp.336-339
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    • 1999
  • Photo-excited $TiO_2$ surface has a strong ability to induce various chemical reactions. Our study concentrates mainly on the utilisation of light energy to induce reactive radicals for environmental protection application. For instance, we have successfully used TiO$_2$ to break down foul smelling substances in air. In order to retain and separate the $TiO_2$ catalyst from the reactants and products, $TiO_2$ was immobilised by fixing onto various substrates. $TiO_2$ catalyst coated onto glass, wall paper and painted panel was found to show significant deodorising effect. The deodorising effect continues as long as$TiO_2$ is exposed to light irradiation.

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Fabrication Of Ultraviolet LED Light Source Module Of Current Limiting Diode Circuit By Using Flip Chip Micro Soldering (마이크로솔더링을 이용한 정전류다이오드 회로 자외선 LED 광원모듈 제작)

  • Park, Jong-Min;Yu, Soon Jae;Kawan, Anil
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.4
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    • pp.237-240
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    • 2016
  • The improvement of irradiation intensity and irradiation uniformity is essential for large area and high power UVA light source application. In this study, large number of chips bonded by micro soldering technique were driven by low current, and current limiting diodes were configured to supply constant current to parallel circuits consisting of large number of series strings. The dimension of light source module circuit board was $350{\times}90mm^2$ and 16,650 numbers of 385 nm flip chip LEDs were used with a configuration of 90 parallel and 185 series strings. The space between LEDs in parallel and series strings were maintained at 1.9 mm and 1.0 mm distance, respectively. The size of the flip chip was $750{\times}750{\mu}m^2$ were used with contact pads of $260{\times}669{\mu}m^2$ size, and SAC (96.5 Sn/3.0 Ag/0.5 Cu) solder was used for flip chip bonding. The fabricated light source module with 7.5 m A supply current showed temperature rise of $66^{\circ}C$, whereas irradiation was measured to be $300mW/cm^2$. Inaddition, 0.23% variation of the constant current in each series string was demonstrated.

Feasibility Study of Cylindrically Diffusing 532 nm Wavelength for Treatment of Pancreatic Cancer

  • Park, Jin-Seok;Jeong, Seok;Lee, Don Haeng;Zheng, Hong-Mei;Kang, Hyun Wook;Bak, Jinoh;Choi, Jongman
    • Journal of the Korean Physical Society
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    • v.73 no.11
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    • pp.1619-1624
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    • 2018
  • Laser ablation may provide a minimally invasive palliative treatment for pancreatic cancer. The aim of the current study was to assess the feasibility of a 532-nm laser equipped with a cylindrical light diffuser for the treatment of pancreatic cancer. Monolayers of BxPC-3 human pancreatic cancer cell were exposed to 532 nm laser light. Power levels of 5 - 7 W were used to uniformly target the entire cell colonies for 60 and 120 seconds. The cells were incubated for 24 hours after treatment and viabilities were determined by using a MTT assay. Laser ablation was performed by using the cylindrical light diffuser on six pancreatic tumor tissues obtained from pancreatic cancer xenograft mouse models, which were exposed to the 532 nm light at 5W or 7W for 10 to 30 seconds. In the in vitro study, the survival rates of the pancreatic cancer cells were reduced by 6.6% to 98.9% after the treatment, and the survival rates were reduced by increasing laser power and/or irradiation time. In the pancreatic tumor tissues, a homogenous circular ablation zone was observed in all tumors and the ablation distance induced by the laser irradiation showed to be constant from the diffuser to all directions (standard deviation, 0.3 - 1.3 mm). Ablation distance and area increased with increasing laser power and/or irradiation time. The 532 nm laser effectively killed pancreatic cancer cells, and the cylindrical light diffuser was found to be suitable for laser ablation as it provided uniform ablation in pancreatic cancer.

Effects of Some Environmental Factors on Mycerial Growth, Sporulation and Sclerotial Formation of Botrytis elliptica (Berk.) Cooke (백합(百合) 잎마름병균(病菌)의 균사생장(菌絲生長), 포자형성(胞子形成) 및 균핵형성(菌核形成)에 미치는 몇가지 환경요인(環境要因)의 영향(影響))

  • Park, Jong Seong;Kim, Hong Gi
    • Korean Journal of Agricultural Science
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    • v.15 no.1
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    • pp.9-14
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    • 1988
  • This experiment was conducted to study the effect of some environmental factors on mycerial growth, sporulation and sclerotial formation of Botrytis elliptica cultured on artificial media. Mycerial growth of B. elliptica was the most favorable on V-8 juice agar among the seven different media tested and sporulation of the fungus was favorable on the medium under NUV light irradiation. Abundant conidia could be obtained from V-8 juice agar medium by NUV light irradiation after 3 days of incubation at $23^{\circ}C$ under darkness. The optimum temperature for mycerial growth and conidial germination was $23^{\circ}C$ and the mycerial growth was favorable at relatively lower temperature ranged $19^{\circ}C$ to $23^{\circ}C$. The optimum pH of the medium for mycerial growth of this fungus ranged 4.5 to 5.0 and that was inhibited at higher pH of the media. Mycerial growth of the fungus was not highly influenced by irradiation of fluorescent light, however sporulation was stimulated under NUV light irradiation. Sclerotia of B. elliptica were formed when it was cultured at lower temperature below $19^{\circ}C$.

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Changes in Allicin Contents of Garlic via Light Irradiation (광 조사에 의한 마늘의 알리신 함량 변화)

  • Jeong, Hoon;Lee, Sun-Ho;Yun, Hong-Sun;Choi, Seung-Ryul
    • Food Science and Preservation
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    • v.20 no.1
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    • pp.81-87
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    • 2013
  • Agri-food garlic has been recognized as healthful because of its antibacterial, anticancer and antioxidant effects. As such, its consumption is steadily increasing. This study was conducted to amplify the healthful ingredient of garlic, allicin, using light irradiation. The following conclusions were drawn from the investigation of peeled garlic under various conditions like fluorescent lighting, color (green, yellow, blue and red) and ultraviolet light (UV-A, UV-B and UV-C). The allicin content increased most with the 15-second $0.129W/m^2$ (40 W) UV-B treatment of the garlic at a 700 mm distance from the light source. At the treatment of the garlic with 126 lx (40W) red light for 24 hours at a 700 mm distance from the light source, its allicin content increased from $15.15{\pm}0.25mg/g$ to $15.15{\pm}0.34mg/g$, for a 10-percent amplification effect. Therefore, it is believed that the healthfulness of garlic can be amplified through irradiation processing of its healthful ingredient, allicin, and the development of its processing unit.

Novel Bi2S3/TiO2 Heterogeneous Catalyst: Photocatalytic Mechanism for Decolorization of Texbrite Dye and Evaluation of Oxygen Species

  • Zhu, Lei;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.53 no.1
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    • pp.56-62
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    • 2016
  • A heterogeneous $Bi_2S_3/TiO_2$ composite catalyst was synthesized via a green ultrasonic-assisted method and characterized by XRD, SEM, EDX, TEM analysis. The results clearly show that the $TiO_2$ particles were homogenously coated with $Bi_2S_3$ particles, indicating that $Bi_2S_3$ particle agglomeration was effectively inhibited after the introduction of anatase $TiO_2$. The Texbrite BA-L (TBA) degradation rate constant for $Bi_2S_3/TiO_2$ composites reached $8.27{\times}10^{-3}min^{-1}$ under visible light, much higher than the corresponding value of $1.04{\times}10^{-3}min^{-1}$ for $TiO_2$. The quantities of generated hydroxyl radicals can be analyzed by DPCI degradation, which shows that under visible light irradiation, more electron-hole pairs can be generated. Finally, the possible mechanism for the generation of reactive oxygen species under visible-light irradiation was proposed as well. Our result shows the significant potential of $Bi_2S_3$-semiconductor-based $TiO_2$ hybrid materials as catalysts under visible light for the degradation of industry dye effluent substances.

Evaluation on the Photodegradation Rate of NOx Using High Efficiency Visible-Light Responsive Photocatalysts (고효율 가시광 반응형 광촉매를 이용한 NOx의 광저감율 평가)

  • Cha, Ji An;An, Sang Hun;Cho, Eun hee;Kim, Tae Oh
    • Particle and aerosol research
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    • v.6 no.4
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    • pp.165-172
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    • 2010
  • Titania is widely used as an effective photocatalyst for the photodegradation of environmental pollutants in air. In this study, novel N-doped $ZrO_2/TiO_2$ photocatalysts were synthesized via sol-gel method and characterized by UV-Vis spectrophotometer, transmission electron microscope, and X-ray diffractometer. N-doped $ZrO_2/TiO_2$ photocatalysts were nano-sized with an average particle size of about 20 nm. The XRD pattern of N-doped $ZrO_2/TiO_2$ photocatalysts showed both anatase and rutile phases. The photocatalytic activity of N-doped $ZrO_2/TiO_2$ photocatalysts was evaluated by degradation of NO under UV and visible light irradiation at various parameters such as amount of photocatalyst, concentration of NO, and intensity of light. The photocatalytic activity of N-doped $ZrO_2/TiO_2$ photocatalysts was effective for the enhancement of the degradation of NO and higher than that of $TiO_2$ photocatlysts under UV and visible light irradiation.