• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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• pp.361-362
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• 2007

Phospho-olivine $LiFePO_4$ cathode materials were prepared by hydrothermal reaction. Carbon black was added to enhance the electrical conductivity of $LiFePO_4$. The structural and morphological performance of $LiFePO_4$ and $LiFePO_4$-C powders were characterized by X-ray diffraction (XRD) and FE-SEM. $LiFePO_4/SPE/Li$ and $LiFePO_4$-C/SPE/Li cells were characterized electrochemically by charge/discharge experiments. The results showed that the discharge capacity of $LiFePO_4$-C/SPE/Li cell was 103 mAh/g at the first cycle. The discharge capacity of $LiFePO_4$-C/SPE/Li cell with 5 wt% carbon black was the largest among $LiFePO_4$-C/SPE/Li cells, 126 mAh/g at the first cycle and 123 mAh/g after 30 cycles, respectively. It was demonstrated that cycling performance of $LiFePO_4$-C/SPE/Li cell with 5 wt% carbon black was better than that of $LiFePO_4$/SPE/Li cell.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2011년도 추계학술대회 초록집
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• pp.137.2-137.2
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• 2011

Poly (sodium 4-styrenesulfonate) (PSS) is ionomer based on polystyrene that is electrical conductivity and isoviscosity. LiFePO4 has been a promising electrode material however its poor conductivity limits practical application. To enhance the electronic conductivity of LiFePO4, in this study we prepared LiFePO4- PSS composite by the hydrothermal method. LiFePO4 was heated at $170^{\circ}C$ for 12h and then different wt% PSS (0%, 2.91%, 4.75%, 7.36%, 10%) are added to LiFePO4 and milled at 300rpm for 10h. And then the obtained powders were subsequently heated at $500^{\circ}C$ for 1h under argon flow. The cathode electrode were made from mixtures of LiFePO4-PSS: SP-270- PVDF in a weighting ratio 75%: 25%:5%. The electrochemical properties of LiFePO4- PSS/Li batteries were analyzed by cyclic voltammetry and charge/discharge tests. LiFePO4-C/Li battery with 4.75 wt% PSS displays discharge capacity of 128 mAh g-1 at room temperature that is considerably higher than pure LiFePO4/Li battery ( 113.48 mAhg-1).

• Transactions on Electrical and Electronic Materials
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• 제8권1호
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• pp.41-45
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• 2007

Phospho-olivine $LiFePO_4$ cathode materials were prepared by hydrothermal reaction. Carbon black was added to enhance the electrical conductivity of $LiFePO_4$. The structural and morphological performance of $LiFePO_4$ and $LiFePO_4$-C powders were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM) and transmission electron microscope (TEM). $LiFePO_4$/Li and $LiFePO_4$-C/Li cells were characterized electrochemically by cyclic voltammogram (CV), charge/discharge experiments and ac impedance spectroscopy. The results showed that the discharge capacity of $LiFePO_4$/Li cell was 147 mAh/g at the first cycle and 118 mAh/g after 30 cycles, respectively. The discharge capacity of $LiFePO_4$-C/Li cell with 5 wt% carbon black was the largest among $LiFePO_4$-C/Li cells, 133 mAh/g at the first cycle and 128 mAh/g after 30 cycles, respectively. It was demonstrated that cycling performance of $LiFePO_4$-C/Li cell with 5 wt% carbon black was better than that of $LiFePO_4$/Li cell.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2006년도 추계학술대회 논문집 광주전남지부
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• pp.48-52
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• 2006

Phospho-olivine $LiFePO_4$ cathode materials were prepared by hydrothermal reaction. Carbon black was added to enhance the electrical conductivity' of $LiFePO_4$. The structural and morphological performance of $LiFePO_4$ and $LiFePO_4$-C powders were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM) and transmission electron microscope (TEM). $LiFePO_4$/Li and $LiFePO_4-C$/Li cells were characterized electrochemically by cyclic voltammogram (CV), charge/discharge experiments and ac impedance spectroscopy. The results showed that the discharge capacity of $LiFePO_4$/Li cell was 147 mAh/g at the first cycle and 118 mAh/g after 30 cycles, respectively. The discharge capacity of $LiFePO_4-C$/Li cell with 5wt% carbon black was the largest among $LiFePO_4-C$/Li cells, 133 mAh/g at the first cycle and 128 mAh/g after 30 cycles, respectively. It was demonstrated that cycling performance of $LiFePO_4-C$/Li cell with 5wt% carbon black was better than that of $LiFePO_4$/Li cell.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2009년도 추계학술대회 논문집
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• pp.132-132
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• 2009

Phospho-olivine $LiFePO_4$ cathode materials were prepared by hydrothermal reaction. In this study, Multi-walled carbon nanotube (MWCNT) and Carbon black was added to enhance the electrical conductivity of $LiFePO_4$. $LiFePO_4$, $LiFePO_4$-MWCNT and $LiFePO_4$-C particles were characterized by X-ray diffraction (XRD), field emission scanning electron microscope (FE-SEM) transmission electron microscope (TEM). $LiFePO_4/SPE/Li$, $LiFePO_4$-MWCMT/SPE/Li and $LiFePO_4$-C/SPE/Li cells were characterized electrochemically by charge/discharge experiments at a constant current density of $0.1mA\;cm^{-2}$ in a range between 2.5 and 4.3 V vs. $Li/Li^+$ and cyclic voltammetry (CV).

• Bulletin of the Korean Chemical Society
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• 제34권2호
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• pp.433-436
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• 2013

Carbon-coated $Li_3V_2(PO_4)_3-LiMnPO_4$ composite cathode materials are first reported in this work, prepared by the mechanochemical process with a complex metal oxide as the precursor and sucrose as the carbon source. X-ray diffraction pattern of the composite material indicates that both olivine $LiMnPO_4$ and monoclinic $Li_3V_2(PO_4)_3$ co-exist. We further investigated the electrochemical properties of our $Li_3V_2(PO_4)_3-LiMnPO_4$ composite cathode materials using galvanostatic charging/discharging tests, where our $Li_3V_2(PO_4)_3-LiMnPO_4$ composite electrode materials exhibit the charge/discharge efficiency of 91.9%, while $Li_3V_2(PO_4)_3$ and $LiMnPO_4$ exhibit the efficiency of 87.7 and 86.7% in the first cycle. The composites display unique electrochemical performances in terms of overvoltage and cycle stability, displaying a reduced gap of 141.6 mV between charge and discharge voltage and 95.0% capacity efficiency after $15^{th}$ cycles.

• 한국전기전자재료학회논문지
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• 제19권6호
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• pp.519-523
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• 2006

$LiFePO_4$ has been received attention as a potential cathode material for the lithium secondary batteries. In our study, $LiFePO_4$ cathode active materials were synthesized by a solid-state reaction. It was modified by coating $TiO_2$ and carbon in order to enhance cyclic performance and electronic conductivity. $TiO_2$ and carbon coatings on $LiFePO_4$ materials enhanced the electronic conductivity and its charge/discharge capacity. For lithium polymer battery applications, $LiFePO_4$/solid polymer electrolyte (SPE)/Li and $LiFePO_{4}-TiO_{2}/SPE/Li$ cells were characterized by a cyclic voltammetry and charge/discharge cycling. The electrode with $LiFePO_{4}-carbon-TiO_{2}$ in PVDF-PC-EC-$LiClO_{4}$ electrolyte showed promising capacity of above 100 mAh/g at 1C rate.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2005년도 춘계학술대회 논문집
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• pp.5-9
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• 2005

$LiFePO_4$ is a potential candidate for the cathode material of the lithium polymer batteries. $LiFePO_4$ cathode active materials were synthesized by coating on the $LiFePO_4$ was tried using $TiO_2$ and corbon in oreder to increase cyclic performance and electronic conductivity. Highly dispersed on the particles enhances the electronic conductivity and increases the capacity. For lithium polymer battery applications, $LiFePO_4$/SPE/Li and $LiFePO_4$-$TiO_2$/SPE/Li 'cells were characterized electrochemically by cyclic volatammetry and charge/discharge cycling. The $LiFePO_4$-carbon-$TiO_2$ cathode in PVDF-PC-EC-$LiCIO_4$ electrolyte showed high capacity at high current density.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2009년도 추계학술대회 논문집
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• pp.133-133
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• 2009

Phospho-olivine $LiFePO_4$ and $LiTi_{0.1}Fe_{0.9}PO_4$ cathode materials were prepared by the solid-state reaction. To improve conductivity we carried out electrochemical performance of $Ti^{2+}$ doped $LiFePO_4$. The $Ti^{2+}$ doped $LiFePO_4$ started 3.36 V of flat voltage on discharge curve and showed a gentle decline in the curve compared to undoped $LiFePO_4$ without great changes of capacity. And so, we could achieve to improve electrochemical performance as reversible, cycle life. Similarly, $LiFePO_4$ doping with $Ti^{2+}$ was showed the effect of dopant which was obtained the improved discharge capacity as 140 mAh/g and good cycling performance.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2011년도 추계학술대회 초록집
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• pp.137.1-137.1
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• 2011

올리빈 구조의 $LiFePO_4$ 정극 활물질은 $650^{\circ}C$에서 고상법으로 제조되었다. $LiFePO_4$의 전자전도도를 향상시키기 위하여 graphite nanofiber(GNF)를 각각 3wt%, 5wt%, 7wt%, 9wt% 첨가하여 $LiFePO_4$-C를 제조하였다. 제조된 분말의 입자 형태를 확인하기 위하여 X-ray diffraction(XRD)과 File Electronic Scaning Electromicroscopy(FE-SEM)를 측정하였다. XRD결과로부터 제조된 분말은 모두 순수한 결정 구조를 나타내었고 입자의 크기는 약 200nm였다. 5wt% GNF를 첨가한 $LiFePO_4$-C는 기타 첨가량에 비해 방전용량이 가장 높았다. 첫 사이클의 용량은 151.73mAh/g 나타났고 50 사이클 뒤에도 92% 이상을 유지하고 있었다. 첨가하지 않은 것에 비해 43% 증가하였다. $LiFePO_4$-C(3wt%), $LiFePO_4$-C(7wt%), $LiFePO_4$-C(9wt%)의 첫 사이클 방전용량은 각각 147.94mAh/g, 136.64mAh/g, 121.07mAh/g 나타났다. $LiFePO_4$-C(5wt%)에 비해 용량은 떨어쪘지만 순수한 $LiFePO_4$보다 많이 높았다. 임피던스 결과를 보면 기타 첨가량에 비해 $LiFePO_4$-C(5wt%)의 저항 제일 낮았다. 이는 충방전 결과와 일치하였다. graphite nanofiber의 첨가로 인하여 $LiFePO_4$ 정극 활물질의 전자전도도가 높아지고, 따라서 전기화학적 특성도 크게 향상되었다.