• Journal of Powder Materials
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• v.25 no.2
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• pp.151-157
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• 2018

In this study, the compound $Li_3BO_3$ (LBO) is intended to be prepared by a polymeric complex method as a sintering aid for the densification of $Li_7La_3Zr_2O_{12}$ (LLZ) solid electrolyte. A polymeric precursor containing Li and B is heat-treated in an air atmosphere at a temperature range between $600^{\circ}C$ and $800^{\circ}C$. Instead of LBO, the compound $Li_{2+x}C_{1-x}B_xO_3$ (LCBO) is unexpectedly synthesized after a heat-treatment of $700^{\circ}C$. The effect of LCBO addition on sintering behavior and ion conductivity of LLZ is studied. It is found that the LCBO compound could lead to significant improvements in the densification and ionic conductivity of LLZ compared to pure LLZ. After sintering at $1100^{\circ}C$, the density of the LLZ-12wt%LBO composite is $3.72g/cm^3$, with a high Li-ion conductivity of $1.18{\times}10^{-4}Scm^{-1}$ at $28^{\circ}C$, while the pure LLZ specimen had a densify of $2.98g/cm^3$ and Li-ion conductivity of $5.98{\times}10^{-6}Scm^{-1}$.

• Resources Recycling
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• v.14 no.6 s.68
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• pp.37-43
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• 2005

[ $LiCoO_{2}$ ] nanoparticles were synthesized from leach liquor of lithium ion battery waste using flame spray pyrolysis. Electrode Materials containing lithium and cobalt could be concentrated with thermal and mechanical treatment. After dissolution of used cathode materials of the lithium battery with nitric acid, the molar ratio of Li/Co in the leach liquor was adjusted at 1.0 by adding a fresh $LiNO_{3}$ solution. The nanoparticles synthesized by the flame spray pyrolysis showed clear crystallinity and were nearly spherical, and their average primary particle diameters ranged from 11 to 35 nm. The average particle diameter increased with an increase in the molar concentration of the precursor. Raising the maximum flame temperature by controlling the gas flow rates also led to an increase in the average diameter of the particles. The $LiCoO_{2}$ powder was proved to have good characteristics as cathode active materials in charge/discharge capacity and cyclic performance.

• The Transactions of the Korean Institute of Power Electronics
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• v.13 no.5
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• pp.360-368
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• 2008

A lumped parameter model of Li-ion battery in hybrid electric vehicle(HEV) is constructed and system parameters are identified by using recursive least square estimation for different C-rates, SOCs and temperatures. The system characteristics of pole and zero in the frequency domain are analyzed with the parameters obtained from different conditions. The parameterized model of a Li-ion battery indicates highly dependent of temperatures. To estimate SOC and polarization voltage, a Luenberger state observer is utilized. The P- or PI-gains of observer based on a suitable natural frequency and damping ratio is adopted for the state estimation. Satisfactory estimation accuracy of output voltage and SOC is especially obtained by a PI-gain. The feasibility of the proposed estimation method is verified through experiment under the conditions of different C-rates, SOCs and temperatures.

• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.132.2-132.2
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• 2010

Mesoporous tinoxide ($SnO_2$) as anode materials for Li-ion battery were prepared by hydrothermal method and templating method using SBA-15 as template. And electrochemical properties of $SnO_2$ electrode were investigated with cyclic voltammogram (CV). The morphology and structures of $SnO_2$ were characterized by transmission electron microscopy (TEM) and X-ray diffractometer (XRD), respectively. The specific surface area was defined by $N_2$ adsorption with BET(Brunauer-Emmett-Teller) method. As a result, the surface area of mesoporous $SnO_2$ which was made from templating method is higher than the case of using hydrothermal method. In addition, in anodic performance, mesoporous $SnO_2$ which is prepared by templating method showed higher charge-discharge capasity compared to hydrothermal method and exhibited excellent stability over the entire cycle number. It was indicated that electrochemical performances of mesoporous $SnO_2$mainly affected to the structural features, such as specific surface area and porosity.

• Transactions of the Korean Society of Automotive Engineers
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• v.17 no.1
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• pp.130-136
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• 2009

A lumped parameter model of Li-ion battery in hybrid electric vehicle(HEV) is constructed and system parameters are identified by using recursive least square estimation for different C-rates, SOCs and temperatures. The system characteristics of pole and zero in frequency domain are analyzed with the parameters obtained from different conditions. The parameterized model of Li-ion battery indicates highly dependant of temperatures. The system pole and internal resistance changes 6.6 and 18 times at $-20^{\circ}C$, comparing with those at $25^{\circ}C$, respectively. These results will be utilized on constructing model-based state observer or an on-line identification and an adaptation of the model parameters in battery management systems for hybrid electric vehicle applications.

• Journal of Aerospace System Engineering
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• v.8 no.4
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• pp.1-6
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• 2014

This paper presents the trade-off study of conducting a survey of the weights for various kind of propulsion systems installed in the Smart Unmanned Aerial Vehicle TR-100, a tilt-rotor vehicle, which is developed by Korea Aerospace Research Institute, in order to predict the appropriate propulsion system for present and future Personal Air Vehicle, which has single mode and vertical take-off & landing. In order to perform the trade-off study, we set the requirements that the vehicle hovers for 1 hour with 1,000 kg maximum take off weights. In this study, the power systems are classified engine, which uses the fossil fuel - turboshaft engine, piston engine, diesel engine and rotary engine, and electric motor with fuelcell or Li-Ion battery. The results of trade-off study shows the power systems using fossil fuel are superior to using fuelcell or Li-Ion battery for weight of propulsion system. Also turboshaft engine is the best power system for the aspects of system weight, and the nexts are rotary engine, piston engine, diesel engine, electric motor with Li-Ion battery, and electric motor with fuelcell.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2005.07a
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• pp.593-594
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• 2005

Lithium-ion batteries have used the layered $LiCoO_2$ materials as cathodes, but Co is relatively toxic and expensive. In this regard, the spinel $LiMn_2O_4$ has become appealing because manganese is inexpensive and environmentally benign. In general, cathodes for lithium ion batteries include carbon as a conductive agent that provides electron transfer between the active material and the current collector. In this work, we selected Acetylene Black and Super P Black as conducting agents, and then carried out comparative investigation for the performances of the cells using different conducting agents with different particle size. As a consequence, Li/$LiMn_2O_4$ cells with Super P Black show better electrochemical performances than those with Acetylene Black.

• Journal of the Semiconductor & Display Technology
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• v.17 no.3
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• pp.46-52
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• 2018

Slitting, which is supposed to be one of the most critical processes in Li-Ion battery manufacturing, is supposed to cut off the uncoated parts of the foil, and cut the wide foils into the size of the Li-ion batteries. Vibrations of slitting machines are the most critical factors for uneven cut surface such as surface roughness and burr, which are the main reasons of the tearing of microporous membranes to separate the cathodes and the anodes, and eventually causing explosion of the batteries. In this study, the structure of a slitting machine has been analyzed through computer simulations to figure out the main reasons of the vibrations. The result of the study shows that simple design alterations of the supporting area and roller without modifying the main structure of the machine can suppress the vibrations effectively, and further to prevent the devastating explosion.

• Proceedings of the Materials Research Society of Korea Conference
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• 2003.11a
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• pp.216-216
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• 2003

The layered nickel oxides (LiNiO$_2$) have been studied for possible use as cathode materials i3l 4V lithium batteries. Although LiCoO$_2$ has been known as the best candidate material for Li-ion batteries, which produces the best performance LiNiO$_2$ is generally accepted as an attractive cathode material, because of its various advantages such as lower cost higher discharge capacity and better reversibility. In this investigation, we calculated the electric state of LiNiO$_2$ using DV-X$\alpha$ molecular orbital method in order to obtain the information of chemical bonding among the Li, Ni and O. In LiNiO$_2$, alternate layers of Li and Ni occupy the octahedral sites of a cubic close packing of oxide ions, making up a rhombohedral structure with an R-3m space group, Li in 3a, Ni in 3b, and O in 6c sites. On the basis of this, we made the cluster model and studied ionization of each atoms and interaction between atoms according to Mullilcen population analysis.

• Ceramist
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• v.21 no.4
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• pp.406-415
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• 2018

Lithium ion batteries have been widely adopted as energy storage and the LIB global market has grown fastest. However, LIB players have struggled against maximizing energy density since commercial monolithic electrodes are limited by electrolyte depletion caused by long and tortuous Li-ion diffusion pathways. Recently, new strategies designing the structure of battery electrodes strive for creating fast Li-ion path and alleviating electrolyte depletion problem in monolithic electrodes. In this paper, given the fundamental and experimental approaches, we compare the monolithic to structured electrodes and demonstrate the ways to fabricate high energy, fast chargeable Lithium ion battery.