• Analytical Science and Technology
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• v.17 no.5
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• pp.369-374
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• 2004

Plastic was decomposed with nitric acid after being carbonized by sulfuric acid. Then excess sulfuric acid and nitric acid was removed by evaporating and drying. Precipitated $SO{_4}^{-2}$ ion of $PbSO_4$ was resolved itself into $H_2S$ by HI in hydrochloric acid and was volatilized. Then $Pb^{+2}$ was dissolved and was measured by AAS and ICP. The test for reproducibility using PVC-Pb standard material (690-34610mg/kg) was conducted and the accuracy was more than 99.9% compared with the estimated concentration. The precision by AAS was 99.8% and that of ICP was 99.9%.

• Journal of Korean Tunnelling and Underground Space Association
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• v.19 no.3
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• pp.489-501
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• 2017

The collapse accidents during a open ground excavation in urban areas not only lead to human injuries and material damages in the construction site, but also lead to road sinks and damages to the adjacent facilities due to settlement of ground around the construction site. Therefore, during a open ground excavation in the urban areas, it is necessary to thoroughly prepare for prevention of collapse accidents, and consider whole construction stage such as planning, design and construction. In this study, the priorities to be managed mainly were obtained in order to prevent collapse accidents during a open ground excavation. After analyzing results from past accidents cases for open ground excavations, priorities were evaluated regarding collapse-inducing elements using the Delphi technique which is a decision-making method by consensus among experts. As a result, insufficient groundwater treatment, bad geotechnical investigation and instability on construction, etc. were obtained as priorities for prevention of collapse accidents.

• Analytical Science and Technology
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• v.13 no.3
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• pp.297-303
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• 2000

Isotope-dilution inductively coupled plasma mass spectrometry was used to determine trace amounts of Cd, Cu, Pb, Ni and Zn in sediment. Sediment samples were dissolved by microwave digestion with addition of mixed acid ($HNO_3$, HF and $HClO_4$). Lead was determined after separation of alkaline and alkaline earth metals by an ammonium pyrrolidenedithiocarbarmate (APDC) solvent extraction. The other elements were determined after separation of iron, tin and titanium by hydroxide precipitation. Recovery efficiency of the analyte elements was not satisfactory, but most of matrix elements causing the isobaric interference could be effectively eliminated by the separation. Good agreement was achieved with the certified values in the analysis of the two sediment reference materials.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.20 no.3
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• pp.219-223
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• 1987

A slightly modified method of Rashid and Potts(1980) to determine riboflavin in milk in which lead acetate was used as a precipitant was employed in tile present study to test applicability to determine that of fish as well. The lead acetate method was found to be sensitive, simple, inexpensive and rapid compared to the modified A.O.A.C. method by Cordon et al. (1979). But higher riboflavin values were obtained in this study than those reported so far. The riboflavin contents of 9 white fleshed fishes were in the range of $0.29\~0.48mg$ per 100g fresh sample. Linear regression equation Y=125.70X+0.71 (R=0.9993) was obtained for the calculation of riboflavin content in the white fleshed fish. Y is the concentration of riboflavin in the final solution to be chocked its OD at fluorometer and X is the dial reading of fluorometer. The stability of riboflavin as the freshness changes during icing storage$(at\;0^{\circ}C)$ was studied with file fish. During the initial stage of storage, the riboflavin content was found to by increased by $14\%$, but the difference was not statistically significant (p>0.05). K-value and VBN-value were increased along with storage time, but Proximate composition was not changed significantly during entire storage of 18 days.

• Korean Journal of Computational Design and Engineering
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• v.13 no.2
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• pp.139-152
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• 2008

In order to survive worldwide competition, today's industries are experiencing strong pressure to introduce higher quality products with lower cost and shorter lead-time. Therefore, the role of design in the process of product development is increasing in significance. In this research, two methods for improving the design capability are proposed: construction of design environment and design automation using 3D CAD system. The designers and design process are the core of product design using 3D CAD system. In order to maximize the design performance, construction of the design environment including selection of a suitable system, designer training for best use of the system, establishment of an efficient design process, and stabilization of the environment are required. A method is suggested to construct design environment by systematizing the contents of the projects and consulting experiences carried out for various categories of business such as electronic devices, motorcycles, electricity parts, sanitary wares, injection molds, and die casing molds. Design automation helps reduce tedious and time-consuming jobs, simplify complicated and error-prone modeling and drawing works to shorten the lead time and improve the product quality. To develop a design automation system, understanding the process and the related knowledge on design are very important before implementing the system using API provided by 3D CAD system. In this research, an eight-step procedure is proposed for the development of a design automation system. These eight steps are analysis of needs, determination of specification, verification of specification using 3D CAD system, inspection of related API functions, programming, field test, application in practice, and maintenance. A case study in which five design automation systems in the design of turbine generators using the proposed method is introduced in detail. These systems play important roles in the generation of various output items including 3D models, drafts, material information, and NC data. The case study shows how effectively the design time is reduced and the quality improved using those systems.

• Journal of Korean Society on Water Environment
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• v.24 no.5
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• pp.543-549
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• 2008

Human activities and land-use practices are intensely widening the urban areas. High impervious surface areas cover much of urban landscapes and are the primary pollutant sources which can lead to water quality and habitat degradation in its watershed. As the urban areas expand, transportation land-use such as parking lots, roads, service areas, toll-gates in highways and bridges also increase. These land-uses are significant in urban pollution due to high imperviousness rate and vehicular activities. To regulate the environmental impacts and to improve the water quality of rivers and lakes, the Ministry of Environment (MOE) in Korea developed the Total Pollution Load Management System (TPLMS) program. The main objective is to lead the watershed for a low impact development. On a local scale, some urban land surfaces can be emitting more pollution than others. Consequently, in urban areas, the unit loads are commonly employed to estimate total pollutant loadings emitted from various land-uses including residential, commercial, industrial, transportation, open lands such as parks and golf courses, and other developed land like parking areas as a result of development. In this research, unit pollutant loads derived specifically from transportation land-uses (i.e. branched out from urban areas) will be provided. Monitoring was conducted over 56 storm events at nine monitoring locations during three years. Results for the unit pollutant loads of transportation land-use are determined to be $399.5kg/km^2-day$ for TSS, $12.3kg/km^2-day$ for TN and $2.46kg/km^2-day$ for TP. The values are higher than those of urban areas in Korean MOE and US highways. These results can be used by MOE to separate the pollutant unit load of transportation landuses from urban areas.

• Journal of Korean Society of Industrial and Systems Engineering
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• v.42 no.1
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• pp.55-63
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• 2019

This paper develops an algorithm to determine the batch size of the batch process in real time for improving production and efficient control of production system with multiple processes and batch processes. It is so important to find the batch size of the batch process, because the variability arising from the batch process in the production system affects the capacity of the production. Specifically, batch size could change system efficiency such as throughput, WIP (Work In Process) in production system, batch formation time and so on. In order to improve the system variability and productivity, real time batch size determined by considering the preparation time and batch formation time according to the number of operation of the batch process. The purpose of the study is to control the WIP by applying CONWIP production system method in the production line and implements an algorithm for a real time batch size decision in a batch process that requires long work preparation time and affects system efficiency. In order to verify the efficiency of the developed algorithm that determine the batch size in a real time, an existed production system with fixed the batch size will be implemented first and determines that batch size in real time considering WIP in queue and average lead time in the current system. To comparing the efficiency of a system with a fixed batch size and a system that determines a batch size in real time, the results are analyzed using three evaluation indexes of lead time, throughput, and average WIP of the queue.

• Analytical Science and Technology
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• v.9 no.4
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• pp.336-344
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• 1996

The extraction of trace cobalt, copper, nickel, cadmium, lead and zinc in urine samples of organic and alkali metal matrix into chloroform by the complex with a dithizone was studied for graphite furnace AAS determination. Various experimental conditions such as the pretreatment of urine, the pH of sample solution, and dithizone concentration in a solvent were optimized for the effective extraction, and some essential conditions were also studied for the back-extraction and digestion as well. All organic materials in 100 mL urine were destructed by the digestion with conc. $HNO_3$ 30 mL and 30% $H_2O_2$ 50 mL. Here, $H_2O_2$ was added dropwise with each 5.0 mL, serially. Analytes were extracted into 15.0 mL chloroform of 0.1% dithizone from the digested urine at pH 8.0 by shaking for 90 minutes. The pH was adjusted with a commercial buffer solution. Among analytes, cadmium, lead and zinc were back-extracted to 10.00 mL of 0.2 M $HNO_3$ from the solvent for the determination, and after the organic solvent was evaporated, others were dissolved with $HNO_3-H_2O_2$ and diluted to 10.00 mL with a deionized water. Synthetic digested urines were used to obtain optimum conditions and to plot calibration-eurves. Average recoveries of 77 to 109% for each element were obtained in sample solutions in which given amounts of analytes were added, and detection limits were Cd 0.09, Pb 0.59, Zn 0.18, Co 0.24, Cu 1.3 and Ni 1.7 ng/mL, respectively. It was concluded that this method could be applied for the determination of heavy elements in urine samples without any interferences of organic materials and major alkaline elements.

• Journal of Energy Engineering
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• v.17 no.4
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• pp.182-188
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• 2008

This paper is to compare the carbon-balanced and liner air-fuel ratio determination methods for alternative fuels. In the previous work, expansion of Eltinge chart, unburned hydrocarbon compensation, comparison of the results from various methods were discussed. It has been also concluded that Eltinge method might be regarded as the most general equation of AFR determination among the existing ones. In the recent years, however, increasing demand for the environmental preservation, including global warming-up protection, and energy conservation lead to introduce the alternative fuel to the internal combustion engine. Therefore, the exact calculations of AFR for these fuels are needed. Especially, for the fuel that contains oxygen, all AFR calculation equations except Eltinge have to be re-formulated. In this paper, the AFR for alternative fuel were calculated by re-formulated carbon balance, accuracy of which was already confirmed, and linear equations, which are newly proposed by statistical method for each fuel. The results show that AFRs based on carbon balance have a little more error compared with gasoline, however, the accuracy is enough for this formula to apply to various fuel. The proposed linear equation also have excellent accuracy below $\lambda=1.2$.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.35 no.3
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• pp.297-302
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• 2022

We investigated the origin of magnetic behaviors induced by an asymmetric spin exchange interaction in Fe-site engineered lead iron niobate [Pb(Fe_1/2Nb_1/2)O₃, PFN], which exhibits a room-temperature multiferroicity. The magnitude of spin exchange interaction was regulated by the introduced transition metals with a distinct Bohr magneton, i.e., Cr, Co, and Ni. All compositions were found to have a single-phase perovskite structure keeping their ferroelectric order except for Cr introduction. We discovered that the incorporation of each transition metal imposes a distinct magnetic behavior on the lead iron niobate system; antiferro-, hard ferro-, and soft ferromagnetism for Cr, Co, and Ni, respectively. This indicates that orbital occupancy and interatomic distance play key roles in the determination of magnetic behavior rather than the magnitude of the individual Bohr magneton. Further investigations are planned, such as X-ray absorption spectroscopy, to clarify the origin of magnetic properties in this system.