• Title/Summary/Keyword: Layered method

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Thermal Curing Behavior and Tensile Properties of Resole Phenol-Formaldehyde Resin/Clay/Cellulose Nanocomposite

  • Park, Byung-Dae;Kadla, John F.
    • Journal of the Korean Wood Science and Technology
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    • v.40 no.2
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    • pp.110-122
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    • 2012
  • This study investigated the effects of layered clay on the thermal curing behavior and tensile properties of resole phenol-formaldehyde (PF) resin/clay/cellulose nanocomposites. The thermal curing behavior of the nanocomposite was characterized using conventional differential scanning calorimetry (DSC) and temperature modulated (TMDSC). The addition of clay was found to accelerate resin curing, as measured by peak temperature ($T_p$) and heat of reaction (${\Delta}H$) of the nanocomposite’ curing reaction increasing clay addition decreased $T_p$ with a minimum at 3~5% clay. However, the reversing heat flow and heat capacity showed that the clay addition up to 3% delayed the vitrification process of the resole PF resin in the nanocomposite, indicating an inhibition effect of the clay on curing in the later stages of the reaction. Three different methods were employed to determineactivation energies for the curing reaction of the nanocomposite. Both the Ozawa and Kissinger methods showed the lowest activation energy (E) at 3% clay content. Using the isoconversional method, the activation energy ($E_{\alpha}$) as a function of the degree of conversion was measured and showed that as the degree of cure increased, the $E_{\alpha}$ showed a gradual decrease, and gave the lowest value at 3% nanoclay. The addition of clay improved the tensile strengths of the nanocomposites, although a slight decrease in the elongation at break was observed as the clay content increased. These results demonstrated that the addition of clay to resole PF resins accelerate the curing behavior of the nanocomposites with an optimum level of 3% clay based on the balance between the cure kinetics and tensile properties.

Effect of Glass Frit in $TiO_2$ Electrode for DSSCs (Glass Frit을 이용한 염료감응 태양전지의 광 특성 연구)

  • Kim, Jongwoo;Jeon, Jaeseung;Kim, Dongsun;Hwang, Seongjin;Kim, Hyungsun
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.75.1-75.1
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    • 2010
  • Dye sensitized solar cells(DSSCs) have been extensively studied due to their various advantages such as low production cost, colorful design, and eco-friendly process. Long optical path length is one of the most effective method to improve light harvest efficiency for DSSCs. Multi-layered $TiO_2$ nano-structured film with scattering layer has been studied to generate scattering effect by many researchers. It was expected that the difference of refractive index between $TiO_2$ particles and glass frit would generate the light scattering effect and provide the long optical path length. Therefore, to enhance the scattering effect, the frits of $Bi_2O_3-B_2O_3$-ZnO glass system that has the different refractive index were added to $TiO_2$ pastes in this study. First of all, the absorbance and haze factor of $TiO_2$ electrode with dyes and the refractive index of glass frit and $TiO_2$ were measured, respectively. To study the effect of frits, the efficiencies of DSSCs added glass frit and without glass frit were compared. Our results showed slightly higher efficiency with the different absorbance and haze factor of $TiO_2$ and glass frit. It was considered that the light scattering effect would be improved with adding frits to $TiO_2$ paste. Our preliminary studies will be useful for increasing efficiency of DSSCs.

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Cyclic Properties of Li[Co0.17Li0.28Mn0.55]O2 Cathode Material

  • Park, Yong-Joon;Hong, Young-Sik;Wu, Xiang-Lan;Kim, Min-Gyu;Ryu, Kwang-Sun;Chang, Soon-Ho
    • Bulletin of the Korean Chemical Society
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    • v.25 no.4
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    • pp.511-516
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    • 2004
  • A Li$[Co_{0.17}Li_{0.28}Mn_{0.55}]O_2$ cathode compound was prepared by a simple combustion method. The X-ray diffraction pattern showed that this compound could be classified as ${\alpha} -NaFeO_2$ structure type with the lattice constants of a = 2.8405(9) ${\AA}$ and c = 14.228(4) ${\AA}$. According to XANES analysis, the oxidation state of Mn and Co ions in the compound were 4+ and 3+, respectively. During the first charge process, the irreversible voltage plateau at around 4.65 V was observed. The similar voltage-plateau was observed in the initial charge profile of other solid solution series between $Li_2MnO_3\;and\;LiMnO_2$ (M=Ni, Cr...). The first discharge capacity was 187 mAh/g and the second discharge capacity increased to 204 mAh/g. As the increase of cycling number, one smooth discharge profile was converted to two distinct sub-plateaus and the discharge capacity was slowly decreased. From the Co and Mn K-edge XANES spectra measured at different cyclic process, it can be concluded that irreversible transformation of phase is occurred during continuous cycling process.

3D Transmitting Boundary for Water-Saturated Transversely Isotropic Soil Strata Based on the u-w Formulation (u-w 정식화에 근거한 지하수로 포화된 가로등방성 층상지반에서의 3차원 전달경계)

  • Lee, Jin-Ho;Kim, Jae-Kwan;Ryu, Jeong-Soo
    • Journal of the Earthquake Engineering Society of Korea
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    • v.13 no.6
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    • pp.67-86
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    • 2009
  • In this study, a 3D transmitting boundary in water-saturated transversely isotropic soil strata has been developed based on u-w formulation for application to general 3D analysis. Behavior in the far field region is expanded in the Fourier series, and dynamic stiffness for each term is obtained based on the u-w formulation. Transformation of the dynamic stiffness is presented to combine the transmitting boundary with the 3D finite elements for the near field region formulated in a 3D Cartesian coordinate system. The developed transmitting boundary is verified through a comparison of the dynamic behavior of a rigid circular foundation with the results from the existing numerical method. In addition, the developed transmitting boundary is applied to the analysis of the dynamic behavior of rigid foundations of diverse shapes, and the effects of the level of the groundwater table on the dynamic stiffness of a rigid rectangular foundation in the water-saturated transversely isotropic layered stratum are studied.

Preparation and Properties of Organic Electroluminescent Devices Using Low Molecule Compounds (저분자 화합물을 이용한 유기 전계발광소자의 제작과 특성 연구)

  • 노준서;조중연;유정희;장영철;장호정
    • Journal of the Microelectronics and Packaging Society
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    • v.10 no.1
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    • pp.1-5
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    • 2003
  • The multi-layered OELDs(organic electroluminescent devices) were prepared on the patterened ITO (indium tin oxide)/glass substrates by the vacuum thermal evaporation method. The $Alq_3$ (tris-(8-hydroxyquinoline)aluminum) low molecule compound was used as the light emission layer. TPD(triphenyl-diamine) and $\alpha-NPD$ were used as the hole transport layer. CuPc (Copper phthalocyanine) was also used as the hole injection layers. In addition, QD2 (quinacridone2) organic material with $10\AA$ thickness was deposited in the $Alq_3$ emission layer to improve the luminance efficiency. The threshold voltage was about 7V for all devices. The luminance and efficiency of devices was improved by substitution the $\alpha-NPD$ for TPD as the hole as the hole transport layer. The luminance efficiency of the OELD sample with QD2 thin film in the $Alq_3$ emission layer was found to be 1.55 lm/W, which is about 8 times larger value compared to the sample without QD2 thin layer.

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Performance of laterally loaded piles considering soil and interface parameters

  • Fatahi, Behzad;Basack, Sudip;Ryan, Patrick;Zhou, Wan-Huan;Khabbaz, Hadi
    • Geomechanics and Engineering
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    • v.7 no.5
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    • pp.495-524
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    • 2014
  • To investigate the soil-pile interactive performance under lateral loads, a set of laboratory model tests was conducted on remoulded test bed of soft clay and medium dense sand. Then, a simplified boundary element analysis had been carried out assuming floating pile. In case of soft clay, it has been observed that lateral loads on piles can initiate the formation of a gap, soil heave and the tension crack in the vicinity of the soil surface and the interface, whereas in medium dense sand, a semi-elliptical depression zone can develop. Comparison of test and boundary element results indicates the accuracy of the solution developed. However, in the boundary element analysis, the possible shear stresses likely to be developed at the interface are ignored in order to simplify the existing complex equations. Moreover, it is unable to capture the influence of base restraint in case of a socketed pile. To bridge up this gap and to study the influence of the initial stress state and interface parameters, a field based case-study of laterally-loaded pile in layered soil with socketed tip is explored and modelled using the finite element method. The results of the model have been verified against known field measurements from a case-study. Parametric studies have been conducted to investigate the influence of the coefficient of lateral earth pressure and the interface strength reduction factor on the results of the model.

Shear Strength of Retrofitted RC Squat Wall by Additional Boundary Element (단부 증타 보강된 RC 전단벽체의 전단강도)

  • Yi, You-Sun;Hong, Sung-Gul;Park, Young-Mi
    • Journal of the Korea Concrete Institute
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    • v.27 no.5
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    • pp.489-499
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    • 2015
  • This study suggested shear strength prediction model for retrofitted single-layered RC squat wall by providing column element as additional boundary element. This model revised existing shear strength prediction model of shear wall to consider detail and shear deformation capacity of column by assuming the length that concentrated shear deformation of the column is occurred. It was able to suggest additional compatibility condition related to shear strain of retrofitted of retrofitted shear wall at the ultimate state by using this length. Therefore, this study proposed a flow chart for predicting shear strength of the retrofitted shear wall considering this additional condition. Moreover, this study also proposed a method for predicting initial stiffness of the retrofitted shear wall by transforming the wall's resisting mechanism against to lateral load to a single diagonal strut mechanism. The proposed methods can predict shear strength and initial stiffness of not only the retrofitted shear wall of this study, also infilled RC shear wall in RC frame.

A New Data Partitioning of DCT Coefficients for Error-resilient Transmission of Video (비디오의 에러내성 전송을 위한 DCT 계수의 새로운 분할 기법)

  • Roh, Kyu-Chan;Kim, Jae-Kyoon
    • Journal of the Institute of Electronics Engineers of Korea SP
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    • v.39 no.6
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    • pp.585-590
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    • 2002
  • In the typical data partitioning for error-resilient video coding, motion and macroblock header information is separated from the texture information. It can be an effective tool for the transmission of video over the error prone environment. For Intra-coded frames, however, the loss of DCT (discrete cosine transform) coefficients is fatal because there is no ther information to reconstruct the corrupted macroblocks by errors. For Inter-coded frames, when error occurs in DCT coefficients, the picture quality is degraded because all DCT coefficients are discarded in those packets. In this paper, we propose an efficient data partitioning and coding method for DCT-based error-resilient video. The quantized DCT coefficients are partitioned into the even-value approximation and the remainder parts. It is shown that the proposed algorithm provides a better quality of the high priority part than the conventional methods.

The Development of Contemporary Fashion Designs Specialized in the Traditional Costume of the Miao (중국 묘족(苗族) 복식을 특화시킨 현대적 패션 디자인 개발)

  • Lee, Keum-Hee;Yoon, Ji-Won;Han, Jung-Ah
    • The Research Journal of the Costume Culture
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    • v.15 no.5
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    • pp.902-915
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    • 2007
  • This study examines decorative features found in the traditional costume of the Miao, one of the minority groups in China, and adapts them for the development of modern Korean-style fashion designs in order to present visual sample data and to introduce techniques. As for the research method, both literature and visual data are examined: the former includes Miao-related books and theses; the latter, pictures from various documents and real-life data in the possession of Seoul Women's University. The study result is as follows: 1. The basic structure of Miao costume is consist of a Caftan-type upper garment and an accentuated lower garment, pleats skirt although they are decorated luxuriously with various techniques such as delicate embroidery and dyeing. 2. Details and trimmings in modern shapes are developed and presented by adding modern materials to satin, twists, cross-stitch embroidery, stripe patterns, geometrical patchwork, machine pleats and smoking, trimmings of fringe & feather, and the border line decoration of coloration, braids, piping, embroidery, belts tied and wound with colorful threads. 3. Detachable accessaries such as front reinforcement strips, back reinforcement strips, belts, decorative aprons and patchwork skirts are developed and designed by adapting highlighted layered effects. 4. The silver decoration used as an necessary by the Miao is suitable for modern fashion design in futuristic sense. Various techniques and decorative features of Miao costume display their true value all the more in modern fashion stream in which ethnic trends draw much attention.

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Synthesis and characterization of LiCoO2 thin film by sol-gel process (Sol-gel법에 의한 LiCoO2 박막의 합성과 특성평가)

  • Roh, Tae-Ho;Yon, Seog-Joo;Ko, Tae-Seog
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.24 no.3
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    • pp.94-98
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    • 2014
  • $LiCoO_2$ thin film has received diverse attention as cathodes material of thin-film micro-batteries. In this study, $LiCoO_2$ thin films were synthesized on Au substrates by sol-gel spin coating method and an annealing process. Their structures were studied using X-ray diffraction and Raman Spectroscopy. The particle morphologies of these thin films were observed by Scaning electron microscope. From the results of X-ray diffractometry and Raman Spectroscopy analyses, it was found that as-grown films had the structure of spinel (LT-$LiCoO_2$) and layered-Rock-salt (HT-$LiCoO_2$) at $550^{\circ}C$ and $750^{\circ}C$ respectively. The annealed films at $650^{\circ}C$ were presumed to be the mixed state of these two types. Throlugh the scanning electron microscope, It was estimated that the particle size in as-grown films at $750^{\circ}C$, were larger crystilline particle than in those at the other lower temperature and well distributed in the film.