• 제목/요약/키워드: Large scale hydrogen

검색결과 124건 처리시간 0.029초

습식 에칭 공정에서의 과산화수소 이상반응에 대한 안전 대책 및 제어에 관한 연구 (A study on Safety Management and Control in Wet-Etching Process for H2O2 Reactions)

  • 유흥렬;손영득
    • 한국산학기술학회논문지
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    • 제19권4호
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    • pp.650-656
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    • 2018
  • TFT-LCD 산업은 반도체와 유사한 공정기술을 갖는 대규모 장치 산업으로 일종의 Giant Microelectronics 산업이다. 습식 에칭(Wet Etching)은 전체 TFT 공정에서 비교적 큰 비중을 차지하고 있지만 발표된 연구사례는 부족한 실정이다. 그 주요 원인은 반응이 일어나는 에칭액(Etchant) 성분이 기업의 비밀로 간주되어 외부에 발표되는 사례가 거의 없기 때문이다. 최근 대면적 LCD 제조를 위하여 사용되는 알루미늄(Al)과 구리(Cu)는 습식 에칭을 진행하기에 매우 까다로운 물질이다. 저 저항성 재료인 Cu는 습식 에칭 공정에서만 가능하며 높은 속도와 낮은 실패율, 적은 소비전력으로 Al 에칭 대용으로 사용하고 있다. 그리고 에칭액으로 사용하는 과산화수소($H_2O_2$)의 이상 반응으로 추가적인 배관 및 전기적인 안전장치가 필요하다. 본 논문에서는 과산화수소의 이상 반응을 제한하지는 못하나 이상 반응 발생 시 설비의 피해를 최소화 할 수 있는 방법을 제안한다. 또한 최근에 알루미늄 에칭설비에서 구리 에칭설비로 변경하는 사례가 많아 구리 에칭설비에 대한 하드웨어 인터록을 제안하고 안전 등급이 높은 안전 PLC로 구현하여 이상 반응에 대한 대비책을 강구하는 방안을 제안한다.

대용량 저온 Ni-Al 합금 분말 제조 공정 개발 (Development of Large-scale Ni-Al Alloy Fabrication Process at Low Temperature)

  • 이민재;강민구;장성철;함형철;안중우;남석우;윤성필;한종희
    • 한국수소및신에너지학회논문집
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    • 제29권1호
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    • pp.64-70
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    • 2018
  • In this study, the kg-class Ni-Al alloy fabrication process at low temperature was developed from the physical mixture of Ni and Al powders. The AlCl3 as an activator was used to reduce the temperature of alloy synthesis below the melting temperature of Ni and Al elements (<$500^{\circ}C$). Mixed phase of Ni3Al intermetallic and Ni-Al solid-solution were identified in the XRD pattern analysis. Furthermore, from the analysis of SEM and particle size analyzer, we found that the particle size of synthesized alloy powders was not changed compared to the initial size of Ni particle after the formation of alloy powder at $500^{\circ}C$. In the creep test, the anode (which was fabricated by the prepared Ni-Al alloy powders in this study) displayed the enhanced creep resistance compared to the conventional anode.

Facile Fabrication of Flexible In-Plane Graphene Micro-Supercapacitor via Flash Reduction

  • Kang, Seok Hun;Kim, In Gyoo;Kim, Bit-Na;Sul, Ji Hwan;Kim, Young Sun;You, In-Kyu
    • ETRI Journal
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    • 제40권2호
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    • pp.275-282
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    • 2018
  • Flash reduction of graphene oxide is an efficient method for producing high quality reduced graphene oxide under room temperature ambient conditions without the use of hazardous reducing agents (such as hydrazine and hydrogen iodide). The entire process is fast, low-cost, and suitable for large-scale fabrication, which makes it an attractive process for industrial manufacturing. Herein, we present a simple fabrication method for a flexible in-plane graphene micro-supercapacitor using flash light irradiation. All carbon-based, monolithic supercapacitors with in-plane geometry can be fabricated with simple flash irradiation, which occurs in only a few milliseconds. The thinness of the fabricated device makes it highly flexible and thus useful for a variety of applications, including portable and wearable electronics. The rapid flash reduction process creates a porous graphene structure with high surface area and good electrical conductivity, which ultimately results in high specific capacitance ($36.90mF\;cm^{-2}$) and good cyclic stability up to 8,000 cycles.

Enhancement of Seed Germination and Uniformity in Triploid Watermelon (Citrullus lanatus (Thunb.) Matsum. and Nakai)

  • Phat, Phanna;Sheikh, Sameena;Lim, Jeong Hyeon;Kim, Tae Bok;Seong, Mun Ho;Chon, Hyong Gwon;Shin, Yong Kyu;Song, Young Ju;Noh, Jaejong
    • 원예과학기술지
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    • 제33권6호
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    • pp.932-940
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    • 2015
  • One of the main factors restricting production of triploid seedless watermelon is poor germination due to weak embryos, thick seed coats, and larger air spaces. This study was carried out to investigate the priming effects of different concentrations of chemicals, including hydrogen peroxide ($H_2O_2$), fusicoccin, and gibberellic acid (GA) on germination and seedling uniformity of triploid watermelon (Citrullus lanatus). Three commercial triploid cultivars, Seedless Plus, Sinus, and Sizero, were pretreated with water and different levels of $H_2O_2$ (2 and 4%), fusicoccin (FC: 1, 5, and $10{\mu}M$), and GA (1, 5, and $10{\mu}M$). The present findings helped to find optimal priming conditions for improving germination of triploid watermelon. Treatment with $5{\mu}M$ GA and hydropriming helped to break seed dormancy, enhancing the final germination percentages in all triploid cultivars and increasing the germination index in Sizero. These seed-priming treatments could be used on large scale for industrial applications. Moreover, hydropriming provides a simple, effective, and costless method to improve seed germination and seedling vigor of Sinus and Sizero varieties.

우주추진용 모노메틸하이드라진 반응에 대한 주요 해외연구 동향 조사 Part I : 모노메틸하이드라진의 열분해 반응 (A Review on Major Foreign Research Trend of Monomethylhydrazine Reaction for Space Propulsion Part I : Thermal Decomposition Reaction of Monomethylhydrazine)

  • 장요한;이균호
    • 항공우주시스템공학회지
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    • 제10권1호
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    • pp.66-73
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    • 2016
  • Space propulsion system produces required thrust for satellites and space launch vehicles by using chemical reactions of a liquid fuel and a liquid oxidizer typically. For example, monomethylhydrazine-dinitrogen tetroxide, liquid hydrogen-liquid oxygen and RP-1-liquid oxygen are conventional combinations of liquid propellants used for the liquid propulsion system. Among several liquid propellants, the monomethylhydrazine is expecially preferred for a satellite fuel due to its better storability in liquid phase during a relatively long mission period under a space environment. Thus, a development importance of a bipropellant system using the monomethylhydrazine fuel is recognized recently as the national space program proceeds on a large scale. The objective of the present study is to review a foreign research trend of a thermal decomposition reaction of monomethyhydrazine to understand a fundamental basis of its chemical reaction to prepare for domestic development in future.

Graphene synthesis by chemical vapor deposition on Cu foil

  • Kim, Sung-Jin;Yoo, Kwon-Jae;Seo, E.K.;Boo, Doo-Wan;Hwang, Chan-Yong
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제40회 동계학술대회 초록집
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    • pp.351-351
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    • 2011
  • Graphene has drawn great interests because of its distinctive band structure and physical properties[1]. A few of the practical applications envisioned for graphene include semiconductor applications, optoelectronics (sola cell, touch screens, liquid crystal displays), and graphene based batteries/super-capacitors [2-3]. Recent work has shown that excellent electronic properties are exhibited by large-scale ultrathin graphite films, grown by chemical vapor deposition on a polycrystalline metal and transferred to a device-compatible surface[4]. In this paper, we focussed our scope for the understanding the graphene growth at different conditions, which enables to control the growth towards the application aimed. The graphene was grown using chemical vapor deposition (CVD) with methane and hydrogen gas in vacuum furnace system. The grown graphene was characterized using a scanning electron microscope(SEM) and Raman spectroscopy. We changed the growth temperature from 900 to $1050^{\circ}C$ with various gas flow rate and composition rate. The growth condition for larger domain will be discussed.

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INTERSTELLAR ENVIRONMENTS IN THE LARGEMAGELLANIC CLOUD

  • KIM SUNGEUN
    • 천문학회지
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    • 제37권4호
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    • pp.211-216
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    • 2004
  • We present the results of an H I aperture synthesis mosaic of the Large Magellanic Cloud (LMC), made by combining data from 1344 separate pointing centers using the Australia Telescope Compact' Array (ATCA) and the Parkes multibeam receiver. The resolution of the mosaiced images is 50" (<15 pc, using a distance to the LMC of 55kpc). This mosaic, with a spatial resolution .15 times higher than that which had been previously obtained, emphasises the turbulent and fractal structure of the ISM on the small scale, resulting from the dynamical feedback of the star formation processes with the ISM. We also have done a widefield panoramic survey of H$\alpha$ emission from the Magellanic Clouds with an imager mounted on the 16-inch telescope at Siding Spring Observatory. This survey produced H$\alpha$ images which are equal to the ATCA survey in area coverage and resolution. This survey allows us to produce a continuum-subtracted image of the entire LMC. In contrast with its appearance in the H$\alpha$ image, the LMC is remarkably symmetric in H I on the largest scales, with the bulk of the H I residing in a disk of diameter 8. $^{\circ}4$ (7.3 kpc) and a spiral structure is clearly seen. The structure of the neutral atomic ISM in the LMC is dominated by H I filaments combined with numerous shells and holes.

Optical properties of dwarf galaxies in Leo I galaxy group

  • Kim, Myo Jin;Chung, Aeree;Lee, Jong Chul;Lim, Sungsoon;Kim, Minjin;Ko, Jongwan;Yang, Soung-Chul;Lee, Joon Hyeop;Hwang, Narea;Park, Byeong-Gon;Lee, Hye-Ran
    • 천문학회보
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    • 제41권1호
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    • pp.33.2-33.2
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    • 2016
  • Since the serendipitous discovery of a large-scale atomic hydrogen ($H_I$) ring discovered in the Leo I galaxy group, its origin has been under debate till today, whether it is the leftover after group formation or stripped gas structure during the galaxy-galaxy interaction. Intriguingly a number of $H_I$ clumps have been identified along the gas ring, some of which turn out to be associated with optically catalogued dwarf galaxies. The formation history based on detailed optical and $H_I$ gas properties of those dwarf galaxies will enable us to verify the origin of the Leo ring. In this work, we first probe the redshift and multi-color properties of those dwarf galaxies, using deep photometric and spectroscopic data from CFHT, Gemini and Magellan telescope.

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모사 합성 가솔린 제조 및 분무 특성 분석 연구 (Study on Lab-scale Production of Simulated e-Gasoline and Analysis of Spray Characteristics)

  • 박정현;최나은;박수한
    • 한국분무공학회지
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    • 제28권4호
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    • pp.176-183
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    • 2023
  • Many countries are striving to reduce carbon emissions with the goal of net zero by 2050. Accordingly, vehicles are rapidly being electrified to reduce greenhouse gases in the transportation sector. However, many organizations predict that internal combustion engines of LDV (light-duty vehicle) will exist even in 2050, and it is difficult to electrify aircraft and large ships in a short time. Therefore, synthetic fuel (i.e., e-Fuel) that can reduce carbon emissions and replace existing fossil fuels is in the spotlight. The e-Fuel refers to a fuel synthesized by using carbon obtained through various carbon capture technologies and green hydrogen produced by eco-friendly renewable energy. The purpose of this study is to compare and analyze the injection and spray characteristics of the simulated e-Gasoline. We mixed the hydrocarbon fuel components according to the composition ratio of the synthetic fuel produced based on the FT(Fischer-Tropsch) process. As a result of injection rate measurement, simulated e-Gasoline showed no significant difference in injection delay and injection period compared to standard gasoline. However, due to the low vapor pressure of the simulated e-Gasoline, the spray tip penetration (STP) was lower, and the size of spray droplets was larger than that of traditional gasoline.

폴리(비닐 알코올) 수용액의 준희박농도 영역에서 사슬 거동에 대한 수소결합의 효과 (Hydrogen Bond Effect on Chain Behavior at the Semidilute Regime of Poly(vinyl alcohol) Aqueous Solution)

  • 박일현;유영철;박기상;이동일;류원석
    • 폴리머
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    • 제30권3호
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    • pp.271-278
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    • 2006
  • 어랙틱 폴리(비닐 알코올)(PVA) 수용액 시스템의 준희박농도에서의 고분자 사슬의 구조 및 거동을 살펴보기 위하여, 온도 $25^{\circ}C$에서 광산란 실험을 실시하였다. 산란 벡터 q에서 얻은 산란광의 세기 I(q)는 Onstein-Zernike 식으로 해석이 불가능하여 단순히 $I(q){\sim}q^{-m}$을 이용하여 fractal 차원 m을 얻었다. 그 결과 농도 3 wt% 이상에서는 $m=2.6{\pm}0.3$으로 일정하게 유지되었다. 동적 광산란으로 얻은 시간상관함수에는 항상 빠른 거동과 느린 거동의 두 종류가 공존하였으며, 빠른 거동의 협동확산계수는 reptation 이론의 농도의존지수 값(=3/4)과 달리 농도 의존성이 거의 나타나지 않았다. 또한 느린 거동은 거대한 크기의 불균일 영역대의 운동으로 해석되며, 이 거동의 농도지수는 -3.0으로써 매우 강한 농도 의존성을 보여 주었다. 이 불균일 영역대의 형성에는 어택틱 PVA의 -OH기 4개의 메소(meso)가 입체 규칙적으로 배향한 부분이 매우 중요한 역할을 하는 것으로 생각되어진다.