• Title/Summary/Keyword: Langmuir-blodgett(LB) method

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Fabrication of Functional Organic Ultrathin (LB) Film and Synthesis of Film Material - N-Alkylquinolium TCNQ Complexes - (기능성 유기초박막의 제작기술과 성막물질의 합성 연구)

  • Shin, Dong-Myung;Sohn, Byung-Chung;Kim, Jung-Soo;Kang, Dou-Yol
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.41 no.7
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    • pp.753-759
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    • 1992
  • For the fabrication of the microscale memory or electrical devices, Langmuir-Blodgett(LB) method is the most possible candidate. N-Alkylquinolium-TCNQ compounds were synthesized. The structure of the compounds were identified by the NMR spectroscopy and the purity were checked to be good by the elemental analysis. The surface pressure($\pi$) was measured at the air-water interface. The isotherm showed two transitions at 30mN/m and 45mN/m. The LB films were deposited by the home-made Kuhn type apparatus. The transfer ratio($\tau$) of the deposition was more than 0.95 for the up-stroke and less than 0.4 for the down-stroke. The absorbance peaks of the LB films appear at around 420nm and 700-820nm.

A Study on the NO$_2$ Gas Detection Characteristics of Octa-dodecy1oxy Copper-Phthalocyanine LB Films (Octa-dodecyloxy Copper-Phthalocyanine LB 막의 NO$_2$ 가스 탐지 특성에 관한 연구)

  • 구자룡;이한성;하윤경;김영관;김정수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.1-4
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    • 1997
  • In this study, ruin films of Octla-dodecyloxy copper-phthalocyanine were prepared by Langmuir-Blodgett (LB) method and characterirzed by using UV-Vis absorption spectroscopy and ellipsometry. [1],r[2] Optimal transfer condition of LB films was investigated and preliminary results of current-voltage(1-V) characteristics of these films exposed to NO$_2$ gas as were discussed functions of film thickness, temperature and NO$_2$ gas concentration.

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Emission Properties of EL Device Fabricated by LB Method (LB법으로 제작한 백색 EL소자의 발광특성)

  • 김주승;이경섭;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.351-354
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    • 2001
  • We fabricated organic electroluminescent(EL) devices with mixed emitting layer of poly (N- vinylcarbazole) ( PVK) , 2,5-bis (5-tert-butyl -2- benzoxaBoly) thiophene ( BBOT) , N,N-diphenyl-N,N- (3-methyphenyl) -1,1-biphenyl-4, 4-thiamine(TPD) and poly(3-hexylthiophene) (P3HT) deposited by LB(Langumuir-Boldgett) method. From the AFM(atomic force microscope) images, the monolayer containing 30% of AA(arachidic acid) showed a roughness value of 28$\AA$. In the voltage-current characteristics of ITO/Emitting layer/BBOT/LiF/A1 devices, current density much smaller than that of the spin-coated devices having a same thickness.

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Elctrical Properties of DLPC Lipid Membrane Fabricated on the Silicon Wafer (실리콘 웨이퍼 위에 제작된 DLPC 지질막의 전기적특성)

  • 이우선;김충원;이강현;정용호;김남오;김상용
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.12
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    • pp.1115-1121
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    • 1998
  • MLS capacitor with lipid ultra thin films were deposited by Langmuir-Blodgett (LB) method on the silicon wafer. The current versus voltage and capacitance versus voltage relationships are depend on the applied voltage, electrode area and electrode materials. LB films deposited were made of L-$\alhpa$-DLPC, the 1 layer’s thickness of 35${\AA}$ was measured by ellipsometer. And MLS capacitor with different electrode materials, the work function of these materials was investigated to increase the leakage current. The result indicated the lower leakage current and very high saturation value of capacitance was reached within 700-800 pF when the two electrode was Ag. And $\varepsilon$1, $\varepsilon$2 versus photon energy showed good film formation.

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A Study on the Stability of Langmuir-Blodgett(LB) Films of L-${\alpha}$-Phosphatidylethanolamine Monolayer (L-${\alpha}$-Phosphatidylethanolamine 단분자층 LB막의 안정성에 관한 연구)

  • Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.1
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    • pp.44-49
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    • 2014
  • We were investigated by cyclic voltammetry to the stability through the electrochemical characteristics of phospholipid(L-${\alpha}$-phosphatidylethanolamine, LAPE) monolayer LB films. LAPE monolayer LB films was deposited by the LB method on the indium tin oxide(ITO) glass. The electrochemical properties was measured by cyclic voltammetry with a three-electrode system in 0.5 N, 1.0 N, 1.5 N and 2.0 N $KClO_4$ solution. The measuring range is continuously oxidized to 1650 mV, with an initial potential of -1350 mV was reduced. Scanning rates of 50, 100, 150, 200, and 250 mV/s was set. As a result, LB monolayer films of LAPE was appeared on irreversible processes by the oxidation current from the cyclic voltammogram. Diffusion coefficient (D) of LAPE was calculated 195, 15.9, 5.75, 1.38 and $0.754cm^2s^{-1}{\times}10^{-9}$ at 0.01 N, 0.05 N, 0.10 N, 0.15 N and 0.20 N $KClO_4$ solutions, respectively.

Electrical Properties of Organic Thin Film for Power Device (전력 소자용 유기박막의 전기적 특성)

  • Song, Jin-Won;Choi, Yong-Sung;Moon, Jong-Dae;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.05a
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    • pp.20-22
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    • 2006
  • Monolayers of lipids on a water surface have attracted much interest as models of biological membranes, but also as precursors of multilayer systems promising many technical applications. Until now, many methodologies have been developed in order to gain a better understanding of the relationship between the structure and function of the monolayers. Maxwell displacement current (MDC) measurement has been employed to study the dielectric property of Langmuir-films. MDC flowing across monolayers is analyzed using a rod-like molecular model. A linear relationship between the monolayer compression speed and the molecular area Am. Compression speed was about 30, 40, 50mm/min. Langmuir-Blodgett(LB)layers of Arachidic acid deposited by LB method were deposited onto slide glass as Y-type film. The structure of manufactured device is Au/Arachidic acid/Al, the number of accumulated layers are 9~21. Also, we then examined of the Metal-Insulator-Metal(MIM) device by means of I-V. The I-V characteristics of the device are measured from -3 to +3[V]. The insulation property of a thin film is better as the distance between electrodes is larger.

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Genome Detection Using Hoechst 33258 Groove Binder (유기박막의 전기적 특성)

  • Song, Jin-Won;Choi, Yong-Sung;Moon, Jong-Dae;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.370-371
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    • 2006
  • Maxwell displacement current (MDC) measurement has been employed to study the dielectric property of Langmuir-films. MDC flowing across monolayers is analyzed using a rod-like molecular model. A linear relationship between the monolayer compression speed and the molecular area Am. Compression speed was about 30, 40, 50mm/min. Langmuir-Blodgett(LB)layers of Arachidic acid deposited by LB method were deposited onto slide glass as Y-type film. The structure of manufactured device is Au/Arachidic acid/Al, the number of accumulated layers are 9~21. Also, we then examined of the Metal-Insulator-Metal(MIM) device by means of I-V. The I-V characteristics of the device are measured from -3 to +3[V]. The insulation property of a thin film is better as the distance between electrodes is larger.

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Fabrication of Ultrathin Polyimide Films by LB Technique (LB법을 이용한 polyimide 초박막의 제작)

  • Kim, J.H.;Yoo, D.S.;Kim, Y.K.;Shon, B.C.;Kang, D.Y.
    • Proceedings of the KIEE Conference
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    • 1993.11a
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    • pp.174-177
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    • 1993
  • The polyimide films were prepared by imidizing the polyamic acid long-chain alkylamine (dimethylhexadecylamine) salt films with a thermal and chemical treatment, where the polyamic acid alkylamine salt film were formed on various substrates by using Langmuir-Blodgett (LB) method. The imidization of polyamic acid alkylamine salt films with various thickness were identified with FT-IR and UV-visible absorption spectroscopies. Atomic Force Microscopy (AFM) have been used to investigate the surface morpology of polyamic acid alkylamine salt and imidized films.

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Study on morphology of silsesquioxane based polymer LB films by using AFM (AFM을 이용한 Silsesquioxane based polymer의 LB막 모폴로지 관찰)

  • Lee, Ji-Yoon;Yang, Chang-Heon;Kim, Chung-Kyun;Park, Jae-Chul;Kwon, Young-Soo
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.1293-1294
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    • 2008
  • The Langmuir-Blodgett (LB) method has been one of the most suitable techniques for fabricating organic thin films with well-controlled structures, compositions and thickness at the molecular level. We investigated the surface activity of dendrimer films at air-water interface by ${\pi}$-A isotherm. Also, we attempted to fabricate a 1G(4,3)-chloride dendrimer LB films. And their surface morphologies were observed by atomic force microscopy (AFM).

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A study on the NO$_2$Gas Detection chracteristics of the Octa (2-ethylhexyloxy) copper-phthalocyanine LB film (Octa (2-ethyls expel oxy) copper-phthalocyanine LB막의 NO$_2$가스 탐지 특성에 관한 연구)

  • 임준석;김영관;김정수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.11a
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    • pp.121-124
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    • 1996
  • It is well known that the metallo- phthalocyanine (MPcs) are sensitive to toxic gaseous molecules such as NO$_2$and also chemically and thermally stable. Therefore, lots of MPcs have been studied for the potential chemical sensor for NO$_2$gas using quartz crystal microbalance(QCM) or electrical conductivity. In this study, thin films of octa(2-ethylhexyloxy) copper-phthalocyanine were prepared by Langmuir -Blodgett method and characterized by using UV-VIS spectroscopy and ellipsometry. Transfer condition, and characterization of LB films were investigated and preliminary results of current-voltage(I-V) characteristics of these films exposed to NO$_2$gas as a function of film thickness, temperature and temperature were discussed.

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