• Title/Summary/Keyword: Lamellar

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A Study on Mobility Gradients and Phase Transitions in N-propyl-N,N-dimethylethanolamine Reaction (N-propyl-N,N-dimethylethanolamine 반응에서 유동성 변화와 상전이에 관한 연구)

  • Kim, Ki-Jun;Sung, Wan-Mo;Lee, Joo-Youb
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.1
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    • pp.165-169
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    • 2015
  • N-propyl-N,N-dimethylethanolamine was directly ultrasonicated in acidic water for 6 minute to give clear stock solutions. The catalytic hydrolysis of N-propyl-N,N-dimethylethanolamine was studied at $30{\sim}55^{\circ}C$ in the presence of uni-lamellar vesicle and mixture of uni- and multi-lamellar aggregates. The difference of rate between uni- and mixture was observed, where uni-lamellar reaction was more catalytic effect. The phase transition temperature of vesicle was $37{\sim}44^{\circ}C$. The particle size of multi-lamellar than that of uni-lamellar of biological membrane was measured more largely.

Evaluation of Settling Characteristics at Lamellar Secondary Clarifier (Lamellar 이차침전지에서의 침강 특성 파악)

  • Lee, Byong-Hi
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.3
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    • pp.471-478
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    • 2012
  • Where an activated sludge system needs to be converted to biological nutrient removal(BNR) system, the secondary clarifier must handle higher MLSS from bioreactor since nitrification in BNR system that requires higher SRTs than activated sludge system. Either increase the clarifier size or modification of clarifier physical structure is required to cope with MLSS surge. One of recommended structural modification is the insertion of Lamellar within clarifier. In this study, two clarifiers - one has Lamellar structure inserted and the other does not - were used to compare the effect of Lamellar in solid/liquid separation. Same MLSS was fed to both clarifiers and concentrations of MLSS were varied. With all MLSS concentrations, attachment of MLSS on Lamellar was observed and it was found that detached MLSS caused the higher effluent SS concentrations than that of non-Lamellar clarifier effluent. From these results, Lamellar should not be inserted in clarifier to handle MLSS from BNR processes and the recommendation must be withdrawn.

Effect of non-metallic inclusion on susceptibility to lamellar tearing (라멜라 테어 발생감수성에 미치는 비금속개재물의 영향)

  • 방국수;이종봉
    • Journal of Welding and Joining
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    • v.3 no.1
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    • pp.3-10
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    • 1985
  • Lamellar tearing susceptibility and through-thickness tensile ductility have been investigated in $40kg/mm^2 and 50kg/mm^2$ class tensile strength steel plates in terms of cleanliness of non-metallic inclusion and welding condition. The plate which had 0.01% cleanliness of A-type inclusion (MnS) had 61% of the reduction of area in the through-thickness direction and did not show lamellar tearing. Lamellar tearing susceptibility decreased with increasing the preheat and interpass temperature. The plate which had 0.04% cleanliness of A-type inclusion did not show lamellar tearing under the condition of 75.deg. C of preheat and interpass temperature.

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Chain orientation and Degradation Behavior of Poly[(R)-3-hydroxybutyrate] Lamellar Crystals

  • Lee, Won Gi;Jo, Nam Ju;Ha, Chang Sik
    • Bulletin of the Korean Chemical Society
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    • v.22 no.8
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    • pp.872-876
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    • 2001
  • Topological changes caused by the alkaline and enzymatic attacks of solution-grown, chain-folded lamellar crystals (SGCs) of poly[(R)-3-hydroxybutyrate] P(3HB) have been studied in order to investigate the chain-folding structure in P(3HB) crystal regions. NaOH and an extracellular PHB depolymerase purified from Alcaligenes faecalis T1 were used for alkaline and enzymatic hydrolysis, respectively. The measurements were performed on crystals attached to a substrate which is inactive to degradation mediums. Both alkaline and enzymatic attacks lead to a breakup of the lamellar crystals along the crystallographic b-axis during initial erosion. Since hydrolysis preferentially occurs in amorphous regions, this morphological result reflects relatively loosely packed chains in core parts of lamellar crystals. Additionally, it was supported by the ridge formation along the b-axis in the lamellar crystals after thermal treatment at a low temperature because of the thermally sensitive nature of the loosely packed chains in lamellar crystals. However, the alkaline hydrolysis accompanied the chain erosions or scissions in quasi-regular folded lamellar surfaces due to smaller size of alkaline ions in comparison to the enzyme, resulting in the decrease of molecular weight.

Structural Analysis of Lamellar Plane in Three-Dimensional Crystal of $Ca^{2+}-ATPase$ ($Ca^{2+}-ATPase$ 3차원 결정의 Lamellar면 구조분석)

  • Cheong, Gang-Won
    • Applied Microscopy
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    • v.27 no.2
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    • pp.111-120
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    • 1997
  • Cylinder-like crystals of $Ca^{2+}-ATPase$ provide views parallel to the lamellar plane, from which parameters of lamellar stacking can be directly measured. These parameters were measured using different preparation methods. Assuming that molecular packing is the same, data from lamellar plane could supplement those obtained by tilting large, thin plate-like crystals. However, base on data obtained .by electron microscopy and x-ray powder patterns, the plate-like crystal may have another scheme for stacking the lamellar. The projection map (h, 0, 1) from cylinder-like crystals using cryoelectron microscopy suggest the lamellar spacing can be variable.

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Study on the beneficial effect of Bio-Mimic Liquid Crystal Emulsion (BLCE) on Skin Barrier Function (피부장벽에 대한 Bio-Mimic Liquid Crystal Emulsion (BLCE)의 긍정적 효과에 관한 연구)

  • Ahn, Yong-Hoon;Bae, Soon-Min;Jung, Jin-Kyo;Hwang, Jeong-Geun
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.33 no.4
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    • pp.227-230
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    • 2007
  • The multi-lamellar and liquid crystal structures have drawn great public attention in the functional cosmetic and skin-related medicinal areas recently. The structure of an emulsion containing aqueous phase as a binding water and fixed oil phase components forming an association compound of the multi-lamellar structure can reconstruct the intercellular lipid lamellar structure in the stratum corneum and restore barrier function of the skin. In this study, we investigated the beneficial effect of bio-mimic liquid crystal emulsions (BLCE) containing higher fatty alcohol, lecithin, and cholesterol on the skin barrier function, and evaluated its cytotoxicity.

Lamellar Body Counts in Fetal Rabbits' Experimental Diaphragmatic Hernia and Tracheal Ligation (기도결찰을 시행한 토끼 태자의 실험적 횡격막탈장에서 Lamellar body counts)

  • Chun, Yong-Soon;Jung, Soo-Jin;Lee, Jeong-Nyeo
    • Advances in pediatric surgery
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    • v.17 no.2
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    • pp.179-187
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    • 2011
  • Experimental tracheal ligation (TL) has been shown to reverse the pulmonary hypoplasia associated with congenital diaphragmatic hernia (CDH) and to normalize gas exchange. The purpose of this study was to determine whether the TL would correct the surfactant deficiency present in the fetal rabbit model of CDH by using lamellar body count. Lamellar bodies are synthesized and secreted by the type II pneumocytes of fetal lung. The phospholipids present in these bodies constitute the major component of pulmonary surfactant. Twenty-one pregnant New Zealand rabbits underwent hysterotomy and fetal surgery on gestational day 24. Two fetuses of each pregnant rabbit were operated. In the fetus of one end of bicornuate uterus, left DH was created by excision of fetal diaphragm through open thoracotomy (DH Group). In the fetus of the other end of bicornuate uterus, left DH and TL were created (TL Group). The fetuses were delivered by Cesarean section on gestational day 31. Fourteen in control group, 12 in the DH group and 13 in TL group were born alive. En bloc excision of lungs, bronchi and trachea was done in all newborn rabbits. A five Fr catheter was inserted through trachea and repeated irrigations with 10 cc normal saline were done. The irrigated fluid was centrifuged at $280{\times}g$ for 5 minutes and the lamellar bodies were counted with the upper level fluid in platelet channel of electronic cell counter. The average lamellar body counts were $37.1{\pm}14.2{\times}10^3/{\mu}L$ in control group, $11.5{\pm}4.4 {\times}10^3/{\mu}L$ in DH group, and $6.5{\pm}0.9{\times}10^3/{\mu}L$ in TL group. Lamellar body count in DH group was lower than in control group and did not increase after TL. This study shows TL has no therapeutic effect on decreased surfactant level of CDH and the pregnant rabbit is appropriate for the animal model of CDH.

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Phase behaviors, lamellar structures, and physical properties of synthetic vitamin E ceramide (Tocomide) mixed with cholesterol and linoleic acid

  • Lee, Young-Jin;Kim, Do-Hoon;Park, Ho-Sik;Kang, Hyung-Seok;Kim, Joong-Soo;Kim, Han-Kon
    • Proceedings of the SCSK Conference
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    • 2003.09b
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    • pp.357-368
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    • 2003
  • II-A isotherms and phase behaviors of 'tocomide', a newly synthesized 1,3-bis(N-(2-hydroxyethyl)-tocopherol succinylamino)-2-hydroxypropane, mixed with cholesterol and linoleic acid, was studied for its monolayer miscibility and a stable delivery formulation for antioxidant applications. The monolayer of tocomide and cholesterol was formed in a homogeneously mixed state at air-water interface. The ternary mixtures with linoleic acid showed various bulk structures, including a stable and transparent solution of thermodynamically stable lamellar phase. The lamellar structure was confirmed by the X-ray diffraction (XRD) patterns and polarized microscopy such that pure tocomide formed a liquid crystal at room temperature with a lamellar periodicity of 36.7 $\AA$(2$\theta$=2.41$^{\circ}$).

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Changes of Lamellar Structure of TiAl Intermetallic Compound Heat Treatment (열처리에 따른 TiAl금속간화합물의 층상조직 변화)

  • Shin, Jae-Kwan;Chung, In-Sang;Park, Kyuong-Chae
    • Journal of the Korean Society for Heat Treatment
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    • v.6 no.3
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    • pp.127-137
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    • 1993
  • The changes of lamellar(${\alpha}_2+{\gamma}$) structure of TiAl intermetallic compound which is a high potential, high temperature aerospace material was investigated by heat treatment. The lamellar structure was short and made subgrain in prior a grains after homogenizing at 1523 K. It became longer and finer, and the subgrain went out during subsequent isothermal heatteating at 1273 K. The yield, fracture strength and strain to fracture if the heat treated specimens was increased and the hardness of them was decreased a little in the finer lamellar structure, because fine lamellar interface, sugrain boundary and grain boundary may block initiation and propagation of crack.

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Lyotropic Mesomorphisms of a Lamellar Liquid Crystalline Phase in Non-hydrous Condition: A Phospholipid Hydrated by Different Polar Solvents

  • Lee, Dong-Kyu;Jeong, Kwan-Young
    • Bulletin of the Korean Chemical Society
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    • v.31 no.5
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    • pp.1165-1171
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    • 2010
  • The lyotropic mesomorphism of lamellar liquid crystalline phase was examined by observing the swelling behavior of Distearoylphosphatidylcholine(DSPC) in glycerin and panthenol without water. The lyotropic mesomorphism was examined by using DSC, XRDs and Cryo-SEM. Increase of two polar solvents under non-hydrous condition showed distinctive differences in the lyotropic mesomorphism from forming different anisotropic structures with DSPC. Glycerin did not affect to the crystalline region of lamellar phase, whereas typical swelling mesomorphism was shown in the noncrystalline region. In contrast, panthenol showed some effect on the crystalline region, but common swelling mesomorphism was found in the non-crystalline region. In this case, the isopropyl and propyl groups in panthenol were the main factor to affect to the lipophilic domain in the crystalline region of lamellar phase. Also, it was found that the formation of well-arranged lamellar structure only by introducing glycerin and panthenol as a solvent without water, was possible. These results were confirmed by examination of the swelling mesomorphism of liquid crystal membrane triggered by introducing the two polar solvents.