• Title/Summary/Keyword: LDPE( Low Density Polyethylene)

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Effect of Thermal Aging on Electrical Properties of Low Density Polyethylene

  • Wang, Can;Xie, Yaoheng;Pan, Hua;Wang, Youyuan
    • Journal of Electrical Engineering and Technology
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    • v.13 no.6
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    • pp.2412-2420
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    • 2018
  • The thermal degradation of low density polyethylene (LDPE) will accelerate the production of carbonyl groups (C=O), which can act as the induced dipoles under high voltage. In this paper, we researched the dielectric properties and space charge behavior of LDPE after thermal aging, which can help us to understand the correlation between carbonyl groups (C=O) and electrical properties of LDPE. The spectra results show that LDPE exhibit obvious thermooxidative reactions when the aging time is 35 days and the productions mainly contain carboxylic acid, carboxylic eater and carboxylic anhydride, whose amount increase with the increasing of aging time. The dielectric properties show that the real permittivity of LDPE is inversely proportional to temperature before aging and subsequently become proportional to temperature after thermal aging. Furthermore, both the real and imaginary permittivity increase sharply with the increasing of aging time. The fitting results of imaginary permittivity show that DC conductivity become more sensitive about temperature after thermal aging. On this basis, the active energies of materials calculated from DC conductivity increase first and then decrease with the increasing of aging time. In addition, the space charge results show that the heterocharges accumulated near electrodes in LDPE change to the homocharges after thermal aging and the mean volume charge density increase with the increasing of aging time. It is considered that the overlaps caused by electrical potential area is the main reason for the increase of DC conductivity.

DC Breakdown Strength Characteristics of Low Density Polyethylene

  • Yun, Jae-Hun;Jeong, Ui-Hwan;Im, Gi-Jo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.231-231
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    • 2009
  • The main objective of the present paper is multiple effects of the incorporation of certain additives into LDPE (low density polyethylene) on some of the properties of the doped material relevant to its use as an insulating material for HVDC cables. in the present work, the effects of additive and breakdown strength, under de conditions. result of experiments are present and discussed. it is concluded that, although the incorporation of the additives may lead to certain beneficial effects such as the reduction of the dependence on temperature and breakdown strength

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Variations of the Electrical Treeing and Breakdown Characteristics on LDPE Due to Gamma-ray Irradiation

  • Lee, Chung;Ryu, Boo-Hyung
    • International Journal of Safety
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    • v.8 no.1
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    • pp.14-17
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    • 2009
  • The $Co^{60}$ $\gamma$-ray irradiation effects on the electrical and thermal characteristics of low density polyethylene crosslinked by Dicumyl peroxide (DCP) were investigated. We experimented on electrical properties as following; electrical tree inception and growing type for applying AC step voltage, AC breakdown strength, volume resistivity with increasing dosage. Also, chemical analyses were performed TGA, gel fraction. These electrical properties changed depending upon its crosslinking degree and byproducts from crosslinking reactions. Crosslinking reactions were considered causing by $\gamma$-ray irradiation and DCP had contained in low density polyethylene.

A study on productivity improvement of Li/MnO$_2$ battery by change of AI Foil spec. (리튬전지의 생산성 향상을 위한 AI Foil spec. 변경에 관한 연구)

  • 김학주;송수정
    • Proceedings of the KAIS Fall Conference
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    • 2001.11a
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    • pp.91-94
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    • 2001
  • 리튬전지의 vent cap ass'y용의 AI foil에 LDPE(low density polyethylene)만을 coating하였으나 LDPE는 vent cover인 sus와의 열접착성이 우수하지 못하기 때문에 vent 조립시 상당한 주의가 필요했다. 그러나, LDPE보다 열접착성이 우수한 EVA(ethylene vinylacetate)와 EAA(ethylene acrylic acid)의 2중 coating된 AI foil을 이용함으로 열접착성을 향상시킬 수 있었다. 이에 따라, 전해액 누액 등의 전지 불량 원인을 제거함과 동시에 vent cap ass'y의 조립시 공정 불량까지 감소시킬 수 있었다.

Processability of Bio-composites Applied Polyolefin to Recycled Fiberboard Flour (Polyolefin계 고분자에 섬유판 가공 부산물을 적용한 환경 친화형 바이오복합재의 가공성)

  • Choi, Seung-Woo;Kim, Hee-Soo;Lee, Byoung-Ho;Kim, Hyun-Joong;Ahn, Sye-Hee
    • Journal of the Korean Wood Science and Technology
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    • v.33 no.6 s.134
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    • pp.55-62
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    • 2005
  • This study was conducted to evaluate the application of a bio-composite made by the addition recycled fiber board flour as filler. Recycled fiber board (high density fiber board, HDF) flour was added to polyolefin polymer low density polyethylene (LDPE) and polypropylene (PP) for the preparation of bio-composite materials. The mechanical properties and processability of the recycled HDF flour filled LDPE and recycled HDF flour filled PP bio-composites were then measured and compared to those of wood flour (WF) and rice-husk flour (RHF) filled LDPE and PP bio-composites, respectively. The tensile and impact strengths of the recycled HDF flour filled LDPE and PP bio-composites had similar mechanical properties to those of the WF and RHF filled LDPE and PP bio-composites. To measure the processability, torques of the bio-composites were also measured. The torques of the HDF flour filled LDPE and PP bio-composites were lower than those of the WF and RHF filled polyolefin (PP and LDPE) bio-composites with a filler loading of 30 wt.%. This result showed definite processability, which was not related with the distribution of the particle size of the material added. The recycled fiber board flour filled bio-composites showed applicability as substitutes for the bio-composites currently used in the bio-composites industry.

Sorption Characteristics of Procymidone and 3,5-Dichloroaniline on Microplastic Films (미세플라스틱 필름의 프로시미돈과 3,5-다이클로로아닐린 흡착 특성)

  • Ji Won Yang;Youn-Jun Lee;Eun Hea Jho
    • Korean Journal of Environmental Agriculture
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    • v.42 no.3
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    • pp.184-192
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    • 2023
  • Microplastics are generated by the breakdown of plastic wastes in agricultural soil and residual pesticides in agricultural soil can adsorb on microplastics. In this study, the sorption characteristics of procymidone (PCM) and one of its metabolites, 3,5-dichloroaniline (DCA), on low-density polyethylene (LDPE) and polyvinyl chloride (PVC) microplastics were investigated. The sorption and desorption tests were carried out for 72 h using LDPE or PVC microplastic films to study the sorption isotherms of PCM and DCA and kinetics for sorption and desorption of PCM. The results show that the sorption data of PCM and DCA were better described by the Freundlich isotherm model (R2=0.7568-0.9915) than the Langmuir isotherm model (R2=0.0545-0.5889). The sorption potential of PVC for both PCM and DCA was greater than that of LDPE. The sorption data of PCM on PVC and LDPE were fitted better to the pseudo-second-order kinetic model than the pseudo-first-order kinetic model. The PCM sorption on LDPE was about three times faster than that on PVC. Both microplastic films released the sorbed PCM back to water, and more PCM was released from PVC than LDPE, but the desorption rate was faster with LDPE than PVC. Overall, the results show that different microplastics have different sorption characteristics for different chemicals. Also, the sorbed chemicals can be released back to environment suggesting the potential of contaminant spread by microplastics. Thus, the management practices of microplastics in agricultural soil need to consider their interaction with the chemical contaminants in soil.

Changes in Quality Characteristics of Bell Pepper Packaged with Different Films (포장 조건에 따른 피망의 저장 중 품질 특성 변화)

  • 박우포;조성환;김철환
    • Food Science and Preservation
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    • v.10 no.2
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    • pp.131-135
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    • 2003
  • Bell pepper was packed with several plastic films, and investigated the quality Characteristics such as gas composition, weight loss, microbial load, soluble solid content, ascorbic acid and color during storage at 10$^{\circ}C$. Cast polypropylene (CPP), low density Polyethylene (LDPE), Polyolefin (MPD, PD961) and linear low density polyethylene (LLDPE) were used for this purpose. Oxygen concentration inside packages generally showed a 10∼14% after 1∼2 weeks, but package with CPP maintained above 15% throughout the storage. Carbon dioxide concentration of CPP was above 2%, but other treatments showed below 2%. Weight loss of all treatments was below 3.0% after 5 weeks. Total microbial count showed a similar pattern compared to yeast and mold, and CPP maintained the highest microbial load after 3 weeks. Yellowness (b value) of bell pepper was generally increased throughout the storage, and MPD and PD961 were higher than other treatments.

Quality Changes of Salted Baechu with Packaging Methods during Long Term Storage (포장방법을 달리한 절임배추의 장기저장중 품질변화)

  • Han, Eung-Soo;Seok, Moon-Sik;Park, Ji-Hyun
    • Korean Journal of Food Science and Technology
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    • v.30 no.6
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    • pp.1307-1311
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    • 1998
  • Optimal packaging methods for the long term storage of salted winter baechu were investigated. Salted baechu was packaged individually in 20 ㎏ unit weight in LDPE (low density polyethylene), HDPE (high density polyethylene), PVC-box and then stored at $0^{\circ}C$ for 8 weeks. During storage, quality index of salted baechu were measured in terms of salinity, pH, reducing sugar content, total cell counts and lactic acid bacterial counts. Salted baechu deteriorated rapidly in PVC-box, and slowly in HDPE but sustained for 8 weeks in LDPE. In all treatment, salted baechu was maintained better at submerged parts in exudate, but deteriorated at emerged parts.

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Combustive Properties of Low Density Polyethylene and Ethylene Vinyl Acetate Composites Including Magnesium Hydroxide (저밀도 폴리에틸렌과 에틸렌 비닐 아세테이트에 수산화마그네슘을 첨가한 복합체의 연소성)

  • Chung, Yeong-Jin
    • Fire Science and Engineering
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    • v.25 no.5
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    • pp.69-75
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    • 2011
  • It was performed to test the combustive properties of low density polyethylene and ethylene vinyl acetate (LDPE-EVA) composite by the addition of magnesium hydroxide. Flame retardant of natural magnesium hydroxide was added to the mixture of LDPE-EVA in 40 to 80 wt% concentration. The composite was compounded to prepare specimen for combustive analysis by cone calorimeter (ISO 5660-1). Comparing with virgin LDPE-EVA, the specimens including the magnesium hydroxide had lower flashover possibility. It is supposed that the combustive properties in the composites decreased due to the endothermic decomposition of magnesium hydroxide. The specimens with magnesium hydroxide showed both the lower total heat release rate (THR) and lower CO production rate than those of virgin polymer. As the magnesium hydroxide content increases, the total smoke release (THR) and smoke extinction area (SEA) decreased.