• Title/Summary/Keyword: L2TP

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Optimization of fractionation efficiency (FE) and throughput (TP) in a large scale splitter less full-feed depletion SPLITT fractionation (Large scale FFD-SF) (대용량 splitter less full-feed depletion SPLITT 분획법 (Large scale FFD-SF)에서의 분획효율(FE)및 시료처리량(TP)의 최적화)

  • Eum, Chul Hun;Noh, Ahrahm;Choi, Jaeyeong;Yoo, Yeongsuk;Kim, Woon Jung;Lee, Seungho
    • Analytical Science and Technology
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    • v.28 no.6
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    • pp.453-459
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    • 2015
  • Split-flow thin cell fractionation (SPLITT fractionation, SF) is a particle separation technique that allows continuous (and thus a preparative scale) separation into two subpopulations based on the particle size or the density. In SF, there are two basic performance parameters. One is the throughput (TP), which was defined as the amount of sample that can be processed in a unit time period. Another is the fractionation efficiency (FE), which was defined as the number % of particles that have the size predicted by theory. Full-feed depletion mode (FFD-SF) have only one inlet for the sample feed, and the channel is equipped with a flow stream splitter only at the outlet in SF mode. In conventional FFD-mode, it was difficult to extend channel due to splitter in channel. So, we use large scale splitter-less FFD-SF to increase TP from increase channel scale. In this study, a FFD-SF channel was developed for a large-scale fractionation, which has no flow stream splitters (‘splitter less’), and then was tested for optimum TP and FE by varying the sample concentration and the flow rates at the inlet and outlet of the channel. Polyurethane (PU) latex beads having two different size distribution (about 3~7 µm, and about 2~30 µm) were used for the test. The sample concentration was varied from 0.2 to 0.8% (wt/vol). The channel flow rate was varied from 70, 100, 120 and 160 mL/min. The fractionated particles were monitored by optical microscopy (OM). The sample recovery was determined by collecting the particles on a 0.1 µm membrane filter. Accumulation of relatively large micron sized particles in channel could be prevented by feeding carrier liquid. It was found that, in order to achieve effective TP, the concentration of sample should be at higher than 0.4%.

Characteristics of Stormwater Runoff from Urban areas with Industrial Complex (산업단지의 도시 강우유출수 배출 특성)

  • Jung, Yong-Jun;Kim, Si-Won
    • Journal of Wetlands Research
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    • v.14 no.1
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    • pp.131-137
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    • 2012
  • This study was investigated to characterize the stormwater runoff pollutant materials from the urban area mixed with industrial area. Almost the similar rainfall pattern is shown during the 5 years, and the yearly precipitation was 5.2~6.6 mm. The first flushing effect during the early-stage rainfall-run off was observed in some events. EMC ranges are 19.3~39.9 mg/L for BOD, 45.2~190 mg/L for CODcr, 67.2~351 mg/L for TSS, 3.6~10.3 mg/L for TN, 1.2~2.5 mg/L for TP. Heavy metal are not detected except Zn which is observed at only one event. The particle size was distributed to 10 ${\mu}m$ at the 3% weight volume and the 50% cumulative weight percent was shown at 12 ${\mu}m$.

Enhanced Anti-oxidant Activity Effects of Smilax china L. Rhizome Water Extracts Added with Its Fermented Leaf Water Extracts (발효 청미래덩굴잎 추출물의 혼합에 의한 토복령의 항산화활성 증진효과)

  • Lee, Sang-Il;Lee, Ye-Kyung;Kim, Soon-Dong;Shim, Soon-Mi;Yang, Seung Hwan;Cheng, Jinhua;Suh, Joo-Won
    • Journal of Applied Biological Chemistry
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    • v.57 no.2
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    • pp.145-152
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    • 2014
  • To evaluate the improving effects of antioxidant activity, we observed antioxidant capacities such as electron donating ability (EDA), Ferric reducing antioxidant power (FRAP), inhibitory activity of xanthine oxidase (XO) and aldehyde oxidase (AO), and sensory characteristics on mixture of Smilax china L. root water extract added with water extract of fermented S. china L. leaf by Aspergillus oryzae (FSCL). Those contents of mixture with higher ratio of FSCL were proportionally high. And OD475 of mixture with higher ratio of FSCL was almost proportionally high ($R^2=0.9850$). Antioxidant capacities of EDA and FRAP of the mixture was higher than that of non-mixture. In addition, XO inhibitory activity ($IC_{50}$) of A (1.19) was 59.80% higher than that of F (2.96), and the activity of mixture by the higher ratio of FSCL was proportionally low ($R^2=0.9490$). Taste acceptability of A was slightly higher than that of F, whereas that of C was highest. And color acceptability of 40-80% mixture was higher than those of A, F, and B. Overall acceptability of C and D was highest than those of others. Moreover, hot water extract of S. china L. leaf fermented with A. oryzae was maroon color, which looks like Puerh tea style, and mixture of S. china L. root extract added with hot water extract of S. china L. leaf was high acceptability of beverage. These results suggest that mixture of extract of S. china L. root and hot water extract of S. china L. leaf fermented with A. oryzae could improve antioxidant activities.

Antioxidant Activity of Fractions from 70% Methanolic Extract of Sonchus oleraceus L.

  • Yin, Jie;Heo, Seong-Il;Jung, Mee-Jung;Wang, Myeong-Hyeon
    • Food Science and Biotechnology
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    • v.17 no.6
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    • pp.1299-1304
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    • 2008
  • The potential antioxidant activities of different fractions from a 70% methanolic (MeOH) extract of Sonchus oleraceus were assayed in vitro. All of the fractions exception of n-hexane showed a strong antioxidant activity, especially the ethyl acetate (EtOAc) fraction, which showed the highest 1,1-diphenyl-2-picrylhydrazyl (DPPH) free radical scavenging activity ($IC_{50}=19.25{\mu}g/mL$). The results of hydroxyl radical scavenging activity and a reducing power assay showed concentration dependence, the EtOAc fraction demonstrating a better result than the other fractions at the same concentration in the studies. Additionally, the fractions' total phenolic (TP) contents was measured, phenolic compounds such as tannic acid, p-coumatric acid, quercetin, epicathchin, and kaempferol being detected by high performance liquid chromatography (HPLC). Meanwhile, a regression analysis revealed a moderate-to-high correlation coefficient between the antiradical activity and the TP contents, suggesting that fractions obtained from the 70% MeOH extract of S. oleraceus are of potential use as sources of antioxidant material.

Water Quality Prediction and Forecast of Pollution Source in Namgang Mid-watershed each Reduction Scenario (남강중권역 오염부하 전망 및 삭감 시나리오별 하류 수질예측)

  • Yu, Jae Jeong;Shin, Suk Ho;Yoon, Young Sam;Kang, Doo Kee
    • Journal of Environmental Impact Assessment
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    • v.21 no.4
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    • pp.543-552
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    • 2012
  • Namgang mid-watershed is located in downstream of Nakdong river basin. There are many pollution sources arround this area and it's control is important to manage a water quality of Nakdong river. A target year of Namgang mid-watershed water environment management plan is 2013. To predict a water quality at downstream of Namgang, we have investigated and forecasted the pollutant source and it's loading. There are some plan to construction the sewage treatment plants to improve the water quality of Nam river. Those are considered on predicting water quality. As results, it is shown that the population is 343,326 and sewerage supply rate is 79.2% and the livestock is 1,662,000 in Namgang mid-watershed. It is estimated that the population is 333,980, the sewerage supply rate is 86.9% in 2013. The milk cow and cattle were estimated upward and the pigs were downward by 2013. The generated loading of BOD and TP is 75,957 kg/day and 4,311 kg/day, discharged loading is 18,481 kg/day and 988 kg/day respectively in 2006. It were predicted upward the discharged loading of BOD and TP by 4.08% and 6.3% respectively. The results of water quality prediction of Namgang4 site were 2.5 mg/L of BOD and 0.120 mg/L of TP in 2013. It is over the target water quality at that site in 2015 about 25.0% and 9.1% respectively. Consequently, there need another counterplan to reduce the pollutants in that mid-watershed.

Treatment of Canine Cervical and Lumbar Disc Disease by Injection-Acupuncture (개 경부 및 요부 디스크의 수침치료)

  • Kim Duck-Hwan;Liu Jian-Zhu;Lee Young-Won;Song Kun-Ho;Kang Sang-Kyu;Choi Ho-Jung;Seo Kang-Moon;Choi Seok-Hwa;Nam Tchi-Chou;Rogers Phil A.M.
    • Journal of Veterinary Clinics
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    • v.23 no.1
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    • pp.65-68
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    • 2006
  • Two cases of canine intervertebral disc disease (IVDD) were treated twice a week with injection-acupuncture (injection-AP) using 0.1 ml/acupoint. In case 1, a paralysed dog with cervical intervertebral disc disease (C3-C4), was submitted to injection-AP with dexamethasone (1 mg/ml) at session 1-2 and thiamine (25 mg/ml) at session 3-5. Injected acupoints included GV-16, GB-20, BL-10, LU-7, LI-4 and SI-6. The acupoints GV-6, GV-20 and SP-6 were added at session 2-5. Trigger point (TP) therapy with 0.2 ml of 2% lidocaine was used in session 3-5 at TP in the infraspinatus and triceps muscles. Treatment was stopped when paralysis disappeared after 5 injection-AP treatments; there were no recurrent symptoms in the follow-up period of 5 months. In case 2, an ataxic dog with lumbar IVDD (L1-L2), was submitted to injection-AP with dexamethasone at session 1 and 2 and thiamine at session 3-4. Injected acupoints included GV-6 as the main point, ST-36, GB-30, ST-40, GB-34, ST-41 and BL-40. TP therapy with 0.2 ml of 2% lidocaine was used at TP in the ileocostorum lumborum and quadriceps muscles. Treatment was stopped when ataxia disappeared after 4 treatments; there were no recurrent symptoms In the fallow-up period of 5 months. Injection-AP using dexamethasone and thiamine, combined with TP therapy using lidocaine, effectively alleviate the symptoms of canine cervical and lumbar IVDD.

Exceptionally stable green-synthesized gold nanoparticles for highly sensitive and selective colorimetric detection of trace metal ions and volatile aromatic compounds

  • Singh, Karanveer;Kukkar, Deepak;Singh, Ravinder;Kukkar, Preeti;Kim, Ki-Hyun
    • Journal of Industrial and Engineering Chemistry
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    • v.68
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    • pp.33-41
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    • 2018
  • The manuscript reports synthesis of exceptionally stable gold nanoparticles (GNPs) using Momordica charantia fruit extract. The synthesis approach was optimized by refining three experimental variables including source of the fruit extract (peel, seed, and seed coat), pH of the solution, and temperature of the reaction medium. As synthesized GNPs showed excellent stability against various thiolated compounds (e.g., thioglycolic acid, thiourea, ${\text\tiny{L}}-cystine$, 1-dodecanethiol, and cysteamine hydrochloride). Moreover, these nanoparticles showed distinctive colorimetric responses against $Cd^{2+}$ and thiophenol (TP) from their potential interferences. The limit of detection (LOD) values for $Cd^{2+}$ and TP were determined as 0.186 and $0.154{\mu}M$, respectively.

Effect of electrocoagulation on sludge characteristics in EC-MBR (EC-MBR에서 전기응집이 슬러지 특성에 미치는 영향)

  • Um, Se-Eun;Chang, In-Soung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.12
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    • pp.42-49
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    • 2017
  • The application of electro-coagulation has been attempted to control the membrane fouling problem in a MBR (Membrane Bio-Reactor). This study examined the effects of the operating parameters (current density and contact time) of the electro-coagulation process on the change in the characteristics of activated sludge. The current density changed from 2.5 to 12, $24A/m^2$, and the contact time was varied from 0 to 2 and 6 hr, respectively. At a current density of $24A/m^2$ and 6 hr of operation, the MLSS changed from 6,800 to 7,000 mg/L (3% increase), but the MLVSS did not increase significantly. After 6 hr of operation, the soluble COD decreased from 71 to 37 mg/L under the $24A/m^2$ condition, from 113 to 67 mg/L under the $12A/m^2$ condition, and from 84 to 80 mg/L under the $2.5A/m^2$ condition. On the other hand, soluble-TN and -TP concentration showed slight changes. The soluble-EPS and Bound-EPS concentration decreased slightly with increasing current density. The membrane filtration performance of activated sludge before and after electro-coagulation was compared. The filtration resistances after electro-coagulation decreased from 6 to 61 %, particularly as the current density and contact time were increased. This indicates that electro-coagulation can be used to control membrane fouling in the MBR process.

Characteristics of Nonpoint Source Pollution and Relationship between Land Use and Nutrient Concentrations in the Han River Watershed (강우시 한강유역에서의 비점오염원 유출 특성과 토지이용도와의 관계)

  • Jung, Sungmin;Eum, Jaesung;Jang, Changwon;Choi, Youngsoon;Kim, Bomchul
    • Journal of Korean Society on Water Environment
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    • v.28 no.2
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    • pp.255-268
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    • 2012
  • Nonpoint source pollution has become a concern for water quality in the Han River system, especially during the high runoff events during the monsoon season. The patterns in nonpoint source runoff the relationships with land use, rainfall intensity, and stream nutrients concentrations were surveyed in 19 streams in the Han River watershed. The results show that the magnitude of NPS inputs of nutrients and sediment in the Han River watershed are of a serious concern. In the South Han River watershed, event mean concentrations (EMC) for biochemical oxygen demand (BOD), suspended sediment (SS), dissolved organic carbon (DOC), dissolved total phosphorus (DTP), total nitrogen (TN) Nitrate ($NO_3$-N) and total phosphorus (TP) were $1.94mg{\cdot}L^{-1},\;251mg{\cdot}L^{-1},\;2.75mg{\cdot}L^{-1},\;0.076mg{\cdot}L^{-1},\;2.82mg{\cdot}L^{-1},\;2.40mg{\cdot}L^{-1}$ and $0.232mg{\cdot}L^{-1}$, respectively. In the North Han River watershed, EMCs for BOD, SS, DOC, DTP, TN, $NO_3$-N and TP were $1.34mg{\cdot}L^{-1},\;172mg{\cdot}L^{-1},\;2.63mg{\cdot}L^{-1},\;0.032mg{\cdot}L^{-1},\;1.97mg{\cdot}L^{-1},\;1.55mg{\cdot}L^{-1}$ and $0.148mg{\cdot}L^{-1}$, respectively. The specific export coefficients of nutrient and sediments were much higher than those of other reports. Our study also found that the proportion of agricultural field area was significantly correlated with the EMCs for nutrients. Therefore, efforts to reduce NPS loading must focus on agricultural practices in the watershed. The relationships between land use and nutrient and sediment export found in this study can be used to derive estimates of runoff coefficients for agricultural field and as input data for modeling works and to develop total maximum daily load and best management practices in the Han River watershed.

Nutrients and Chlorophyll Dynamics Along the Longitudinal Gradients of Daechung Reservoir (대청호에서 종적구배에 따른 영양염류 및 엽록소의 역동성)

  • Bae, Dae-Yeul;Yang, Eun-Chan;Jung, Seung-Hyun;Lee, Jae-Hoon;An, Kwang-Guk
    • Korean Journal of Ecology and Environment
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    • v.40 no.2
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    • pp.285-293
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    • 2007
  • The study was to determine zonal characteristics of nutrients and chlorophyll and evaluate their trophic relations in Daechung Reservoir. For this study, we compared longterm water quality data among three zones along with trophic state using 1993 to 2002 dataset, obtained from the Ministry of Environment, Korea. Total phosphorous (TP), Secchi depth (SD) and chlorophyll (CHL) showed typical longitudinal declines from the riverine to lacustrine zone, but total nitrogen (TN) was not evident. Largest seasonal variations in TP and CHL occurred during the summer monsoon from July to August. In the reservoir, ambient TN averaged 1.67 mg $L^{-1}$ and ratios of TN : TP averaged 88.04, indicating that nitrogen is not likely limited but phosphorus limitation was evident. Trophic State Index (TSI), based on CHL, TP, and SD, varied depending on the zones and seasons. Mean TSI (TP) in the riverine zone was 62 during the monsoon, indicating a hypertrophic condition, whereas the mean was 40 in the lacustrine, indicating a nearly oligotrophic. Values of TSI (CHL) showed maximum in the transition zone during the monsoon. The deviation analysis of TSI showed that about 65% of TSI (CHL)-TSI (TP) and TSI (CHL)-TSI (SD) values were less than zero and the lowest values were -42, indicating an effect of inorganic turbidity on algal growth in the reservoir. Correlation analysis of CHL vs. SD shewed greater correlation coefficient (p<0.001, r=-0.47) in the transition than other two zones (p<0.001, $r{\leq}-0.40$). Correlation analysis of TP vs. CHL was greatest in the lacustrine and TP was minimum in the lacustrine zone, indicating a lowest yield of algal biomass in the lacustrine. Overall data suggests that zonal response of chlorophyll yield at a given nutrient unit is clearly differed among the longitudinal gradients, so the management strategy such as cross sectional modelling should be provided in each zone.