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태양전지 적용을 위한 실리콘 표면 passivation 방법과 그 특성 분석에 대한 연구

  • Kim, Bong-Gi;Gong, Dae-Yeong;Park, Seung-Man;Lee, Jun-Sin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.154-154
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    • 2010
  • 표면 passivation 효과향상 기술은 고효율의 결정질 실리콘 태양 전지를 제작하는데 필수적 요소이다. passivation을 통해서 전자와 전공의 재결합 속도를 낮출 수 있어 $V_{oc}$가 상승하고, 전류 값 증가를 통하여 효율 향상의 결과를 얻을 수 있기 때문이다. passivation을 위해서 다양한 각도로 접근하였다. 첫째는 $SiN_x$를 이용한 passivation효과 실험 둘째는 plasma 분위기에서 $N_2O$를 이용한 passivation효과 실험 그리고 마지막으로 RTO를 이용한 passivation 효과를 실험하였다. 첫 번째 실험은 PECVD를 이용하여 $SiN_x$를 증착한 후 굴절률 1.9 2.66으로 가변 한 결과 $SiN_x$ n=2.66에서 $D_{it}=8.82{\times}10^9$ [$cm^{-2}eV^{-1}$]로 우수한 passivation 효과를 얻을 수 있었다. 두 번째 실험에서는 PECVD를 이용해서 $N_2O$ treatment 후 SiON 증착한 샘플을 이용하여 시간 가변에 따른 passivation 효과를 확인하였다. 그 결과 $N_2O$ 50sccm, 100mTorr, 20W, $400^{\circ}C$ 8min 조건에서 가장 우수한 passivation 효과를 관찰할 수 있었다. 마지막 실험은 RTP를 이용하여 $SiO_2$ 박막에 대한 온도, 시간에 따른 passivation효과를 확인하였다. 그 결과 $O_2$ 3L/min $800^{\circ}C$ 2~3nm 3min 공정에서 lifetime이 220us(n형)의 결과를 얻을 수 있었다. 상기 세 실험결과를 태양전지제작에 응용한다면 고효율의 태양전지 제작이 가능할 것으로 사료된다.

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Characterization of rock bream (Oplegnathus fasciatus) fin cells and its susceptibility to different genotypes of megalocytiviruses

  • Jeong, Ye Jin;Kim, Young Chul;Min, Joon Gyu;Jeong, Min A;Kim, Kwang Il
    • Journal of fish pathology
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    • v.34 no.2
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    • pp.149-159
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    • 2021
  • Genus Megalocytivirus cause red sea bream iridoviral disease (RSIVD) and scale drop disease (SDD). Based on the phylogeny of the major capsid protein (MCP) and adenosine triphosphatase (ATPase) genes, megalocytiviruses except for SDD virus (SDDV) could be three different genotypes, red sea bream iridovirus (RSIV), infectious spleen and kidney necrosis (ISKNV), and turbot reddish body iridovirus (TRBIV). In this study, primary cells derived from the caudal fin of rock bream (Oplegnathus fasciatus) grew at 25℃ in Leibovitz's medium supplemented with 10% (v/v) fetal bovine serum and primocin (100 ㎍/mL). Rock bream fin (RBF) cells exhibited susceptibility to infections by different genotypes of megalocytiviruses (RSIV, ISKNV and TRBIV) with the appearance of cytopathic effects with an increase in the viral genome copy number. Furthermore, compared to grunt fin (GF) cells, even though 10 times lower number of RSIV genome copies were inoculated in RBF cells, viral genome copy number produced on RBF cells were 44 times higher than that of GF cells at 7 d post-inoculation. As the isolated RBF cells are sensitive to different genotypes of megalocytiviruses (RSIV, ISKNV and TRBIV), they can be used for future studies regarding in vitro viral infection and subsequent diagnosis.

The Effect of Seawater Temperature on the Electrochemical Corrosion Behaviour of Stainless Steels and Anodized Aluminum Alloys (스테인리스강과 양극산화된 알루미늄 합금의 전기화학적 부식특성에 미치는 해수온도의 영향)

  • Chong, Sang-Ok;Kim, Seong-Jong
    • Corrosion Science and Technology
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    • v.20 no.2
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    • pp.85-93
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    • 2021
  • The corrosion damage of materials in marine environment mainly occurs by Cl- ions due to the breakdown of passive films. Additionally, various characteristics in seawater such as salinity, temperature, immersion time, flow rate, and biological activity also affect corrosion characteristics. In this study, the corrosion characteristics of stainless steels (STS 304 and STS 316L) and anodized aluminum alloys (AA 3003 and AA 6063) were evaluated with seawater temperature parameters. A potentiodynamic polarization experiment was conducted in a potential range of -0.25 V to 2.0 V at open circuit potential (OCP). Corrosion current density and corrosion potential were obtained through the Tafel extrapolation method to analyze changes in corrosion rate due to temperature. Corrosion behavior was evaluated by measuring weight loss before/after the experiment and also observing surface morphology through a scanning electronic microscope (SEM) and 3D microscopy. Weight loss, maximum damage depth and pitting damage increased as seawater temperature increased, and furthermore, the tendency of higher corrosion current density with an increase of temperature attributed to an increase in corrosion rate. There was lower pitting damage and lower corrosion current density for anodized aluminum alloys than for stainless steels as the temperature increased.

Thermophilic Co-Digestion of Municipal Sewage Sludge and Food Waste (음식물쓰레기의 하수슬러지를 이용한 고온통합 소화)

  • Han, So-Young;Kang, Ho;Choi, Yeon-Seok;Kim, Chi-Yeol
    • Journal of Korea Society of Waste Management
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    • v.35 no.8
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    • pp.731-743
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    • 2018
  • This study was performed to test the feasibility of thermophilic ($55^{\circ}$) co-digestion of municipal sewage sludge and food wastes. The management variables of co-digestion were the mixed ratios of municipal sewage sludge and food waste hydraulic retention times (HRTs). During the operation of thermophilic co-digestion, the reactor pH ranged from 7.0 to 7.5 and the reactor alkalinity remained above 3,200 to 4,000 mg/L as $CaCO_3$. The volatile fatty acids concentration increased as the HRT shortened from 20 days to 10 days and the mixture ratio increased to 1:4, but did not reach toxic levels for co-digestion of sewage sludge and food wastes. Methane productivity increased gradually as the organic loading rate increased. Maximum methane productivity reached 1.03v/v-d at an HRT of 10 days and at the mixture ratio of 1:4. The TVS removal efficiency decreased from 70.6% to 58.3% as the HRT shortened from 20 days to 10 days. TVS removal efficiency ranged from 57.0% to 77% during the entire operation. It is likely that thermophilic co-digestion of sewage sludge and food wastes is a very effective method both to environmentally treat food waste and to economically produce gas for energy.

TEM investigation of helium bubble evolution in tungsten and ZrC-strengthened tungsten at 800 and 1000℃ under 40keV He+ irradiation

  • I. Ipatova;G. Greaves;D. Terentyev;M.R. Gilbert;Y.-L. Chiu
    • Nuclear Engineering and Technology
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    • v.56 no.4
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    • pp.1490-1500
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    • 2024
  • Helium-induced defect nucleation and accumulation in polycrystalline W and W0.5 wt%ZrC (W0.5ZrC) were studied in-situ using the transmission electron microscopy (TEM) combined with 40 keV He+ irradiation at 800 and 1000℃ at the maximum damage level of 1 dpa. Radiation-induced dislocation loops were not observed in the current study. W0.5ZrC was found to be less susceptible to irradiation damage in terms of helium bubble formation and growth, especially at lower temperature (800 ℃) when vacancies were less mobile. The ZrC particles present in the W matrix pin the forming helium bubbles via interaction between C atom and neighbouring W atom at vacancies. This reduces the capability of helium to trap a vacancy which is required to form the bubble core and, as a consequence, delays, the bubble nucleation. At 1000 ℃, significant bubble growth occurred in both materials and all the present bubbles transitioned from spherical to faceted shape, whereas at 800 ℃, the faceted helium bubble population was dominated in W.

Physical and γ-ray shielding properties of Vietnam's natural stones: An extensive experimental and theoretical study

  • Ta Van Thuong;O.L. Tashlykov;A.M. Shironina;I.P. Voronin;E.V. Kuvshinova;D.O. Pyltsova;E.I. Nazarov;K.A. Mahmoud
    • Nuclear Engineering and Technology
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    • v.56 no.5
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    • pp.1932-1940
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    • 2024
  • The current work deals with investigation of the gamma ray shielding properties for various natural stones from Vietnam to be applied in the radiation shielding applications. The physical and chemical properties affecting the γ-ray shielding performance were examined. The MH-300A density meter was utilized to measure the density (ρ, g/cm3) of stone samples, as well as the chemical composition of Vietnamese natural stones was measured using the X-ray fluorescence analyzer (Olympus X-5000). The study shows that the increase in Fe + Ca concentrations within the stone samples increases their density (from 2.48 to 2.86 g/cm3) accompanied with a reduction in the porosity (Φ, %) (from 8.23 to 0.15%) and water absorption (K, %) (from 3.42 to 0.05%) factors. Additionally, the increase in Fe + Ca concentrations increases the linear attenuation coefficient (μ, cm-1) of the studied stones, where the Vietnamese marble stone (M 3.1) with the highest Fe + Ca concentration (65.97 wt%) has the highest linear attenuation coefficient which varied between 3.781 and 0.155 cm-1 with raising the gamma ray energy between 0.040 and 1.332 MeV.

Feeding dietary non-starch polysaccharides supplemented with xylanase could improve the performance of broilers

  • Venuste Maniraguha;Jun Seon Hong;Myunghwan Yu;Elijah Ogola Oketch;Young-Joo Yi;Hyeonho Yun;Dinesh Darshaka Jayasena;Jung Min Heo
    • Journal of Animal Science and Technology
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    • v.66 no.5
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    • pp.999-1009
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    • 2024
  • The impact of dietary non-starch polysaccharides (NSP) on performance and carcass traits of broilers fed wheat-bran substituted into corn-soybean meal-based diets supplemented with xylanase was investigated. A total of 280 (7-day-old) Ross 308 broilers were randomly allotted to one of five dietary treatments with 8 replicates, 7 chicks per pen. Treatments were; i) CON: Control diet, ii) CON-X (CON + 3,000 U/kg xylanase), iii) L-X: low NSP (2% wheat bran in CON + 3,000 U/kg xylanase), iv) M-X: medium NSP (4% wheat bran in CON + 3,000 U/kg xylanase), v) H-X: higher NSP (8% wheat bran in CON+ 3,000 U/kg xylanase). Birds fed the H-X diet increased (p < 0.05) daily gains, and average daily feed intake and had marginally improved body weights (p = 0.074) on day 35. Relatively, the H-X diet tended to increase the average daily gains (p = 0.053; p = 0.073) of birds during the grower phase (d 24-35) and the entire experimental period (d 8-35), respectively. Moreover, there were no significant differences among treatments in the feed conversion ratio of birds throughout the entire experiment period. Birds fed diets CON-X, L-X, and M-X had improved (p < 0.05) the ileal digestibility of energy on d 24 and 35 compared to those fed the H-X diet. Furthermore, birds fed diet CON-X improved (p < 0.05) N digestibility on d 24. Improved carcass moisture content and lowered crude fat of leg meat (p < 0.05) were noted in birds fed the diet M-X and H-X on d 35, respectively. The intestinal viscosity was reduced (p < 0.05) in xylanase-supplemented treatments CON-X, L-X, M-X, and H-X diets when compared to CON. Our results suggest that supplementing 3,000 U/kg xylanase in a higher NSP (8% wheat bran substituted level) diet could improve the intestinal viscosity and growth performance of broilers.

Bacterins to Prevent the Contamination of Vbrio vulnificus in the Flounder, Paralichthys olivaceus (넙치에서의 Vbrio vulnificus 오염 방지를 위한 백신 연구)

  • Son Sang Gyu;Kim Myoung Sug;Park Jun Hyo;Yoo Min Ho;Jeong Hyun Do
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.35 no.1
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    • pp.1-7
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    • 2002
  • To study the increased resistance in fish against Vibrio vulnificus known as an important agent of vibrio septicemia in human, we analyzed specific and nonspecific immune response in flounder after administration of V. vulnificus bacterins by oral route. It contained the comparison of antibody concentrations in the sera of flounder after oral administration by two different protocols with uncoated heat killed bacterin of V vulnificus (UHKB, 20 mg/kg body weight), i.e., 4 weeks continuously (group 4W) and taking 2 weeks resting period between the 1st and last week of administration (group 1-2-1W). Even though, 1-2-1W group showed significantly increased level of specific antibody in serum, it did not reach to that of 4W group. Certainly, flounder vaccinated twice a week for four weeks (20 mg/kg b.w.) showed increased concentration of specific antibody against V. vulnificus at week 2 after last administration by oral route and maintained throughout the experimental period. It also was confirmed by the increased numbers of specific antibody secreting cells (SASC) in the leukocytes isolated from the splenocytes of the flounder of 4W group at week 1 after last administration until the end of experimental period. However, enteric, acid-resistant film coated heat killed bacterin (ECHB) did not show both greater immune reaction for antibody production and faster elimination of a challenge dose of V. vulnificus compared with those of the UHKB. These results suggested that UHKB administered by oral route was very effective method to prevent the contamination of V vulnificus in flounder, and did not show the increased antigenicity by coating the surface with acid-resistant film.

Measurement of Ballooning Gap Size of Irradiated Fuels Using Neutron Radiography Transfer Method and HV Image Filter

  • Sim, Cheul-Muu;Kim, TaeJoo;Oh, Hwa Suk;Kim, Joon Cheol
    • Journal of the Korean Society for Nondestructive Testing
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    • v.33 no.2
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    • pp.212-218
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    • 2013
  • A transfer method of neutron radiography was developed to measure the size of the end plug and a gap of an intact K102L-2, the irradiated fuel of a ballooned K174L-3, a ballooned and ruptured K98L-3. A typical irradiation time of 25 min. was determined to obtain a film density of between 2 and 3 of SR X-ray film with neutrons of $1.5{\times}10^{11}n{\cdot}cm^{-2}$. To validate and calibrate the results, a RISO fuel standard sample, Cd plate and ASTM-BPI/SI were used. An activated latent image formed in the $100{\mu}m$ Dy foil was subsequently transferred in a dark room for more than 8 hours to the SR film which is a maximum of three half-lives. Due to the L/D ratio an unsharpness of $9.82-14{\mu}m$ and a magnification of 1.0003 were given. After digitizing an image of SR film, the ballooning gap of the plug was discernible by an H/V filter of image processing. The gap size of the ballooned element, K174L-3, is equal to or greater than 1.2 mm. The development of a transfer method played a pivotal role in developing high burn-up of Wolsung and PWR nuclear fuel type.

SINGULAR INNER FUNCTIONS OF $L^{1}-TYPE$

  • Izuchi, Keiji;Niwa, Norio
    • Journal of the Korean Mathematical Society
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    • v.36 no.4
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    • pp.787-811
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    • 1999
  • Let M be the maximal ideal space of the Banach algebra $H^{\infty}$ of bounded analytic functions on the open unit disc $\triangle$. For a positive singular measure ${\mu}\;on\;{\partial\triangle},\;let\;{L_{+}}^1(\mu)$ be the set of measures v with $0\;{\leq}\;{\nu}\;{\ll}\;{\mu}\;and\;{{\psi}_{\nu}}$ the associated singular inner functions. Let $R(\mu)\;and\;R_0(\mu)$ be the union sets of $\{$\mid$\psiv$\mid$\;<\;1\}\;and\;\{$\mid${\psi}_{\nu}$\mid$\;<\;0\}\;in\;M\;{\setminus}\;{\triangle},\;{\nu}\;\in\;{L_{+}}^1(\mu)$, respectively. It is proved that if $S(\mu)\;=\;{\partial\triangle}$, where $S(\mu)$ is the closed support set of $\mu$, then $R(\mu)\;=\;R0(\mu)\;=\;M{\setminus}({\triangle}\;{\cup}\;M(L^{\infty}(\partial\triangle)))$ is generated by $H^{\infty}\;and\;\overline{\psi_{\nu}},\;{\nu}\;{\in}\;{L_1}^{+}(\mu)$. It is proved that %d{\theta}(S(\mu))\;=\;0$ if and only if there exists as Blaschke product b with zeros $\{Zn\}_n$ such that $R(\mu)\;{\subset}\;{$\mid$b$\mid$\;<\;1}\;and\;S(\mu)$ coincides with the set of cluster points of $\{Zn\}_n$. While, we proved that $\mu$ is a sum of finitely many point measure such that $R(\mu)\;{\subset}\;\{$\mid${\psi}_{\lambda}$\mid$\;<\;1}\;and\;S(\lambda)\;=\;S(\mu)$. Also it is studied conditions on \mu for which $R(\mu)\;=\;R0(\mu)$.

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