• Title/Summary/Keyword: L-curve criterion

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Cadmium Extraction from Solutions by Solid-Phase and its Trace Determination (고상에서 용액으로 부터 카드뮴 추출과 잔유물 측정)

  • Ashrafi, F.;Attaran, A.M.;Kermani, N. Memar
    • Journal of the Korean Chemical Society
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    • v.52 no.2
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    • pp.133-139
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    • 2008
  • A new sensitive and selective spectrophotometric method for determination of trace amounts of cadmium using a polyvinyl chloride membrane containing bis-(2-ethylhexyl)phthalate as a solid phase extraction medium was investigated. Bis-(2-ethylhexyl)phthalate has used as a plasticizer. Cd(II) in an aqueous solution was trapped on the membrane in the form of colorful Cd (II)-I- - MG complexes (which MG is malachite green) and the cadmium complex was concentrated in the membrane. The absorbance of the green membrane was measured at 629 nm using a spectrophotometer, and then, the concentration of the cadmium was calculated using a calibration curve, which expressed the relationship between the Cd(II) concentration and the membrane absorbance after coloring for 25 min. The calibration curve was linear in the range of 10-760 μgL-1 cadmium in the test solution. The detection limit based on the 3Sbl criterion was 1.8199 μgL-1 and the relative standard deviations (RSD) were less than 4 % (n=5). The proposed method has been successfully applied to the determination of trace amounts of cadmium in the Tadjan River water sample (Sari-Iran), and the mean value of 28.7 μgL-1 was obtained.

Effect of Combustors and Propellant Parameters on the L* Instability of Solid Rocket Motors (연소실 및 추진제 변화에 따른 고체로켓 모터의 L* 불안정에 관한 연구)

  • Lee, Donghee;Ryu, Seunghyun;Joo, Seongmin;Kim, Junseong;Moon, Heejang;Sung, Honggye;Yang, Juneseo
    • Journal of the Korean Society for Aviation and Aeronautics
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    • v.23 no.4
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    • pp.30-35
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    • 2015
  • In this paper, a theoretical study of low frequency non acoustic instability, the $L^*$ instability, of a solid rocket motor is investigated. The $L^*$ stability criterion is determined by analysing the $L^*$ stability curves of two very distinct propellants for five different geometrical combustors. The $L^*$ instability of two extreme fuels showed totally different behavior in terms of operating pressure of the combustor. A parametric study on the stability for different chamber volume and different throat area keeping constant $L^*$ is conducted and analyzed. It was found that one of the main parameters, the non-dimensional critical characteristic time, requires an enough margin from the critical $L^*$ stability curve.

Collapse mechanism for deep tunnel subjected to seepage force in layered soils

  • Yang, X.L.;Yan, R.M.
    • Geomechanics and Engineering
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    • v.8 no.5
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    • pp.741-756
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    • 2015
  • The prediction of impending collapse of deep tunnel is one of the most difficult problems. Collapse mechanism of deep tunnel in layered soils is derived using a new curved failure mechanism within the framework of upper bound theorem, and effects of seepage forces are considered. Nonlinear failure criterion is adopted in the present analysis, and the possible collapse shape of deep tunnel in the layered soils is discussed in this paper. In the layered soils, the internal energy dissipations along velocity discontinuity are calculated, and the external work rates are produced by weight, seepage forces and supporting pressure. With upper bound theorem of limit analysis, two different curve functions are proposed for the two different soil stratums. The specific shape of collapse surface is discussed, using the proposed curve functions. Effects of nonlinear coefficient, initial cohesion, pore water pressure and unit weight on potential collapse are analyzed. According to the numerical results, with the nonlinear coefficient increase, the shape of collapse block will increase. With initial cohesion of the upper soil increase, the shape of failure block will be flat, and with the lower soil improving, the size of collapsing will be large. Furthermore, the shape of collapsing will decrease with the unit weight decrease.

Ductile Fracture Behaviour of SPS Specimen Under Pure Mode II Loading (순수 모드 II하중 하에서의 SPS 시험편의 연성파괴 특성에 관한 연구)

  • O, Dong-Jun
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.25 no.2
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    • pp.289-295
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    • 2001
  • The aim of this study is to investigate the ductile fracture behaviour under pure Mode II loading using A533B pressure vessel steel. Single punch shear(SPS) test was performed to obtain the J-R curve under pure Mode II loading which was compared with that of the Model I loading. Simulation using Rousellier Ductile Damage Theory(RDDT) was carried out with 4-node quadrilateral element(L(sub)c=0.25mm). For the crack advance, the failed element removal technique was adopted with a $\beta$ criterion. Through the $\beta$ value tuning-up procedures, $\beta$(sub)crit(sup)II was determined as 1.5 in contrast with $\beta$(sub)crit(sup)I=5.5. In conclusion, it was found that the J-R curve under Mode II loading was located at lower part than that under Mode I loading obtained from the previous study and that the $\beta$ values strongly depended on the loading type. In addition, the predicted result using RDDT showed a good agreement with the SPS experimental one under pure Mode II loading.

Automation of Model Selection through Neural Networks Learning (신경 회로망 학습을 통한 모델 선택의 자동화)

  • 류재흥
    • Proceedings of the Korean Institute of Intelligent Systems Conference
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    • 2004.10a
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    • pp.313-316
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    • 2004
  • Model selection is the process that sets up the regularization parameter in the support vector machine or regularization network by using the external methods such as general cross validation or L-curve criterion. This paper suggests that the regularization parameter can be obtained simultaneously within the learning process of neural networks without resort to separate selection methods. In this paper, extended kernel method is introduced. The relationship between regularization parameter and the bias term in the extended kernel is established. Experimental results show the effectiveness of the new model selection method.

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Roof collapse of shallow tunnel in layered Hoek-Brown rock media

  • Yang, X.L.;Li, K.F.
    • Geomechanics and Engineering
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    • v.11 no.6
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    • pp.867-877
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    • 2016
  • Collapse shape of tunnel roof in layered Hoek-Brown rock media is investigated within the framework of upper bound theorem. The traditional collapse mechanism for homogeneous stratum is no longer suitable for the present analysis of roof stability, and it would be necessary to propose a curve failure mode to describe the velocity discontinuity surface in layered media. What is discussed in the paper is that the failure mechanism of tunnel roofs, consisting of two different functions, is proposed for layered rock media. Then it is employed to investigate the impending roof failure. Based on the nonlinear Hoek-Brown failure criterion, the collapse volume of roof blocks are derived with the upper bound theorem and variational principle. Numerical calculations and parametric analysis are carried out to illustrate the effects of different parameters on the shape of failure mechanism, which is of overriding significance to the stability analysis of tunnel roof in layered rock media.

Tikhonov's Solution of Unstable Axisymmetric Initial Value Problem of Wave Propagation: Deteriorated Noisy Measurement Data

  • Jang, Taek-Soo;Han, So-Lyoung
    • Journal of Ocean Engineering and Technology
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    • v.22 no.4
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    • pp.1-7
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    • 2008
  • The primary aim of the paper is to solve an unstable axisymmetric initial value problem of wave propagation when given initial data that is deteriorated by noise such as measurement error. To overcome the instability of the problem, Tikhonov's regularization, known as a non-iterative numerical regularization method, is introduced to solve the problem. The L-curvecriterion is introduced to find the optimal regularization parameter for the solution. It is confirmed that fairly stable solutions are realized and that they are accurate when compared to the exact solution.

Collapse mechanism of tunnel roof considering joined influences of nonlinearity and non-associated flow rule

  • Yang, X.L.;Xu, J.S.;Li, Y.X.;Yan, R.M.
    • Geomechanics and Engineering
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    • v.10 no.1
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    • pp.21-35
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    • 2016
  • Employing non-associated flow rule and Power-Law failure criterion, the failure mechanisms of tunnel roof in homogeneous and layered soils are studied in present analysis. From the viewpoint of energy, limit analysis upper bound theorem and variation principle are introduced to study the influence of dilatancy on the collapse mechanism of rectangular tunnel considering effects of supporting force and seepage force. Through calculation, the collapsing curve expressions of rectangular tunnel which are excavated in homogeneous soil and layered soils respectively are derived. The accuracy of this work is verified by comparing with the existing research results. The collapsing surface shapes with different dilatancy coefficients are draw out and the influence of dilatancy coefficient on possible collapsing range is analyzed. The results show that, in homogeneous soil, the potential collapsing range decreases with the decrease of the dilatancy coefficient. In layered soils, the total height and the width on the layered position of possible collapsing block increase and the width of the falling block on tunnel roof decrease when only the upper soil's dilatancy coefficient decrease. When only the lower soil's dilatancy coefficient decrease or both layers' dilatancy coefficients decrease, the range of the potential collapsing block reduces.

Ductile Fracture Behaviour under Mode I Loading Using Rousellier Ductile Damage Theory

  • Oh, Dong-Joon;Howard, I.C.;Yates, J.R.
    • Journal of Mechanical Science and Technology
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    • v.14 no.9
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    • pp.978-984
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    • 2000
  • The aim of this study is to investigate the ductile fracture behaviour under Mode I loading using SA533B pressure vessel steel. Experiments consist of the Round Notch Bar Test (RNB), Single Edge Crack Bending Test (SECB), and V-Notch Bar Test (VNB). Results from the RNB test were used to tune the damage modelling constant. The other tests were performed to acquire the J-resistance curves and to confirm the damage constants. Microstructural observation includes the measurement of crack profile to obtain the roughness parameter. Finally, simulation using Rousellier Ductile Damage Theory (RDDT) was carried out with 4-node quadrilateral element ($L_c=0.25\;mm$). For the crack advance, the failed element removal technique was adopted with a ${\beta}$ criterion. In conclusion, the predicted simulation using RDDT showed a good agreement with the experimental results. A trial using a roughness parameter was made for a new evaluation of J-resistance curve, which is more conservative than the conventional one.

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