• Title/Summary/Keyword: L-S theory

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Gas/particle Partitioning of PAHs Segregated with Particle Size in Equilibrium States (대기 중 PAHs의 입경별 가스/입자 분배평형에 관한 연구)

  • Park, Jin-Soo;Lee, Dong-Soo;Kim, Jong-Guk
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.12
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    • pp.1270-1276
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    • 2005
  • When gas/particle partitioning of PAHs in the atmosphere approached an equilibrium state, the slope of linear regression between gas/particle partitioning coefficient($logK_p$) and subcooled liquid vapour pressure($logP_L^O$) was -1. But it was alleged that the slope of equilibrium state might not be -1 in real atmospheric environment due to heterogeneous characteristics of particulate matter. In This study, it would be found if gas/particle partitioning of PAHs segregated with particle size in equilibrium state was based on the hypothesis mentioned above. We have calculated the slopes of $logK_p$ v.s. $logP_L^O$ after collecting 10 set samples which consisted of particulate and vaporous phases. The slope was close to -1 in equilibrium states. But despite of equilibrium state, all slopes segregated with particle size were not close to -1 and those were gentler with larger particle size. The difference of slopes in equilibrium states was almost against the assumption of gas/particle partitioning theory. When the gas/particle partitioning was due to adsorption, the desorption enthalpy was different in each particle size. When it was absorption, the activity coefficient was different. The difference of desorption enthalpy and activity coefficient in each particle size indicate the heterogeneous characteristics of the bulk particle. This may be the reason for slope variation with particle size even though in an equilibrium state.

Study on the Severity Measurement and the Correlation between Acupoints on the Face and the Upper limb in Bell's Palsy Patients by using of DITI (DITI를 이용한 Bell's palsy환자의 증상 중등도 및 안면과 상지에 분포한 경혈의 관계에 대한 고찰)

  • Lee, Won-Hui;Lim, Ho-Jea;Song, Soo-Cheol;Kim, Jung-Uk;Bae, Ki-Tae;Moon, Sung-Il
    • Journal of Acupuncture Research
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    • v.23 no.5
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    • pp.93-103
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    • 2006
  • Objectives : To Investigate Severity Measurement and the Correlation between Acupoints on the Face and the Upper limb in Bell's Palsy Patients by Using of DITI. Methods : By using of DITI, thermal differences between abnormal and normal site in acupoints on the face and the upper limbs of 21 Bell's palsy patients who visited department of Acupuncture & Moxibustion in National Medical Center from 1st February 2004 to 31th December 2005 were measured around 7days after the onset in standardized Environment. The patients were classified by severity scale. Results : The means of thermal difference of the facial acupoints were significantly distributed at each grade. The thermal difference of GB14 was significantly correlated with thermal difference of TE4, the thermal difference of S4 was significantly correlated with thermal difference of L6 and SI4, the thermal difference of STI18 was significantly correlated with thermal difference of LI11 and the thermal difference of LI20 was significantly correlated with thermal difference of LI11 and LI4. The thermal differences of acupoints in Large intestine meridian were more closely correlated with thermal difference of the facial acupoints than thermal difference of acupoints in the other meridians. Conclusion : Severity of Bell's palsy can be presumed through DITI image. And the theory of meridian was confirmed by DITI in Bell's palsy patients.

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The Analytic Gradient with a Reduced Molecular Orbital Space for the Equation-of-Motion Coupled-Cluster Theory: Systematic Study of the Magnitudes and Trends in Simple Molecules

  • Baek, Gyeong Gi;Jeon, Sang Il
    • Bulletin of the Korean Chemical Society
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    • v.21 no.7
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    • pp.720-726
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    • 2000
  • The analytic gradient method for the equation-of-motion coupled-cluster singles and doubles (EOM-CCSD) energy has been extended to employ a reduced molecular orbital (MO) space. Not only the innermost core MOs but also some of the outermost virtua l MOs can be dropped in the reduced MO space, and a substantial amount of computation time can be reduced without deteriorating the results. In order to study the magnitudes and trends of the effects of the dropped MOs, the geometries and vibrational properties of the ground and excited states of BF, CO, CN, N2, AlCl, SiS, P2, BCl, AIF, CS, SiO, PN and GeSe are calculated with different sizes of molecular orbital space. The 6-31 G* and the aug-cc-pVTZ basis sets are employed for all molecules except GeSc for which the 6-311 G* and the TZV+f basis sets are used. It is shown that the magnitudes of the drop-MO effects are about $0.005\AA$ in bond lengths and about 1% on harmonic frequencies and IR intensities provided that the dropped MOs correspond to (1s), (1s,2s,2p), an (1s,2s,2p,3s,3p) atomic orbitals of the first, the second, and the third row atoms, respectively. The geometries and vibrational properties of the first and the second excited states of HCN and HNC are calculated by using a drastically reduced virtual MO space as well as with the well defined frozen core MO space. The results suggest the possibility of using a very smalI MO space for qualitative study of valence excited states.

Comparison in Porous Structure and Water Eetention with the Different Porous Media by Fractal Fragmentation Model (다공성 매체의 차원 분열 모델 적용에 의한 토양과 상토의 공극분포와 보수력 비교)

  • Oh, Dong-Shig;Kim, Lee-Yul;Jung, Yeong-Sang
    • Korean Journal of Soil Science and Fertilizer
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    • v.40 no.3
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    • pp.189-195
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    • 2007
  • Using fractal dimensionality theory proposed by Riew and Sposito (1991), we attempted to analyze quantitatively the characteristics of porous distribution for built-in soils in the mini-lysimeter and artificial seed-bed media. The 2" stainless core soil samples were taken from lysimeter soils. Artificial seed-bed media were compacted in the acrylic core filled with raw materials consisted of cocopeat, zeolite and perlite. N (Constant number of partitioned group size smaller media volumes) and r (Self-similarity ratio) parameters consisting of fractal dimension D=log(N)/log(1/r) were obtained by Excel Programme using the Riew and Sposito's fractal model. The pore distribution of tested media was screened in pore size and its occurring frequency. The results reveal that the distribution range of pores is wider in the lysimeter soils than in the seed-bed media, while average size of pores in the media is smaller in lysimeter core soils than in seed-bed media.

A Study on the Detergency Performance of Zeolite A in the Detergent Solution (세제용액 중에서 Zeolite A의 세정성능에 관한 연구)

  • Kang, Yun-Seog;Kim, Hyun-Chang;Nam, Ki-Dae
    • Applied Chemistry for Engineering
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    • v.8 no.4
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    • pp.624-630
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    • 1997
  • Zeolite A helps an increase of detergency performance according to showing the ion exchange effect for polyvalant ions and it's detergency performance could be calculated quantitatively by using the disperse stabilization theory because it is water-insoluble material and is as colloid particles in aqueous solution. In this study, zeta potential of carbon black, cellulose, and Zeolite A were measured in each inorganic salt solutions and applied to the theory of Heterocoagulation in order to evaluate the detergency performance of Zeolite A about the particulate soil at the view point of interaction potential energy. Zeolite A was shown help an increase of detergency performance according to the increasing of the steric repulsion between Zeolite A and cellulose in $Na2CO_3$ solution and the decrease of re-deposition of carbon black on the fabric by rapid coagulation with carbon black in $Na_2SO_4$ solution.

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Priority Evaluation of Preliminary Cases for IMO Information Management System using Fuzzy TOPSIS and AHP (퍼지 TOPSIS&AHP를 이용한 IMO 정보관리시스템 예비과제 우선순위 평가)

  • Jang, Woon-Jae
    • Journal of Navigation and Port Research
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    • v.37 no.5
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    • pp.493-498
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    • 2013
  • This paper is aimed to priority evaluation of preliminary cases for IMO -IMS(International Maritime Organization- Information Management System) using fuzzy TOPSIS(Technique for Order Performance by Similarity to Ideal Solution) and AHP(Analytic Hierarchy Process). To this solve, therefore, this paper extract 24 preliminary cases and select 4 major preliminary alternative cases after analysing the structure of its alternative cases using FSM(Fuzzy Structure Modeling). Also, the weights of evaluation factors determine using AHP which able to keep the consistency when decision-makers assess. In AHP method, but, the numbers of paired comparison incerase as much as the numbers of the comparison items increase and because this evaluation have the many of vagueness, the decision of final ranking is used to fuzzy TOPSIS method which is included TOPSIS and Fuzzy Set Theory. The result are developed as order as Management of IMO Convention Information, Delivery of IMO Convention Information, Total IMO Database, Knowledge Hub of IMO Convention Information in IMO-IMS.

A Study of the Case Analysis of Conceptual Modeling of Medical Terminologies by Ontology (온톨로지를 이용한 의학용어의 개념 모델링 사례 분석 연구)

  • Lee, Hyun-Sil
    • Journal of the Korean Society for information Management
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    • v.21 no.3
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    • pp.141-160
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    • 2004
  • Recent reseach in the field of medical information systems has paid much attention to an ontology based medical terminology system to support clinical study and effective information search. This study aims to conduct research for further application or construction of ontology systems in Korea. This research reviews the theory of concept modeling and ontology. and analyses 4 cases of conceptual modeling of medical tenrminologies by ontology, The findings ot this study display these specific characteristics in medscal ontologies: (UHe standardization of terrrinology on MeSH. (2) The conceptualization of tenninology on UMLS. (l) ane. (2) are showed as untormal ontologies. (3) The theory of ontology integration in ON9, (4) The reference model of medical knowledge with formalization in GALEN. (3) and (4) are showed as formal ontologies. The application and construction of ontology should be differentiated according to the level of the proposed system, and then this analysis will provide useful information for the researcher and developer of the system.

Effects of Information on User's Personal Norm and Rule-Violating Behavior in a Recreation Setting (휴양지역(休養地域)에서 이용자(利用者)의 개인규범(個人規範)과 규칙위반(規則違反) 행위(行爲)에 미치는 정보(情報)의 효과(效果))

  • Kim, Sang-Oh;Shelby, Bo
    • Journal of Korean Society of Forest Science
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    • v.85 no.2
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    • pp.251-259
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    • 1996
  • This study was conducted to find out whether information based on norm activation theory affects personal norm and rule-violating behavior in a recreation setting, using the data collected from the Second Campground in Chiri-Mountain National Park in 1994. Of the total 280 questionnaires distributed, 253(90.4%) were usable for data analysis. Results showed that information did not increase awareness of consequences(AC) of their actions or ascription of responsibility(AR) for acts and consequences to themselves, and did not directly decrease the quiet time rule-violating behavior. However, it was found that respondents with high ACR(combination of AC and AR) or personal norms less violated the rule. Management implications of these findings were discussed.

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Numerical simulation of electrokinetic dissipation caused by elastic waves in reservoir rocks

  • Zhang, Xiaoqian;Wang, Qifei;Li, Chengwu;Sun, Xiaoqi;Yan, Zheng;Nie, Yao
    • Geomechanics and Engineering
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    • v.19 no.1
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    • pp.11-20
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    • 2019
  • The use of electrokinetic dissipation method to study the fluid flow law in micro-pores is of great significance to reservoir rock microfluidics. In this paper, the micro-capillary theory was combined with the coupling model of the seepage field and the current field under the excitation of the harmonic signal, and the coupling theory of the electrokinetic effect under the first-order approximation condition was derived. The dissipation equation of electrokinetic dissipation and viscous resistance dissipation and its solution were established by using Green's function method. The physical and mathematical models for the electrokinetic dissipation of reservoir rocks were constructed. The microscopic mechanism of the electrokinetic dissipation of reservoir rock were theoretically clarified. The influencing factors of the electrokinetic dissipation frequency of the reservoir rock were analyzed quantitatively. The results show that the electrokinetic effect transforms the fluid flow profile in the pores of the reservoir from parabolic to wavy; under low-frequency conditions, the apparent viscosity coefficient is greater that one and is basically unchanged. The apparent viscosity coefficient gradually approaches 1 as the frequency increases further. The viscous resistance dissipation is two orders of magnitude higher than the electrokinetic effect dissipation. When the concentration of the electrolyte exceeds 0.1mol/L, the electrokinetic dissipation can be neglected, while for the electrolyte solution (<$10^{-2}M$) in low concentration, the electrokinetic dissipation is very significant and cannot be ignored.

Multiscale bending and free vibration analyses of functionally graded graphene platelet/ fiber composite beams

  • Garg, A.;Mukhopadhyay, T.;Chalak, H.D.;Belarbi, M.O.;Li, L.;Sahoo, R.
    • Steel and Composite Structures
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    • v.44 no.5
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    • pp.707-720
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    • 2022
  • In the present work, bending and free vibration analyses of multilayered functionally graded (FG) graphene platelet (GPL) and fiber-reinforced hybrid composite beams are carried out using the parabolic function based shear deformation theory. Parabolic variation of transverse shear stress across the thickness of beam and transverse shear stress-free conditions at top and bottom surfaces of the beam are considered, and the proposed formulation incorporates a transverse displacement field. The present theory works only with four unknowns and is computationally efficient. Hamilton's principle has been employed for deriving the governing equations. Analytical solutions are obtained for both the bending and free vibration problems in the present work considering different variations of GPLs and fibers distribution, namely, FG-X, FG-U, FG-Λ, and FG-O for beams having simply-supported boundary condition. First, the matrix is assumed to be strengthened using GPLs, and then the fibers are embedded. Multiscale modeling for material properties of functionally graded graphene platelet/fiber hybrid composites (FG-GPL/FHRC) is performed using Halpin-Tsai micromechanical model. The study reveals that the distributions of GPLs and fibers have significant impacts on the stresses, deflections, and natural frequencies of the beam. The number of layers and shape factors widely affect the behavior of FG-GPL-FHRC beams. The multilayered FG-GPL-FHRC beams turn out to be a good approximation to the FG beams without exhibiting the stress-channeling effects.