• Title/Summary/Keyword: Kinetics model

Search Result 956, Processing Time 0.054 seconds

Sorption Kinetics of Hydrophobic Organic Compounds in Wetland Soils (습지 토양에서 소수성 유기화합물질의 흡착 동력학)

  • Park, Je-Chul;Shin, Won-Sik
    • Korean Journal of Ecology and Environment
    • /
    • v.36 no.3 s.104
    • /
    • pp.295-303
    • /
    • 2003
  • Sorption kinetics of hydrophobic organic compounds (chlorobenzene and phenanthrene) in natural wetland soils was investigated using laboratory batch adsorbers. One -site mass transfer model (OSMTM) and two compartment first-order kinetic model (TCFOKM) were used to analyze sorption kinetics. Analysis of OSMTM reveals that apparent sorption equilibria were obtained within 10 to 75 hours for chlorobenzene and 2 hours for phenanthrene, respectively. For chlorobenzene, the sorption equilibrium time for surface soil was longer than that of deeper soil presumably due to physico-chemical differences between the soils. For phenanthrene, however, no difference in sorption equilibrium time was observed between the soils. As expected from the number of model parameters involved, the three-parameter TCFOKM was better than the two-parameter OSMTM in describing sorption kinetics, The fraction of fast sorption ($f_1$) and the first-order sorption rate constants for fast ($k_1$)and slow ($k_2$) compartments were determined by fitting experimental data to the TCFOKM. The results of TCFOKM analysis indicate that the sorption rate constant in the fast compartment($k_1$) was much greater than that of slow fraction($k_2$) . The fraction of the fast sorption ($f_1$) and the sorption rate constant in the fast compartment($k_1$) were increasing in the order of increasing $k_{ow}$, phenanthrene > chlorobenzene. The first-order sorption rate constants in the fast ($k_1$) and slow ($k_2$) compartments were found to vary from $10^{-0.1}\;to\;-10^{1.0}$ and from $10^{-4}\;to-10^{-2}$, respectively.

Effect of Glucose, Its Analogs and Some Amino Acids on Pre-steady State Kinetics of ATP Hydrolysis by PM-ATPase of Pathogenic Yeast (Candida albicans)

  • Bushra, Rashid;Nikhat, Manzoor;M., Amin;Luqman A., Khan
    • Animal cells and systems
    • /
    • v.8 no.4
    • /
    • pp.307-312
    • /
    • 2004
  • Fast kinetics of transient pH changes and difference spectrum formation have been investigated following mixing of ADP/ATP with partially purified plasma membrane PM-ATPase of the pathogenic yeast Candida albicans in the presence of five nutrients: glucose, glutamic acid, proline, lysine, and arginine and two analogs of glucose: 2-deoxy D-glucose and xylose. Average $H^+$- absorption to release ratio, indicative of population of ATPase undergoing complete hydrolytic cycle, was found to be 0.27 for control. This ratio varied between 0.25 (proline) to 0.36 (arginine) for all other compounds tested, except for glucose. In the presence of glucose, $H^+$- absorption to release ratio was exceptionally high (0.92). While no UV difference spectrum was observed with ADP, mixing of ATP with ATPase led to a large conformational change. Exposure to different nutrients restricted the magnitude of the conformational change; the analogs of glucose were found to be ineffective. This suppression was maximal in the case of glucose (80%); with other nutrients, the magnitude of suppression ranged from 40-50%. Rate of $H^+$- absorption, which is indicative of E~P complex dissociation, showed positive correlation with suppression of conformational change only in the case of glucose and no other nutrient/analog. Mode of interaction of glucose with plasma membrane $H^+$-ATPase thus appears to be strikingly distinct compared to that of other nutrients/analogs tested. The results obtained lead us to propose a model for explaining glucose stimulation of plasma membrane $H^+$-ATPase activity.

Lattice based Microstructure Evolution Model for Monte Carlo Finite Element Analysis of Polycrystalline Materials (격자식 미세구조 성장 모델을 이용한 다결정 박막 소재의 유한 요소 해석)

  • 최재환;김한성;이준기;나경환
    • Transactions of Materials Processing
    • /
    • v.13 no.3
    • /
    • pp.248-252
    • /
    • 2004
  • The mechanical properties of polycrystalline thin-films, critical for Micro-Electro-Mechanical Systems (MEMS) components, are known to have the size effect and the scatter in the length scale of microns by the numbers of intensive investigation by experiments and simulations. So, the consideration of the microstructure is essential to cover these length scale effects. The lattice based stochastic model for the microstructure evolution is used to simulate the actual microstructure, and the fast and reliable algorithm is described in this paper. The kinetics parameters, which are the key parameters for the microstructure evolution based on the nucleation and growth mechanism, are extracted from the given micrograph of a polycrystalline material by an inverse method. And the method is verified by the comparison of the quantitative measures, the number of grains and the grain size distribution, for the actual and simulated microstructures. Finite element mesh is then generated on this lattice based microstructure by the developed code. And the statistical finite element analysis is accomplished for selected microstructure.

The Effect of the Collision Process Between Molecules on the Rates of Thermal Relaxation of the Translational-Rotational-Vibrational Energy Exchange (분자간 충돌과정에 따른 병진-회전-진동에너지의 이완율)

  • Heo, Joong-Sik
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.28 no.12
    • /
    • pp.1494-1500
    • /
    • 2004
  • A zero-dimensional direct simulation Monte Carlo(DSMC) model is developed for simulating diatomic gas including vibrational kinetics. The method is applied to the simulation of two systems: vibrational relaxation of a simple harmonic oscillator and translational-rotational-vibrational energy exchange process under heating and cooling. In the present DSMC method, the variable hard sphere molecular model and no time counter technique are used to simulate the molecular collision kinetics. For simulation of diatomic gas flows, the Borgnakke-Larsen phenomenological model is adopted to redistribute the translational and internal energies.

Modeling of PhaseTransformation Kinetics in the CGHAZ Considering Prior Austenite Grain Size (오스테나이트 결정립 크기를 고려한 CGHAZ에서의 상변태 거동 예측)

  • 이찬우;엄상호;이경종;이창희
    • Journal of Welding and Joining
    • /
    • v.18 no.5
    • /
    • pp.55-62
    • /
    • 2000
  • A metallurgical model for the phase transformation kinetics at Coarsened Grain Heat Affected Zone(CGHAZ) on the basis of Johnson-Mehl-Avrami equation(JMA equation) was proposed. In this model, the effect of prior austenite grain size on the transformation and the morphological changes of ferrite were considered. Isothermal dilatometer tests were performed to determine the effect of prior austenite grain size (AGS) on the austenite decomposition to ferrite and pearlite in a plain carbon steel. By comparing the calculated volume fraction with measured data, the reliability of the developed model was discussed.

  • PDF

Zricaloy-4 Oxidation Kinetics in High-Pressure High-Temperature Steam (지르칼로이-4의 고압 고온 수증기에서 산화 반응 속도)

  • 박광헌;김규태
    • Journal of the Korean institute of surface engineering
    • /
    • v.34 no.1
    • /
    • pp.17-24
    • /
    • 2001
  • A model for quantifying the effect of steam pressure on the oxide thickness growth was developed based on the experimental data available. First, empirical equations for the thickness estimation of oxide formed in 1 atm steam were made. The oxide growth kinetics turned out to be dependent on 0.4th power of oxidation time. With an assumption that the transition oxide thickness be only a function of temperature, a model for the enhancement of steam pressure on oxide growth was developed. The enhancement coefficient for steam pressure is calculated to be 0.01~0.013 $bar^{-}$. The developed model generally well explains the experimental data.a.

  • PDF

Decomposed "Spatial and Temporal" Convolution for Human Action Recognition in Videos

  • Sediqi, Khwaja Monib;Lee, Hyo Jong
    • Proceedings of the Korea Information Processing Society Conference
    • /
    • 2019.05a
    • /
    • pp.455-457
    • /
    • 2019
  • In this paper we study the effect of decomposed spatiotemporal convolutions for action recognition in videos. Our motivation emerges from the empirical observation that spatial convolution applied on solo frames of the video provide good performance in action recognition. In this research we empirically show the accuracy of factorized convolution on individual frames of video for action classification. We take 3D ResNet-18 as base line model for our experiment, factorize its 3D convolution to 2D (Spatial) and 1D (Temporal) convolution. We train the model from scratch using Kinetics video dataset. We then fine-tune the model on UCF-101 dataset and evaluate the performance. Our results show good accuracy similar to that of the state of the art algorithms on Kinetics and UCF-101 datasets.