• 제목/요약/키워드: Kinetics Model

검색결과 956건 처리시간 0.031초

습지 토양에서 소수성 유기화합물질의 흡착 동력학 (Sorption Kinetics of Hydrophobic Organic Compounds in Wetland Soils)

  • 박제철;신원식
    • 생태와환경
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    • 제36권3호통권104호
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    • pp.295-303
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    • 2003
  • 자연습지 토양에서 소수성 유기화합물(염화벤젠 및 페난쓰린)의 흡착동력학을 실험실규모의 회분식 반응기를 이용하여 조사하였다. 단일영역 물질전달모델 (one-site mass transfer model, OSMTM)과 두영역 1차속도모델 (two compartment first-order kinetic model, TCFOKM)을 사용하여 흡착속도를 분석하였다. OSMTM 분석결과 염화벤젠의 경우 10${\sim}$75시간 이내에, 페난쓰린의 경우 약 2시간 이내에 각각 겉보기 흡착평형에 도달하였다. 염화벤젠의 경우, 표면 토양에서의 흡착평형시간이 하부 토양보다 길게 나타났는데, 이는 토양 유기탄소의 물리화학적 특성의 차이에 기인한다. 그러나, 페난쓰린의 경우 각 토양간에 흡착평형시간의 차이는 없었다. 관련 모델매개변수의 수에서 기대되듯이 변수가 3개인 TCFOKM이 변수가 2개인 OSMTM보다 흡착속도를 더 잘 표현할 수 있었다. 실험결과에 대한 TCFOKM의 곡선맞춤으로부터 얻은 매개변수인 빠른 흡착영역의 분율($f_1$)과 빠른 흡착영역과 느린 흡착영역의 1차 흡착속도 상수($k_1$,및 $k_2$)를 얻을 수 있었다. TCFOKM 분석결과 빠른 흡착영역에서의 흡착속도 상수는 느린 흡착영역에서의 흡착속도 상수 보다 큰 것으로 나타났다. 빠른 흡착영역의 분율 ($f_1$)과 흡착속도상수 ($k_1$)는 $k_{ow}$ 값이 증가(페난쓰린>염화벤젠)함에 따라 증가하였다. 빠른 흡착영역과 느린 흡착영역에서의 1차 흡착 속도상수는 각각$10^{-0.1}\;-10^{+1}$$10^{-4}\;-10^{-2}$의 범위에서 변화하였다.

Effect of Glucose, Its Analogs and Some Amino Acids on Pre-steady State Kinetics of ATP Hydrolysis by PM-ATPase of Pathogenic Yeast (Candida albicans)

  • Bushra, Rashid;Nikhat, Manzoor;M., Amin;Luqman A., Khan
    • Animal cells and systems
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    • 제8권4호
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    • pp.307-312
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    • 2004
  • Fast kinetics of transient pH changes and difference spectrum formation have been investigated following mixing of ADP/ATP with partially purified plasma membrane PM-ATPase of the pathogenic yeast Candida albicans in the presence of five nutrients: glucose, glutamic acid, proline, lysine, and arginine and two analogs of glucose: 2-deoxy D-glucose and xylose. Average $H^+$- absorption to release ratio, indicative of population of ATPase undergoing complete hydrolytic cycle, was found to be 0.27 for control. This ratio varied between 0.25 (proline) to 0.36 (arginine) for all other compounds tested, except for glucose. In the presence of glucose, $H^+$- absorption to release ratio was exceptionally high (0.92). While no UV difference spectrum was observed with ADP, mixing of ATP with ATPase led to a large conformational change. Exposure to different nutrients restricted the magnitude of the conformational change; the analogs of glucose were found to be ineffective. This suppression was maximal in the case of glucose (80%); with other nutrients, the magnitude of suppression ranged from 40-50%. Rate of $H^+$- absorption, which is indicative of E~P complex dissociation, showed positive correlation with suppression of conformational change only in the case of glucose and no other nutrient/analog. Mode of interaction of glucose with plasma membrane $H^+$-ATPase thus appears to be strikingly distinct compared to that of other nutrients/analogs tested. The results obtained lead us to propose a model for explaining glucose stimulation of plasma membrane $H^+$-ATPase activity.

격자식 미세구조 성장 모델을 이용한 다결정 박막 소재의 유한 요소 해석 (Lattice based Microstructure Evolution Model for Monte Carlo Finite Element Analysis of Polycrystalline Materials)

  • 최재환;김한성;이준기;나경환
    • 소성∙가공
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    • 제13권3호
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    • pp.248-252
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    • 2004
  • The mechanical properties of polycrystalline thin-films, critical for Micro-Electro-Mechanical Systems (MEMS) components, are known to have the size effect and the scatter in the length scale of microns by the numbers of intensive investigation by experiments and simulations. So, the consideration of the microstructure is essential to cover these length scale effects. The lattice based stochastic model for the microstructure evolution is used to simulate the actual microstructure, and the fast and reliable algorithm is described in this paper. The kinetics parameters, which are the key parameters for the microstructure evolution based on the nucleation and growth mechanism, are extracted from the given micrograph of a polycrystalline material by an inverse method. And the method is verified by the comparison of the quantitative measures, the number of grains and the grain size distribution, for the actual and simulated microstructures. Finite element mesh is then generated on this lattice based microstructure by the developed code. And the statistical finite element analysis is accomplished for selected microstructure.

분자간 충돌과정에 따른 병진-회전-진동에너지의 이완율 (The Effect of the Collision Process Between Molecules on the Rates of Thermal Relaxation of the Translational-Rotational-Vibrational Energy Exchange)

  • 허중식
    • 대한기계학회논문집B
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    • 제28권12호
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    • pp.1494-1500
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    • 2004
  • A zero-dimensional direct simulation Monte Carlo(DSMC) model is developed for simulating diatomic gas including vibrational kinetics. The method is applied to the simulation of two systems: vibrational relaxation of a simple harmonic oscillator and translational-rotational-vibrational energy exchange process under heating and cooling. In the present DSMC method, the variable hard sphere molecular model and no time counter technique are used to simulate the molecular collision kinetics. For simulation of diatomic gas flows, the Borgnakke-Larsen phenomenological model is adopted to redistribute the translational and internal energies.

오스테나이트 결정립 크기를 고려한 CGHAZ에서의 상변태 거동 예측 (Modeling of PhaseTransformation Kinetics in the CGHAZ Considering Prior Austenite Grain Size)

  • 이찬우;엄상호;이경종;이창희
    • Journal of Welding and Joining
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    • 제18권5호
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    • pp.55-62
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    • 2000
  • A metallurgical model for the phase transformation kinetics at Coarsened Grain Heat Affected Zone(CGHAZ) on the basis of Johnson-Mehl-Avrami equation(JMA equation) was proposed. In this model, the effect of prior austenite grain size on the transformation and the morphological changes of ferrite were considered. Isothermal dilatometer tests were performed to determine the effect of prior austenite grain size (AGS) on the austenite decomposition to ferrite and pearlite in a plain carbon steel. By comparing the calculated volume fraction with measured data, the reliability of the developed model was discussed.

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지르칼로이-4의 고압 고온 수증기에서 산화 반응 속도 (Zricaloy-4 Oxidation Kinetics in High-Pressure High-Temperature Steam)

  • 박광헌;김규태
    • 한국표면공학회지
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    • 제34권1호
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    • pp.17-24
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    • 2001
  • A model for quantifying the effect of steam pressure on the oxide thickness growth was developed based on the experimental data available. First, empirical equations for the thickness estimation of oxide formed in 1 atm steam were made. The oxide growth kinetics turned out to be dependent on 0.4th power of oxidation time. With an assumption that the transition oxide thickness be only a function of temperature, a model for the enhancement of steam pressure on oxide growth was developed. The enhancement coefficient for steam pressure is calculated to be 0.01~0.013 $bar^{-}$. The developed model generally well explains the experimental data.a.

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Decomposed "Spatial and Temporal" Convolution for Human Action Recognition in Videos

  • Sediqi, Khwaja Monib;Lee, Hyo Jong
    • 한국정보처리학회:학술대회논문집
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    • 한국정보처리학회 2019년도 춘계학술발표대회
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    • pp.455-457
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    • 2019
  • In this paper we study the effect of decomposed spatiotemporal convolutions for action recognition in videos. Our motivation emerges from the empirical observation that spatial convolution applied on solo frames of the video provide good performance in action recognition. In this research we empirically show the accuracy of factorized convolution on individual frames of video for action classification. We take 3D ResNet-18 as base line model for our experiment, factorize its 3D convolution to 2D (Spatial) and 1D (Temporal) convolution. We train the model from scratch using Kinetics video dataset. We then fine-tune the model on UCF-101 dataset and evaluate the performance. Our results show good accuracy similar to that of the state of the art algorithms on Kinetics and UCF-101 datasets.