• Nuclear Engineering and Technology
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• 제13권3호
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• pp.153-161
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• 1981

고리 원자력 1호기에서 일어날 수 있는 가상사고에 의한 동특성 현상이 점근사 원자로 모델에 의한 중성자 및 온도 방정식을 사용하여 해석되었다. 일반적으로 수치해석 결과는 사고해석에 있어서 확실한 동특성 시간전이 현상을 예견하기 위채서는 보다 정밀한 계산모델을 사용해야 된다는 것을 지시한다. 전출력 상태에서 RCCA 인출에 따르는 출력반응의 경우는 점근사 원자로 모델이 고리 1호기의 최종 안정성 분석 보고서의 해석결과와 우수한 일치를 보여줬다.

• 한국환경과학회지
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• 제27권2호
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• pp.83-90
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• 2018

In this study, zeolite (Z-C2) was synthesized using a fusion/hydrothermal method on coal fly ash (FA) discharged from a thermal power plant in the Ulsan area and then analyzed via scanning electron microscopy (SEM) and X-ray diffraction (XRD). The Z-C2 was characterized in terms of mineralogical composition and morphological analysis. The XRD results showed that its peaks had the characteristics of Na-A zeolite in the range of $2{\theta}$ of 7.18~34.18. The SEM images confirmed that the Na-A zeolite crystals had a chamfered-edge crystal structure almost identical to that of the commercial zeolite. The adsorption kinetics of Cu, Co, Mn and Zn ions by Z-C2 were described better by the pseudo-second-order kinetic model more than by the pseudo-first-order kinetic model. The Langmuir model fitted the adsorption isotherm data better than the Freundlich model did. The maximum adsorption capacities of Cu, Co, Mn and Zn ions obtained from the Langmuir model were in the following order : Cu (94.7 mg/g) > Co (77.7 mg/g) > Mn (57.6 mg/g) > Zn (51.1 mg/g). These adsorption capacities are regarded as excellent compared to those of commercial zeolite.

• Advances in Energy Research
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• 제2권2호
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• pp.73-84
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• 2014

Fuel cells of proton exchange membrane type (PEMFC) working with hydrogen in the anode and ambient air in the cathode ('air breathing') have been prepared and characterized. The cells have been studied with variable thickness of the cathode catalyst layer ($L_{CL}$), maintaining constant the platinum and ionomer loads. Polarization curves and electrochemical active area measurements have been carried out. The polarization curves are analyzed in terms of a model for a flooded passive air breathing cathode. The analysis shows that $L_{CL}$ affects to electrochemical kinetics and mass transport processes inside the electrode, as reflected by two parameters of the polarization curves: the Tafel slope and the internal resistance. The observed decrease in Tafel slope with decreasing $L_{CL}$ shows improvements in the oxygen reduction kinetics which we attribute to changes in the catalyst layer structure. A decrease in the internal resistance with $L_{CL}$ is attributed to lower protonic resistance of thinner catalyst layers, although the observed decrease is lower than expected probably because the electronic conduction starts to be hindered by more hydrophilic character and thicker ionomer film.

• 제어로봇시스템학회:학술대회논문집
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• 제어로봇시스템학회 2004년도 ICCAS
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• pp.1158-1161
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• 2004

This paper describes the construction of a half sphere screen driving tilting simulator that can perform six degree-of-freedom (DOF) motions simulator to a tilting train. The mathematical equations of Tilting Train dynamics are first derived from the 6-DOF bicycle model and incorporated with the bogie, carbody, and suspension subsystems. The equations of motion are then programmed by visual C++ code. To achieve the simulator functions, a motion platform that is constructed by six electric-driven actuators is designed, and its kinetics/inverse kinetics analysis is also conducted. Driver operation signals such as carbady angle, accelerator, and tilting positions are measured to trigger the Tilting dynamics calculation and further actuate the cylinders by the motion platform control program. In addition, a digital PID controller is added to achieve the stable and accurate displacements of the motion platform. The experiments prove that the designed simulator is adequate in performing some special rail road driving situations discussed in this paper.

• 한국마이크로전자및패키징학회:학술대회논문집
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• 한국마이크로전자및패키징학회 2001년도 추계 기술심포지움
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• pp.134-137
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• 2001

The cure kinetics of a cycloalipatic epoxy / anhydride / Co(II) system for a no-flow underfill encapsulant, has been studied by using a differential scanning calorimetry(DSC) under isothermal and dynamic conditions over the temperature range of $160^{\circ}C ~220^{\circ}C$. The kinetic analysis was carried out by fitting dynamic/isothermal heating experimental data to the kinetic expressions to determine the reaction parameters, such as order of reaction and reaction constants. Diffusion-controlled reaction has been observed as the cure conversion increases and successfully analyzed by incorporating the diffusion control term into the rate equation. The prediction of reaction rates by the model equation corresponded well to experimental data at all temperature.

• Journal of applied mathematics & informatics
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• 제8권1호
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• pp.165-180
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• 2001

This paper presents a new difference scheme for numerical solution of stiff system of ODE’s. The present study is mainly motivated to develop an absolutely stable numerical method with a high order of approximation. In this work a double implicit A-stable difference scheme with the sixth order of approximation is suggested. Another purpose of this study is to introduce automatic choice of the integration step size of the difference scheme which is derived from the proposed scheme and the one step scheme of the fourth order of approximation. The algorithm was tested by means of solving the Kreiss problem and a chemical kinetics problem. The behavior of the gas explosive mixture (H₂+ O₂) in a closed space with a mobile piston is considered in test problem 2. It is our conclusion that a hydrogen-operated engine will permit to decrease the emitted levels of hazardous atmospheric pollutants.

• 한국운동역학회지
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• 제22권2호
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• pp.243-251
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• 2012

The purpose of this study was to develop an impact force measurement device in order to facilitate the acquisition of quantitative data for the analysis of various sporting events. The device was designed to include cylindrical aluminum supports of 220 mm diameter, which allows mounting and dismounting of the device on walls and frames. In addition, a hard sponge for impact absorption, as well as 4 springs, were attached to the plate. Both were attached to prevent psychological variables and injuries. When a subject applies force on the device, accurate data about the maximum repulsive force is acquired in real time, with a lag of only 0.001 s. The device was calibrated in four steps: (1) increase, (2) increase, (3) increase-decrease, and (4) increase-decrease. The maximum relative expanded uncertainty was 0.166%, indicating that the impact force measurement was sufficiently reliable. The proposed device can be applied to various sporting situations and is expected to be useful for studying kinetics.

• 한국미생물·생명공학회지
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• 제25권2호
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• pp.173-177
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• 1997

Glycerol-3-phosphate cytidylyltransferase from Bacillus subtilis was modified with various chemical modifiers to determine the active sites of the enzyme. Treatment of the enzyme with group-specific reagents diethylpyrocarbonate, N-bromosuccinimide, or carbodiimide resulted in complete loss of enzyme activity, which shows histidine, tryptophan, and glutamic acid or aspartic acid residues are at or near the active site. In each case, inactivation followed pseudo first-order kinetics. Inclusion of glycerol-3-phosphate and/or CTP prevented the inactivation, indicating the presence of tryptophan and glutamic acid or aspartic acid residues at the substrate binding site. Analysis of kinetics of inactivation showed that the loss of enzyme activity was due to modification of a two histidine residues, single tryptophan residue, and two glutamic acid or aspartic acid residues.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1998년도 추계학술대회 논문집
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• pp.163-166
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• 1998

The mechanism of methane sensing by Pd-SiC diode was investigated over the temperature range of 400~$600^{\circ}C$. The effects or methane gas reaction on the parameters such as barrier height, initial rate of methane gas reaction are investigated. The methane gas reaction kinetics on the device are also discussed. The physical and chemical mechanism responsible for methane detection are proposed. Analysis of steady-state reaction kinetics using I-V method confirmed that methane gas reaction processes are responsible for the barrier height change in the diode.

• 한국결정성장학회지
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• 제7권2호
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• pp.324-333
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• 1997

초음파 분무 열분해 알루미나 분체로부터 $1600^{\circ}$~$1700^{\circ}C$ 범위의 소정 온도에서 소결한 다공질 시편의 상대밀도는 80~92%이다. 소결 온도 및 유지 시간이 길어지면 과대 입성장을 일으킨다. 소결 중의 미세 구조 발달을 이미지 분석하였다. 초음파 분무 열분해 알루미나 분체의 소성시 결정립 성장 동력학에 대한 연구로부터 정상 입성장 결정립 성장 활성화 에너지는 386.77 kJ/mol이다.