• Title/Summary/Keyword: Kinetic determination

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Estimation of Erositivity Using an Impact Disdrometer in East of Alagoas (충격 입자 분포 탐지기를 이용한 침식도 추정)

  • Tenorio, R.S.;Kwon, Byung Hyuk;Moraes, M.C. da S.;Yoon, Hong-Joo
    • The Journal of the Korea institute of electronic communication sciences
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    • v.15 no.2
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    • pp.371-378
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    • 2020
  • Rainfall is one of the most active forces that cause soil erosion. The action of rain on the soil exerts an erosive power caused by the impact of the drops, which fall with variable speed and kinetic energy, depending directly on the diameter of the drop. The objective of this study is to determine algorithms capable of estimating rainfall erosivity for the region of Maceió-AL. For this purpose, erosion rains were collected between 2003 and 2006 using a RD-69 disdrometer, which continuously and automatically measures rainfall distribution in a range of 1 min. The determination of algorithms in the form of power equation to estimate was adjusted with one and two independent variables (amount of rainfall, duration and maximum intensity).

The drivers and energetics of ionized gas outflows in powerful Type 2 AGN in the local Universe

  • Karouzos, Marios;Woo, Jong-Hak;Bae, Hyun-Jin
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.1
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    • pp.37.2-37.2
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    • 2016
  • There exist scaling relations that link the mass of supermassive black holes with both the velocity dispersion and the mass of the central stellar cusp of their host galaxies. This implies that galaxies co-evolve with their central black holes, potentially through the feedback from actively accreting supermassive black holes (AGN). We use integral field spectroscopy data from the 8.2m Gemini-North telescope to investigate ionized gas outflows in luminous local (z<0.1) Type 2 AGN. Our sample of 6 galaxies was selected based on their [OIII] dust-corrected luminosity (>$10^{42}erg/s$) and signatures of outflows in the [OIII] line profile of their SDSS spectra. These are arguably the best candidates to explore AGN feedback in action since they are < 1% of a large local type 2 AGN SDSS sample selected based on their [OIII] kinematics. Expanding on previously reported results concerning the kinematic decomposition and size determination of these outflows, here we report their photoionization properties and energetics. We find strong evidence that connect the extreme kinematics of the ionized gas with AGN photoionization. The kinematic component related to the AGN-driven outflow is clearly separated from other kinematic components, such as gravitation- or stellar-driven motions, on the velocity and velocity dispersion diagram. Our spatially resolved kinematic analysis reveals that up to 90% of the mass and kinetic energy of the outflow is contained within the central kiloparcec of the galaxy. The total mass and kinetic energy of the outflow correlate well with the AGN bolometric luminosity, resulting in energy conversion efficiencies between 0.01% and 1%. Intriguingly, we detect ubiquitous signs of ongoing circumnuclear star formation. Their small size, the centrally contained mass and energy, and the universally detected circumnuclear star formation cast doubts on the potency of these AGN-driven outflows as agents of negative feedback.

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The Determination of Anaerobic Biodegradability Rates Livestock Byproducts Using Double First-Order Kinetic Model

  • Shin, Kook-Sik;Yoon, Young-man;Jung, Ha-Il;Hyun, Byung-Geun;Cho, Hyun-Joon;Sonn, Yeon-Kyu
    • Korean Journal of Soil Science and Fertilizer
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    • v.48 no.5
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    • pp.542-548
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    • 2015
  • This study investigated methane productions and a degradation rate of organic matters by German standard method, VDI4630 test. In this study, 4 livestock byproducts from livestock farm were selected for the investigation. The objective of this study was to estimate a distribution of organic matters by using the double first-order kinetics model in order to calculate the rate of biodegradable organic matters which degrade rapidly in the initial stage and the persistently biodegradable organic matters which degrade slowly later. As a result, all the byproducts applied in this study showed rapid decomposition in the initial stage. Then the decomposition rate began to slow down for a certain period and the rate became 5 times slower than the initial decomposition rate. This trend of decomposition rate changes is typical conditions of organic matter decompositions. The easily degradable factors ($k_1$) ranged between $0.145{\sim}0.257day^{-1}$ and persistent degradable factors ($k_2$) were $0.027{\sim}0.080day^{-1}$. Among these results, greater organic matter decomposition rates from VDI4630 had greater $k_1$ values (0.257, $0.211day^{-1}$) and smaller $k_2$ values (0.027, $0.030day^{-1}$) for dairy wastewater and forage byproduct, respectively.

Rockfall Behavior with Catchment Area Condition (포집공간 조건에 따른 낙석의 거동)

  • Lee, Jundae;Kwon, Youngcheul;Bae, Wooseok
    • Journal of the Korean GEO-environmental Society
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    • v.20 no.1
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    • pp.35-42
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    • 2019
  • Various development works inevitably increase cutting slopes due to land use, and many of trails managed by different authorities are being deteriorated by long-term weathering. Collapse of slopes causes unavoidable damage of property and loss of lives because of its uncertainty and difficulty in predicting its occurrence. In order to overcome the unavoidability, America, Japan, and several European nations analyze the kinetic energy and moving distance when rocks of upper slope move along the inclined plane, via field tests and computerized interpretation of the test results. Also, they are making efforts to develop measures with which the kinetic energy of the rocks moving along the slope is absorbed and fails to reach to specific structures. However, domestic researches just focus on fragmentary prediction of rockfall using existing programs, and there have been few approaches to identify interpretation methods appropriate for domestic cases or determination of parameters. In this context, we in this study defined rockfall types and affecting factors and analyzed effects of parameters using a general-purpose rockfall simulation program to understand principles of rockfall and to estimate effects of various parameters.

Enhancement of phosphate removal using copper impregnated activated carbon(GAC-Cu) (Cu(II)를 이용하여 표면개질된 활성탄의 인산염 제거효율 향상)

  • Shin, Jeongwoo;Kang, Seoyeon;An, Byungryul
    • Journal of Korean Society of Water and Wastewater
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    • v.35 no.6
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    • pp.455-463
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    • 2021
  • The adsorption process using GAC is one of the most secured methods to remove of phosphate from solution. This study was conducted by impregnating Cu(II) to GAC(GAC-Cu) to enhance phosphate adsorption for GAC. In the preparation of GAC-Cu, increasing the concentration of Cu(II) increased the phosphate uptake, confirming the effect of Cu(II) on phosphate uptake. A pH experiment was conducted at pH 4-8 to investigate the effect of the solution pH. Decrease of phosphate removal efficiency was found with increase of pH for both adsorbents, but the reduction rate of GAC-Cu slowed, indicating electrostatic interaction and coordinating bonding were simultaneously involved in phosphate removal. The adsorption was analyzed by Langmuir and Freundlich isotherm to determine the maximum phosphate uptake(qm) and adsorption mechanism. According to correlation of determination(R2), Freundlich isotherm model showed a better fit than Langmuir isotherm model. Based on the negative values of qm, Langmuir adsorption constant(b), and the value of 1/n, phosphate adsorption was shown to be unfavorable and favorable for GAC and GAC-Cu, respectively. The attempt of the linearization of each isotherm obtained very poor R2. Batch kinetic tests verified that ~30% and ~90 phosphate adsorptions were completed within 1h and 24 h, respectively. Pseudo second order(PSO) model showed more suitable than pseudo first order(PFO) because of higher R2. Regardless of type of kinetic model, GAC-Cu obtained higher constant of reaction(K) than GAC.

Enhancement of phosphate removal using stabilized Fe-Mn particle (Fe-Mn 입자의 안정화를 통한 인산염 효율 향상)

  • Seoyeon Kang;Jeongwoo Shin;Byugnryul An
    • Journal of Korean Society of Water and Wastewater
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    • v.37 no.6
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    • pp.375-382
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    • 2023
  • The binary oxide adsorbent using Fe and Mn (Fe-Mn) has been prepared by precipitation method to enhance the removal of phosphate. Different amounts of chitosan, a natural organic polymer, were used during preparation of Fe-Mn as a stabilizer to protect an aggregation of Fe-Mn particles. The optimal amount of chitosan has been determined considering the separation of the Fe-Mn particles by gravity from solution and highest removal efficiency of phosphate (Fe-Mn10). The application of Fe-Mn10 increased removal efficiency at least 15% compared to bare Fe-Mn. According to the Langmuir isotherm model, the maximum uptake (qm) and affinity coefficient (b) were calculated to be 184 and 240 mg/g, and 4.28 and 7.30 L/mg for Fe-Mn and Fe-Mn10, respectively, indicating 30% and 70% increase. The effect of pH showed that the removal efficiency of phosphate was decrease with increase of pH regardless of type of adsorbent. The enhanced removal efficiency for Fe-Mn10 was maintained in entire range of pH. In the kinetics, both adsorbents obtained 70% removal efficiency within 5 min and 90% removal efficiency was achieved at 1 h. Pseudo second order (PSO) kinetic model showed higher correlation of determination (R2), suggesting chemisorption was the primary phosphate adsorption for both Fe-Mn and Fe-Mn10.

Evaluation of Removal Properties of Cu(II) from Aqueous Solutions by Inflated Vermiculites (팽창질석에 의한 수용액내의 구리 제거능 평가)

  • Song, Jaehong;Lee, Junki;Kim, Seogku;Lee, Taeyoon
    • Journal of the Korean GEO-environmental Society
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    • v.10 no.7
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    • pp.25-32
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    • 2009
  • The main objective of this study was to examine the removal properties of Cu from water by inflated vermiculites. The component of vermiculites was analyzed by XRF and the concentration of Copper ion was measured by UV-VIS. Serial batch Kinetic tests and batch sorption tests were conducted to determine the removal characteristics for Cu in aqueous solutions. The result shows that removal rate, $K_{obs}$, of Cu are 0.73, 1.52, and 1.71 for initial pH 3, pH 4, pH 5, respectively, and are 3.19, 1.90, and 0.73 for the initial concentration of $1mg\;L^{-1}$, $5mg\;L^{-1}$, $10mg\;L^{-1}$, respectively. It leads to the conclusion that the removal rates are inversely proportional to the initial Cu concentration and are increased proportionally to the initial pHs. Finally, Sorption data were correlated with both Langmuir and Freundlich isotherms. As a result, Langmuir and Freundlich models were well fitted to batch isotherm data with good values of the determination coefficient. but the determination coefficient value for the Freundlich model fit was slightly higher than that of Langmuir model (0.965 for the Freundlich model and 0.936 for the Langmuir model). Using the Langmuir model, the maximum sorption capacity ($Q_{max}$), Freundlich partition coefficient, and the numerical value of n wrer estimated as $1,250mg\;kg^{-1}$, $635.1L\;kg^{-1}$ and 1.69, respectively. These results show that the inflated vermiculites could be used as an excellent adsorbent for copper contained in various types of aqueous solutions.

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Ammonia Microdiffusion and Colorimetic Method for Determining Nitrogen in Plant Tissues (암모니아 확산 및 발생에 의한 식물조직의 질소분석 방법)

  • Tae-Hwan Kim;Byung Ho-Kim
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.16 no.4
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    • pp.253-259
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    • 1996
  • Ammonia microdiffusion method and colorimetric measurement are described for the nitrogen determination. The diffusion of ammonia could be successfully induced by using a microdiffusion cell. It is a simple and rapid technique, which is suitable for transforming the nitrogen in digests into $NH_4CI$ for the colorimetric N determination with ammonia color reagent. Above 99% of N recovery were obtained with microdiffusion up to 15 hours. The coloration method of collected $NH_4CI$ for the colorimetric N determination was also estabilshed with a scanning in U.V. spectrophotometer. Under the proposed coloration method (0.5 mL of sample digest, 4.0 mL of $H_2O$ and 0.5 mL of ammonia color reagent), a maximal absorbance was observed at 410 nm. The kinetic measurement of absorbance showed a high stability from 5 to 45 minutes after color development. Absorbance was directly proportional to the amount of $NH_4^+-N$ present. The microdiffusion-ammonia coloration method was successfully applied to the nitrogen determination in the forms of protein-N or total -N in plant tissue. Comparing with Kjeldahl distillation method, the values obtained with described method were slightly higher and more reliable.

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A Kinetic Studies of the Pyrolysis of Waste Plastic Based on the Thermogravimetic Analyses (폐플라스틱의 열분해 시 열중량 분석 및 동역학 연구)

  • Jung, Won Hak;Hwang, Hyeon Uk;Kim, Myung Gyun;Sun, JianFeng;Mutua, Nzioka Antony;Kim, Young Ju
    • Resources Recycling
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    • v.24 no.5
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    • pp.15-21
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    • 2015
  • Waste plastic differs in its speed of combustion owing to its variety in composition as well as kinds of plastic. This study is aimed at examining the thermal weight analysis and determination of its kinetics in order to derive the design element in pyrolysis of RPF (Refused Plastic Fuel) as the plastic solid fuel. Based on the result of TGA (Thermogravimetric analysis), kinetic characteristics were analyzed by using Kissinger method which are the most common method for obtaining activation energy, and experimental conditions of TGA were set as follows: in a nitrogen atmosphere, gas flow rate of 20 ml/min, heating rate of $5{\sim}50^{\circ}C/min$, and maximum hottest temperature of $800^{\circ}C$. The method used for determining the property of waste plastic when thermally decomposed was thought feasible as the basic data in deciding the performance, design, and optimal operating condition of the reactor in the actual reactor.

The Experimental Study on Electrokinetic Injection Improvement of Low Permeable Ground (저 투수성 지반의 동전기 주입 개량의 실험 연구)

  • Kim, Soo-Sam;Han, Sang-Jae;Kim, Ki-Nyun
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.2C
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    • pp.99-108
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    • 2006
  • In this study a series of bench scale test are conducted to increase the undrained shear strength of clayey soils using by Electro-kinetic injection stabilization method. The sodium silicate was injected in anode reservoir and its concentration was changed with 500, 1000, 1500, 2000, 2500mM for configuration of applicability of Electro-kinetic injection stabilization method. Also, the treatment time and electric gradient was changed to acquire the optical influence factors. For increasing the shear strength to maximum values, the calcium chloride and aluminium hydroxide, which concentration was changed with 50, 250, 500, 750, 1000mM, were added at anode reservoir for 5 days after the treatment of sodium silicate in 5 days as the 2nd additives. The test of results in determination of sodium silicate concentration show that the undrained shear strength at each point had a tendency to converge into a constant value when the concentration of sodium silicate came to 1000mM and above. The maximum shear strength increasement was 800% compared with initial value. After a series of test, the electric gradient and treatment time for application of electric fielld were 1V/cm and 6 days. In case of 2nd additives test, the concentration for maximum shear strength is 250mM in all additives and the effects of shear strength improvement was developed approximately 20~30% in comparison to addition of single injection material.