• 제목/요약/키워드: Kadam

검색결과 18건 처리시간 0.024초

Phosphomolybdic Acid Supported on Silica Gel as an Efficient and Reusable Catalyst for Cyanosilylation of Aldehydes

  • Kadam, Santosh T.;Kim, Sung-Soo
    • Bulletin of the Korean Chemical Society
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    • 제29권7호
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    • pp.1320-1322
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    • 2008
  • Phosphomolybdic acid supported on silica gel (PMA-$SiO_2$) is an efficient catalyst for the activation of TMSCN for the facile cyanosilylation of various aldehydes. Cyano transfer from TMSCN to aldehyde proceeds smoothly at rt in presence of 0.8 mol % of PMA-$SiO_2$ leading to a range of cyanosilylether in excellent yield (mostly over 93%) within short reaction time (30 min). The catalyst can be recovered and reused several times without loss of activity.

TMEDA Catalyzed Henry (Nitroaldol) Reaction under Metal and Solvent-free Conditions

  • Majhi, Anjoy;Kadam, Santosh T.;Kim, Sung-Soo
    • Bulletin of the Korean Chemical Society
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    • 제30권8호
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    • pp.1767-1770
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    • 2009
  • The Henry (nitroaldol) reaction proceeds under mild conditions with catalytic amount of tetramethylethylenediamine (TMEDA) to afford $\beta$-nitro alkanol in considerably excellent yield. Structurally diverse aldehydes react with nitromethane in presence of 0.3 equiv of TMEDA under solvent-free condition at rt. The low catalytic loading and mild reaction condition are the key features of the catalytic method.

TMEDA: Efficient and Mild Catalyst for the Acylation of Alcohols, Phenols and Thiols under Solvent-free Condition

  • Kadam, Santosh T.;Lee, Han-Bin;Kim, Sung-Soo
    • Bulletin of the Korean Chemical Society
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    • 제30권5호
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    • pp.1071-1076
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    • 2009
  • N,N,N′,N′-tetramethylethylenediamine (TMEDA) acts as a simple, mild and efficient catalyst for the acylation of alcohols, phenols and thiols at room temperature under solvent-free condition. Acylation reaction with acetic anhydride and benzoic anhydride proceeds with good to excellent yield in the presence of TMEDA as the catalyst.

ULAM STABILITIES FOR IMPULSIVE INTEGRO-DIFFERENTIAL EQUATIONS

  • Sandhyatai D. Kadam;Radhika Menon;R. S. Jain;B. Surendranath Reddy
    • Nonlinear Functional Analysis and Applications
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    • 제29권1호
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    • pp.197-208
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    • 2024
  • In the present paper, we establish Ulam-Hyres and Ulam-Hyers-Rassias stabilities for nonlinear impulsive integro-differential equations with non-local condition in Banach space. The generalization of Grownwall type inequality is used to obtain our results.

Mannich-type Reactions of in Situ Generated N-Acyliminium Ions from α-Amido p-Tolylsulfones with Silyl Enolates

  • Lee, Sang-Hyeup;Kadam, Santosh T.
    • Bulletin of the Korean Chemical Society
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    • 제32권10호
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    • pp.3738-3742
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    • 2011
  • Bismuth tribromide ($BiBr_3$) catalyzed Mannich-type reactions of N-acyliminium ions which generated in situ from N-benzyloxycarbonylamino p-tolylsulfones have been developed. In the presence of catalytic amount of $BiBr_3$, N-benzyloxycarbonylamino p-tolylsulfones prepared from aromatic and aliphatic aldehydes reacted with silyl enol ether and silyl enol ester under mild reaction conditions to afford N-Cbz-protected ${\beta}$-amino ketones and N-Cbz-protected ${\beta}$-amino esters in moderate to good yield, respectively.

Closed-loop controller design, stability analysis and hardware implementation for fractional neutron point kinetics model

  • Vyawahare, Vishwesh A.;Datkhile, G.;Kadam, P.;Espinosa-Paredes, G.
    • Nuclear Engineering and Technology
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    • 제53권2호
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    • pp.688-694
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    • 2021
  • The aim of this work is the analysis, design and hardware implementation of the fractional-order point kinetics (FNPK) model along with its closed-loop controller. The stability and closed-loop control of FNPK models are critical issues. The closed-loop stability of the controller-plant structure is established. Further, the designed PI/PD controllers are implemented in real-time on a DSP processor. The simulation and real-time hardware studies confirm that the designed PI/PD controllers result in a damped stable closed-loop response.

CURVELET TRANSFORM AS AN EXTENSION OF WAVELET TRANSFORM AND ITS OPERATIONAL CALCULUS

  • Sachin Mane;Bharat Bhosale;Shubham D. Shedge
    • 한국수학교육학회지시리즈B:순수및응용수학
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    • 제31권2호
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    • pp.179-187
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    • 2024
  • In image and signal processing, the wavelet transform is frequently employed. However, it has the drawback of having weak directionality, which has limited its use in many applications. A recent addition to the wavelet transform, the curvelet transform attempts to address crossing phenomena that occur along curved edges in 2-D images. As an extension of the wavelet transform, we discuss various curvelet transform features in this paper. There are numerous uses for the curvelet and wavelet transforms in image and signal processing.

Competition Impacts on the Financial Distress of Firms in the Healthcare Sector in India

  • Venkata Mrudula, BHIMAVARAPU;Jagjeevan, KANOUJIYA;Vikas, TRIPATI;Pracheta, TEJASMAYEE;Rameesha, KALRA;Sanjeev, KADAM;Poornima, TAPAS;Shailesh, RASTOGI
    • The Journal of Asian Finance, Economics and Business
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    • 제10권2호
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    • pp.175-181
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    • 2023
  • Competition assures improved products and services to meet customers' needs. The soundness of a firm's financial health is crucial for the country's economic well-being. Distressed companies cause investor panic, which has a knock-on effect on the economy and leads to a deterioration in the image and value of the companies. This paper aims to empirically investigate the influence of competition on financial distress (FD) in the healthcare industry using the Altman Zscore values as the proxy for FD. This study uses secondary data from ten healthcare companies operating in India between 2016 and 2020. The study's findings indicate a significant negative relation with the exogenous variables of the study, implying that a higher level of competition enhances a firm's FD or adversely affects financial health. The main implication of the study is two-pronged. Firstly, the firms' managers and decision-makers need not worry about competition as a deterrent to stability. Secondly, the policymakers need not be concerned that high competition may lead to financial stress for the firms. Therefore, this paper concludes that competition is good for firms operating in India.

A Survey of State-of-the-Art Multi-Authority Attribute Based Encryption Schemes in Cloud Environment

  • Reetu, Gupta;Priyesh, Kanungo;Nirmal, Dagdee
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • 제17권1호
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    • pp.145-164
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    • 2023
  • Cloud computing offers a platform that is both adaptable and scalable, making it ideal for outsourcing data for sharing. Various organizations outsource their data on cloud storage servers for availing management and sharing services. When the organizations outsource the data, they lose direct control on the data. This raises the privacy and security concerns. Cryptographic encryption methods can secure the data from the intruders as well as cloud service providers. Data owners may also specify access control policies such that only the users, who satisfy the policies, can access the data. Attribute based access control techniques are more suitable for the cloud environment as they cover large number of users coming from various domains. Multi-authority attribute-based encryption (MA-ABE) technique is one of the propitious attribute based access control technique, which allows data owner to enforce access policies on encrypted data. The main aim of this paper is to comprehensively survey various state-of-the-art MA-ABE schemes to explore different features such as attribute and key management techniques, access policy structure and its expressiveness, revocation of access rights, policy updating techniques, privacy preservation techniques, fast decryption and computation outsourcing, proxy re-encryption etc. Moreover, the paper presents feature-wise comparison of all the pertinent schemes in the field. Finally, some research challenges and directions are summarized that need to be addressed in near future.

양식장 환경 데이터 모니터링 및 예측 시스템의 설계 (Design of the Environmental Data Monitoring and Prediction System for the Fish Farms)

  • 리타 리자얀티;아쉬위니 카담;아리아 비스마 와휴타마;이본영;황민태
    • 한국정보통신학회:학술대회논문집
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    • 한국정보통신학회 2021년도 춘계학술대회
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    • pp.178-180
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    • 2021
  • 본 논문에서는 바다 환경의 변화로 인한 양식장의 피해를 막을 수 있도록 양식장의 환경 데이터를 실시간 모니터링하고 기계 학습 기반의 예측 서비스를 제공하는 시스템 설계를 다룬다. 제안 시스템은 양식장의 주요 위치에 수소 농도, 염도, 용존 산소량 그리고 수온을 측정할 수 있는 센서들로 구성되는 사물인터넷 기반의 디바이스 모듈을 설치하며, 이들로 부터 수집한 데이터는 LTE 또는 LoRa 통신 기술을 이용해 클라우드 DB로 전송한 후 웹사이트나 모바일 애플리케이션을 통해 실시간으로 양식장의 환경 데이터 모니터링을 가능하게 한다. 아울러 수집된 데이터를 활용한 기계학습 기반의 예측 기술을 적용해 양식장의 환경 변화에 미리 대비할 수 있도록 하는 기능을 가진다.

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