• Title/Summary/Keyword: KOH solution

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A Study on the Subcritical Crack Growth and the Life Prediction for Sintered Silicon Carbide (소결탄화규소의 완속균열성장 및 수명예측에 관한 연구)

  • 한원식;김영욱;이상호;장감용;이준근
    • Journal of the Korean Ceramic Society
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    • v.22 no.4
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    • pp.26-32
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    • 1985
  • The subcritical crack growth of sintered SiC is investigated under various corrosive atmospheres such as distilled water Murakami solution and saturated KOH solution. The KI-V diagrams are obtained by the load relaxation method and incremental displacement rate method using the double torsion technique. The obtained fracture mechanics parameters (n) of sintered SiC are 79 in Murakami solution and 39 in saturated KOH solution. These data indicate that the subcritical crack growth of sintered SiC is taking place in these two conditions and the stress-corrosion cracking is suggested to be the mechanism. With these KI-V diagrams the life of sintered SiC in these conditions is predicted.

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Microdrilling of Glass Substrates by Electrochmical Discarge Machining in NaOH Solutions (NaOH 수용액에 있어서 전기화화적 방전가공법에 의한 유리기판의 미세가공)

  • Hong, Seog-Woo;Che, Woo-Seong;Chio, Youngg-Kuy;Chung, Gwiy-Sang
    • Proceedings of the KIEE Conference
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    • 1998.07d
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    • pp.1500-1502
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    • 1998
  • Electro Discharge Machining (EDM) is a so-call nonconventional machining technique. This paper presents the experimental results of an EDM technique for the fabircation of microholes on #7440 pyrex glass substrates. With various applied voltages and various concentration of NaOH or KOH solution, the glass substrates have been microdrilled using the copper electrodes of which diameters are 250 ${\mu}m$ to 450 ${\mu}m$. The machined throughholes have been observed the top diameter, the bottom diameter and machining time have been measured. EDM in NaOH solution causes the fabrication to have better the surface condition, higher selective of electrode, lower concentration of solution with respect to EDM in KOH solution machined fabrication.

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Carbon Dioxide Capture and Carbonate Synthesis via Carbonation of KOH-Dissolved Alcohol Solution (KOH-알코올 용액의 탄산화를 통한 이산화탄소 포집 및 탄산염 합성)

  • Kim, Eung-Jun;Han, Sang-Jun;Wee, Jung-Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.11
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    • pp.597-606
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    • 2015
  • This work investigates the carbonation of KOH-dissolved methanol and ethanol solution systems carried out for $CO_2$ fixation. Potassium methyl carbonate (PMC) and potassium ethyl carbonate (PEC) were synthesized during the reaction in each solution as the solid powder, and they were characterized in detail. The amount of $CO_2$ chemically absorbed to produce the PMC and PEC precipitates were calculated to be 97.90% and 99.58% of their theoretical values, respectively. In addition, a substantial amount of $CO_2$ was physically absorbed in the solution during the carbonation. PMC precipitates were consisted of the pure PMC and $KHCO_3$ with the weight ratio of 5:5, respectively. PEC precipitates were also mixture of the pure PEC and $KHCO_3$ with the weight ratio of 8:2, respectively. When these two precipitates were dissolved in excess water, methanol and ethanol were regenerated remaining solid $KHCO_3$ in the solutions. Therefore, the process has the potential to be one of the efficient options of CCS and CCU technologies.

The Physical Properties and Dyeability of KOH Treated Cotton Fabrics (KOH 처리 면직물의 물성 및 염색성)

  • Song, Hyun-Joo;Kim, Su-Mi;Song, Wha-Soon
    • Fashion & Textile Research Journal
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    • v.7 no.1
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    • pp.91-95
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    • 2005
  • The purpose of this study is to investigate the improvement of fiber surface, physical properties and research the physical properties and dyeability of cotton fabrics treated with KOH solution at low and high temperature. The treatment conditions for mercerization with KOH were changed various temperatures(25, $90^{\circ}C$), concentrations(15, 20, 25, 30%. w/v) and times(30, 60, 180, 300sec). The effects of mercerization after KOH treatment estimated with tensile strength, tearing strength, shrinkage, drape stiffness, moisture regain, fiber surface, and dyeability. The optimal conditions were concentration of KOH 20%, time 180sec in low temperature and concentration of KOH 20%, time 60sec in high temperature. The results are as follows; Tensile strength, tearing strength and moisture regain were much improved than those of untreated cotton fabric. Shrinkage and drape stiffness of KOH treated cotton were more increased at $25^{\circ}C$ than $90^{\circ}C$. Fiber surface showed more rounded shape at $25^{\circ}C$ than $90^{\circ}C$. Dyeability of cotton fabrics improved by KOH treatment.

Pattern Fabrication on Si (100) Surface by Using Both Nanoscratch and KOH Etching Technique (나노스크래치와 KOH 에칭 기술을 병용한 Si (100) 패턴제작)

  • 윤성원;이정우;강충길
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2003.05a
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    • pp.448-451
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    • 2003
  • This study describes a new maskless nano-fabrication technique of Si (100) using the combination of nanometer-scale mechanical forming by nano-indenter XP and KOH wet etching. First the surface of a Si (100) specimen was machined by using the nano-machining system, which utilizes the mechanism of the nano-indenter XP. Next, the specimen was etched by KOH solution. After the etching process, the convex structure or deeper hole is made because of masking or promotion effect of the affected layer generated by nano-machining. On the basis of this interesting fact, some sample structures were fabricated.

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A study on the activation characteristics of multi-phase Zr-based hydrogen storage alloy for Ni-MH rechargeable battery (Ni-MH 2차전지용 다상의 Zr계 수소저장합금 전극의 활성화 특성에 관한 연구)

  • Lee, Ho;Jang, Kuk-Jin;Lee, Jai-Young
    • Transactions of the Korean hydrogen and new energy society
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    • v.8 no.4
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    • pp.161-171
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    • 1997
  • $AB_2$ type Zr-based Laves phase alloys have been studied for potential application as negative electrode in Ni/MH batteries. However, They have a serious disadvantage of poor activation behavior in KOH solution. In this work, a new method of alloy design method was tried for improving Zr-based alloy activation. this method has focused on phase controlling to make multi-phase microstructure. In the case of multi-phase Zr-V-Mn-Ni shows good performance in activation, but activation mechanism has not been known. So, we were in search of elucidating this mechanism, Using morphological and electrochemical analysis, we could find that surface morphology and electocatalytic activity of the alloy change during immersion in KOH solution. V-rich second phases are selectively corroded and dissolved and then become Ni-rich phases. Resulting from these surface reaction in KOH solution, self-hydrogen charging occurs through Ni-rich phase. However, the alloy has poor cyclic durability because of such a corrosion mechanism. Therefore, finally we developed durable alloys by substitution of other alloying element.

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Studies on the Germination Promotion of the Zoysia japonica seeds. (한국잔디(Zoysia japonica Steud.) 종자의 발아촉진에 관한 연구)

  • 전우방
    • Asian Journal of Turfgrass Science
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    • v.1 no.1
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    • pp.30-36
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    • 1987
  • In order to promote the germination of Korean lawn grass(Zoysia japonica Steud.) seeds a gravimetric seed selection with a mixed chemical solution and the germination promotion with KOH treatment were studied and following results were obtained. 1. When immersed into methanol(S.G., 0.7) 14 percent of immature seeds were precipitated. 2. With water (S.G., 1.0) 36.5 percent of mature seeds were submerged. 3. On a mixture of carbon tetrachloride (S.G., 1.6) and ethylether (S.G., 0.7) in a ratio of 4:6 the seed selection was most effective. 4. When treated with KOH solution the germination rate was 71.01 percent in contrast to 6.0 percent of germination without the treatment. 5. As for concentration of KQH solution, 15 percent depressed the germination (46.7 %) whereas above 20 % the germination rate was gradually increased (79.32 %) up to 40 percent of concentration where the concentration started to depress germination ratio (77.32 %). 6. Finally, in connection with the duration of KOH treatment, a time lapse of up to 20 minutes depressed the germinating ratio(70.02 %) and 30 minutes to 45 minutes increased this ratio to 94.52 percent. 60 minutes of treatment depressed the germination to 75.62 percent.

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Photo-assisted GaN wet-chemical Etching using KOH based solution (KOH계열 수용액을 이용한 GaN 박막의 photo-assisted 식각 특성)

  • Lee, Hyoung-Jin;Song, Hong-Ju;Choi, Hong-Goo;Ha, Min-Woo;Roh, Cheong-Hyun;Lee, Jun-Ho;Park, Jung-Ho;Hahn, Cheol-Koo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.339-339
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    • 2010
  • Photo-assisted wet chemical etching of GaN thin film was studied using KOH based solutions. A $2{\mu}m-2{\mu}m$ titanium line-and-space pattern was used as a etching mask. It is found that the etching characteristics of the GaN thin film is strongly dependent on the pattern direction by unisotropic property of KOH based solution. When the pattern was aligned to the [$11\bar{2}0$] directions, ($10\bar{1}n$)-facet is revealed constructing V-shaped sidewalls.

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Growth of zincite(ZnO) single crystal by hydrothermal method (수열법에 의한 산화아연(ZnO) 단결정 성장)

  • 이영국;유영문
    • Korean Journal of Crystallography
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    • v.7 no.2
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    • pp.183-190
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    • 1996
  • Single crystals of ZnO were grown hydrothermally with KOH solution in silver lined autoclave. The effect of LiOH and NH4OH on the morphology of as-grown crystals was studied. As-grown crystals were pale green and the maximum size was 30×30×20mm3. Addition of LiOH reduced the density of flaws on the (0001) face of as-grown ZnO crystals. In highly concentrated KOH solution, ZnO had a strong tendency to grow along the c-axis. When 1.0-2.0 M of NH4OH was added into mineralizer, growth rate along the direction of a-axis increased. From this result, ZnO single crystals of equant-faced hexagonal prism could be grown with acicular seeds.

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Manufacturing Large-scale SiNx EUV Pellicle with Water Bath (물중탕을 이용한 대면적 SiNx EUV 펠리클 제작)

  • Kim, Jung Hwan;Hong, Seongchul;Cho, Hanku;Ahn, Jinho
    • Journal of the Semiconductor & Display Technology
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    • v.15 no.1
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    • pp.17-21
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    • 2016
  • EUV (Extreme Ultraviolet) pellicle which protects a mask from contamination became a critical issue for the application of EUV lithography to high-volume manufacturing. However, researches of EUV pellicle are still delayed due to no typical manufacturing methods for large-scale EUV pellicle. In this study, EUV pellicle membrane manufacturing method using not only KOH (potassium hydroxide) wet etching process but also a water bath was suggested for uniform etchant temperature distribution. KOH wet etching rates according to KOH solution concentration and solution temperature were confirmed and proper etch condition was selected. After KOH wet etching condition was set, $5cm{\times}5cm$ SiNx (silicon nitride) pellicle membrane with 80% EUV transmittance was successfully manufactured. Transmittance results showed the feasibility of wet etching method with water bath as a large-scale EUV pellicle manufacturing method.