• Transactions of the Korean hydrogen and new energy society
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• v.25 no.5
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• pp.509-515
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• 2014

At the fuel processing system (FPS) of fuel cell vehicle, hydrogen recirculation blower (HRB) is used for the recirculation of remained hydrogen after reaction. In this paper, noise and vibration improvement of HRB is studied by changing design and control. It is checked the campbell diagram and critical speed for stability of rotor, and housing stiffness is improved using simulation of frequency response function (FRF). A method is suggested that can decrease the unbalance amount of the rotor and impeller which main source of noise and vibration. In order to reduce the noise during deceleration of blower, electrical braking is applied and tested the risk impact of durability. Founded the optimum switching frequency of the motor control, and reduced the idle rpm by increasing of aerodynamic performance. The superiority of paper is proved by measurement of the improved product's noise and vibration.

• Transactions of the Korean hydrogen and new energy society
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• v.25 no.5
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• pp.533-540
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• 2014

The remanufacturing industry for automotive parts is a major issue which affects the environment protection and CO2 reduction throughout the world. Beside this, remanufacturing technologies of worn-out diesel engines have been developing to make as close to new as possible. In this study, the characteristics of the engine-power output and exhaust emissions of remanufactured diesel engine by hydrogen enrichment are evaluated by measuring the engine and vehicle test. Moreover, with worn-out diesel engine and first generation common-rail engine, we compared by testing their characteristics, resulting in the restoration of engine-power output more than 93%, as well as marvelously reduces the THC and NOx emission. At a guess, high pressure injection of diesel increases fuel atomization characteristics with excellence combustion efficiency, resulting in reduction of THC emission. Also, rapid cooling of EGR decreases combustion temperature, resulting in reduction of NOx emission. Consequently, these remanufacturing for diesel engine enables worn-out diesel engine to have restoration to the original state. Simultaneously achieved 2 goals called that CO2 emission reduction and protection of environment by remanufacturing engine.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.3
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• pp.283-291
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• 2011

Polymer electrolyte membrane fuel cells (PEMFCs) use the bipolar plate of various materials between electrolyte and contact electrode for the stable hydrogen ion exchange activation. The bipolar plate of various materials has representatively graphite and stainless steel. Specially, stainless steels have advantage for low cost and high product rate. In this study, SUS 316 was effectively coated with 600 nm thick F-doped tin oxide (SnOx:F) by electron cyclotron resonance-metal organic chemical vapor deposition and investigated in simulated fuel cell bipolar plates. The results showed that an F-doped tin oxide (SnOx:F) coating enhanced the corrosion resistance of the alloys in fuel cell bipolar plates, though the substrate steel has a significant influence on the behavior of the coating. Coating SUS 316 for fuel cell bipolar plates steel further improved the already excellent corrosion resistance of this material. After coating, the increased ICR values of the coated steels compared to those of the fresh steels. The SnOx:F coating seems to add an additional resistance to the native air-formed film on these stainless steels.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.3
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• pp.380-385
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• 2011

$MgH_2$ was synthesized by hydriding chemical vapor deposition (HCVD). In this study, we examined the hydrogen storage property of $MgH_2$ synthesized by HCVD. The results of pressure-composition-temperature (PCT) measurement showed that the HCVDed $MgH_2$ reversibly absorbed hydrogen as much as 6 wt%. Each hydrogenation rate was very greater than the conventional alloy methods. The reason was that the particle size made by HCVD was small as approximately 1 ${\mu}m$. The PCT of $MgH_2$ made by HCVD methode was similar to a commercial $MgH_2$. The ${\Delta}H$ and ${\Delta}S$ value are respectively -76.8 $kJ/mol{\cdot}H_2$ and -137.4 $kJ/mol{\cdot}H_2$. Mg made by HCVD methode was activated easily than commercial Mg. Also the initial reaction rate was faster than that of commercial $MgH_2$. 70% of the total storage were stored during 400s.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.3
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• pp.386-401
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• 2011

Mathematical models for various steps in coal gasification reactions were developed and applied to investigate the effects of operation parameters on dynamic behavior of gasification process. Chemical reactions considered in these models were pyrolysis, volatile combustion, water shift reaction, steam-methane reformation, and char gasification. Kinetics of heterogeneous reactions between char and gaseous agents was based on Random pore model. Momentum balance and Stokes' law were used to estimate the residence time of solid particles (char) in an up-flow reactor. The effects of operation parameters on syngas composition, reaction temperature, carbon conversion were verified. Parameters considered here for this purpose were $O_2$-to-coal mass ratio, pressure of reactor, composition of coal, diameter of char particle. On the basis of these parametric studies some quantitative parameter-response relationships were established from both dynamic and steady-state point of view. Without depending on steady state approximation, the present model can describe both transient and long-time limit behavior of the gasification system and accordingly serve as a proto-type dynamic simulator of coal gasification process. Incorporation of heat transfer through heterogenous boundaries, slag formation and steam generation is under progress and additional refinement of mathematical models to reflect the actual design of commercial gasifiers will be made in the near futureK.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.3
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• pp.363-371
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• 2011

In this paper, a three-dimensional hydrogen desorption model is developed to precisely study the hydrogen desorption kinetics and resultant heat and mass transport phenomena in metal hydride hydrogen storage vessels. The metal hydride hydrogen desorption model, i.e. governed by the conservation of mass, momentum, and thermal energy is first experimentally validated against the temperature evolution data measured on a cylindrical $LaNi_5$ metal hydride vessel. The equilibrium pressure used for hydrogen desorption simulations is derived as a function of H/M atomic ratio and temperature based on the experimental data in the literature. The numerical simulation results agree well with experimental data and the 3D desorption model successfully captures key experimental trends during hydrogen desorption process. Both the simulation and experiment display an initial sharp decrease in the temperature mainly caused by relatively slow heat supply rate from the vessel external wall. On the other hand, the effect of heat supply becomes influential at the latter stages, leading to smooth increase in the vessel temperature in both simulation and experiment. This numerical study provides the fundamental understanding of detailed heat and mass transfer phenomena during hydrogen desorption process and further indicates that efficient design of storage vessel and heating system is critical to achieve fast hydrogen discharging performance.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.3
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• pp.409-414
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• 2011

To promote the industry of PEMFC, the commercialization of its parts especially bipolar plate is needed. The bipolar plate is one of key parts for PEMFC, which occupies cost portion of 5~8% in the system. To replace the bipolar plate of machined graphite highly costly, the stamped thin matal or the molded carbon composite has been developed. According to the merits and demerits of each material and its forming process, the stamped metallic plate has been considered to the bipolar plate of PEMFC for automotive, and on the other hand, the molded composite plate has been considered to one for building applications. Hankook Tire Co., Ltd. has developed the carbon composite material and the manufacturing process for the bipolar plates. The developed bipolar plates were proved to be fully applicable to PEMFC of building applications in characteristics and performance, and so government strategic project to develop the mass-production technology for bipolar plates was started and is being conducted by the company. Through the government project for obtaining both the commercialization technology and production capacity for the bipolar plates, the price and the performance of domestic PEMFCs are expected to become competitive in international market.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.3
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• pp.292-298
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• 2011

This study examines the effects of the ambient temperature (AT), methanol feeding temperature (MFT), methanol concentration (MC) and methanol flow rate (MFR) on the performance and cell temperature (CT) of a 5-stacked direct methanol fuel cell (DMFC). The AT, MFT, MC, and MFR are varied from $-10^{\circ}C$ to $+40^{\circ}C$, $50^{\circ}C$ to $90^{\circ}C$, 0.5M to 3.0M and 11.7 mL $min^{-1}$ to 46.8 mL $min^{-1}$, respectively. The performance of the DMFC under various operating conditions is analyzed from the I-V polarization curve, and the methanol crossover is estimated by gas chromatography (GC). The performance of the DMFC improves significantly with increasing AT. The open circuit voltage (OCV) decreases with increasing MC due to the enhanced likelihood of methanol crossover. The cell performance is improved significantly when the MFR is increased from 11.7 mL $min^{-1}$ to 28.08 mL $min^{-1}$. The change in cell performance is marginal with further increases in MFR. The CT increases significantly with increasing AT. The effect of the MFT and MFR is moderate, and the effect of MC is marginal on the CT of the DMFC.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.3
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• pp.333-339
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• 2011

In the present work, it was attempted to produce $H_2$ from food waste by the two-stage fermentation system. Food waste was acidified to lactate by using indigenous lactic acid bacteria under mesophilic condition, and the lactate fermentation effluent (LFE) was subsequently converted to $H_2$ by photo-fermentation. $Rhodobacter$ $sphaeroides$ KD131 was used as the photo-fermenting bacteria. The optimal conditions for lactate fermentation were found to be pH of 5.5 and substrate concentration of 30 g Carbo. COD/L, under which yielded 1.6 mol lactate/mol glucose. By filtering the LFE and adding trace metal, $H_2$ production increased by more than three times compared to using raw LFE, and finally reached the $H_2$ yield of 3.6 mol $H_2$/mol lactate. Via the developed two-stage fermentation system $H_2$ yield of 5.8 mol $H_2$/mol glucose was achieved from food waste, whose value was the highest that ever recorded.

• Transactions of the Korean hydrogen and new energy society
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• v.31 no.1
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• pp.82-88
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• 2020

Recently, a fuel reforming plant for supplying high purity hydrogen has been studied to increase the operation time of underwater weapon systems. Since steam reforming is an endothermic reaction, it is necessary to continuously supply heat to the reactor. A fuel reforming plant needs a methanol-O₂ catalytic burner to obtain heat and supply heat to the reformer. In this study, two types of designs of a catalytic burner are presented and the results are analyzed through the experiments. The design of the catalytic burner is divided into that the O₂ supply direction is perpendicular to the methanol flow direction (Design 1) and the same as the methanol flow direction (Design 2). In case of Design 1, backfire and flame combustion occurred in the mixing space in front of the catalyst, and in the absence of the mixing space, combustion reaction occurred only in a part of the catalyst. For above reasons, Design 1 could not increase the exhaust gas temperature to 750℃. In Design 2, no flashback and flame combustion were observed, the exhaust gas could be maintained up to 750℃. However, the O₂ distributor was exposed to high temperatures, resulting in thermal damage.