DOI QR코드

DOI QR Code

Characteristics of Methanol-O2 Catalytic Burner according to Oxidant Supply Method

산화제 공급 방법에 따른 메탄올-산소 촉매연소기 특성

  • Received : 2019.12.13
  • Accepted : 2020.02.28
  • Published : 2020.02.28

Abstract

Recently, a fuel reforming plant for supplying high purity hydrogen has been studied to increase the operation time of underwater weapon systems. Since steam reforming is an endothermic reaction, it is necessary to continuously supply heat to the reactor. A fuel reforming plant needs a methanol-O2 catalytic burner to obtain heat and supply heat to the reformer. In this study, two types of designs of a catalytic burner are presented and the results are analyzed through the experiments. The design of the catalytic burner is divided into that the O2 supply direction is perpendicular to the methanol flow direction (Design 1) and the same as the methanol flow direction (Design 2). In case of Design 1, backfire and flame combustion occurred in the mixing space in front of the catalyst, and in the absence of the mixing space, combustion reaction occurred only in a part of the catalyst. For above reasons, Design 1 could not increase the exhaust gas temperature to 750℃. In Design 2, no flashback and flame combustion were observed, the exhaust gas could be maintained up to 750℃. However, the O2 distributor was exposed to high temperatures, resulting in thermal damage.

Keywords

References

  1. A. Psoma and G. Sattler, "Fuel cell systems for submarines: from the first idea to serial production", J. Power Sources, Vol. 106, No. 1-2, 2002, pp. 381-383, doi: https://doi.org/10.1016/S0378-7753(01)01044-8.
  2. S. Krummrich and J. Llabres, "Methanol reformer - the next milestone for fuel cell powered submarines", Int. J. Hydrogen Energy, Vol. 40, No. 15, 2015, pp. 5482-5486, doi: https://doi.org/10.1016/j.ijhydene.2015.01.179.
  3. "HDW, SENER develop methanol reformer for fuel cell submarines", Fuel Cells Bulletin, Vol. 2012, No. 12, 2012, pp. 2, doi: https://doi.org/10.1016/S1464-2859(12)70342-5.
  4. "UTC power to develop fuel cell for Spanish sub", Fuel Cells Bulletin, Vol. 2008, No. 1, 2008, pp. 4, doi: https://doi.org/10.1016/S1464-2859(08)70009-9.
  5. H. J. Ji, J. H. Lee, E. Y. Choi, and I. S. Seo, "Hydrogen production from steam reforming using an indirect heating method", Int. J. Hydrogen Energy, Vol. 43, No. 7, 2018, pp. 3655-3663, doi: https://doi.org/10.1016/j.ijhydene.2017.12.137.
  6. U. R. Cheon, K. S. Ahn, and H. K. Shin, "Study on the characteristics of methanol steam reformer using latent heat of steam", Trans. of the Korean Hydrogen and New Energy Society, Vol. 29, No. 1, 2018, pp. 19-24, doi: https://doi.org/10.7316/KHNES.2018.29.1.19.
  7. H. J. Ji, E. Y. Choi, and J. H. Lee, "Optimal operation condition of pressurized methanol fuel processor for underwater environment", Trans. of the Korean Hydrogen and New Energy Society, Vol. 27, No. 5, 2016, pp. 485-493, doi: http://dx.doi.org/10.7316/KHNES.2016.27.5.485.
  8. H. J. Ji, K. D. Baik, S. H. Yang, and S. K. Jung, "Start-up strategy of multi-stage burner for methanol fuel reforming plant", Trans. of the Korean Hydrogen and New Energy Society, Vol. 30, No. 3, 2019, pp. 201-208, doi: http://dx.doi.org/10.7316/KHNES.2019.30.3.201.
  9. T. Ghang, Y. Kim, S. Lee, and K. Ahn, "An experimental study on the performances of a coupled reactor with catalytic combustion and steam reforming for SOFC and MCFC", Trans. of the Korean Hydrogen and New Energy Society, Vol. 25, No. 4, 2014, pp. 364-377, doi: https://doi.org/10.7316/KHNES.2014.25.4.364.
  10. T. G. Ghang, H. J. Sung, S. M. Lee, K. Y. Ahn, and Y. M. Kim, "Performance comparison of integrated reactor with steam reforming and catalytic combustion using anode off-gas for high temperature fuel cells", Trans. of the Korean Hydrogen and New Energy Society, Vol. 22, No. 6, 2011, pp. 800-809, doi: https://doi.org/10.7316/KHNES.2011.22.6.800.
  11. S. M. Lee, Y. H. Lee, K. Y. Ahn, and S. S. Yu, "Performance analysis of off-gas/syngas combustor for thermal management of high temperature fuel cell systems", Trans. of the Korean Hydrogen and New Energy Society, Vol. 21, No. 3, 2010, pp. 193-200. Retrieved from http://www.koreascience.or.kr/article/JAKO201030853092575.page.
  12. S. M. Lee, Y. D. Lee, K. Y. Ahn, D. J. Hong, and M. Y. Kim, "A study on the design of MCFC off-gas catalytic combustor", Trans. of the Korean Hydrogen and New Energy Society, Vol. 18, No. 4, 2007, pp. 406-412. Retrieved from http://www.koreascience.or.kr/article/JAKO200710736976340.page.
  13. H. J. Ji, J. M. Bae, S. B. Cho, and I. Y. Kang, "Start-up strategy and operational tests of gasoline fuel processor for auxiliary power unit", Int. J. Hydrogen Energy, Vol. 40, No. 11, 2015, pp. 4101-4110, doi: https://doi.org/10.1016/j.ijhydene.2015.01.157.
  14. H. J. Ji and S. B. Cho, "Steam-to-carbon ratio control strategy for start-up and operation of a fuel processor", Int. J. Hydrogen Energy, Vol. 42, No. 15, 2017, pp. 9696-9706, doi: https://doi.org/10.1016/j.ijhydene.2017.01.153.
  15. Methanol Institute, "Methanol safe handling manual, 4th edition", 2017, pp. 253. Retrieved from http://www.methanol.org/wp-content/uploads/2017/03/Safe-Handling-Manual.pdf.