• 제목/요약/키워드: K3 surface

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Effects of Plasma Surface Treatments Using Dielectric Barrier Discharge to Improve Diamond Films

  • Kang, In-Je;Ko, Min-Guk;Rai, Suresh;Yang, Jong-Keun;Lee, Heon-Ju
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.552-552
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    • 2013
  • In our study we consider Al2O3 ceramic substrates for Plasma Surface Treatments in order to improve deposited diamond surface and increase diamond deposition rate by applying DBD (Dielectric Barrier Dischrge) system. Because Plasma Surface Treatments was used as a modification method of material surface properties like surface free energy, wettability, and adhesion. By applying Plasma Surface Treatments diamond films are deposited on the Al2O3 ceramic substrates. DC Arc Plasmatron with mathane and hydrogen gases is used. Deposited diamond films are investigated by SEM (Scanning Electron Microscopy), AFM (Atomic Force Microscopy) and XRD (X-ray Diffractometer). Then the C-H stretching of synthetic diamond films by FTIR (Fourier Transform Infrared Spectroscopy) is studied. As a result, nanocrystalline diamond films were identified by using SEM and diamond properties in XRD peaks at (111, $43.8{\Box}$, (220, $75.3{\Box}$ and (311, $90.4{\Box}$ were shown. Absorption peaks in FTIR spectrum, caused by CHx sp3 bond stretching of CVD diamond films, were identified as well. Finally, we improved such parameters as depostion rate ($2.3{\mu}m$/h), diamond surface uniformity, and impurities level by applying Plasma Surface Treatments. These experimental results show the importance of Plasma Surface Treatments for diamond deposition by a plasma source.

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알칼리 표면개질을 통한 메조포러스 알루미늄 하이드록사이드 필름 형성 기구 (Formation Mechanism of Mesoporous Aluminum Hydroxide Film by Alkali Surface Modification)

  • 서영익;전용진;이영중;김대건;이규환;김영도
    • 한국재료학회지
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    • 제20권2호
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    • pp.97-103
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    • 2010
  • In this study, a new, relatively simple fabrication method for forming a mesoporous $Al(OH)_3$ film on Al substrates was demonstrated. This method, i.e., alkali surface modification, was simply comprised of dipping the substrate in a $5\times10^{-3}$ M NaOH solution at $80^{\circ}C$ for one minute and then immersing it in boiling water for 30 minutes. After alkali surface modification, a mesoporous $Al(OH)_3$ film was formed on the Al substrate, and its chemical state and crystal structure were confirmed by XPS and TEM. According to the results of the XPS analysis, the flake-like morphology after the alkali surface modification was mainly composed of $Al(OH)_3$, with a small amount of $Al_2O_3$. The mesoporous $Al(OH)_3$ layer was composed of three regions: an amorphousrich region, a region of mixed amorphous and crystal domains, and a crystalline-rich region near the $Al(OH)_3$ layer surface. It was confirmed that the stabilization process in the alkali surface modification strongly influenced the crystallization of the mesoporous $Al(OH)_3$ layer.

리륨이차전지용 $LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$ 양극활물질의 표면개질에 따른 전지특성 (Cell Performances of Surface-Treated $LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$ Material for Li Secondary Battery)

  • 김현수;공명철;김기택;문성인
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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    • pp.294-295
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    • 2007
  • $LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$ material was surface modified with Zr-phosphate. Scanning electron microscope, energy dispersive spectroscopy and electrochemical studies indicate that surface modification improve the rate capability. Electrochemical studies were performed by assembling 2032 coin cells with lithium metal as an anode.

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수복용복합레진의 표면처리방법에 따른 표면중합률 및 변색정도의 변화와 그 상관관계에 대한 연구 (THE CHANGE IN SURFACE CONVERSION AND DISCOLORATION IN DENTAL RESTORATIVE COMPOSITE RESIN UNDER DIFFERENT POLISHING METHODS; THE CORRELATION BETWEEN SURFACE CONVERSION AND SURFACE DISCOLORATION)

  • 박성호;노병덕;김모란;안현정
    • Restorative Dentistry and Endodontics
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    • 제25권3호
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    • pp.482-486
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    • 2000
  • The purpose of the present study was first, to evaluate the relationship between composite surface conversion and surface discoloration, second, to know if there was difference in surface discoloration between celluloid-strip-finished composite surface and polished surface. In addition, the discoloration of composite surface was also evaluated with visual inspection or digital camera with high resolution monitor, Z100, Tetric Ceram, Spectrum, and Aelitfil were used. The composite surfaces were celluloid-strip finished (group 1), polished (group 2), celluloid-strip finished under nitrogen gas purging (group 3) or only light cured without finishing or polishing under nitrogen gas purging (group 4). The microhardness of each samples were also measured in each group. The samples of each group were also divided into 4 subgroup whether they were immediately placed in disclosing solution (0.2% Elythrosin, pH 7.0) (subgroup1), 1 day after light curing(subgroup 2), 3day after light curing(subgroup 3) or 7 day after light curing(subgroup 4). The computer controlled spectrophotometer was used to determine CIELAB coordinates ($L^*$, $a^*$, $b^*$). The amounts of color difference were compared. The results were as follows; 1. There was no difference in discoloration between celluloid strip finished composite surface and polished surface. 2. The samples discolored more when they were placed in disclosing solution immediately after polymerization than other groups. 3. When the samples were light cured under nitrogen gas purging and without polishing process, they discolored more than other groups even though they showed higher micro hardness. 4. With visual inspection or digital camera, only a limited information was available in detecting composite surface discoloration.

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스피넬 페라이트의 비이완 표면에너지 계산 (Calculating of the Unrelaxed Surface Energy of Spinel Ferrites)

  • 신형섭;손정호
    • 한국재료학회지
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    • 제25권12호
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    • pp.713-718
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    • 2015
  • A new method is proposed for the calculation of the unrelaxed surface energy of spinel ferrite. The surface energy calculation consists of (1) setting the central and computational domains in the semi-infinite real lattice, having a specific surface, and having an infinite real lattice; (2) calculation of the lattice energies produced by the associated portion of each ion in the relative domain; and (3) dividing the difference between the semi-infinite lattice energy and the infinite lattice energy on the exposed surface area in the central domain. The surface energy was found to converge with a slight expansion of the domain in the real lattice. This method is superior to any other so far reported due to its simple concept and reduced computing burden. The unrelaxed surface energies of the (100), (110), and (111) of $ZnFe_2O_4$ and $Fe_3O_4$ were evaluated by using in the semi-infinite real lattices containing only one surface. For the normal spinel $ZnFe_2O_4$, the(100), which consisted of tetrahedral coordinated $Zn^{2+}$ was electrostatically the most stable surface. But, for the inverses pinel $Fe_3O_4$, the(111), which consisted of tetrahedral coordinated $Fe^{3+}$ and octahedral coordinated $Fe^{2+}$ was electrostatically the most stable surface.

Comparison of surface roughness effects upon the attachment of osteoblastic progenitor MC3T3-E1 cells and inflammatory RAW 264.7 cells to a titanium disc

  • Noh, Se-Ra;Im, Tae-Yoon;Lee, Eun-Young;Jang, Ha-Na;Dung, Tran D.;Kim, Myung-Soo;Yoo, Hoon
    • International Journal of Oral Biology
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    • 제34권1호
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    • pp.37-42
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    • 2009
  • The attachment and adhesion of RAW 264.7 and MC3T3-E1 cells to titanium (Ti) discs with various degrees of roughness was investigated. The attachment, adhesion, and proliferation of these cells were evaluated after 4 hr, 24 hr and 7 day incubations. Both RAW 264.7 and MC3T3-E1 cells showed a time-dependant correlation between attachment and adhesion on the surface of the titanium discs. Both types of cells tended to have higher survival rate on these discs as the surface roughness increased. The percentage of adherent inflammatory RAW 264.7 cells was greater than MC3T3-E1 cells at 24 hr, but this was reversed at 7 days in culture. The morphology of osteoblastic MC3T3-E1 cells at 24 hr, determined using a surface emission microscope (SEM), appeared flattened and spread out while inflammatory RAW 264.7 cells were predominantly spherical in shape. The adhesion of both cell types on the titanium discs was dependant on the levels of fibronectin adsorbed on the disc surface, indicating that serum constituents modulate the efficient adhesion of these cells. Our data indicate that the cellular response to the titanium surface is dependent on the types of cells, surface roughness and serum constituents.

Development of Digital Surface Model and Feature Extraction by Integrating Laser Scanner and CCD sensor

  • Nagai, Masahiko;Shibasaki, Ryosuke;Zhao, Huijing;Manandhar, Dinesh
    • 대한원격탐사학회:학술대회논문집
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    • 대한원격탐사학회 2003년도 Proceedings of ACRS 2003 ISRS
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    • pp.859-861
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    • 2003
  • In order to present a space in details, it is indispensable to acquire 3D shape and texture simultaneously from the same platform. 3D shape is acquired by Laser Scanner as point cloud data, and texture is acquired by CCD sensor. Positioning data is acquired by IMU (Inertial Measurement Unit). All the sensors and equipments are assembled on a hand-trolley. In this research, a method of integrating the 3D shape and texture for automated construction of Digital Surface Model is developed. This Digital Surface Model is applied for efficient feature extraction. More detailed extraction is possible , because 3D Digital Surface Model has both 3D shape and texture information.

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전역 변형을 갖는 활성곡면을 사용한 모델 적합 (Model Fitting using an Active Surface with Global Detormations)

  • 김동근;최증원;황치정
    • 한국정보처리학회논문지
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    • 제4권3호
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    • pp.792-801
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    • 1997
  • 본 논문에서는 전역 변형을 갖는 활성 곡면을 사용하여 잡음으로 오염된 데이터를 곡면으로 적합하는 알고리즘을 제안하였다. 이것은 2차원 곡선 모델에서 이전에 연구 [11,12]된 알고리즘의 3차원 곡면으로의 확정이다. 제안된 방법에서는 유한 차분을 사용하며, 각 노드점에서 주위의 외부힘을 사용하여 부분적으로 수축 또는 팽챙을 허용하는 balloon 모델[2,3]에 기반으로 진행하는 동안 곡면의 모양을 전역 변형 후의 곡면으로의 전역 변환이 결정적 최소 자승법에 의하여 계산되고, 마지막으로 전역 변환을 변형 전의 곡면에 적용한다. 실험에서 아핀변형을 갖는 활성 곡면을 사용하여 잡음으로 오염된 데이터를 곡면(타원체, B스플라인)으로 적합하였다.

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금강하구 표층퇴적물의 지화학적 특성에 관한 연구 (Geochemical Characteristics of Surface Sediments in the Keum River Estuary Adjacent to Coastal Area)

  • 서만석;박영석
    • 수산해양교육연구
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    • 제19권1호
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    • pp.1-7
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    • 2007
  • The purpose of this study was to investigate geochemical characteristics of surface sediments in the Keum river estuary adjacent to coastal area. For this study we collected the 21 surface sediments samples. Mean size of surface samples was $3.24{\sim}6.65{\phi}$ on inner estuary and was $2.15{\sim}3.42{\phi}$ on outside estuary. Surface samples were composed of silt on inner estuary and were composed of sand which was more larger than $4{\phi}$ on outside estuary. Most major elements except CaO, $Na_2O$ showed good relationships between variation of contents and grain size. Contents of $Al_2O_3$, $Fe_2O_3$, MgO, $K_2O$, $TiO_2$, $P_2O_5$ and $M_nO$ were increased predominately owing to the variation of mean size of surface samples. Contents of Co, Cr, Cu, Li, Sr, Zn, La, Ce, Pb, Rb, Nd have a good relationships with grain size but Ba, Th, Sm have not. All of major and minor elements contents except $K_2O$ and Ba were less than world mean contents of shallow surface sediments but apprehend a high pollution possibility on silt sediments in the estuaries.

Derivation of a Simplified Measure of Slope Rotatability for a Particular Class of Response Surface Designs

  • Kim, Hyuk Joo;Park, Sung Hyun;Kim, Tae-Sung
    • Communications for Statistical Applications and Methods
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    • 제11권3호
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    • pp.563-574
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    • 2004
  • Slope rotatability of response surface designs is a desirable property when we are interested in estimating slopes of response surfaces. In this paper, we derive a simplified measure of slope rotatability from new viewpoints for response surface designs that are frequently used in response surface methodology.