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Crystal Characteristics of 3C-SiC Thin-films Grown on 2 inch Si(100) wafer (2 inch Si(100)기판위에 성장된 3C-SiC 박막의 결정특성)

  • Chung, Su-Young;Chung, Yun-Sik;Ryu, Ji-Goo;Chung, Gwiy-Sang;Shigehiro, Nishino
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.452-455
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    • 2002
  • Single crystal 3C-SiC(cubic silicon carbide) thin-films were deposited on Si(100) substrate up to a thickness of $4.3{\mu}m$ by APCVD method using HMDS(hexamethyildisilane) at $1350^{\circ}C$. The HMDS flow rate was 0.5 sccm and the carrier gas flow rate was 2.5 slm. The HMDS flow rate was important to get a mirror-like crystal surface. The growth rate of the 3C-SiC films was $4.3{\mu}m/hr$. The 3C-SiC epitaxical films grown on Si(100) were characterized by XRD, AFM, RHEED, XPS and raman scattering, respectively. The 3C-SiC distinct phonons of TO(transverse optical) near $796cm^{-1}$ and LO(longitudinal optical) near $974{\pm}1cm^{-1}$ were recorded by raman scattering measurement. The heteroepitaxially grown films were identified as the single crystal 3C-SiC phase by XRD spectra$(2{\theta}=41.5^{\circ})$.

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A RESULT ON AN OPEN PROBLEM OF LÜ, LI AND YANG

  • Majumder, Sujoy;Saha, Somnath
    • Bulletin of the Korean Mathematical Society
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    • v.58 no.4
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    • pp.915-937
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    • 2021
  • In this paper we deal with the open problem posed by Lü, Li and Yang [10]. In fact, we prove the following result: Let f(z) be a transcendental meromorphic function of finite order having finitely many poles, c1, c2, …, cn ∈ ℂ\{0} and k, n ∈ ℕ. Suppose fn(z), f(z+c1)f(z+c2) ⋯ f(z+cn) share 0 CM and fn(z)-Q1(z), (f(z+c1)f(z+c2) ⋯ f(z+cn))(k) - Q2(z) share (0, 1), where Q1(z) and Q2(z) are non-zero polynomials. If n ≥ k+1, then $(f(z+c_1)f(z+c_2)\;{\cdots}\;f(z+c_n))^{(k)}\;{\equiv}\;{\frac{Q_2(z)}{Q_1(z)}}f^n(z)$. Furthermore, if Q1(z) ≡ Q2(z), then $f(z)=c\;e^{\frac{\lambda}{n}z}$, where c, λ ∈ ℂ \ {0} such that eλ(c1+c2+⋯+cn) = 1 and λk = 1. Also we exhibit some examples to show that the conditions of our result are the best possible.

Water Vapor Adsorption and Hydrogen Peroxide Decomposition on Date Pit Carbonization Products

  • Youssef, A.M.;El-Nabarawy, Th.;Ahmed, S.A. Sayed;Rashwan, W.E.
    • Carbon letters
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    • v.6 no.4
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    • pp.227-233
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    • 2005
  • Carbonization products C1, C2, C3, C4 and C5 were prepared by the carbonization of date pit in limited air, at 500, 600, 700, 800 and $1000^{\circ}C$, respectively. C1-V-600, C3-V-600, C1-V-1000 and C3-V-1000 were prepared by thermal treatment of C1 and C3 under vacuum at 600 and $1000^{\circ}C$. The textural properties were determined from nitrogen adsorption at 77 K and from carbon dioxide adsorption at 298 K. The surface pH, the FTIR spectra and the acid and base neutralization capacities of some carbons were investigated. The amounts of surface oxygen were determined by out-gassing the carbon-oxygen groups on the surface as $CO_2$ and CO. The adsorption of water vapor at 308 K on C1, C2, C3 and C4 was measured and the decomposition of $H_2O_2$ at 308 K was also investigated on C1, C2, C3, C4 and C5. The surface area and the total pore volume decreased with the rise of the carbonization temperature from 500 to $1000^{\circ}C$. The adsorption of water vapor is independent on the textural properties, while it is related to the amount of acidic carbon-oxygen groups on the surface. The catalytic activity of $H_2O_2$ decomposition does not depend on the textural properties, but directly related to the amount of basic carbon-oxygen complexes out-gassed as CO, at high temperatures.

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Properties of SiC-$ZrB_2$ Electroconductive Ceramic Composites by Spark Plasma Sintering (방전플라즈마 소결에 의한 SiC-$ZrB_2$ 도전성 세라믹 복합체 특성)

  • Shin, Yong-Deok;Ju, Jin-Young;Jo, Sung-Man;Lee, Jung-Hoon;Kim, Cheol-Ho;Lee, Hee-Seung
    • Proceedings of the KIEE Conference
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    • 2009.07a
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    • pp.1252_1253
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    • 2009
  • The composites were fabricated by adding 0, 15, 20, 25[vol.%] Zirconium Diboride(hereafter, $ZrB_2$) powders as a second phase to Silicon Carbide(hereafter, SiC) matrix. The physical, mechanical and electrical properties of electroconductive SiC ceramic composites by spark plasma sintering(hereafter, SPS) were examined. Reactions between $\beta$-SiC and $ZrB_2$ were not observed in the XRD analysis The relative density of mono SiC, SiC+15[vol.%]$ZrB_2$, SiC+20[vol.%]$ZrB_2$ and SiC+25[vol.%]$ZrB_2$ composites are 90.97[%], 74.62[%], 77.99[%] and 72.61[%] respectively. The XRD phase analysis of the electroconductive SiC ceramic composites reveals high of SiC and $ZrB_2$ and low of ZrO2 phase. The electrical resistivity of mono SiC, SiC+15[vol.%]$ZrB_2$, SiC+20[vol.%]$ZrB_2$ and SiC+25[vol.%]$ZrB_2$ composites are $4.57{\times}10^{-1}$, $2.13{\times}10^{-1}$, $1.53{\times}10^{-1}$ and $6.37{\times}10^{-2}[{\Omega}{\cdot}cm]$ at room temperature, respectively. The electrical resistivity of mono SiC, SiC+15[vol.%]$ZrB_2$, SiC+20[vol.%]$ZrB_2$ and SiC+25[vol.%]$ZrB_2$ are Negative Temperature Coefficient Resistance(hereafter, NTCR) in temperature ranges from 25[$^{\circ}C$] to 100[$^{\circ}C$]. It is convinced that SiC+20[vol.%]$ZrB_2$ composite by SPS can be applied for heater above 1000[$^{\circ}C$].

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The Analysis of Vitamin C Concentration in Organs of $Gulo^{-/-}$ Mice Upon Vitamin C Withdrawal

  • Kim, Hye-Min;Bae, Se-Yeon;Yu, Yeon-Sil;Kim, Ye-Jin;Kim, Hang-Rae;Hwang, Young-Il;Kang, Jae-Seung;Lee, Wang-Jae
    • IMMUNE NETWORK
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    • v.12 no.1
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    • pp.18-26
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    • 2012
  • Background: Vitamin C is an essential nutrient for maintaining human life. Vitamin C insufficiency in the plasma is closely related with the development of scurvy. However, in vivo kinetics of vitamin C regarding its storage and consumption is still largely unknown. Methods: We used $Gulo^{-/-}$ mice, which cannot synthesize vitamin C like human. Vitamin C level in plasma and organs from $Gulo^{-/-}$ mice was examined, and it compared with the level of wild-type mice during 5 weeks. Results: The significant weight loss of $Gulo^{-/-}$ mice was shown at 3 weeks after vitamin C withdrawal. However, there was no differences between wild-type and vitamin C-supplemented $Gulo^{-/-}$ mice (3.3 g/L in drinking water). The concentration of vitamin C in plasma and organs was significantly decreased at 1 week after vitamin C withdrawal. Vitamin C is preferentially deposited in adrenal gland, lymph node, lung, and brain. There were no significant changes in the numbers and CD4/CD8 ratio of splenocytes in $Gulo^{-/-}$ mice with vitamin C withdrawal for 4 weeks. And the architecture of spleen in $Gulo^{-/-}$ mice was disrupted at 5 weeks after vitamin C withdrawal. Conclusion: The vitamin C level of $Gulo^{-/-}$ mice was considerably decreased from 1 week after vitamin C withdrawal. Vitamin C is preferentially stored in some organs such as brain, adrenal gland and lung.

Conservation status assessment of archaeological bone from Fourier Transform Infrared Spectroscopy and histological Analysis (적외선 분광 분석과 조직 분석을 통한 출토 인골의 보존 상태 평가)

  • Lee, Jeongwon;Kim, Sue Hoon;Kim, Yun-Ji;Cho, Eun Min;Kang, Soyeong
    • 보존과학연구
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    • s.35
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    • pp.87-98
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    • 2014
  • Fourier transform infrared spectroscopy(FTIR-ATR) was applied to chemical analysis for conservation status of 10 human bone remains from Joseon Dynasty. The result of crystallinity index (CI) is $4.25{\pm}0.78$, carbonate to carbonate ratio (C/C) is $0.91{\pm}0.04$ and cabonate content (C/P) is $0.19{\pm}0.06$. The higher histological index (HI) confirmed CI and C/P value was increased and C/C value was reduced. While C/C or C/P values analysis is possible. While DNA analysis can be extracted from the bone, C/C values are lower or C/P values are higher was found to the analysis is possible. Chemical assessment of FTIR and histological index consequence is expected to be applicable as a basis for comprehensive understanding of the conservation status excavated bones.

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Preparation of minor ginsenosides C-Mc, C-Y, F2, and C-K from American ginseng PPD-ginsenoside using special ginsenosidase type-I from Aspergillus niger g.848

  • Liu, Chun-Ying;Zhou, Rui-Xin;Sun, Chang-Kai;Jin, Ying-Hua;Yu, Hong-Shan;Zhang, Tian-Yang;Xu, Long-Quan;Jin, Feng-Xie
    • Journal of Ginseng Research
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    • v.39 no.3
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    • pp.221-229
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    • 2015
  • Background: Minor ginsenosides, those having low content in ginseng, have higher pharmacological activities. To obtain minor ginsenosides, the biotransformation of American ginseng protopanaxadiol (PPD)-ginsenoside was studied using special ginsenosidase type-I from Aspergillus niger g.848. Methods: DEAE (diethylaminoethyl)-cellulose and polyacrylamide gel electrophoresis were used in enzyme purification, thin-layer chromatography and high performance liquid chromatography (HPLC) were used in enzyme hydrolysis and kinetics; crude enzyme was used in minor ginsenoside preparation from PPD-ginsenoside; the products were separated with silica-gel-column, and recognized by HPLC and NMR (Nuclear Magnetic Resonance). Results: The enzyme molecular weight was 75 kDa; the enzyme firstly hydrolyzed the C-20 position 20-O-${\beta}$-D-Glc of ginsenoside Rb1, then the C-3 position 3-O-${\beta}$-D-Glc with the pathway $Rb1{\rightarrow}Rd{\rightarrow}F2{\rightarrow}C-K$. However, the enzyme firstly hydrolyzed C-3 position 3-O-${\beta}$-D-Glc of ginsenoside Rb2 and Rc, finally hydrolyzed 20-O-L-Ara with the pathway $Rb2{\rightarrow}C-O{\rightarrow}C-Y{\rightarrow}C-K$, and $Rc{\rightarrow}C-Mc1{\rightarrow}C-Mc{\rightarrow}C-K$. According to enzyme kinetics, $K_m$ and $V_{max}$ of Michaelis-Menten equation, the enzyme reaction velocities on ginsenosides were Rb1 > Rb2 > Rc > Rd. However, the pure enzyme yield was only 3.1%, so crude enzyme was used for minor ginsenoside preparation. When the crude enzyme was reacted in 3% American ginseng PPD-ginsenoside (containing Rb1, Rb2, Rc, and Rd) at $45^{\circ}C$ and pH 5.0 for 18 h, the main products were minor ginsenosides C-Mc, C-Y, F2, and C-K; average molar yields were 43.7% for C-Mc from Rc, 42.4% for C-Y from Rb2, and 69.5% for F2 and C-K from Rb1 and Rd. Conclusion: Four monomer minor ginsenosides were successfully produced (at low-cost) from the PPD-ginsenosides using crude enzyme.

HOMOGENEOUS $C^*$-ALGEBRAS OVER A SPHERE

  • Park, Chun-Gil
    • Journal of the Korean Mathematical Society
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    • v.34 no.4
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    • pp.859-869
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    • 1997
  • It is shown that for $A_{k, m}$ a k-homogeneous $C^*$-algebra over $S^{2n - 1} \times S^1$ such that no non-trivial matrix algebra can be factored out of $A_{k, m}$ and $A_{k, m} \otimes M_l(C)$ has a non-trivial bundle structure for any positive integer l, we construct an $A_{k, m^-} C(S^{2n - 1} \times S^1) \otimes M_k(C)$-equivalence bimodule to show that every k-homogeneous $C^*$-algebra over $S^{2n - 1} \times S^1)$. Moreover, we prove that the tensor product of the k-homogeneous $C^*$-algebra $A_{k, m}$ with a UHF-algebra of type $p^\infty$ has the tribial bundle structure if and only if the set of prime factors of k is a subset of the set of prime factors of pp.

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ON SOME PROPERTIES OF BOUNDED HOMOMORPHISMS AND DERIVATIONS OF A C*-ALGEBRA

  • Nagisa, Masaru;Nam, Young-Man
    • East Asian mathematical journal
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    • v.4
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    • pp.1-13
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    • 1988
  • We consider some properties of the completely bounded representations of C*-algebras. We discuss the relation between the k-similarity and the property $D_k$ and get the result every k-similar C*-algebra has property $D_k$. Moreover we determine the similarity problem for the algebra C$\bigoplus$C precisely and constructively.

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