• Title/Summary/Keyword: Iron-acetate

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Dyeing properties of Gardenia on Han Jee (치자를 이용한 한지의 염색성)

  • 김애순
    • Journal of the Korean Society of Clothing and Textiles
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    • v.25 no.8
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    • pp.1493-1499
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    • 2001
  • This paper investigated the dyeabiltiy and surface color of Han Jee dyed with Gardenia extract after mordanted with mordants under the various dyeing conditions. The results obtained were as follows 1) λmax of the dyeing Han Jee dyed with Gardenia appeared at 660 and 710nm. 2)K/s value of dyeing Han Jee was increased when dyeing condition, temperature, time was higher. 3) Surface color of Han Jee with mordants changed differently according to the mordants used : 3.2Y by Aluminum acetate, 2.0GY by Copper sulfate, 9.5YR by Iron sulfate. 3.4Y by Tin chloride, and 4.5Y by non-mordanting.

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Characterization of Microbial Diversity of Metal-Reducing Bacteria Enriched from Groundwater and Reduction/Biomineralization of Iron and Manganese (KURT 지하심부 지하수 내 토착 금속환원미생물의 종 다양성 및 철/망간의 환원과 생광물화작용)

  • Kim, Yumi;Oh, Jong-Min;Jung, Hea-Yeon;Lee, Seung Yeop;Roh, Yul
    • Economic and Environmental Geology
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    • v.47 no.4
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    • pp.431-439
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    • 2014
  • The purposes of this research were to investigate the enrichment of metal-reducing bacteria from KURT groundwater and the identification of the microbial diversity by 16S rRNA as well as to examine microbial Fe(III)/Mn(IV) reduction and to analyze morphological features of interactions between microbes and precipitates and their mineralogical composition. To cultivate metal-reducing bacteria from groundwater sampled at the KURT in S. Korea, different electron donors such as glucose, acetate, lactate, formate, pyruvate and Fe(III)-citrate as an electron accepter were added into growth media. The enriched culture was identified by 16S rRNA gene sequence analysis for the diversity of microbial species. The effect of electron donors (i.e., glucose, acetate, lactate, formate, pyruvate) and electron acceptors (i.e., akaganeite, manganese oxide) on microbial iron/manganese reduction and biomineralization were examined using the 1st enriched culture, respectively. SEM, EDX, and XRD analyses were used to determine morphological features, chemical composition of microbes and mineralogical characteristics of the iron and manganese minerals. Based on 16S rRNA gene analysis, the four species, Fusibacter, Desulfuromonas, Actinobacteria, Pseudomonas sp., from KURT groundwater were identified as anaerobic metal reducers and these microbes precipitated metals outside of cells in common. XRD and EDX analyses showed that Fe(III)-containing mineral, akaganeite (${\beta}$-FeOOH), reduced into Fe(II)/Fe(III)-containing magnetite ($Fe_3O_4$) and Mn(IV)-containing manganese oxide (${\lambda}-MnO_2$) into Mn(II)-containing rhodochrosite ($MnCO_3$) by the microbes. These results implicate that microbial metabolism and respiratory activities under anaerobic condition result in reduction and biomineralization of iron and manganese minerals. Therefore, the microbes cultivated from groundwater in KURT might play a major role to reduce various metals from highly toxic, mobile to less toxic, immobile.

Natural Dyeing of Hanji with Alnus japonica Fruit Extractive (오리나무 열매 추출물을 이용한 한지의 천연염색)

  • Choi, Tae-Ho;Yoo, Seung-Il;Lee, Sang-Hyun;Jeong, Hee-Won;Yang, Eun-Jung
    • Journal of the Korean Wood Science and Technology
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    • v.37 no.4
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    • pp.414-420
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    • 2009
  • We dyed traditional Korean hand-made papers (Hanji) with colorants extracted from fruits of Alnus japonica to investigate the effect of various dyeing factors (mordant, dye concentration and dyeing assistant) on colors, K/S values and light fastness of the dyed Hanji. The dyed hanji had brown color. The K/S value of dyed Hanji was increased by mordanting with alum and copper acetate. $a^*$ and $b^*$ value of dyed Hanji was decreased slightly by mordanting with alum and Iron(II) chloride. The K/S value and $b^*$ of dyed Hanji increased with increasing concentration of dye, but $L^*$ value of dyed Hanji decreased. The K/S value of dyed Hanji was also increased by fixing agent. When Hanji was mordanted with Iron(II) chloride and was not mordanted, use of fixing agent resulted in greater increase of K/S value. Use of fixing agent resulted in poor light fastness. When fixing agent was used, mordanting with copper acetate resulted in smaller color difference than mordanting with alum after aging test.

The effects of lead poisoning on the accumulation of lead, zinc, copper, iron and calcium in tissues of rats (Rat에 있어서 실험적 납중독이 체조직내 납 및 무기질함량에 미치는 영향)

  • Kwon, Oh-deog;Lee, Joo-mook;Lee, Seung-ok;Park, Jin-ho;Lee, Hyun-beom;Jang, Jong-sik;Chae, Joon-seok
    • Korean Journal of Veterinary Research
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    • v.36 no.3
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    • pp.709-718
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    • 1996
  • This experiment was carried out to clarify the effect of lead poisoning on the lead and essential trace elements homeostasis of tissues in rats. Fifty female Wistar rats, 7 weeks old, were divided into four experimental groups(B, C, D, and E) and a control(A). The four experimental groups received diets contaminated artificially with 10 (B group), 100 (C group), 1,000 (D group) and 5,000 (E group) ${\mu}g/g$ of lead as lead acetate, respectively. The control group received normal diet. Rats were necropsied on the 4th or 8th week of experimental periods and heart, liver, spleen, kidney, muscle, lung and hair were taken. The tissues were analysed for lead, copper, zinc, iron and calcium content by atomic absorption spectrophotometry. From these experiments following results ware obtained ; In C group, lead content of the heart, liver, kidney and hair were significantly increased both on the 4th and 8th week of experiment. In D and E group, lead content of all tissues including heart, liver, spleen, kidney, muscle, hair and lung were significantly increased in accordance with the lead contamination both on the 4th and 8th week of experiment. In C group, copper content of tissues were significantly increased in the heart, liver, kidney and lung on the 4th week and all tissues on the 8th week of experimental periods. In D and E group, copper content of the liver were significantly increased both on the 4th and 8th week of experiment. But the copper content of tissues were gradually decreased compared with C group in accordance with the lead contamination. Especially the content in spleen, heart or kidney were significantly decreased compared with the control group. The zinc content of kidney, heart, or spleen were decreased in D and E groups whereas the iron and calcium content showed no significant change.

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Antibiotic Production of Pseudomonas otitidis PS and Mode of Action (Pseudomonas otitidis PS 균주의 항생물질 생산과 작용 기작)

  • Ahn, Kyung-Joon
    • Microbiology and Biotechnology Letters
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    • v.46 no.1
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    • pp.40-44
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    • 2018
  • An isolate capable of inhibiting the growth of gram-positive bacteria was obtained from the soil of Mushim stream, Cheongju. The isolate was identified as Pseudomonas otitidis PS by 16S rRNA gene sequence analysis. P. otitidis PS produced antibiotics as a secondary metabolite when cultured in 1% soybean meal with 0.5% glucose. The maximum yield was about 0.1%. The antibiotic substance of P. otitidis PS extracted using ethyl acetate displayed a minimum inhibitory concentration of $2{\mu}g/ml$ for Staphylococcus aureus KCTC 1261. The antibiotic substance produced an orange halo on chrome azurol S agar due to siderophore activity. Growth inhibition was decreased when the iron was depleted. Since the antibiotic activity was lost upon the addition of the reducing agent ascorbic acid or during anaerobic culture, it was considered that antibiotic of P. otitidis PS strain exerts its bactericidal effect by the generation of reactive oxygen species.

Suppression of Pyrite Oxidation by Formation of Iron Hydroxide and Fe(III)-silicate Complex under Highly Oxidizing Condition

  • Lee, Jin-Soo;Chon, Chul-Min;Kim, Jae-Gon
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.2
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    • pp.297-302
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    • 2011
  • Acid drainage generated by pyrite oxidation has caused the acidification of soil and surface water, the heavy metal contamination and the corrosion of structures in abandoned mine and construction sites. The applicability of Na-acetate (Na-OAc) buffer and/or Na-silicate solution was tested for suppressing pyrite oxidation by reacting pyrite containing rock and treating solution and by analyzing solution chemistry after the reaction. A finely ground Mesozoic andesite containing 10.99% of pyrite and four types of reacting solutions were used in the applicability test: 1) $H_2O_2$, 2) $H_2O_2$ and Na-silicate, 3) $H_2O_2$ and 0.01M Na-OAc buffer at pH 6.0, and 4) $H_2O_2$, Na-silicate and 0.01M Na-OAc buffer at pH 6.0. The pH in the solution after the reaction with the andesite sample and the solutions was decreased with increasing the initial $H_2O_2$ concentration but the concentrations of Fe and $SO_4^{2-}$ were increased 10 - 20 times. However, the pH of the solution after the reaction increased and the concentrations of Fe and $SO_4^{2-}$ decreased in the presence of Na-acetate buffer and with increasing Na-silicate concentration at the same $H_2O_2$ concentration. The solution chemistry indicates that Na-OAc buffer and Na-silicate suppress the oxidation of pyrite due to the formation of Fe-hydroxide and Fe-silicate complex and their coating on the pyrite surface. The effect of Na-OAc buffer and Na-silicate on reduction of pyrite oxidation was also confirmed with the surface examination of pyrite using scanning electron microscopy (SEM). The result of this study implies that the treatment of pyrite containing material with the Na-OAc buffer and Na-silicate solution reduces the generation of acid drainage.

Determination of Aluminum Leached from Cooking Utensils by using Flow Injection Analysis (흐름주입분석법에 의한 주방용기로부터 용출된 알루미늄의 정량)

  • Choi, Yong Wook
    • Journal of Korean Society on Water Environment
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    • v.20 no.3
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    • pp.281-289
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    • 2004
  • Optimal analytical conditions have been established for mixing and reaction coil length, concentrations of ECR, CTAB, and acetate, reaction temperature and pH in the determination of aluminum by using flow injection analysis(FIA). Detection limit and repeatability for this system were $3{\mu}g/L$ and better than 1% of relative standard deviation, respectively. The interference from iron(III) was suppressed up to 6mg/L of iron(III) by $0.1{\mu}M$ ascorbic acid, and the interference from fluoride could be tolerated in absorption of Al/ECR/CTAB derivative by 10mM boric acid at pH 3.5 adjusted with nitric acid. This FIA system was applied to the determination of aluminum leached from cooking utensils by distilled and tap water containing fluoride ranged from 0.5 to 2mg/L by measurement of absorbance for Al/ECR/CTAB at 585nm. The leached aluminum content was increased with increasing concentration of fluoride. The aluminum contents leached from aluminum utensils by tap water were about 9 fold higher than those leached by distilled water, whereas aluminum contents leached by distilled water containing fluoride were about 2 fold higher compared to those leached by distilled water. That represented that other dissolved substances as well as fluoride in tap water contributed to liberation of aluminum from aluminum utensils. A comparison between FIA data and ICP-AES data by correlation and paired t test showed that the FIA system could be accepted as a good alternative method for the determination of aluminum in tap water.

Dyeing of Wool and Nylon Fabrics with Chinese Scholar Tree Extract (괴화 추출물에 의한 모와 나일론직물의 염색성)

  • 배정숙;허만우
    • Journal of the Korean Home Economics Association
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    • v.41 no.2
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    • pp.107-121
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    • 2003
  • This study was discussed the dyeing of wool and nylon fabrics with Chinese Scholar Tree extract. The extracts of Chinese Scholar Tree was prepared in the condition of heating at $95{\pm}5C$, for 1 hour and cooling to 40C. And then the extracts of color matter treate with vacuum concentration at $60{\pm}2^{\circ}C$, 30mmHg and dried with spray dryer. The dyeing of wool and nylon fabric in this experiment was also employed the mordant dyeing method such as pre-mordant, post-mordant and simultaneous mordant method. The mordanting agents used in this study were as followings ; aluminium potassium sulfate, copper(II) acetate monohydrate, chromium potassium sulfate$.$$7H_2O$, Tin(II) chloride dihydrate, iron(II)sulfate $7H_2O$. For an evaluation of the dyeing property of the mordanting agents, the pre-mordant method, the repeat dyeing and the fastness of the light, dry cleaning, washing and rubbing measured respectively. From the results of the dye absorption, the optimum dyeing condition of the wool and nylon fabrics with Chinese Scholar Tree extract is at 80C dyeing temperature for 60 minutes. The optimum concentration of mordanting agent is Al, Cr, Sn 1%, Fe, Cu 2% solution. In general, the fastness property of the dyed wool and nylon fabrics had a comparatively high grade.

PHYSICOCHEMICAL CHARACTERIZATION OF UASB GRANULAR SLUDGE WITH DIFFERENT SIZE DISTRIBUTIONS

  • 안영희;송영진;이유진;박성훈
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.04a
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    • pp.172-181
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    • 2001
  • Upflow anaerobic sludge blanket (UASB) system employs granular sludge to treat various wastewaters including landfill leachate. CH$_4$ production of the granules determines overall performance of a UASB reactor. Sludge granules are developed by self-granulation of microorganisms and dynamic balance between granule growth and decay results in coexistence of granules with different sizes in the reactor. In this study, granules taken from a laboratory-scale UASB reactor were classified into 4 groups based on their diameters and their Physicochemical characteristics we were investigated. Each group was analyzed for settling ability, specific methanogenic activity (SMA), and elemental content. Settling ability was proportional to granule diameter. suggesting effective detainment of larger granules in the reactor. When acetate or glucose was used as a substrate, all groups showed relatively slight difference in SMA. However SMA with a volatile fatty acid mixture showed significant increase with granule diameter, suggesting better establishment of syntrophic relationship in larger granules. Larger granules showed higher value of SMA upon environmental changes (i.e., PH, temperature, or toxicant concentration). Comparative analysis of elemental contents showed that content (dry weight %) of most tested elements (iron, calcium, phosphorus, zinc, nickel. and manganese) deceased with granule diameter, suggesting importance of these elements for initial granulation. Taken together, this study verified experimentally that Physicochemical Properties of granules are related to granule size distributions. Overall results of physicochemical characterization supports that larger.

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Changes in Optical Properties of Crystalline-Si PV Modules after Natural Light Exposure (자연광 노출 후 결정질 실리콘 PV모듈의 광학적 특성 변화)

  • Kong, Ji-Hyun;Ji, Yang-Guen;Kang, Gi-Hwan;Yu, Gwon-Jong;Ahn, Hyung-Keun;Han, Deuk-Young
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.64-64
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    • 2010
  • This paper presents the results of changes of optical properties of front materials in crystalline PV modules. If PV modules on the outdoor, transmittance of front materials is reduced by solar light. That is UV, IR included Solar spectrum will have change the properties of glass. Therefore decrease in transmittance leads to loss of the PV modules output. All the PV modules showed the loss in Isc by 1~5% within few hors. To investigate the changes we are analyzed using spectrophotometer from raw glass to laminated glass.

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