• 보존과학회지
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• 제34권1호
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• pp.39-50
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• 2018

본 연구에서는 전통 제련법을 토대로 사철을 이용해 괴련철 생산을 재현하고 슬래그 및 괴련철을 분석하여 재료학적 특성을 알아보았다. 원료는 고문헌을 토대로 경주사철과 포항사철을 이용했다. WD-XRF 및 XRD 결과 경주사철은 저티탄사철의 Magnetite이며 포항사철은 고티탄사철의 Magnetite와 Ilmenite가 혼합됨을 확인하였다. 슬래그의 XRD 및 미세조직 분석결과 경주사철 슬래그는 Fayalite와 $W{\ddot{u}stite$, 포항사철 슬래그는 Titanomagnetite와 Fayalite가 확인되어 사철의 Ti 함량에 따른 조직의 차이를 확인하였다. 괴련철의 미세조직의 분석결과 경주사철 괴련철은 표면에 공석강에 가까운 탄소함량을 보이는 Pearlite가 우세하며, 내부는 Ferrite와 Pearlite가 혼재된 아공석강이었다. 포항사철 괴련철은 순철에 가까운 Ferrite이었다. 괴련철의 철물화를 위해서는 내부 불순물 제거, 조직을 치밀하게 하는 정련 및 단접이 필요함을 확인하였다. 향후 다양한 조건의 전통 제철 실험을 통해 제철부산물의 성격을 규명하고 제철 유적의 특징을 알아보는데 중요한 데이터로 활용 가능할 것이다.

• 대한기계학회논문집B
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• 제28권7호
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• pp.747-754
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• 2004

Thermo-fluid characteristics in coke oven, sintering machine and blast furnace in iron-making facility are key processes related to the quality and productivity of the pig iron. Solid material in the processes usually forms a bed in a gas flow. For simulation of the processes by mathematical model, the solid beds are idealized to be a continuum and a reacting solid flow in the gas flow. Governing equations in the form of partial differential equations for the solid material can be constructed based on this assumption. Iron ore sintering bed is simulated and limited amount of parametric study have been performed. The results have a good agreement with the experimental results or physical phenomena, which shows the validity and applicability of the model.

• 보존과학회지
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• 제20권
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• pp.67-80
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• 2007

이천 설봉산성은 경기도 이천시 사음동에 소재하는 석성으로 단국대학교 박물관에 의한 발굴조사 결과 4세기 후반의 백제시대로 편년되었다. 출토 유물은 토기, 기와, 자기, 금속유물 등 다양한 종류를 나타내며 특히 백제 토기가 출토된 토광에서 철제유물이 다량으로 수습됨으로써 철기가 백제시대에 제작되었음을 알 수 있다. 이중 철제 낫 6점(벌낫 2점, 밀낫 4점)을 대상으로 시편을 채취하여 미세조직을 분석하고 이를 근거로 유물 제작에 사용된 철 소재, 성형, 제강법, 열처리 등을 살펴보았다. 이를 통해 산성이 속한 4세기 후반 백제의 철기 제작공정 체계를 설정하였다. 그 결과 낫의 용도에 따라 부위별로 다른 처리를 한 것을 알 수 있었다. 벌낫은 날 부위에 담금질을 하여 강도를 요구하는 특별한 용도로 사용되었고 밀낫은 특별한 처리를 실시하지 않아 벼나 풀을 베는데 사용되었던 것으로 추정된다. 사용 소재는 강으로 미리 어떤 제강법으로 강을 만들고 이를 성형하여 철기를 제작하였고 특별한 강도가 요구되는 부위는 열처리를 실시하여 단단하게 하였다. 이상의 결과로 당시 백제 철기의 제작공정은 제강$\rightarrow$성형$\rightarrow$열처리 과정이 적용된 것을 알 수 있다.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2006년도 제32회 KOSCO SYMPOSIUM 논문집
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• pp.181-188
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• 2006

Operation parameters for large scale industrial facility such as iron making plant are carefully selected through elaborate tests and monitoring rather than through a mathematical modeling. One of the recent progresses for better energy utilization in iron ore sintering process is the distribution pattern of fuel inside a macro particle which is formed with fines of iron ore, coke and limestone. Results of model tests which have been used as a basis for the improved operation in the field are introduced and a theoretical modeling study is presented to supplement the experiment-based approach with fundamental arguments of physical modeling, which enables predictive computation beyond the limited region of tests and adjustment. A single fuel particle model along with one-dimensional bed combustion model of solid particles are utilized, and thermal processes of combustion and heat transfer are found to be dominant consideration in the discussions of productivity and energy utilization in the sintering process.

• 보존과학연구
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• 통권27호
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• pp.165-180
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• 2006

The research was conducted to understand type of iron used by those who lived at dwelling site of Yangsoo-ri in between the first century B.C. and the first century A.D. to make steel products and their technique such as steel making process and heat treatment, based on micro structure information obtained through microscopic metallographic structure analysis with SEM-EDS of six steel productsexhumed at the site. Key findings are summarized as below. In the sense that Si-Ca-Al style and less than 0.5% of Ti were found in the non-metallic inclusion, the material used for forged iron ware was magnetite resolved in that. It is, however, unclear whether magnetite was resolved at high temperature or at low temperature. Microscopic structure analysis revealed that forged steel products were made through repeated hot working, the technique of molding by hitting after heating in the process of resolving and molding iron. As a result, the iron used here for the products was not the iron ore which was produced through resolution from discarded cast iron axe, ingot iron. It is probable that to make those steel products, disposed-of cast iron was reused after being molded by decarburizing. Although a few of relics were analyzed for the research, they were of critical importance in defining the process of ironware production from the first century B.C. and the first century A.D. at the Yangsoo-ri region. Judging from the iron from A-19 dwellingsite, it is possible to conclude that the iron was manufactured from cast iron decarburized and yet more research has to be done into relics yetto be exhumed in order to ascertain the finding. All of these findings are believed to play a critical role in further studies to define the steel-manufacturing technique used on the central Korean peninsular in the ancient times.

• 열처리공학회지
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• 제9권1호
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• pp.62-68
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• 1996

In order to establish making process of water atomized iron powder for powder metallurgy, effect of heat treatment condition on change of powder properties and impurities was investigated at each tempeature of $850{\sim}950^{\circ}C$. The results are as follows. Particle morphology of iron powder changed slightly from sphercial type to irregular type and the amount of fine particle decreased more and more with increasing of heat treatment time at each temperature. The flow rate and apparent desity of iron powder also decreased due to particle coalescence in order of $850^{\circ}C$, $950^{\circ}C$, $900^{\circ}C$. Those powder Properties became to decrease particularly at $900^{\circ}C$ in alpha iron region. On the other hand, residual carbon and oxygen contents in iron powder decreased extremely with increasing of heat treatment temperature and time.

• 한국광학회:학술대회논문집
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• 한국광학회 2000년도 제11회 정기총회 및 00년 동계학술발표회 논문집
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• pp.240-241
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• 2000

Sapphire fiber has been used to provide an optical path for the total radiation pyrometry. In measuring the temperature, we use the two-color detector, which consists of a high-performance Silicon detector mounted in a "sandwich" configuration over a Germanium detector. Sapphire fiber can withstand high temperature in the molten steel for two and a half hours. The maximum value of the error is the $\pm$2.5$^{\circ}C$ in the range of 152$0^{\circ}C$~1$600^{\circ}C$. This paper presents the simple scheme for measuring the molten steel temperature in the blast furnace of the iron ＆ steel making process.g process.

• 한국정밀공학회지
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• 제16권5호통권98호
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• pp.98-103
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• 1999

The application field of porous mold is more and more expended. A mixture of alumina and cast iron is used for making porous mold using slip and vacuum casting method in this study. Slip casting is a process that slurry is poured into silicon rubber mold, dried in vacuum oven, debinded and sintered in furnace, In this procedure, slurry is composed of powder, binder, dispersion agent, and water. Vacuum casting is a technique for removing air bubbles existed in the slurry under vacuum condition. Since ceramics has a tendency of over-shrinkage after sintering, cast iron is used to compensate dimensional change. The results shows that sintering temperature has a great effect on characteristics of alumina-cast iron composite sintered parts. Finally ceramic-metal composite sintered mold can be used for aluminum alloy casting of shoe mold using this process.

• 한국기계가공학회지
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• 제9권6호
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• pp.71-77
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• 2010

Although the problems of defects and nonmetallic inclusion in metal fatigue are very complicated, it is particularly important to view these problems from the perspective that defects and inclusions are virtually equivalent to small cracks. This concept will help one to understand various fatigue phenomena caused by Ductile Cast Iron. For different ferrite-pearlite matrix structure, containing more than 90% spheroidal ratio of graphite, GCD 45-3, GCD 50, GCD 60 series and 70%, 80%, 90% spheroidal ratio of graphite, GCD 40, GCD 45-1, GCD 45-2 series, this paper has carried out image analyzer, estimated maximum and mean size of graphite, investigated correlation. It was concluded as follows. (1) A good quality of Ductile cast iron using in this experiment, the graphite was separated well. The effect of the interaction by graphite was verified by microscopic observation and by fracture mechanics investigation in surface, interior of the specimen. (2)${\sqrt{area}}_{max}$ of graphite can be used to predict fatigue limit of Ductile Cast Iron. The Statistical distribution of extreme values of ${\sqrt{area}}$ may be used as a guide line for the control of inclusion size in the steel making processes.

• 보존과학회지
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• 제34권5호
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• pp.433-442
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• 2018

본 연구에서는 전통 제철법을 이용해 사철강괴와 사철강괴에 현대강을 접합한 응용강괴 2개를 생산한 후 철제 칼 3자루를 제작하여 금속학적 특성을 비교하였다. 금속현미경과 SEM-EDS 분석결과, Fe-C 합금의 아공석강이었으며, 미세한 Ferrite와 Pearlite가 전체적으로 관찰되며, 칼날에 Martensite가 관찰되었다. 비커스 경도 분석 결과, 사철강 칼(K1)이 533.38 HV, 사철-니켈탄소강 칼(K3)은 514.8 HV, 사철-탄소강 칼(K2)가 477.02 HV로 측정되었다. 마모에 의한 질량감소율은 K1이 0.058%, K3는 0.060%, K2가 0.144%로 측정되었다. 시료의 표면무늬에 대한 EPMA 분석 결과, 표면무늬는 C의 함량의 차이 혹은 화학조성에 의해 무늬가 드러난다는 것을 확인하였다. 향후 칼날의 경도 값을 올려 내마모성을 증가시키기 위해서는 열처리 공정에 대한 추가적인 연구가 필요하며, 전통 제철법으로 제작한 강괴는 니켈 탄소강과 접합하여 사용한다면 우수한 품질의 철제품을 제작할 수 있을 것이다.