• Title/Summary/Keyword: Ion oxide

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Phase Formation and Oxygen Ion Conduction of $La(Ba)Ga(Mg)O_3_\delta$ Perovskite Oxide System ($La(Ba)Ga(Mg)O_3_\delta$계 Perovskite 산화물의 생성상 및 산소이온전도)

  • Lee, Ki-Tae;Kim, Shin;Lee, Hong-Lim
    • Journal of the Korean Ceramic Society
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    • v.36 no.10
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    • pp.1056-1061
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    • 1999
  • Phase formation and oxygen ion conduction of La(Ba)Ga(Mg)O3-$\delta$ system was studied, BaLaGa3O7 and BaLaGaO4 formed as a secondary phase above the solubility limit of Ba2+ in La3+ sites. The oxygen ionic conductivity of La(Ba)Ga(Mg)O3-$\delta$ was 0.1 S/cm 80$0^{\circ}C$ The activation energy of the oxygen ion conduction was dependent on temperature. This value was higher at low temperature than at high temperature.

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BIOCOMPATIBISITY OF ION BEAM PROCESSED FILMS DEPOSITED ON SURGICAL TI-6AI-4V

  • Lee, I-S;Song and I-j Yu
    • Journal of the Korean Vacuum Society
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    • v.6 no.S1
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    • pp.16-22
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    • 1997
  • ion beam processing of materials for medical application has gained increasing interest in the last decade and the implantation of nitrogen into TI-6AI-4V to improve corrosive-wear performance is currently used for processing of total hip and knee joints. Oxides and nitrides of Ti, Zr, Al, Cr were deposited on TI-6AI-4V substrates by DC magnetron sputtering dual ion beam sputtering and ion beam assisted deposition. The cytotoxicity of these films were investigated by MTT method and showed comparable to untreated TI-6AI-4V Plasm-sprayed hydroxyapatite(HAp) coatings showed excellent cytotoxicity regardless of heat treatment. intermediate layer coatings of nitrides and oxides increased the bond strength of HAp to substrate by intrdducing chemical bond at interface. Heat treatment of HAp coatings also improved the chemical bond at interfaces and increased the bond strength of untreated TI-6AI-4V to 16.4 kg/$\textrm{cm}^2$ but still lower than 33.1 kg./$\textrm{cm}^2$ of ir oxide as a imtermediate layer caoting.

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The characteristics of MgO films prepared by Ion Plating and its applications to AC PDP (Ion Plating법에 의해 제작된 MgO 박막의 특성 및 AC PDP에의 응용)

  • Jeong, Dong-Cheol;Jeong, Heui-Seob;Shin, Buhm-Jae;Whang, Ki-Woong
    • Proceedings of the KIEE Conference
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    • 1993.11a
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    • pp.255-257
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    • 1993
  • MgO(Magnesium Oxide) film was deposited by the Ion Plating method and the characteristics of the MgO films were analyzed by XRD and SEM. The MgO films prepared by Ion Plating were used in AC Plasma Display Panel and breakdown voltage, minimum sustain voltage and memory margin of fabricated panel were investigated.

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Improvement of the Carbon Nanotube Tip by Focused Ion Beam and it Performance Evaluation (탄소나노튜브 팁의 집속이온빔에 의한 개선 및 성능 평가)

  • Han, Chang-Soo;Shin, Young-Hyun;Yoon, Yu-Hwan;Lee, Eung-Sug
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.31 no.1 s.256
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    • pp.139-144
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    • 2007
  • This paper presents development of carbon nanotube (CNT) tip modified by focused ion beam (FIB) and experimental results in non-contact mode of atomic force microscopy (AFM) using fabricated tip. We used an electric field which causes dielectrophoresis, to align and deposit CNTs on a conventional silicon tip. The morphology of the fabricated CNT tip was then modified into a desired shape using focused ion beam. We measured anodic aluminum oxide sample and trench structure to estimate the performance of FIB-modified tip and compared with those of conventional Si tip. We demonstrate that FIB modified tip in non contact mode had superior characteristics than conventional tip in the respects of wear, image resolution and sidewall measurement.

ITO deposition by Ion beam sputtering

  • 한영건;조준식;최성창;고석근;김동환
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.97-97
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    • 1999
  • 이온빔 스퍼터링을 이용해 유리 기판위에 Tin-doped Indium Oxide (ITO) 투명 전도성 박막을 성장시켜 이온빔의 전류밀도와 에너지 그리고 기판 온도에 따르는 ITO박막의 구조적, 전기적, 광학적 특성을 분석하였다. 또한, 반응성 가스인 산소의 아르곤에 대한 유량비를 변화시켜 이온 빔 스퍼터링시에 산소 분압이 ITO 박막의 물성에 미치는 영향을 조사하였다. 이온 소스는 직경 5-cm인 cold hollow cathode ion gun을 이용하였으며 base pressure는 2$\times$10-5 Torr이며 가스 주입 후의 3$\times$10-4 Torr이하의 working pressure에서 박막을 증착하였다. 이온 전류 밀도는 5$\mu$A~15$\mu$A까지 변화시켰으며 이온 에너지는 0.7keV~1.3keV까지 변화시켰다. 반응성 가스는 아르곤에 대하여 Zmrp 0, 50, 100%까지 변화시켰으며 기판 온도는 50, 100, 150, 20$0^{\circ}C$로 변화시켰다. ITO 박막의 결정구조는 Ar 이온만으로 스퍼터링한 경우에는 XRD 상에서 [400] 방향으로 우선성장하였으며 산소분압이 증가함에 따라 [222] 방향으로 우선 성장함을 확인 할 수 있었다. 전기적 특성은 Ar ion에 Oxygen ion의 비율이 약간만 증가하여도 비저항의 큰 증가를 보여 주었다. 이는 산소 vacancy의 감소에 의한 것으로 여겨진다.

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Trimeric Chromium Oxyformate Route to Chromia-Pillared Clay

  • Yun, Ju Byeong;Hwang, Seong Ho;Choe, Jin Ho
    • Bulletin of the Korean Chemical Society
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    • v.21 no.10
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    • pp.1049-1051
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    • 2000
  • A chromia-pillared clay has been prepared by ion exchange type intercalation reaction between the sodium ion in montmorillonite and the trimeric chromium oxyformate (TCF) ion, and by subsequent heat-treatment. The structural and thermal properties have been systematically studied by thermal analysis, powder XRD, IR spec-troscopy, and XAS. The gallery height of~6.8 $\AA$ upon intercalation of the TCF ion suggests that the $Cr_3O$ plane is parallel to the aluminosilicate layers. Even though the basal spacing of TCF intercalated clay decreases slightly upon heating, the layer structure was retained up to $550^{\circ}C$ as confirmed by XRD and TG/DTA. Ac-cording to the EXAFS spectroscopic analysis, it is identified that the (Cr-Cr) distance of 3.28 $\AA$ between vertex-linked CrO6 octahedra in TCF splits into 2.64 $\AA$, 2.98 $\AA$, and 3.77 $\AA$ due to the face-, edge-, and corner-shared CrO6 octahedra after heating at $400^{\circ}C$, implying that a nano-sized chromium oxide phase was stabilized within the interlayer space of clay.

Structure and Electric Properties of $(Ba_{1-x}Pb_x)TiO_3$ Ceramics ($(Ba_{1-x}Pb_x)TiO_3$ 세라믹의 구조와 전기적 특성)

  • Kim, Si-Joong;Kim, Keon;Park, Hyu-Bum;Ahn, Byeung-Joon
    • Journal of the Korean Ceramic Society
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    • v.29 no.4
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    • pp.259-264
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    • 1992
  • The crystal structures and the bonding characteristics in $(Ba_xPb_{1-x})TiO_3$ have been investigated by X-ray diffraction analysis and infrared spectrophotometry. As $Ba^{2+}$ ion in $BaTiO_3$ were substituted by $Pb^{2+}$ ion, the structures were changed to orthorhombic from tetragonal, and also the covalent character in Ti-O bond increased, and then the dielectric constants decreased gradually. In the mixed oxide containing $Pb^{2+}$ ion more than 50%, the change-transfer energy of titanium ion increased.

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A New Method for the Oxide Lattice Energy Computation (산화물의 격자에너지의 새로운 계산방법)

  • 신형섭;권순주
    • Journal of the Korean Ceramic Society
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    • v.31 no.4
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    • pp.420-426
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    • 1994
  • A new method is proposed for the oxide lattice energy calculation. It is consisted of (1) setting a central and a computation domains in a real lattice, (2) calculation of inter-ionic potential producted by the associated portion of each ion to the relative domain, and (3) summing up the potential energies. Even with a slight expansion of the domain, the lattice energy converges to the published data. The method is superior than any other reported due to the simple and clear concept and the reduced computing.

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