• Korean Journal of Fisheries and Aquatic Sciences
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• v.29 no.6
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• pp.843-848
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• 1996

As the first step of studies related to production of chitooligosaccharides by physical methods, chitosan solution were sonicated with 20 kHz and various treatment effects were examined to present fundamental data of sonicated chitosan solution. Intrinsic viscosity of chitosan solution sharply decreased from 3.76 dl/g to 2.90 dl/g until 5 minutes of sonication and then slowly decreased. With low volume of chitosan solution, sonication was very effective and temperature of chitosan solution slightly affected the efficiency of sonication. In case of changing the solvent, no significant differences were observed on the effect of sonication, however, acetate buffer had highest sonication effect among various solvents. The sonication effect was increased as the increasement of the value of pH, on the contrary, ionic strength and type of counterions showed no effect on sonication. With these results, we assumed that optimal sonication treatment would be as follows, solution volume was $10\~20\;ml$, temperature range was $20\~30^{\circ}C$, pH value of solution was 4.5 and type of solvent was acetate buffer.

• Applied Biological Chemistry
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• v.35 no.1
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• pp.10-13
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• 1992

Starches from three varieties of naked barley were fractionated into two populations according to the granule sizes and physicochemical properties were compared. Number of small granules was comprised in 62% of Saessalbori and 75% of Nulssalbori and Mudungssalbori. The proximate composition and water binding capacity were lower in large granules, the large granules showed higher values in blue value and intrinsic viscosity than those of small ones. There no differences in swelling power and X-ray diffraction pattern between small and large granules. The viscosities of alkali-gelatinized starch were higher on large granules, but the temperature of birefringennce loss was not different.

• Korean Journal of Food Science and Technology
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• v.25 no.3
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• pp.264-269
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• 1993

Molecular structural properties of legume starches were investigated. In intrinsic viscosity and degree of Polymerization of amylose and amylopectins, cow pea and mung bean were high, but kidney bean was low. Low molecular weight fractions for kidney bean starch were much eluted by gel chromatography. In the elution profiles of their amylose by Sepharose 2B-CL, molecular weight of kidney bean amylose was smaller than that of other amylose Molecular weights of cow pea and mung bean amyloses were large, but that of kidney bean amylose was small and red bean amylose was medium. The elution profiles by Sephadex G-50 after debranching amylopectins with pullulanase showed similar patterns.

• Journal of the Korean Applied Science and Technology
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• v.6 no.1
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• pp.1-7
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• 1989

To developed new process for obtaining maximum molecular weight of anionic acrylamide and acrylic acid copolymer by inverse emulsion polymerization. Concentration of initiator, reducing agent, surfactant and mole ratio of acrylamide-acrylic acid were studied for the process. Semi-batch processes with method of redox, control of reaction temperature, feeding method of monomer and reaction time, was suitable for maximum molecular weight of P(AMAC) from this process obtained $3.09\;{\time}\;10^6({\bar{M}}n.)$ and $4.41\;{\time}\;10^6({\bar{M}}w.)$ in molecular weight measured by the intrinsic viscosity method. inverse emulsion polymerization mechanism of P(AMAC) does not followed the Smith-Ewart and Medvedev theory, but selected for concentration of initiator, reducing agent, surfactant, water solubility of monomer.

• Food Science and Preservation
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• v.5 no.4
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• pp.368-373
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• 1998

The effects of steeping and washing were investigated in the physicochemical properties of acorn flour. The contents of crude protein, ash and total phenol of acm flour were gradually decreased with the steeping days and washing times. However, the contents of crude fat and dietary fiber were little different. The more steeping days and/or washing times became large, the more the color of acorn flour became light. Swelling power was enhanced by increasing of steeping days and washing times but solubility was some decreased Water binding capacity was decreased and intrinsic viscosity was increased with the increased steeping days and washing times. Washing times were more influential than steeping days to those changes.

• Macromolecular Research
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• v.12 no.3
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• pp.303-310
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• 2004

We have prepared an aqueous dispersion of poly(aniline-dodecyl benzene sulfonic acid complex) (PANI-DC) that has an intrinsic viscosity (〔η〕) near 1.3 dL/g using aniline as a monomer, dodecyl benzene sulfonic acid(DBSA) as a dopant/emulsifier, and ammonium peroxodisulfate(APS) as an oxidant. We found that the electrical conductivity of a PANI-DC pellet was 0.7 S/cm. A waterborne-polyurethane (WBPU) dispersion, obtained from isophorone diisocyanate/polytetramethylene oxide glycol/dimethylol propionic acid/ethylene diamine/triethylene amine, was used as a matrix polymer. We prepared blend films of WBPU/PANI-DC with variable weight ratios (from 99/1 to 66/34) by solution blending/casting and investigated the effects that the PANI-DC content has on the mechanical and dynamic mechanical properties, hardness, electrical conductivity, and antistaticity of these films. The tensile strength, percentage of elongation, and hardness of WBPU/PANI-DC blend films all decreased markedly upon increasing the PANI-DC content. The antistatic half-life time ($\tau$$\sub$$\frac{1}{2}$/) of pure WBPU film was about 110 s, but we found that those of WBPU/ultrasound-treated PANI-DC blend films decreased exponentially from 1.2 s to 0.1 s to almost 0 s upon increasing the PANI-DC content from 1 wt% to 15 wt% to > 15 wt%, respectively.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.11a
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• pp.284-287
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• 2001

Multi-pole anisotropic Sr-fertile sintered magnets has been studied by powder injection molding under applied magnetic field. The orientation of anisotropic Sr-ferrite powders higher than 80% during injection molding is achieved at the following conditions; apparent viscosity lower then 2500 poise in 1000 sec$\^$-1/ shear rate and applied magnetic field higher then 4 kOe. For the high fluidity and strength of injection molded compact, and the effective binder removal without defects during solvent extraction and thermal debinding, the optimum multi-binder composition is paraffin wax(PW)/carnauba wax(CW)/HDPE = 50/25/25 wt%. The rate of binder removal is proportional to the mean particle size of Sr-ferrite powders whereas it is inversely proportional to the content of Sr-ferrite powders and the sample thickness. The high magnetic properties of Sr-ferrite sintered magnets are; 3.8 kG of remanent flux density, 3.4 kOe of intrinsic coercivity, and 1.2 kG of surface flux density (1-mm-thick) in the direction of applied magnetic field.

• Applied Biological Chemistry
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• v.35 no.5
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• pp.389-394
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• 1992

Effect of dry-heat treatment $(130{\sim}220^{\circ}C)$ on properties of corn starch was investigated. No significant changes of surface color and swelling power were observed. Blue value, water-binding capacity, solubility and degree of hydrolysis by acid or glucoamylase were increased; however, intrinsic viscosity and crystallinity were decreased as heating temperature was raised. Noticeable changes occurred between $170{\sim}190^{\circ}C$.

• International Journal of Reliability and Applications
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• v.17 no.2
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• pp.137-147
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• 2016

The engine mount of a car subjected to a pre-load related to the weight of the engine, and acts to insulate the vibration coming from the engine by moving on large or small displacement depending on the driving condition of the car. The vibration insulation of the engine mount is an effect obtained by dissipating the mechanical energy into heat by the viscosity characteristic of the rubber and the microscopic behavior of the additive carbon black. Therefore, dynamic stiffness from the intrinsic properties of rubber filled with carbon black at the design stage is an important design consideration. In this paper, we introduced a hyper-elastic, visco-elastic and elasto-plastic model to predict the dynamic characteristics of rubber, and developed a fitting program to determine the material model parameters using MATLAB. The dynamic characteristics analysis of the rubber insulator of the ACTIVE MOUNT was carried out by using MSC.MARC nonlinear structural analysis software, which provides the dynamic characteristics material model. The analysis results were compared with the dynamic characteristics test results of the rubber insulator, which is one of the active mount components, and the analysis results were confirmed to be valid.

• Journal of the Korean Magnetics Society
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• v.5 no.5
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• pp.740-744
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• 1995

For the fabrication of a multi-pole anisotropic Sr-ferrite magnet by powder injection molding, it is important to control effectively the alignment of magnetic powders during the injection molding process. The effect of the fluidity of powder/binder mixture on the powder alignment was studied with changing the particle sizes and the volume fraction of Sr-ferrite magnetic powders. The critical volume fraction of Sr-ferrite powders increases from 58 vol.% to 64 vol.% as the mean powder size increases from $0.8\;\mu\textrm{m}$ to $1.2\;\mu\textrm{m}$. A Sr-ferrite powder alignment greater than 80 % is achieved at the conditions of an apparent viscosity lower than 1000 poise at $1600\;sec^{-1}$ shear rate, an applied magnetic field higher than 4 kOe, and a powder volume fraction 8 vol.% lower than the critical fraction. The powder alignment obtained during the injection molding process is not much affected by the subsequent processes of debinding and sintering, showing the magnetic properties of 3.8 kG of remanent flux density and 3.37 kOe of intrinsic coercivity.